• The Transactions of the Korean Institute of Electrical Engineers P
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• v.61 no.3
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• pp.134-139
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• 2012

The power characteristics of the Mg-Air fuel cell were investigated with regard to variation of load conditions. The types of load current using for the Mg-Air fuel cell with 10% NaCl electrolyte were step type, ramp type and pulse type. It was found that transient phenomena occurred in the step current load, which is due to activate of the oxidation-reduction reaction process. And the transient time increase with the load current increase. In the load current of ramp type, the slop of voltage drop increased with current load slop ${\alpha}$ increase. The load voltage and power decreased according to the pulse period of load current decrease were attributed to the metal sludges.

• Nuclear Engineering and Technology
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• v.29 no.2
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• pp.99-109
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• 1997

A dynamic model for hydrogen generation by Fuel-Coolant Interactions(FCI) is developed with separate models for each FCI stage, coarse mixing and stratification. The model includes the physical concept of FCI, semi-empirical heat and mass transfer correlation and the concentration diffusion equation with the general non-zero boundary condition. The calculated amount of hydrogen, which is mainly generated in stratification, is compared with the FITS experiments. The model developed in this study shows a good agreement within a range of 10 % fuel oxidation rate and predicts the controlled mechanism of the chemical reaction very well. And this model predicts more accurately than the previous works. It is shown from the sensitivity study that the higher initial temperature of fuel particle is, the larger the reaction rate is. Up to 2700 K of temperature of the particle, the reaction rate increases rapid, which can lead to metal ignition.

• Proceedings of the KSME Conference
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• 2000.04a
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• pp.731-736
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• 2000

An optimal design method is adopted for a spacer grid in nuclear power plant. It is made of punched sheet metal process, functioning as springs and dimples supporting fuel rods. For stress analysis of the assembled fuel rod support, a typical cell out of the repeated pattern in the assembly is modeled using 4-node shell elements. A commercial code, ABAQUS, is used for detailed analysis of contacting phenomena with friction. For the optimization, design varibles are taken from geometric parameters representing the shape of the bent leaf spring part and mating contact region with fuel rod. Objective function is considered in relation to mechanical functions and durability. Maximum yon Mises stress is considered in relation to constrained contact stress.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2004.10a
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• pp.311-314
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• 2004

The housing of the fuel injector supports the rod, the niddle valve and the solenoid. Based on the procedure of process design, in this paper, the forming operation is designed by the rigid-plastic finite element method. The metal flow during the forming of the fuel injector housing is axisymmetric until the final forming process. The response surface method has been performed to reduce the under-fill and the maximum effective strain. From the results of RSM, the second order regression model of equation is calculated by the least square method and used to determine the optimal values of design variables by simultaneously considering the responses. It is noted that upper under-fill is affected by the design variables of the $2^{nd}$ forming process and lower under-fill is affected by the design variables of the 1st forming process.

• Nuclear Engineering and Technology
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• v.34 no.2
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• pp.176-185
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• 2002

A 4-bundle shift refuelling method of CANDU6 F/H (Fuel Handling) System is analyzed to assess the operational flexibility and capacity of F/H system. The current 8-bundle shift refuelling scheme requires to refuel eight fuel bundles from a single fuel channel, and to refuel 14 fuel channels in a week on average assuming that the reactor is in a steady state. The analysis showed that the 4-bundle shift refuelling method increases F/M (Fuelling Machine) duty cycle and operator load. However, the fuellin’g method change from the 8- to 4-bundle shift refuelling ill not require additional team of operators. A marginal increase in the maintenance cost may be resulted in by the change of fuelling method and the increase of fatigue usage factors requires some components to be replaced during the FM lifetime.

• Journal of the Korea Institute of Military Science and Technology
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• v.24 no.4
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• pp.418-425
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• 2021

Submarines are weapons systems that have been proven to be useful in battle since World War I and have continued to improve the efficiency of propulsion systems in order to be used efficiently on the battlefield. In particular, countries that unable to utilize nuclear propulsion systems make efforts to increase the efficiency of Air Independent Propulsion systems, and typical examples are fuel cells, Stirling engines and MESMA. It is also expected that the development of new propulsion systems such as hydrogen-reformer fuel cells, metal-air fuel cell and direct combustion propulsion systems will continue, so the characteristics of these will be examined and the performance based on the published data be checked in this thesis.

