• Proceedings of the KSME Conference
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• 2000.04b
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• pp.51-56
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• 2000

The Finite Element Solutions Is reported on solid-liquid phase change in porous media with natural convection including freezing. The model is based on volume averaged transport equations, while phase change is assumed to occur over a small temperature range. The FEM (Finite Element Method) algorithm used in this study is 3-step time-splitting method which requires much less execution time and computer storage the velocity-pressure integrated method and the penalty method. And the explicit Lax-Wendroff scheme is applied to nonlinear convective term in the energy equation. For natural convection including melting and solidification the numerical results show reasonable agreement with FDM (Finite Difference Method) results.

• Macromolecular Research
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• v.8 no.6
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• pp.261-267
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• 2000

It is well known that poly(cyclohexylene dimethylene terephthalate) (PCT) is used as the engineering plastics with high melting temperature and fast crystallization rate compared with poly(butylene terephthalate)(PBT). However, poor thermal stability of PCT has limited its practical application due to the drastic decrease of molecular weight during the processing temperature. In order to improve the thermal stability of PCT homopolymer, the copolymer of PCT and PBT was synthesized and the thermal properties of the copolymer have been studied. P(CT/BT) copolymer was obtained by condensation polymerization of DMT, CHDM, and 1,4-butanediol. The chemical structure and composition of the copolymer was investigated by FTIR and NMR analysis. The thermal behavior of copolymer was studied using DSC and it was found that the crystallization-melting behavior of the copolymer was observed for the whole composition range. TGA analysis exhibited that P(CT/BT) copolymer is more stable at the initial stage of thermal decomposition compared with PCT and PBT homopolymers.

• Journal of Welding and Joining
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• v.18 no.6
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• pp.42-47
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• 2000

The object of this study is to estimate Sn-Ag-Bi-Ga solder alloy as a substitute for Sn-37Pb alloy. For Sn-Ag-Bi-Ga alloys, Ag, Bi and Ga contents are varied. (Ag : 1~5%, Ga : 3%, Bi : 3~6%) Comparing to Sn-37Pb alloy Sn-Ag-Bi-Ga alloys have wider melting temperature range up to max. $18.7^{\circ}C$. With increasing Ag, Bi contents, the wettability of the alloys increased up to max. 6.6 mN. The vickers hardness of the alloys was max. 46.4 Hv. The ultimate tensile stress of the alloys was max. 60.3 MPa and the elongation was max. 1.2%. The joint strength between circuit board and solder was max. 55.5 N and the joint strength between connector and solder was max. 176.1 N. There were no cracks in this alloys after thermal shock test.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.2256-2261
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• 2008

The electric snow melting and deicing system by electric heating cable which is adopted in this study is a part of road facilities to keep surface temperature of the road higher than freezing point of water for melting the snow or ice accumulated on it. The electric heating cables are buried under paved road at a certain depth and a certain pitch and operated automatically and manually. Design theory, amount of heating, and installation standard vary according to economic situation, weather condition, and installation place. A main purpose of this study is figuring out the appropriate range of required heat capacity and installation depth and pitches for solving snowdrifts and freezing problems with minimum electric power consumption. This study was performed under the ambient air temperature($-2^{\circ}C$, $-5^{\circ}C$), the pitches of the electric heating cables (200 mm, 300 mm), heating value ($250\;W/m^2$, $300\;W/m^2$, $350\;W/m^2$).

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.17 no.6
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• pp.673-677
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• 2004

We present the basic properties of a superconductive fuse (SF) based on YBCO/Au films. The SF consists of YBCO stripes covered with Au layers for current shunt. The fault current was limited to a designed value in less than 0.4 msec by resistance development in YBCO/Au upon quenching. This enabled the SF to transfer small fault power and the suppressed current was sustained for more than 0.5 msec while Au layer melting and arcing. The arcing time was less than 2.5 msec, that is short enough to do self-interruption. Under the source voltage of 100 $V_{rms}$, the longer the duration time of fault current was, the shorter its discharge time was. The duration time of fault current and its discharge time were reduced by increased voltages in the range of 200 - 300 $V_{rms}$. We thought that this was because the quench propagation was limited by local melting generated with higher voltage.age.

