• Economic and Environmental Geology
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• v.45 no.5
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• pp.535-549
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• 2012

Main aspect of this study are to clarify mineral compositions on granites in Youngkwang-Naju area. These granites are is divided into four rock facies based on the geologic ages, mineralogical composition and chemical constituents, and texture : hornblende-biotite granodiorite, biotite granite, porphyritic granite and two mica granite. These granites constitude an igneous complex formed by a series of differentiation from cogenetic magma. In compressive stress field between the Ogcheon folded belt and the Youngnam massif, the foliated and undeformed granites had formed owing to heterogeneous distribution of stress. The geochemical data of study area indicate magma of these rocks would had been generated by melting in lower and middle crust. The major minerals of granitic rocks in study area are plagioclase, biotite, muscovite and hornblende. Plagioclase range in composition from oligoclase ($An_{19.3-27.7}$) to andesine ($An_{28.4-31}$), and shows normal zoning patterns, This uniformed composition indicated slow crystallization, and it is obvious that the growth of these crystal occurred before final consolidation of the magma. The Mg content of biotite are increases with increasing of $f_{O2}$ and grade of differentiation, changing from phlogopite to siderophyllite. Its $Al^{iv}$/$Al^{total}$ ratios are propertional to bulk rock alumina content. Muscovite is primary in origin with high content of $TiO_2$, and Its composition correspond to celadonitic muscovite. Hornblende indicated calc amphibole group ($(Ca+Na)_{M4}{\geq}1.43$, $Na_{M4}<0.67$). and consolidation pressure of granitic body by geobarometer of Hammerstrume and Zen show 11.3~17.2 Km.

• Applied Chemistry for Engineering
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• v.7 no.5
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• pp.970-976
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• 1996

An ester-carbonate copolymer was synthesized, in which carbonate was inserted into a biodegradable aliphatic polyester, poly(butylene succinate) (PBS), to modify its mechanical properties. The synthesis was carried out by condensation reactions in two steps. In the first step, oligo(butylene succinate) was prepared by the reaction of succinic acid with 1,4-butanediol (BD). In the second step, it was reacted with oligohexamethylenecarbonate diol (OHMCG) to prepare the ester-carbonate copolymer. Titanium(IV) isopropoxide (TIP) was used as a catalyst for the reaction. The structure of the copolymer was confirmed by FT-IR and $^1H$-NMR and the thermal behavior and mechanical properties were investigated by differential scanning calorimetry (DSC) and universal testing machine (UTM), respectively. It was found that optimum amount of the catalyst for the formation of high molecular weight copolymer was 1wt% for succinic acid. When the BD:OHMCG is in the range 149:1~249:1, the copolymer with high viscosity was obtained. As the OHMCG content was increased, melting temperature ($T_m$) of the copolymer was decreased. When BD:OHMCG is 149:1, the copolymer showed a increase in ultimate strain by two times and the slight decrease in modulus compared to those of PBS.

• Applied Chemistry for Engineering
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• v.26 no.5
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• pp.615-620
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• 2015

Polypropylene (PP)/bamboo fiber (BF) composites were fabricated by twin screw extruder in order to investigate effects of the compatibilizer on physical properties of PP/BF composites. The content of BF changed from 10 to 25 wt% and that of the compatibilizer was fixed at 3 wt%. Maleic anhydride grafted PP (PP-g-MAH) was used to increase the compatibility between PP and BF as a compatibilizer. Chemical structures of the composites were confirmed by the existence of carbonyl group (C=O) stretching peak at $1,700cm^{-1}$ in FT-IR spectrum. Considering the degradation and mechanical properties, the optimum extrusion conditions were selected to be $210^{\circ}C$ and 100 rpm, respectively. There was no distinct changes in melting temperature of the composites, but the crystallization temperature increased by $10-20^{\circ}C$ owing to the heterogeneous nuclei of BF. It was checked that the optimum BF content was in the range of 15-20 wt% from the results of tensile and flexural properties of the composites. The effect of the compatibilizer on mechanical properties was confirmed by SEM images of fractured surface and contact angles.