• Applied Chemistry
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• v.15 no.2
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• pp.137-140
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• 2011

Excellent active and stable platinum catalyst fuel cells currently being used as a catalyst. However, because of the high price of platinum catalyst, such as non-precious catalyst has been studied by a variety of fuel cell catalysts. In this study, Co/ PANi//CNT composite catalyst after synthesis through various heating process was to increase the activity of the catalyst. At 700℃ showed the best catalytic activity, using a composite catalyst was to be used as cathode electrodes in fuel cell.

• Korean Chemical Engineering Research
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• v.45 no.2
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• pp.143-148
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• 2007

In hydrogen production for fuel cell by reforming city-gas, sulfur compounds, odorant in city-gas, are detrimental to reforming catalyst and fuel cell electrodes. We prepared metal salt impregnated ${\beta}-zeolite(BEA)$ to remove sulfur compound in city-gas by adsorption. The sulfur breakthrough adsorption capacity was changed depending on the concentration and species of metal salt. $AgNO_3$ impregnated BEA showed the highest sulfur breakthrough capacity among adsorbents used in this experiment(41.1 mg/g). But metal salt impregnated BEA such as $Ni(NO_3)_2/BEA$, $Fe(NO_3_)_3/BEA$, $Co(NO_3)_2/BEA$ showed a certain amount of sulfur adsorption capacity comparable to $AgNO_3/BEA$. Adsorption temperature effect, desorption study, and x-ray photoelectron spectroscopy analysis revealed that the dominant interaction between metal impregnated adsorbent and sulfur compounds was not chemisorption but physisorption.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.31 no.5
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• pp.345-350
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• 2018

Nanomaterials have considerable potential to solve several key challenges in various electrochemical devices, such as fuel cells. However, the use of nanoparticles in high-temperature devices like solid-oxide fuel cells (SOFCs) is considered problematic because the nanostructured surface typically prepared by deposition techniques may easily coarsen and thus deactivate, especially when used in high-temperature redox conditions. Herein we report the synthesis of a self-regenerated Pd metal nanoparticle on the perovskite oxide anode surface for SOFCs that exhibit self-recovery from their degradation in redox cycle and $CH_4$ fuel running. Using Pd-doped perovskite, $La(Sr)Fe(Mn,Pd)O_3$, as an anode, fairly high maximum power densities of 0.5 and $0.2cm^{-2}$ were achieved at 1,073 K in $H_2$ and $CH_4$ respectively, despite using thick electrolyte support-type cell. Long-term stability was also examined in $CH_4$ and the redox cycle, when the anode is exposed to air. The cell with Pd-doped perovskite anode had high tolerance against re-oxidation and recovered the behavior of anodic performance from catalytic degradation. This recovery of power density can be explained by the surface segregation of Pd nanoparticles, which are self-recovered via re-oxidation and reduction. In addition, self-recovery of the anode by oxidation treatment was confirmed by X-ray diffraction (XRD) and scanning electron microscopy (SEM).

• Korean Journal of Materials Research
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• v.12 no.2
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• pp.140-145
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• 2002

This study was conducted to investigate the brazing characteristics between Zircaloy-4 nuclear fuel cladding tubes and bearing pads with filler metals of amorphous $Zr_{1-x}Be_x$(0.3$\leq$x$\leq$0.5) binary alloy, in which they were produced in the ribbon form by the melt-spinning metod. The crystallization behavior, stability, hardness and micro-structure of brazed zone were examined by X-ray diffraction, differential scanning calorimetry, micro-Vickers hardness test, optical microscopy, and transmission electron microscopy. $Zr_{1-x}Be_x$(0.3$\leq$x$\leq$0.4) amorphous alloys were crystallized to $\alpha$-Zr with increasing the temperature, and the rest were transformed to ZrBe$_2$at higher temperatures. On the other hand, $Zr_{1-x}Be_x$(0.4$\leq$x$\leq$0.5) amorphous alloys were crystallized to $\alpha$-Zr and ZrBe$_2$, simultaneously. The thickness of the layer brazed with amorphous alloy was increased with increasing the beryllium content due to the higher diffusion of Be. The morphology of brazed layer with PVD Be filler metal showed dendrite while that brazed with amorphous alloys appeared globular. Micro-Vickers hardness of brazed zone increased as the beryllium content of filler metal was decreased.