• Journal of the Korean Society of Safety
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• v.15 no.3
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• pp.14-22
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• 2000

A numerical analysis has been performed on the two-dimensional rectangular gallium melting problem using the enthalpy method. The major advantage of this method is that the physical domain is discretized with fixed grids without transforming variables and the interface conditions of phase change are accounted for the definition of suitable source terms in the governing equations. But in the fixed method, there is some ambiguity in defining the porosity constant which has no physical interpretation. If the velocity correction is included in the momentum equation, for the appropriate range of porosity constant, the realistic predictions are obtained. The object of the present work is to predict the phase change within the molten steel with thin riser slab using the modified enthalpy-porosity method. The computational procedures for predicting velocity and temperature are based on the finite volume method and the non-staggered grid system. The influence of natural convection on the melting process is considered. A comparison with the experimental results shows that the modified method is better than the previous one.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.07a
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• pp.527-530
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• 2004

High-temperature Superconductor(HTS) tubes were fabricated in term of different diameter, length and thickness by centrigugal forming method. For powder melting by induction the optimum range of melting temperatures and preheating temperature were $1050^{\circ}C{\sim}1100^{\circ}C\;amd\;550^{\circ}C$ for 30min, respectively. The mould renting speed was 1000rpm. A tube was annealed at $840^{\circ}C$ for 72hours in oxygen atmosphere. The plate-like grains were well developed along the renting direction and typical grain size was about more than $40{\mu}m$. It was found that Ic values increased with increasing the tube diameter while the Ic decreased with increasing tube thickness. Also Ic decreased with increasing the tube length. The measured Ic in $50mm{\times}70mm{\times}25mm$ tube was about 896Amp.

• Bulletin of the Korean Chemical Society
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• v.18 no.1
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• pp.38-43
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• 1997

Poly(ethylene 2, 6-naphthalate-co-tetramethylene 2, 6-naphthalate) (PEN/PBN) copolymers were synthesized and studied by 13C NMR spectroscopy, DSC analysis and X-ray diffraction. A minimum in the melting point vs. composition curve was found at approximately 60 mol% tetramethylene 2, 6-naphthalate. The PEN/PBN copolymers were shown to be statistically random throughout the range of 1, 4-butanediol compositions. The melting point depression behavior of annealed PEN/PBN copolymers depended upon the sequence propagation probability, PS, which is suggested by indivisual crystal formation of two pure comonomers; that is, ethylene-naphthalate-ethylene, EE, and tetramethylene-naphthalate-tetramethylene, BB. However, it can be seen from the X-ray curve that the peaks of PEN/PBN copolymers appear from a crystal lattice which is governed only by the rich component between two different aliphatic units in the copolymer composition.

• Bulletin of the Korean Chemical Society
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• v.7 no.5
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• pp.353-357
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• 1986

Mutual miscibility between thermotropic, nematic compounds with two terminal mesogenic units and a central spacer was studied by differential scanning calorimetry (DSC) and on a polarizing microscope. It was found that the isomorphous, nematic dimesogenic compounds with wide variety of structures are miscible in mesophases with each other over the whole range of composition and that Schroder-van Laar equation almost correctly predicts the melting temperature and composition of eutectic mixtures. There was a pair of compounds which were exceptional and did not form a eutectic mixture and, instead, revealed a monotonous change in melting (T$_{m}$) and isotropic transition temperatures (T$_{i}$) as the composition of the mixture was varied. The compounds were of almost same structure in shape and seemed to undergo formation of solid solution.

• Korean Journal of Materials Research
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• v.8 no.11
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• pp.1011-1019
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• 1998

This work designed Sn-5%Pb-1.5%Ag-x%In solder alloy to develop the solder alloy with low Pb content. This solder alloy doesn't cause environmental pollution. and this study reviewed the probability of replacement of Sn-37%Pb solder as evaluation of melting range, wettability. microstructure, microhardne'ss, tensile strength, drossability of this new solder alloys. The level of international regulation in dissolution amount of Pb ion was 3ppm. But dissolution amount of Pb ion in Sn-5%Pb solder alloy confirmed not to threat the global environmental is 0.46ppm. The melting range of this solder alloy was $183-192^{\circ}C$. Also the range of solidification was very narrow within $5^{\circ}C$. The wettability was similar to Sn-37%Pb solder, and the effect of amount of In addition of wettability couldn't be founded. The probability of replacement in the melting range and wettability is very high. And microhardness of this solder alloy was 1.5 times of conventional type solder. Tensile strength of new solder alloys was a little high than that of conventional type solder. With increasing amount of In% addition, tensile strength was increased, but elongation was decreased. The solder alloy of l%In addition revealed AgSn and Pb on dendrite microstructure boundary, and $Ag_3Sn$, $Ag_3In$ and Pb were revealed on it at the solder alloy of 3% In addition. The drossability was superior to Sn-37%Pb solder alloy and the solder alloys of 2% In addition was not generated for 3hrs.