• Journal of the Korean Ceramic Society
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• v.55 no.1
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• pp.50-54
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• 2018

This study investigated the long-term durability of catalyst(Pd or Fe)-infiltrated solid oxide cells for $CO_2$/steam co-electrolysis. Fuel-electrode supported solid oxide cells with dimensions of $5{\times}5cm^2$ were fabricated, and palladium or iron was subsequently introduced via wet infiltration (as a form of PdO or FeO solution). The metallic catalysts were employed in the fuel-electrode to promote $CO_2$ reduction via reverse water gas shift reactions. The metal-precursor particles were well-dispersed on the fuel-electrode substrate, which formed a bimetallic alloy with Ni embedded on the substrate during high-temperature reduction processes. These planar cells were tested using a mixture of $H_2O$ and $CO_2$ to measure the electrochemical and gas-production stabilities during 350 h of co-electrolysis operations. The results confirmed that compared to the Fe-infiltrated cell, the Pd-infiltrated cell had higher stabilities for both electrochemical reactions and gas-production given its resistance to carbon deposition.

• The Bulletin of The Korean Astronomical Society
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• v.41 no.1
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• pp.50.2-50.2
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• 2016

Continuous accretion of metal-poor gas can explain the discrepancy between the number of observed G-dwarfs and the number predicted by the "simple model" of galactic evolution. The maximum accretion rate estimated based upon approaching high velocity clouds (HVCs) can be up to ${\sim}0.4M_{\odot}{\cdot}yr^{-1}$ which is comparable with the accretion rate required by many chemical evolution models that is at least ${\sim}0.45M_{\odot}{\cdot}yr^{-1}$. However, it is not clear to what extent the exchange of gas between the disk and the cloud can occur when an HVC collides with the galactic disk. Therefore, we examined a series of HVC-Disk collision simulations using the FLASH 2.5 hydrodynamics simulation code. The outcomes of our simulations show that an HVC will more likely take away substances from the galactic disk rather than adding new material to the disk. We define this as an HVC having a "negative fuel rate". Further results in our study also indicate that the process and amount of fuel rate change can have various forms depending on the density, radius and velocity of an approaching HVC. The simulations in our study covers HVCs with a neutral hydrogen volume density from $1.0{\times}10^{-2}cm^{-3}$ to $41.0cm^{-3}$, radius of 200 pc to 1000 pc and velocity in the range between $40km{\cdot}s^{-1}$ and $100km{\cdot}s^{-1}$.

• Proceedings of the Materials Research Society of Korea Conference
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• 2009.05a
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• pp.55.2-55.2
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• 2009

A polymer electrolyte membrane (PEM) fuel cell has been getting large interest as a typical issue in useful applications. The PEMFC is composed of a membrane, catalyst and the bipolar plate. SnOx:F films on SUS316 stainless steel were prepared as a function of substrate with using electron cyclotron resonance-metal organic chemical vapor deposition (ECR-MOCVD) in order to achieve the corrosion-resistant and low contact resistance bipolar plates for PEM fuel cells. The SnOx:F films coated on SUS316 substrate at surface plasma treatment for excellent stability, before/after heat treatment for good crystalline structure and microwave power for were characterized by X-ray diffraction (XRD), auger electron microscopy (AES) and field emission-scanning electron microscopy (FE-SEM). The SnOx:F film coated on SUS316 substrate with various process parameters were able to observe optimum interfacial contact resistance (ICR) and corrosion resistance. It can be concluded that fluorine-doping content plays an important function in electrical property and characteristic of corrosion-protective film.

• Journal of the Korean Society of Mechanical Technology
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• v.13 no.2
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• pp.137-143
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• 2011

Fuel Test Loop(FTL) is a facility which could conduct a fuel irradiation test at HANARO(High-flux Advanced Neutron Application Reactor). FTL simulates commercial NPP's operating conditions such as the pressure, temperature and neutron flux levels to conduct the irradiation and thermo-hydraulic tests. The In-Pile Test Section(IPS) installed in HANARO FTL is designed as a pressure vessel design conditions of $350^{\circ}C$, 17.5MPa. The instrumentation MI-cables for thermocouples, SPND and LVDT are passed through the sealing plug, which is in the pressure boundary region and is a part of instrumentation feedthrough of MI-cable. In this study, the brazing method and performance test results are introduced to the sealing plug with BNi-2 filler metal, which is selected with consideration of the compatibility for the coolant. The performance was verified through the insulation resistance test, hydrostatic test, and helium leak test.