• Korean Journal of Materials Research
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• v.28 no.4
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• pp.254-259
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• 2018

General D-glass(Dielectric glass) fibers are adaptable to PCBs(Printed circuit boards) because they have a low dielectric constant of about 3.5~4.5. However, very few papers have appeared on the physical characteristics of D-glass fibers. D-glass fibers were fabricated via continuous spinning process using bulk D-glass. In order to fabricate the D-glass, raw materials were put into a Pt crucible, melted at $1650^{\circ}C$ for 2 hrs, and then annealed at $521{\pm}10^{\circ}C$ for 2 hrs. We obtained transparent clear glass. The transmittance and adaptable temperature for spinning of the bulk marble glass were characterized using a UV-visible spectrometer and a viscometer. Continuous spinning was carried out using direct melting spinning equipment as a function of the fiberizing temperature in the range of $1368^{\circ}C$ to $1460^{\circ}C$, while the winder speed was between 100 rpm and 200 rpm. We investigated the physical properties of the D-glass fibers. The average diameters of the glass fibers were measured by optical microscope and FE-SEM. The average diameters of the D-glass fibers were 21.36 um at 100 rpm and 34.06 um at 200 rpm. The mechanical properties of the fibers were confirmed using a UTM(Universal materials testing machine). The average tensile strengths of the D-glass fibers were 467.03 MPa at 100 rpm and 522.60 MPa at 200 rpm.

• Polymer(Korea)
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• v.29 no.2
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• pp.183-189
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• 2005

Films of poly(vinyl alcohol)(PVA)/chitosan blends and its blend hydrogels were prepared by the solution casting method. The state of miscibility of the blends and blend hydrogels were examined over the entire composition range by differential scanning carorimetry (DSC), thermogravimetry (TGA), and dynamic mechanical analysis (DMA). DSC analysis shows the depression of melting point of PVA in the blends and the decrease of crystallization temperature of PVA in the blends were observed with increasing chitosan content in the blends. TGA analysis indicates that chitosan was thermally more stable than PVA and the thermal stability of PVA in the blends was higher than that of pure PVA, due to some interactions between two component polymers in the blend. The glass transition temperature $(T_g)$ of the chitosan and of PVA, measured by DMA, were at 160 and $90^{\circ}C$, respectively. The $T_g$ of the blends was changed with the content of chitosan in the blends. The results of thermal and viscoelastic analysis indicate some miscibility between component polymers in the blend exists. Moisture and cross linking in the blend and blend hydrogel, which strongly change thermal and physical properties of hydrophilic polymers, affected the miscibility of chitosan and PVA to a small extent.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.17 no.2
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• pp.69-74
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• 2007

[ $0.6Pb(Sc_{1/2}Ta_{1/2})O_3-0.4PbTiO_3$ ] (hereafter PSTT) ceramics were prepared by the molten salt synthesis (MSS) method using KCI as a flux. Formation of perovskite phase was investigated by a differential thermal analysis (DTA) and X-ray diffraction (XRD) analysis in the temperature range from $600^{\circ}C$ to $850^{\circ}C$. A 92% perovskite phase was synthesized at $750^{\circ}C$ for 2 hrs using the MSS method, while 82% perovskite phase was synthesized at $850^{\circ}C$ for 4ks using the calcining of mixed oxide (CMO) method. This result could be due to the improvement in reactivity of $Sc_2O_3$ by melting of KCI. The MSS specimen sintered at $1,100^{\circ}C$ for 4hrs showed a dielectric constant of 11,200, a remnant polarization of $13.5{\mu}C/cm^2$ and a coercive field of 10.198 kV/cm, which was discussed in view of the microstructure.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.2
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• pp.595-600
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• 2020

The purpose of this paper was to prepare and evaluate solid dispersions (SD) that can increase the dissolution rate of dexibuprofen as a model drug with low solubility in water using saccharides and sugar alcohols as dispersion materials. DSC, XRD, content and content uniformity test, dissolution test, and disintegration test were conducted for physicochemical evaluation of the prepared SD. For the results, it was confirmed using differential scanning calorimetry that fructose, which has a melting point around 120 ℃ of the device operating temperature range, is a suitable excipient for the preparation of SD by the rotary hot-melt granulation (RHMG) method. X-ray diffraction analysis was conducted to confirm that the crystallinity of dexibuprofen was reduced. Disintegration test of the prepared tablet using SD-containing dexibuprofen and fructose confirmed a very fast disintegration time within 1~2 seconds and also showed that the dissolution rate was about 20% faster than that of the dexibuprofen raw material. Dexibuprofen with reduced crystallinity by SD confirmed through the RHMG method can be used to increase the dissolution rate of the drug and increase the disintegration time of the tablet. Thus, it can be used in the manufacturing of various solid preparations.

