• The Journal of the Acoustical Society of Korea
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• 제15권1E호
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• pp.5-19
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• 1996

This paper proposes a loose part monitoring system (LPMS) design with a signal processing method based on fuzzy logic. Considering fuzzy characteristics of metallic impact waveform due to not only interferences from various types of noises in an operating nuclear power plant but also complex wave propagation paths within a monitored mechanical structure, the proposed LPMS design incorporates the comprehensive relation among impact signal features in the fuzzy rule bases for the purposes of alarm discrimination and impact diagnosis improvement. The impact signal features for the fuzzy rule bases include the rising time, the falling time, and the peak voltage values of the impact signal envelopes. Fuzzy inference results based on the fuzzy membership values of these impact signal features determine the confidence level data for each signal feature. The total integrated confidence level data is used for alarm discrimination and impact diagnosis purposes. Through the perpormance test of the proposed LPMS with mock-up structures and instrumentation facility, test results show that the system is effective in diagnosis of the loose part impact event(i.e., the evaluation of possible impacted area and degree of impact magnitude) as well as in suppressing false alarm generation.

• 대한화학회지
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• 제44권3호
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• pp.243-248
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• 2000

다층 구조로 이루어진 유기 전계발광소자(OELD)는 평판 디스플레이에 응용될 수 있으므로 활발히 연구되고 있다. 금속 킬레이트 착물은 발광층을 구성하는 물질로 개발되고 있는데 이 중 몇 가지는 효율적인 전계발광(EL) 특성을 가진다고 알려져 있다. 본 연구에서는 청색 발광을 나타내는 몇 가지 금속 킬레이트 착물들을 합성하였다. 리간드 quinaldat나 8-quinoline carboxylate를 사용하였고 중심 금속으로는 베릴륨과 아연을 도입하였다. 이 착물들에 대하여 FT-IR, MS/FAB, $^1$H-NMR, UVvis, 광발광(PL) 특 성을 고찰하였다. 또한 순환 전압전류법(CV)으로 이들 착물로 형성된 필름의 전기화학적 밴드갭(Eg), 전자친화도(EA), 이온화 에너지(IP)를 조사하였다. 앞에서 얻은 UV-vis의 에너지 홉수 파장과 순환 전압전류법으로 구한 전기화학적 밴드갭올 비교, 논의하였다. 이러한 연구는 새로운 고효율 금속 착물 발광체의 개발에 밑거름이 될 것이며, 현재 이들 화합물로 EL 소자를 제작하는 연구가 진행 중에 있다.

• 대한화학회지
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• 제38권1호
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• pp.50-54
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• 1994

흐름주입법에 의하여 분광광도법으로 몇 가지 가벼운 란탄족 원소를 정량하였다. Chromeazurol S는 양이온 계면활성제인 DTAB존재하에서 란탄족 이온과 착물을 형성한다. Tris 완충용액(pH 10.5)에서 이 착물의 최대흡수파장은 650 nm 에서 655 nm범위이고 몰흡광계수는 약 $1.8{\times}10^5\;L mol^{-1}cm^{-1}$였다. FIA에 의한 Nd(III), Eu(III) 및 Sm(III)의 검정곡선은 0.1 ~ 0.6 ppm에서 직선관계를 보였고, 이 검정곡선의 상관계수(${\gamma}$)는 0.9993이였다. 검출한계(S/N)는 Nd(III)과 Eu(III)에 대하여는 10 ppb이고, Sm(III)에 대하여는 20 ppb였다. 상대표준편차는 시료 0.4 ppm에 대하여 약 ${\pm}$1.2%이고, 시료의 분석 속도는 약 $50hr^{-1}$였다.

• Bulletin of the Korean Chemical Society
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• 제32권2호
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• pp.639-644
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• 2011

A simple and highly sensitive chemiluminescence method to determine norfloxacin (NFLX) has been proposed by measuring the chemiluminescence (CL) intensities using a flow injection (FI) system. The CL intensity of the luminol-$H_2O_2$ system is strongly enhanced by the addition of Cu (II) in alkaline condition. The CL intensity is substantially increased after the injection of NFLX into the luminol-$H_2O_2$-Cu (II) system. The enhancement effect is attributed to a catalytic effect of Cu (II) due to the interaction with NFLX which forms a complex with the catalyst. Under the optimal conditions, the sensitizing effect of the CL intensity is proportional to the concentration of NFLX in the range of $1.5{\times}10^{-9}-5.9{\times}10^{-7}molL^{-1}$ (r = 0.9994) with a detection limit ($3{\sigma}$) of $2.98{\times}10^{-10}molL^{-1}$. The proposed method had good reproducibility with the relative standard deviation (RSD, n = 5) of 1.6% for $1{\times}10^{-7}molL^{-1}$ of NFLX. The possible reaction mechanism of the CL reaction is also discussed. This method has been successfully applied for the determination of trace amount of NFLX in pharmaceutical preparations and serum samples.