• Nuclear Engineering and Technology
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• v.30 no.2
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• pp.99-111
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• 1998

Chemical composition of the insoluble residue in a simulated spent PWR fuel(SIMRJEL) were studied. SIMFUELS were prepared by adding calculated amount of FP(fission product) elements with a burnup of 3.6% FIMA(fission per initial metal atom) to uranium in nitrate solution, evaporating the mixed solution to dryness, calcining at 90$0^{\circ}C$ in a stream of 4% H$_2$ + 96% He, and heating the pellet at 140$0^{\circ}C$ under high and low oxygen potentials. Insoluble residue was obtained from the dissolution of the SIMFUEL with HNO$_3$(1 : 1). The chemical composition of the SIMFUELs and the insoluble residues was determined by EPMA(electron probe microanalysis), XPS(X-ray photoelectron spectroscopy) and by XRD (X-ray diffraction) measurements. All of the insoluble residues suspended and precipitated were composed mainly of Mo, Ru with a small amount of Zr, Rh, Pd and Cd. The amount of insoluble residue(<1 wt.%) and a Mo/Ru ratio decreased with increasing oxygen potential. Formation of the zirconium molybdate precipitate, ZrMo$_2$O$_{7}$(OH)$_2$($H_2O$)$_2$, was observed in the residues. The possible role of Mo on the phase formation was discussed in regard to oxygen potential.l.

• Transactions of the Korean Society of Automotive Engineers
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• v.14 no.4
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• pp.157-163
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• 2006

A modified ratio control algorithm is proposed for the improvement of the fuel economy for a metal belt CVT. In the modified ratio control algorithm, the CVT ratio is controlled to operate the engine on the optimal operation region which provides the best efficiency from the view point of the overall efficiency of the engine-CVT system. In order to construct the modified ratio map, the CVT system loss model is used by assuming that the all the loss is attributed to the torque loss. It is found from the simulation results that the fuel economy by the modified ratio control algorithm is improved by 5.5 percents compared with the existing ratio control.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.560-563
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• 2008

A modified polyol process is developed to enhance Pt loading during the preparation of Pt/C catalysts. With the help of the zeta potential, the effect of pH on the electrostatic forces between the support and the Pt colloid is investigated. It is shown experimentally that the surface charge on the carbon support becomes more electropositive when the solution pH is changed from alkaline to acidic. However, this change does not affect the electronegative surface charge of Pt colloids already attained and stabilized by glycolate anions. This new behavior caused by the change in the solution pH accounts for the enhanced yield of the process and does not affect the Pt particle size. All our experimental results reveal that this simple modification is a cost effective method for the synthesis of highly Pt loaded Pt/C catalysts for fuel cells.

• Proceedings of the KSME Conference
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• 2007.05a
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• pp.23-27
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• 2007

To store hydrogen with high pressure is one of key technologies in developing FCVs (fuel cell vehicles). Especially, metal lined composite structure, which is called Type 3, is expected to effectively stand highly pressurized hydrogen since it has high specific strength and stiffness as well as excellent storage ability. However, it has many difficulties to design Type 3 vessels because of their complex geometry, fabrication process variables, etc. In this study, therefore, optimal design of Type 3 vessels was performed in consideration of such actual circumstances using genetic algorithm. Additionally, detailed finite element analysis was followed for the optimal result.

• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.133-136
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• 2007

In this work, 3-dimensional, non-isothermal numerical simulation was performed to analyse the effects of contact resistance and electric conductivity of GDL on the fuel cell performance. For numerical simulation contact resistance of Carbon and Stainless steel was measured. The simulation results reveal that 10 times change of electric conductivity leads only 6.5% decrease of PEMFC performance. But stainless steel which has high contact resistance decrease fuel cell performance over 25% at a high current density region than carbon. This results show that suitable Surface treatment technology is needed for metal bipolar plate, especially stainless steel.

• New & Renewable Energy
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• v.9 no.1
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• pp.51-59
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• 2013

Tantalum carbide crystallites which is to be used for $H_2$ fuel cell has been synthesized via a temperature-programmed reduction of $Ta_2O_5$ with pure $CH_4$. The resultant Ta carbide crystallites prepared using two different heating rates and space velocity exhibit the different surface areas. The $O_2$ uptake has a linear relation with surface area, corresponding to an oxygen capacity of $1.36{\times}10^{13}\;O\;cm^{-2}$. Tantalum carbide crystallites are very active for hydrogen production form ammonia decomposition reaction. Tantalum carbides are as much as two orders of magnitude more active than Pt/C catalyst (Engelhard). The highest activity has been observed at a ratio of $C_1/Ta^{{\delta}+}=0.85$, suggesting the presence of electron transfer between metals and carbon in metal carbides.