• Title/Summary/Keyword: Membrane Process Modeling

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Permeability of pH-sensitive membranes grafted by Fenton-type reaction: An experimental and modeling study

  • Gac, Jakub M.;Bojarska, Marta;Stepniewska, Izabela;Piatkiewicz, Wojciech;Gradon, Leon
    • Membrane and Water Treatment
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    • v.6 no.5
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    • pp.411-422
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    • 2015
  • Membrane modification by different concentrations of acrylic acid has been described. Grafting of acrylic acid to the surface of a polypropylene membrane was obtained by a Fenton-type reaction. Membrane permeability seemed to have been dependent on the value of pH in the solution. To explain tendency, a simple theoretical model was developed. The model incorporates explicitly statistical conformations of a polyacid chain grafted onto the pore surface. The charged capillary model with a varying diameter for porous membranes was then used to evaluate the permeability of the membrane. It has been shown both theoretically and experimentally that the permeability of a grafted membrane depends on the pH of the solution.

A process diagnosis method for membrane water treatment plant using a constant flux membrane fouling model (정유량 막여과 파울링 모델을 이용한 막여과 정수 플랜트 공정 진단 기법)

  • Kim, Suhan
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.1
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    • pp.139-146
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    • 2013
  • A process diagnosis method for membrane water treatment plant was developed using a constant flux membrane fouling model. This diagnosis method can be applied to a real-field membrane-based water treatment plant as an early alarming system for membrane fouling. The constant flux membrane fouling model was based on the simplest equation form to describe change in trans-membrane pressure (TMP) during the filtration cycle from a literature. The model was verified using a pilot-scale microfiltraton (MF) plant with two commercial MF membrane modules (72 m2 of membrane area). The predicted TMP data were produced using the model, where the modeling parameters were obtained by the least square method using the early plant data and modeling equations. The diagnosis was carried out by comparing the predicted TMP data (as baseline) and real plant data. As a result of the case study, the diagnsis method worked pretty well to predict the early points where fouling started to occur.

Development of a Parametric Design System for Membrane Structures (연성 막구조의 파라메트릭 설계 시스템 개발)

  • Choi, Hyun-chul;Lee, Si Eun;Kim, Chee Kyeong
    • Journal of Korean Association for Spatial Structures
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    • v.16 no.4
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    • pp.29-36
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    • 2016
  • The objective of this research is to development of a parametric design system for membrane structures. The parametric design platform for the spatial structures has been designed and implemented. Rhino3D is used as a 3D graphic kernel and Grasshopper is introduced as a parametric modeling engine. Modeling components such as structural members, loading conditions, and support conditions are developed for structural modeling of the spatial structures. The interface module with commercial structural analysis programs is implemented. An iterative generation algorithm for design alternatives is a part of the design platform. This paper also proposes a design approach for the parametric design of Spoke Wheel membrane structures. A parametric modeling component is designed and implemented. SOFiSTik is examined to interact with the design platform as the structural analysis module. The application of the developed interface is to design optimally Spoke Wheel Shaped Ductile Membrane Structure using parametric design. It is possible to obtain objective shape by controlling the parameter using a parametric modeling designed for shape finding of spoke wheel shaped ductile membrane structure. Recently, looking at the present Construction Trends, It has increased the demand of the large spatial structure. But, It requires a lot of time for Modeling design and the Structural analysis. Finally an optimization process for membrane structures is proposed.

A Study on Carbon Dioxide Removal Process Using Composite Membrane in DME Production Process (DME 생산공정에서 복합막을 이용한 이산화탄소 제거공정 전산모사)

  • Noh, Sang-Gyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.7
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    • pp.4698-4706
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    • 2014
  • In this study, the simulation was performed for the CO removal process using a composite membrane in DME production. The composite membrane, PEI-PDMS (polyetherimide- polydimethyl siloxane) manufactured by Airrane Co. Ltd., was used in the modeling through a commercial simulation design program, PRO/II with PROVISION 9.2 by Invensys. To simulate the process, the permeability constants of each of the pure component from Airrane Co. Ltd. were determined by regression analysis from the experimental data. The required separation membrane area and utility cost in the CO removal process were obtained using a chemical process simulator and composite membrane with a compatible permeability constant.