• Bulletin of the Korean Chemical Society
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• 제32권7호
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• pp.2351-2357
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• 2011

Three new metal-organic copper(II) complexes, $[Cu(H_2PZTC)_2]_n{\cdot}2nH_2O$ (1), $[Cu(HPZTC){\cdot}2H_2O]_n{\cdot}2nH_2O$ (2), and $Cu_2[(PZHD)(OH)(H_2O)_2]_n$ (3) ($H_3PZTC$ = pyrazine-2,3,5-tricarboxylic acid, $PZHD^{3-}$ = 2-hydroxypyrazine-3,5-dicarboxylate), have been synthesized from $Cu(II)/H_3PZTC$ system under different synthetic conditions, and characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy and thermogravimetric analysis. In complexes 1 and 2, $H_3PZTC$ ligands loose one and two protons, which were transformed into $H_2PZTC^-$ anion and $HPZTC^{2-}$ dianion under different preparation condition, respectively. Furthermore, two ligands coordinate with Cu(II) cations in different modes, leading to the formation of the different chain structures. In complex 3, $H_3PZTC$ ligand was converted into a new ligand-PZHD by in situ decarboxylation and hydroxylation under a higher pH value than that for complexes 1 and 2. PZHD ligands link the Cu(II) cations to form a 2D layer structure. These results demonstrate that the preparation conditions, including pH value and reaction temperature etc, play an important role in the construction of complexes based on $H_3PZTC$ ligand.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2007년도 춘계학술대회 논문집
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• pp.1097-1106
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• 2007

Rail provides running tract for train and broadly and widely conveys the weight of the train exerted from the train wheels that the rail directly supports onto the cross tie and roadbed, and supports the cross-sectional pressure exerted by centrifugal force at curvatures. That is, stationary rail provides surface on which dynamic train runs and guarantees cross-sectional resistance to enable the vertical snake motion of the train wheels as well as to maintain lateral force at curvatures. Rail provides running surface on which train wheels can run smoothly, and secures vertical and lateral force. However, it undergoes continuous destructive reactions (wearing and damages) and abrasion of the cladding by the train wheels. It is obvious that wearing will result when two metal parts act against each other. However, occurrence of abnormal wearing such as rapid wearing of the rail side due to complex generation of various mechanisms at the contact surface between the rail and train wheel flange. It is not easy to simply examine the causes of occurrence of abnormal wearing of rail and train wheel flange. Although countless number of academicians and specialists are conducting researches on abnormal wearing of rail and vertical wearing of train wheels, I believe it is too early to argue on pros and cons due to insufficiency of officially verified information on the issue. This review will be focusing on the examples of repairs that reduced the generation of abnormal wearing of rail by reviewing and improving characteristics of wearing and slack, speed of the train and cant as well as status of lubricator by choosing the compound curves present in the section between the $Anguk{\sim}Jongno3-ga$ Stations of the Route No. 3 among the compound curve tracks of the Seoul Metro Routes No. 3 & 4 at which abnormal wearing is generated continuously.

• 한국가구학회지
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• 제25권1호
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• pp.45-54
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• 2014

Wood cutting utilizing CNC art in the field of furniture design industry, art, education are diverse. However, there is lack of data in the case for wood cutting, such as cutting conditions and wood cutting. So this article is to establish furniture design processing using CNC. The researchers investigated the processed products using CNC, the data of the web site and CNC relevant articles, then organized its impact on the furniture industry today. History and definition of CNC have studied for a discussion of the advantages and disadvantages. Then, the researchers analyzed the cases to investigate the wood cutting conditions, was applied to the fabrication of furniture domestic and foreign. CNC organized systematically design information through the computer So, it allowed to reduce the repetitive behavior that has to work hand in the furniture manufacture existing. CNC has made it possible to design a fine complex in furniture design industry. So it became possible to make a new representation and production of various forms. Material about CNC are mostly for milling machine and shelves for metal processing. So, the researchers investigated and precautions general content of wood cutting. The enhanced understanding to investigate an example that is applied outside the country, is used to analyze the expression various techniques CNC. It is difficult to obtain accurate data processing, it has various characteristics in the same timber, Future research is about analyzing type applications and CNC machining range at the time of processing the various wood.

