• Journal of Soil and Groundwater Environment
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• v.15 no.3
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• pp.61-68
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• 2010

Phytoextraction, one type of phytoremediation processes, has been widely used in the removal of heavy metals from polluted soil. This paper reviewed literature on metal uptake by plants and characterized the metal uptake by types of metals (Zn, Cu, Pb, Cd, and As), plant species, initial metal concentrations in soil and the distribution of metals in different parts of plants. The potential of metal accumulation and transport by plants was closely related to plants species, types of metals, and initial metal concentrations in soil. The plants belonging to Brassicaceae, Solanaceae, Poaceae, and Convolvulaceae families have shown the high potential capacity of Cd accumulation. The Gentianaceae, Euphorbiaceae, and Polygonaceae families have exhibited relatively high Pb uptake potential while the Pteridaceae and Cyperaceae families have shown relatively high Zn uptake potential. The Pteridaceae family could uptake a remarkably high amount of As compared with other plant families. The potential metal accumulation per plant biomass has increased with increasing initial metal concentration in soil up to a certain level and then decreased for Cd and Zn. For As, only Pteris vittata had a linear relationship between initial concentration in soil and potential of metal uptake. However, a meaningful relationship for Pb was not found in this study. Generally, the plants having high metal uptake potential for Cd or Pb mainly accumulated the metal in their roots. However, the Euphorbiaceae family has accumulated more than 80% of Pb in shoot. Zn has evenly accumulated in roots and stems except for the plants belonging to the Polygonaceae and Rosaceae families which accumulated Zn in their leaves. The Pteridaceae family has accumulated a higher amount of As in leaves than roots. The types of metals, plant species, and initial metal concentration in soil influence the metal uptake by plants. It is important to select site-specific plant species for effective removal of metals in soil. Therefore, this study may provide useful and beneficial information on metal accumulation by plants for the in situ phytoremediation.

• Journal of Society of Preventive Korean Medicine
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• v.13 no.2
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• pp.77-87
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• 2009

Purpose : To evaluate the effects of Samultang(SMT) on the metals in the dams and fetuses Method : SMT(Decoction) was administered orally using different concentrations to pregnant Sprague-Dawley rats for 20days after being assigned randomly to 5 groups. Each group has 11 dams. Pregnant rats were sacrificed at the 20th day of gestation and metal concentration in the dams and fetuses was observed using a ICP-MS and mercury analyzer. Results : Hg concentration in the blood of dams was lower in the $SMT{\times}1$, $SMT{\times}2$, $SMT{\times}4$group than VC(Vehicle Control) and Control group. Hg concentration in the organs of dams was lower in the $SMT{\times}1$, $SMT{\times}2$, $SMT{\times}4$ group than VC, Control group. Whereas Cd concentration in the organs of fetuses was getting lower as increasing SMT dose, Hg concentration in the organs of fetuses was getting higher as increasing SMT dose. Discussion and Conclusion : There were not any significant harmful differences of metal concentration in the dams and fetuses treated by SMT. Particularly, SMT showed the possibility of efficacy to reduce the concentration of Hg in dams but to increase the concentration of Hg in fetuses. The mechanism of reduction is not yet proven. A hypothesis says there is a possibility of the chelation effect between the essential elements of herbs and heavy metals. Another hypothesis is the possibility of Hg transmission from dam to fetus. Further study should be conducted to make guidelines for the safe use of herbal medicine.

• Journal of Electrochemical Science and Technology
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• v.10 no.1
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• pp.14-21
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• 2019