Polymer Electrolyte Fuel Cell Simulation Using Simulink (Simulink를 이용한 고분자 전해질 연료전지 시스템 시뮬레이션)

  • Hwang, Nam-Sun;Lee, Ho-Jun;Ju, Byung-Su
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.109-112
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    • 2007
  • In this paper, a mathematical modeling was developed to simulate 1kW class air cooled Polymer Electrolyte Membrane Fuel Cell(PEMFC) system. The proposed modeling was conducted under SIMULINK based environment. The model ing was developed based on the thermodynamic and chemical equilibrium. The objective is to design and implement the entire fuel cell system model ing including the system controller modeling. The fuel cell process and the control system modeling should have to be connected with each other simultaneously, therefore the two types of modeling influences each other when the system simulator run. The fuel cell modeling libraries are simulated using the SIMULINK under the thermodynamic and chemical equilibrium base. The PID controller application was designed and developed to test the process modeling and verify it. This the prototype development of the fuel cell system to design and test more complicate fuel cell systems, like the residential power generation system. The simulation results was compared to the real PEMFC system performance. We have achieved the reasonable accordance with the Lab test and the simulation results.

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MEMBRANE CONTACTORS IN INTEGRATED SYSTEMS

  • Criscuoli, Alessandra;Drioli, Enrico
    • Proceedings of the Membrane Society of Korea Conference
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    • 1999.07a
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    • pp.52-54
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    • 1999
  • In the present work, results of simulation studies carried out for the water carbonation process are presented and compared with experimental data obtained for the same system. Furthermore, the use of membrane contactors in integrated membrane operations is proposed and discussed as a mean to enhance the performance of processes.

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Review of Basics Reverse Osmosis Process Modeling: A New Combined Fouling Index Proposed (역삼투 공정을 위한 모델링 총설 및 새로운 복합적 막오염도의 제안)

  • Kim, Albert S.
    • Membrane Journal
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    • v.27 no.4
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    • pp.291-312
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    • 2017
  • Seawater desalination is currently considered to be one of the primary technologies to resolve the global water scarcity problem. A basic understanding of membrane filtration phenomena is significant not only for further technological development but also for integrated design, optimal control, and long-term maintenance. In this vein, the present work reviews the major transport and filtration models, specifically related to reverse osmosis phenomena, provides theoretical insights based on statistical mechanics, and discusses model-based physical meanings as related to their practical implications.

Simulation of transport phenomena in porous membrane evaporators using computational fluid dynamics

  • Mohammadi, Mehrnoush;Marjani, Azam;Asadollahzadeh, Mehdi;Hemmati, Alireza;Kazemi, Seyyed Masoud
    • Membrane and Water Treatment
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    • v.7 no.2
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    • pp.87-100
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    • 2016
  • A numerical simulation of membrane evaporation process was carried out in this work. The aim of simulation is to describe transport of water through porous membranes applicable to the concentration of aqueous solutions. A three-dimensional mathematical model was developed which considers transport phenomena including mass, heat, and momentum transfer in membrane evaporation process. The equations of model were then solved numerically using finite element method. The results of simulation in terms of evaporation flux were compared with experimental data, and confirmed the accuracy of model. Moreover, profile of pressure, concentration, and heat flux were obtained and analyzed. The results revealed that developed 3D model is capable of predicting performance of membrane evaporators in concentration of aqueous solutions.

Multiscale Modeling and Simulation of Direct Methanol Fuel Cell (직접메탄올 연료전지의 Multiscale 모델링 및 전산모사)

  • Kim, Min-Su;Lee, Young-Hee;Kim, Jung-Hwan;Kim, Hong-Sung;Lim, Tae-Hoon;Moon, Il
    • Membrane Journal
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    • v.20 no.1
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    • pp.29-39
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    • 2010
  • This study focuses on the modeling of DMFC to predict the characteristics and to improve its performance. This modeling requires deep understanding of the design and operating parameters that influence on the cell potential. Furthermore, the knowledge with reference to electrochemistry, transport phenomena and fluid dynamics should be employed for the duration of mathematical description of the given process. Considering the fact that MEA is the nucleus of DMFC, special attention was made to the development of mathematical model of MEA. Multiscale modeling is comprised of process modeling as well as a computational fluid dynamics (CFD) modeling. The CFD packages and process simulation tools are used in simulating the steady-state process. The process simulation tool calculates theelectrochemical kinetics as well as the change of fractions, and at the same time, CFD calculates various balance equations. The integrated simulation with multiscal modeling explains experimental observations of transparent DMFC.