• Title/Summary/Keyword: Metal Composites

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A Study on Fracture Toughness of Metal Matrix Composites Reinforced with $Al_{18}B_4O_{33}$ ($Al_{18}B_4O_{33}$휘스커 강화 금속기 복합재료의 파괴인성에 관한 연구)

  • Park, Sung-Ho;Choi, Yong-Bum;Park, Won-Jo;Huh, Sung-Chul;Yun, Han-Gi
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2002.10a
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    • pp.335-340
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    • 2002
  • In recent years, the study of metal matrix composite has increased specially, aluminum alloy, research and development are briskly progress to find new metal matrix composite. this study is following the this purpose; This study is used metal matrix composite that was produced by matrix, AC4CH. and reinforcement $A_{18}B_4O_{33}$ metal matrix composite to add $Al_2O_3,\;TiO_2$ for strengthen of binding together among the Whisker. Each Metal matrix composite is produced using the squeeze casting method. Fracture tounghness test was in accordance with the provisions of ASTM E399; Specimen was produced half-size CT specimen W=25mm, B=12.5mm, Cross head speed 0.05mm/min in room temperature. The plane strain fracture toughness $K_{IC}$ is $8.7MPa-m^{0.5}$ for $Al_{18}B_4O_{33}$/AC4CH., $9.28MPa-m^{0.5}$ for $Al_{18}B_4O_{33}$/AC4CH added $TiO_2$. and $Al_2O_3$ but AC4CH alloy was violated the critical stipulated by ASTM standard for a valid measurement of $K_{IC}$. In case of, it was performed $I_{IC}$ test instead of $K_{IC}$ based on ASTM E 1820

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Synthesis and electrochemical performance of transition metal-coated carbon nanofibers as anode materials for lithium secondary batteries

  • Choi, Jin-Yeong;Hyun, Yura;Park, Heai-Ku;Lee, Chang-Seop
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.161-167
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    • 2018
  • In this study, transition metal coated carbon nanofibers (CNFs) were synthesized and applied as anode materials of Li secondary batteries. CNFs/Ni foam was immersed into 0.01 M transition metal solutions after growing CNFs on Ni foam via chemical vapor deposition (CVD) method. Transition metal coated CNFs/Ni foam was dried in an oven at $80^{\circ}C$. Morphologies, compositions, and crystal quality of CNFs-transition metal composites were characterized by scanning electron microscopy (SEM), Raman spectroscopy (Raman), and X-ray photoelectron spectroscopy (XPS), respectively. Electrochemical characteristics of CNFs-transition metal composites as anodes of Li secondary batteries were investigated using a three-electrode cell. Transition metal/CNFs/Ni foam was directly employed as a working electrode without any binder. Lithium foil was used as both counter and reference electrodes while 1 M $LiClO_4$ was employed as the electrolyte after it was dissolved in a mixture of propylene carbonate:ethylene carbonate (PC:EC) at 1:1 volume ratio. Galvanostatic charge/discharge cycling and cyclic voltammetry measurements were taken at room temperature using a battery tester. In particular, the capacity of the synthesized CNFs-Fe was improved compared to that of CNFs. After 30 cycles, the capacity of CNFs-Fe was increased by 78%. Among four transition metals of Fe, Cu, Co and Ni coated on carbon nanofibers, the retention rate of CNFs-Fe was the highest at 41%. The initial capacity of CNFs-Fe with 670 mAh/g was reduced to 275 mAh/g after 30 cycles.

A Study on Microstructure and Mechanical Properties of TiC/Steel Composites Fabricated by Powder Metallurgy Process (분말야금공정으로 제조된 TiC/steel 금속복합재료의 미세조직 및 기계적 물성 연구)

  • Lee, Jihye;Cho, Seungchan;Kwon, Hansang;Lee, Sang-Kwan;Lee, Sang-Bok;Kim, Daeha;Kim, Junghwan
    • Composites Research
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    • v.34 no.5
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    • pp.311-316
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    • 2021
  • In this study, TiC/steel metal matrix composites were fabricated by powder metallurgy process using Fealloy powders with 3 wt.% Cr and 10 wt.% Cr, respectively, as matrix material. Subsequently, the composite samples were heat treated by the annealing and quenching-tempering(Q-T), respectively, to understand the effect of heat treatment on the mechanical properties of the composites. The correlation between microstructure and structural strength depending on the chromium content and the heat treatment conditions was studied through tensile, compressive, and transverse rupture test and microstructural analysis. In the case of TiC/steel composite containing 10 wt.% Cr, the tensile strength and transverse rupture strength at room temperature were significantly lowered by the influence of coarse chromium carbide formed at the TiC/steel interface. On the other hand, both TiC/steel composites containing 3 wt.% Cr and 10 wt.% Cr showed much higher compressive strength of about 4 GP after quenching-tempering compared to the annealed specimens regardless of the presence of the chromium carbide.