Supported liquid membrane process usually is used for recovering or enrichment of valuable metals in the industrial wastewater. But, even if the metals in the wastewater was separated with high chemical selectivity, it cannot be enough concentrated since separation performance of supported liquid membrane (SLM) process is limited by concentration gradient between feed solution and stripping solution. If metal concentration in the stripping solution to be enough low, transport of metal through membrane can be accomplishment constantly. Therefore, Electrodialysis (ED) has been placed after SLM process and the stripping solution of SLM was used as the feed solution for the ED process. Transport of ions in the solutions is successfully performed by ED process. Thus, the metal concentration in the stripping solution does not rise as to stop ion transport. Besides, valuable metals easily are concentrated by ED process for re-use. In this study, effects of operation parameters like initial Cd(II) concentration, HCl concentration in the feed solution of SLM and applied voltage are investigated on separation efficiency, flux and permeability of the both processes. As the feed solution concentration increased, all performance values has increased. When initial concentration of 100 mg/L is used, separation performances (SP) are 55% and 70%, for SLM and consecutive process, respectively. The best HCl concentration in the feed solution of SLM has determined as 2 M, in this conditions SP are 64% and 72%, for SLM and consecutive process, respectively. With increased of applied voltage on ED process, SP of the consecutive process has been raised from 72% to 83%. According to the obtained experimental data, consecutive process has better separation performance than SLM. When the separation performances of both processes were compared for the same operating conditions, it was determined higher the separation efficiency, permeability and flux values of the consecutive process, 8%, 9% and %10.6, respectively. Consequently, the use of the consecutive process increases the performance efficiency of both processes. The consecutive process studied has quite a good chemical separation efficiency, and enrichment capability. Moreover, this process requires few water and energy.

• Journal of Environmental Health Sciences
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• v.20 no.3
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• pp.78-84
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• 1994

The effects of heavy metal, Cd on the degradation of the herbicide butachlor (N-Butoxymethyl-2-chlor-2',6'-diethylacetanilide) in soils were examined the laboratory. The degradation of the herbicide in soil was greatly inhibited by the amendment of the heavy metal, Cd. The inhibited rate of Cd concentration was high in the order of 30 ppm>20 ppm> 10 ppm>0 ppm. And tile degradation rate of butachlor was high in order of 80 $\mu$M>40 $\mu$M>20 $\mu$M. The effects of Cd on the degradation of the butachlor in soil varied with concentration of heavy metal and butachlor.

• Korean Journal of Soil Science and Fertilizer
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• v.46 no.3
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• pp.193-202
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• 2013

The concentrations of heavy metals such as cadmium (Cd), chromium (Cr), copper (Cu), lead (Pb), zinc (Zn), nickel (Ni), and arsenic (As) in sand samples collected from selected children's playground and their correlation with environmental parameters, such as concentration of particulate matter in the atmosphere ($PM_{10}$), apartment age (> 5 years), clay and organic matter contents in sand samples, were analyzed. The average heavy metal concentration in samples was 0.040 mg $kg^{-1}$ for Cd, 0.200 mg $kg^{-1}$ for Cr, 1.75 mg $kg^{-1}$ for Cu, 15.1 mg $kg^{-1}$ for Ni, 3.42 mg $kg^{-1}$ for Pb, 66.7 mg $kg^{-1}$ for Zn and 0.750 mg $kg^{-1}$ for As, all of which were below the environmental regulatory level established by Korea Ministry of Environment. However, in the consideration of direct and oral exposure by children to playground sand, the risk of the concentration range in the samples might be greatly enhanced. Heavy metal concentration in samples collected from high $PM_{10}$ (> $70{\mu}gm^{-3}$) area was slightly greater than in samples from low $PM_{10}$ (< $70{\mu}gm^{-3}$), indicating the contribution of particulate matter in air phase to heavy metal concentration in playground sand samples. The concentrations of both Cd and Pb were the highest in apartments older than 21 years (0.050 mg $kg^{-1}$ and 5.28 mg $kg^{-1}$ for Cd and Pb respectively) and showed positive correlation with apartment age (p<0.01 and p<0.001 for Cd and Pb, respectively). Clay content in playground sands ranged 3.8~11.2% and was positively correlated with heavy metal concentration. Organic matter content was negligible (mostly < 0.1%) and showed poor correlation with heavy metal concentration. In conclusion, concentration of heavy metals in playground sand was found to be predominantly influenced by the apartment age and clay content in sand samples and supplemented by dust deposition of particulate matter ($PM_{10}$) from atmosphere.