• 한국산업보건학회지
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• 제3권2호
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• pp.227-239
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• 1993

The author selected 77 dust emissing processes from 71 types of industries which placed in Sasang Industrial Complex in Pusan. The level of total dust was measured as areal concentration and personal exposure concentration by low volume air sampler and personal air sampler, respectively. Collected samples were classified into 5 groups (chemicals and rubber product, metal product, sawmills and wood, foundries and others). Respirable particulate and total dust of areal and personal exposure were analyzed. The results were as follows; 1. All of the respirable dust concentration and total dust of areal and personal concentration were log-normally distributed. 2. Geometric mean of respirable particulate of personal exposure concentration measured $0.55mg/m^3$ in the first group, $0.86mg/m^3$ in the second group, $0.39mg/m^3$ in the third group, $0.81mg/m^3$ in the forth group and $0.52mg/m^3$ in the fifith group. The exceed rates over TLV (thehold limit values) of total dust were 31.3% in the first group, 31.3% in the second group, 70% in the third group, 80% in the forth group and 13.3% in the fifth group. 3. There were singnificant difference between areal and personal exposure concentration and personal exposure concentration was higher than that of area. 4. In the case of high ratio of respirable particulate to total dust, pneumoconiosis incidence was high even though the workshop was opened and emissing dust concentration was low. These findings suggest that it is desirable to measure respirable particulate in environmental assessment of dust emissing workshops.

• 한국산업보건학회지
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• 제19권4호
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• pp.336-346
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• 2009

As a follow-up survey of A Study of Monitoring Method on Exposure Level and Biomarkers of Environmental Pollutants-Focused on Ulsan Industrial Comlpex Area, published in 2005, a close examination of the health status was conducted for selected Ulsan residents. Based on the previous study, a total number of 129 subjects were divided into two groups: the exposure group consisted of 39 residents whose blood levels of lead, mercury and/or cadmium were higher than international reference values, and 90 residents of control group with normal levels. Environmental exposure level and its association with health condition were examined by various methods such as questionnaire, analyses of lead, mercury and cadmium in blood and medical examinations. The geometric mean concentrations of lead, mercury and cadmium in blood were respectively $2.07{\mu}g/d{\ell}$ (exposure $2.54{\mu}g/d{\ell}$, control $1.90{\mu}g/d{\ell}$), $5.94{\mu}g/L$ (exposure $8.57{\mu}g/L$, control $5.07{\mu}g/L$), $1.32{\mu}g/L$ (exposure $1.30{\mu}g/L$, control $1.33{\mu}g/L$). The concentrations of the three heavy metals in blood showed lower levels than internationally recommended values except for blood mercury. Also, any abnormal or, peculiar disease, or target tissue damage related to the heavy metals was not observed among the all subjects. Therefore, it can be said that no significant difference of heavy metal concentrations and health conditions was found between the two groups.

• 한국해양공학회지
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• 제22권6호
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• pp.75-82
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• 2008

Flame bending has been extensively used in the shipbuilding industry for hull plate forming In flame bending it is difficult to obtain the desired shape because the residual deformation dependson the complex temperature distribution and the thermal plastic strain. Mechanical bending such as reconfigurable press forming multi-point press forming or die-less forming has been found to improve the automation of hull plateforming because it can more accurately control the desired shape than line heating. Multi-point forming is a process in which external forces are used to form metal work-pieces. Therefore it can be a flexible and efficient forming technique. This paper presents an optimal approach to determining the press-stroke for multi-point press forming of curved shapes. An integrated configuration of Finite element analysis (FEA) and spring-back compensation algorithm is developed to calculate the strokes of the multi-point press. Not only spring-back is modeled by elastic plastic shell elements but also an iterative algorithm to compensate the spring-back is applied to adjust the amount of pressing stroke. An iterative displacement adjustment (IDA) method is applied by integration of the FEA procedure and the spring-back compensation work. Shape deviation between the desired surface and deform￡d plate is minimized by the IDA algorithm.