Electromagnetic Interference Shielding Behaviors of Electroless Nickel-loaded Carbon Fibers-reinforced Epoxy Matrix Composites (무전해 니켈도금된 탄소섬유강화 에폭시기지 복합재료의 전자파 차폐특성)

  • Hong, Myung-Sun;Bae, Kyong-Min;Lee, Hae-Seong;Park, Soo-Jin;An, Kay-Hyeok;Kang, Shin-Jae;Kim, Byung-Joo
    • Applied Chemistry for Engineering
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    • v.22 no.6
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    • pp.672-678
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    • 2011
  • In this work, carbon fibers were electrolessly Ni-plated in order to investigate the effect of metal plating on the electromagnetic shielding effectiveness (EMI-SE) of Ni-coated carbon fibers-reinforced epoxy matrix composites. The surfaces of carbon fibers were characterized by scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). Electric resistance of the composites was tested using a 4-point-probe electric resistivity tester. The EMI-SE of the composites was evaluated by means of the reflection and adsorption methods. From the results, it was found that the EMI-SE of the composites enhanced with increasing Ni plating time and content. In high frequency region, the EMI-SE didn't show further increasing with high Ni content (Ni-CF 10 min) compared to the Ni-CF 5 min sample. In conclusion, Ni content on the carbon fibers can be a key factor to determine the EMI-SE of the composites, but there can be an optimized metal content at a specific electromagnetic frequency region in this system.

Surface Electrode Modification and Improved Actuation Performance of Soft Polymeric Actuator using Ionic Polymer-Metal Composites (이온성고분자-금속복합체를 이용한 유연고분자 구동체의 표면특성 개선과 구동성 향상)

  • Jung, Sunghee;Lee, Myoungjoon;Song, Jeomsik;Lee, Sukmin;Mun, Museoung
    • Applied Chemistry for Engineering
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    • v.16 no.4
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    • pp.527-532
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    • 2005
  • Ionic polymer metal composites (IPMC) are soft polymeric smart materials having large displacement at low voltage in air and water. The polymeric electrolyte actuator consists of a thin and porous membrane and metal electrodes plated on both faces, in impregnation electro-plating method. The response and actuation of actuator are governed. Among many factors governing the activation and response of IPMC actuator, the surface electrode plays an important role. In this study, the well-designed modification of electrode surface was carried out in order to improve the chemical stability well as electromechanical characteristics of the IPMC actuator. We employed Ion Beam Assisted Deposition (IBAD) method to prepare the topologically homogeneous thin surface electrode. After roughing the surface of Nafion membrane in order to get a larger surface area, the IPMC was prepared by impregnation for electro-plating and re- coating on the surface through traditional chemical deposition, followed by an additional surface treatment with high conductive metals with IBAD. It was observed that our IPMC specimen shows the enhanced surface electrical properties as well as the improved actuation and response characteristics under applied electric field.

Micromechanical Model for the Consolidation Behavior in SiC-Ti Metal Matrix Composites (SiC-Ti금속기 복합재료의 강화거동에 관한 미시역학적 모델)

  • 김준완;김태원
    • Composites Research
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    • v.16 no.3
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    • pp.1-8
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    • 2003
  • Densification occurs by the inelastic flow of the matrix materials during the consolidation processes at high temperature for MMCs, and the results depend on many process conditions such as applied pressure, temperature and volume fraction of fiber and matrix materials. This is particularly important in titanium matrix composites since material failure may occur by either the applied conditions or microstructural parameters through the processes, and thus a generic model based on micro-mechanical approaches enabling the evolution of density over time to be predicted has been developed. The mode developed is then implemented into FEM so that practical process simulation has been carried out. Further the experimental investigation of the consolidation behavior of SiC/Ti-6Al-4V composites using vacuum hot pressing has been performed, and the results obtained are compared with the model predictions.