• Applied Biological Chemistry
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• v.20 no.3
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• pp.300-309
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• 1977

The information related to the heavy metal pollution in the environment was obtained from studies on the effects of pH, phosphate and soil properties on the adsorption of metal ions (Cd, Cu, Ni, and Zn) by soils. Three soil materials; soil 1 with low CEC (8.2 me/100g) and low organic carbon content (0.34%); soil 2 with high CEC (36.4 me/100g) and low organic carbon content (1.8%) and soil 3 with high CEC (49.9 me/100g) and high organic carbon content (14.7%) were used. Soils were adjusted to several pH's and equilibrated with metal ion mixtures of 4 different concentrations, each having equal equivalents of each metal ion (0.63, 1.88, 3.12 and 4.38 micromoles per one gram soil with and without 10 micromoles of phosphate per one gram soil). Reported here are the results of the equilibrium study on soil I. The rest of the results on soil 2 and soil 3 will be repoted subsequeutly. Generally higher metal ion concentration solution resulted in higher final metal ion concentrations in the equilibrated solution and phosphate had minimal effect except it tended to enhance removal of cadmium and zinc from equilibrated solutions while it tended to decrease the removal of copper and nickel. In soil 1, percentages of added metal ions removed at pH 5.10 were; Cu 97, Ni 69, Cd 63, and Zn 55, while increasing pH to 6.40, they were increased to Cu 90.9, Zn 99, Ni 96, and Cd 92 per As initial metal ion concentration increased, final metal ion concentrations in the equilibrated solution showed a relationship with pH of the system as they fit to the equation $p[M^{++}]=a$ pH+b where $p[M^{++}]=-log$[metal ion concentration in Mol/liter]. The magnitude of pH and soil effects were reflected in slope (a) of the equation, and were different among metal ions and soils. Slopes (a) for metal ions in the aqueous system are all 2. In soil 1 they were; Zn 1.23, Cu 0.99, Ni 0.69 and Cd 0.59 at highest concentration. The adsorption of Cd, Ni, and Zn in soil 1 could be represented by the Iangmuir isotherm. However, construction of the Iangmuir isotherm required the correction for pH differences.

• Korean Journal of Soil Science and Fertilizer
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• v.51 no.2
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• pp.128-141
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• 2018

Industrial complex releasing huge amounts of dusts, fumes and wastewater containing heavy metal(loid)s could be a source of heavy metal(loid)s pollution in arable soil. Heavy metal(loid)s pollution in arable soil adversely affect crops safety, subsequently human being. Hence, it is important to accurately assess the heavy metal(loid)s pollution in soil using pollution indices. The objectives of this study are 1) to compare assessment methods of heavy metal(loid)s pollution in arable soils located near industrial complex in Gyeongsang provinces and 2) to determine the relationship between concentration of plant available heavy metal(loid)s and chemical properties of soil. Soil samples were collected from 85 sites of arable lands nearby 10 industrial complex in Gyeongsang provinces. The average total concentration of all heavy metal(loid)s of the studied soils was higher than that of Korean arable soils but did not exceed the warning criteria established by the Soil Environmental Conservation Act of Korea. Only six sites of arable soils for the total concentration of As, Cu and Ni exceeded the warning criteria (As: $25mg\;kg^{-1}$, Cu: $150mg\;kg^{-1}$, Ni: $100mg\;kg^{-1}$). The contamination factor (CF) and geoaccumulation index ($I_{geo}$) of the heavy metal(loid)s in arable soils varied among the sampling sites, and the average values of As and Cd were relatively higher than that of other metals. Results of integrated indices of As and Cd in arable soils located near industrial complex indicated that some arable soils were moderately or heavily polluted. The plant available concentration of heavy metal(loid)s was negatively related to the soil pH and negative charge of soil. Available Cd, Pb, and Zn concentrations had relatively high correlation coefficient with pH and negative charge of soil when compared with other heavy metal(loid)s. Based on the above results, it might be a good soil management to control pH with soil amendments such as lime and compost to reduce phytoavailability of heavy metal(loid)s in arable soil located near industrial complex.

• Journal of Preventive Medicine and Public Health
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• v.13 no.1
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• pp.3-12
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• 1980