• Journal of Korean Ophthalmic Optics Society
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• v.16 no.1
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• pp.13-19
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• 2011

Purpose: The purpose of this study was to assess characterize overseas company's Cellulose acetate glasses frame sheets (overseas company's CA sheet) Also, the optimum content of plasticizer and melt extrusion condition of industrial CA resin were established for appropriate glasses frame. Methods: Overseas company's Cellulose acetate glasses frame sheets (overseas company's CA sheet) were characterized by $^1H$-NMR, GPC, and TGA. Also, the optimum content of plasticizer and melt extrusion condition of industrial CA resin were established. Results: The plasticizer of overseas company's CA sheet measured by $^1H$-NMR was diethyl phthalate, and its content was measured 30 wt% by TGA. Also, industrial CA resin showed enough melting behavior in the range of 190~200$^{\circ}C$. Compared to overseas company's CA sheet's tensile strength value of 2.2~2.8 kgf/$mm^2$, industrial CA resin exhibited sufficient tensile strength value of 2.3 kgf/$mm^2$ for glasses frame. Conclusions: Industrial CA resin with 30 wt% plasticizer content would be a promising material for glasses frame prepared by melt extrusion to replace China CA sheet.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.10
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• pp.1881-1891
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• 2000

Cenosphere particles of different fly ash formed at the pulverized coal power plant were hollow sphere or filled with small particles inside solid particles. And size was relatively larger than other fly ash particles as well as specific gravity was small to suspend in the water. In this paper, it was demonstrated to contain a variety of morphological particle type, and the physical and chemical properties related to the cenosphere and fly ash particles. Furthermore it was estimated the possibility to reuse the cenosphere particles on the base of cenosphere properties. Cenosphere formation resulted from melting of mineral inclusion in coal, and then gas generation inside the molten droplet. As the aluminosilicate particle was progressively heated, a molten surface layer developed around the solid core. Further heating leaded to cause the formation of fine particles at the core. The mass median diameter(MMD) of cenosphere particles was $123.11{\mu}m$ and the range of size distribution was $100{\sim}200{\mu}m$ with single modal. It was represented that specific density was $0.67g/cm^3$ fineness was $1135g/cm^3$. The chemical components of cenosphere were similar to other fly ash including $SiO_2$, $Al_2O_3$, but the amount of the chemical component was different respectively. In the case of fly ash, $SiO_2$ concentration was 54.75%, and $Al_2O_3$ concentration was 21.96%, so this two components was found in 76.71% of the total concentration. But in the case of cenosphere, it was represented that $SiO_2$ concentration was 59.17% and $Al_2O_3$ concentration was 30.16%, so this two components was found in 89.33% of the total concentration. Glassy component formed by the aluminosilicate was high in the cenosphere, so that it was suitable to use insulating heat material.

• Journal of Hydrogen and New Energy
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• v.16 no.2
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• pp.122-129
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• 2005

The characteristics of hydrogen storage have been investigated in the Ti-Cr-Mo and Ti-Cr-V ternary alloys with bcc structure. The alloys were melted by arc furnace and remelted 4-5 times for homogeneity. The lattice parameters, microstructures and phases of the alloys were examined by SEM, EDX and XRD, and the Pressure-Composition isotherms of the alloys were measured. From these data the relationship of the maximum and effective hydrogen storage capacities vs. chemical composition, lattice parameter and the radius of tetrahedral site were analyzed and discussed. The results showed that all of these alloy, in the range of the this study, had mainly bcc solid solutions with small amount of Ti segregation due to a lower melting point of Ti compared with other elements. Lattice parameters of the alloys were very near to the atomic average values of lattice parameters of the constituent elements. It was also found that maximum hydrogen storage capacities of the Ti-Cr-Mo alloys increased with increasing Ti content and the radius of tetrahedral site but the effective hydrogen storage capacities decreased after showing the maximum. The hydrogen storage capacities of the Ti-Cr-V alloys were almost same even though the V contens were quite different from alloy to alloy and this could be attributed to the almost same Ti/Cr ratio of the alloys. The maximum effective hydrogen storage capacity of the Ti-Cr-Mo alloys was revealed at Ti content of about 40${\sim}$50 at% and radius of tetrahedral site of 0.43${\sim}$0.45 nm. The Ti-Cr-V alloys showed the hydrogen storage capacities of 3.0 wt% and effective hydrogen storage capacities of 1.5 wt%.