Fatigue and Cyclic Deformation Behavior with the Unreinforced Matrix Alloy and Al/$Al_2O_3$ Metal Matrix Composites (기지금속과 $Al_2O_3$/Al 금속복합재료의 피로 및 주기적 변형거동)

  • 송정일
    • Composites Research
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    • v.12 no.5
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    • pp.1-11
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    • 1999
  • Cyclic deformation and fatigue behavior of $Al/$Al_2O_3$ metal matrix composites and matrix alloy were studied. Hatigue strength Al/$Al_2O_3$ composites was about 210MPa, and that of Al matrix alloy was 170MPa. Most of the resultant displacement due to permanent plastic deformation occurred in less than the first 5% of fatigue life. In case of composites, decrease of cyclic displacement was smaller than that of matrix because the reinforcements acted as barriers to dislocation movement. Consequently, cyclic stress-displacement response curve can be considered to have these atages ; an initial few cycles of rapid hardening, followed by progressive hardening for most the fatigue life, and then just prior to failure, an instantaneous drop in stress carrying capability of the material due to multiple microcrack initiation, eventual coalescence of microcrack to form a macrocrack and then rapid macroscopic crack growth.

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Strengthening Mechanism of Hybrid Short Fiber/Particle Reinforced Metal Matrix Composites (섬유/입자 혼합 금속복합재료의 강화기구 해석)

  • 정성욱;이종해;정창규;송정일;한경섭
    • Composites Research
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    • v.13 no.1
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    • pp.50-60
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    • 2000
  • This paper presents an analytical method considering tensile strength enhancement in hybrid $Al_2O_3$ fiber/particle/aluminum composites(MMCs). The tensile strength and elastic modulus of the hybrid MMCs are even 20% higher than those of the fiber reinforced MMCs with same volume fraction of reinforcements. This phenomenon is explained by the cluster model which is newly proposed in this research, and the strengthening mechanisms by a cluster is analyzed using simple modified rule of mixtures. From the analysis, it is observed that cluster structure in hybrid MMCs increase the fiber efficiency factor for the tensile strength and the orientation factor for the elastic modulus. The present theory is then compared with experimental results which was performed using squeeze infiltrated hybrid MMCs made of hybrid $Al_2O_3$ short fiber/particle preform and AC8A alloy as base metal, and the agreement is found to be satisfactory.

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Wear Properties of Thermal Sprayed Al-based Metal Matrix Composites Against Different Counterparts (용사법에 의해 제조된 $Al/Al_2O_3$ 복합재료의 상대재에 따른 마모특성)

  • Kim, K.T.;Kim, Y.S.
    • Journal of Power System Engineering
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    • v.12 no.3
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    • pp.60-65
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    • 2008
  • This study aims at investigating the wear properties of thermally sprayed $Al/Al_2O_3$ metal matrix composite(MMC) coating against different counterparts. $Al/Al_2O_3$ MMC coatings were fabricated using a flame spray system on an Al 6061 substrate. Dry sliding wear tests were performed using the sliding speeds of 0.2m/s and the applied loads of 1 and 2 N. AISI 52100, $Al_2O_3$, $Si_3N_4\;and\;ZrO_2$ balls(diameter: 8mm) were used as counterpart materials. Wear properties of $Al/Al_2O_3$ MMC coatings were analyzed using a scanning electron microscope(SEM) and energy dispersive X-ray spectroscopy (EDX). It was revealed that wear properties of $Al/Al_2O_3$ composite coatings were much influenced by counterpart materials. In the case of AISI 52100 used as counterparts, the wear rate of composites coating layer increased according to the increase of the applied load. On the contrary, in the case of ceramics used as counterparts, the wear rate of composites coating layer decreased according to the increase of the applied load.

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Finite Element Analysis for the Design of Fiber Reinforced Metal Cylinder (강/복합재 이중구조 실린더 설계를 위한 유한요소 해석)

  • Kim, Tae-Hwan;Kim, Wie-Dae;Jeong, Chul-Gon
    • Composites Research
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    • v.26 no.1
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    • pp.7-13
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    • 2013
  • This paper describes the design of dual-structured and thick-walled cylinder made of composites and special steel. The structure of special steel and composites reduce the weight of a product maintaining its property which is proper to the characteristics. Hence they are used in the fields, such as various ground weapons, aerospace and sports industries, where high elasticity and low weight are required. Thus in this study, the analysis was conducted to find the most proper composite application method changing its types and angle of laminates for the design. Through the comparison of the results, we suggest the method for composite application which is the most appropriate to the designing purpose of this study.