Certain heavy metals which may lead peoples to poisonous status are widely used in industry and their uses have been increasing along with rapid industrialization of this country. Such an increasement of metal uses aggravates the status of environmental pollution affecting foodstuffs which are the most important life supporting factor of animal and humanbeing. Concerning the safety measures to minimize food-borne transmission of such hazardous metals, surveillance is the backbone of them and probably more so with a potential problem such as intoxication. Theoretically, this surveillance should include the determination of levels of heavy metal toxicants in foods, the determination of food consumption patterns and typical total diet, and the estimation of total load of the metal contaminant from all sources of exposure including air, water, and occupational sources. In recent year, actually, such estimates on the total daily intake of some heavy metals from foods have been made in several developed countries and a wide variation of date by season, locality, and research method was recognized. Also in this country, this kind of research data is vitally needed to make up for the serious shortage or lack of references to estimate the total amount of heavy metal intake of the people. In this study, a modification model for estimation of the total daily intake of cadmium copper, nickel, zinc, and lead through foods was applied and concentrations of the above metals in crops cultivated in this country were measured with atomic absorption spectro photometer to get the following results. 1. Level of heavy metal concentration in crops Generally, the levels of such metals in essential crops such as rice, cucumber, radish. chinese cabbage, apple, pear, grape, and orange are similar or lower than those in Japan and other developed countries. By the way, a striking result on cadmium concentration was increasement of its concentration in rice from $0{\sim}0.035ppm$ in 1970 to 0.11ppm in this study. However, the value is still far below the. Japanese Permissible Lebel of 1.0ppm. 2. Estimation of total daily intake per capita from foods A new model for estimation was devised utilizing levels of metal concentration in foods, amount of food consumed, and other food factors. Based on the above method, the daily intake of cadmium was estimated to be $70.53{\mu}g/man/day$ in average which was as high as the Limit Value of ILO/WHO(up to $71.4{\mu}g/man/day$). Also, 3.89mg of Zinc, 1.65mg of cuppor, 0.32mg of lead were given as the total daily intake per capita by this research. 3. Efficacy of washing or skinning to decrease the amount of metals in crops After washing the crops sufficiently with commercial linear alkylate sulfonate, the concentration of heavy metals could be reduced to $50{\sim}80%$ showing decreasement rate of $20{\sim}50%$. Also, after skinning the fruits, decreasement rate of the heavy metal concentration shelved $0{\sim}50%$.

• Journal of Environmental Health Sciences
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• v.38 no.5
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• pp.424-430
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• 2012

Objective: The purpose of this study was to present the standard deviation of the elemental normalization of concentration of selected heavy metals in the surface sediment of Lake Paldang. Methods: Grain size dependency of selected heavy metal concentrations in the surface sediments of Lake Paldang was analyzed by the extrapolation method. The heavy metal concentrations were the sum of all fractions. Results: Cd and Cu showed an increase of the coefficient of determination($r^2$) in the fractional content of particle size, from <256 ${\mu}m$ to <20 ${\mu}m$, and a decrease from <20 ${\mu}m$ to <1 ${\mu}m$. The normalized concentration of Cd and Cu by extrapolation at 50% <20 ${\mu}m$ were 0.8 mg/kg, 37.0 mg/kg, 57.6 mg/kg and 201.7 mg/kg respectively. Conclusions: The normalized concentrations in the sediment of Lake Paldang are 1.5-2.0 times higher than mean average concentration. We concluded that in interpretation of heavy metal concentration in the sediment of Lake Paldang, normalization of grain size dependency should be considered.

• Membrane and Water Treatment
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• v.10 no.3
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• pp.201-206
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• 2019

In this study, we performed an electrowinning process for effective removal of metals (Cu and Ni) in solution and their recovery as solid forms. A complete removal of Cu and Ni (1,000 mg/L) was observed during four times recycling test, indicating that our electrowinning system can ensure the efficient metal removal with high stability and durability. In addition, we investigated effect of operation parameters (i.e., concentration of boric acid only for Ni, variation of pH, concentration of electrolyte ($H_2SO_4$), and cell voltage) on the efficiency of metal removal (Cu and Ni) during the electrowinning. The addition of boric acid significantly enhanced removal efficiency of Ni as the concentration of boric acid increased up to 10 g/L. Compared to negligible pH effect (pH 1, 2, and 4) on the Cu removal, we observed the increase in removal efficiency of Ni as the pH increased from 1 to 4. The electrolyte concentration did not significantly influence the removal of Cu and Ni in this study. We also obtained great removal rates of Cu and Ni at 2.5 V and 4.0 V, which were much faster than those at lower voltages. Finally, almost 99% of each Cu and Ni (1,000 mg/L) was selectively removed from the mixture of metals by adjusting pH and addition of boric acid after the completion of Cu removal. The findings in this study can provide a fundamental knowledge about effect of important parameters on the efficiency of metal recovery during the electrowinning.