• Title/Summary/Keyword: Melted slag

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An Study on Compressive Strength Properties of Mortar with Municipal Solid Waste Incineration Ash Melted Slag Powder (쓰레기 소각재 용융슬래그 미분말을 혼입한 모르타르의 압축강도 특성에 대한 연구)

  • Lee, Yong-Moo;Kim, Young-Su
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.1
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    • pp.53-58
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    • 2016
  • In order to investigate the feasibility of municipal solid waste incineration ash melted slag powder as admixture, an experimental study was performed on cement mortar with municipal solid waste incineration ash melted slag powder. Fresh mortar properties and strength properties with various municipal solid waste incineration ash melted slag powder replacement ratios were estimated. There replacement ratio adopted in this study was 0, 10, 20, 30, 40, 50%. After then flow properties was considered as properties of fresh mortar. And compressive strength was determined 3, 7, 14, 28, 56 days for the hardened mortar specimens. According to the test results, the flow of mortar was increased with in replacement amount of municipal solid waste incineration ash melted slag powder. Furthermore, compressive strength at early age was decreased, whereas the compressive strength at the age of 28, 56day was increased.

Feasibility of Powdered MSWI Ash Melted Slag as a Seed Crystal of crystallization reaction for the Removal of Phosphorus from Sewage (하수중 인제거를 위한 정석탈인반응의 정석재로서 소각분말 용융슬래그의 이용 가능성 평가)

  • Kim, Choong Gon;Shin, Hyun Gon;Kim, Seung Won
    • Journal of the Korea Organic Resources Recycling Association
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    • v.21 no.1
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    • pp.69-75
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    • 2013
  • This study is a fundamental research to test the applicability of powdered MSWI(Municipal Solid Waste Incinerator) ash melted slag as a seed Crystal for crystallization reaction. Powdered ash melted slag was melted at $1100^{\circ}C$ and ground to lesser than 0.35mm. According to the result of the tests, calcium, enough for crystallization reaction, was eluted from powdered ash melted slag. Moreover, sample(Phosphorus concentration is under 10 mg/L), more than 90% of Phosphorus can be removed. So we rectify the Phosphorus concentration to 100 mg/L. Alkalinity, being well known that it interferes crystallization reaction, effect was studied for synthetic solution(100 mg/L initial Phosphorus concentration, 50 mg/L calcium, pH 8, 1% powdered ash melted slag dosage). For this result, we know that Phosphorus removal is hindered by alkalinity. In addition, the effect of reaction temperature was performed at the same method. The reaction velocity was increased through raising the reaction temperature.

A Transient Modeling of Temperature Variation in a Melting Furnace of a Pyrolysis Melting Incinerator (열분해 용융소각로 내 용융로에서의 온도변화에 대한 과정론적 모델링)

  • Kim, Bong-Keun;Yang, Won;Yu, Tae-U
    • 한국연소학회:학술대회논문집
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    • 2006.04a
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    • pp.167-171
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    • 2006
  • The previous models for thermal behavior in the melting furnace were deterministic, composed of such a form that if the initial input conditions are determined, the results would have been come out by using the basic heat equilibrium equations. But making the experiment by trusting the analysis results, the melted slag is fortuitously set often, because temperature variation of the melted slag in the reaction process is not point function but path function. So in this study, a transient model was developed and verified by comparing with the experimental results.

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An Experimental Study on the Freezing and Thawing of Concrete Mixed with Steel Slag (제강 슬래그를 이용한 콘크리트의 동결융해에 대한 실험적 연구)

  • 정원섭;조성현;권기주;박성우;김진만
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.48-53
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    • 2003
  • The steel slag, a by-product which is produced on the process of manufacturing steel by refining pig iron is mainly used as road materials after aging it. It is necessary to age steel slag for long time in air because the reaction with water and free-CaO in steel slag could make the volume expanded. Due to this reason it prevents steel slag from being used as aggregate of concrete. But steel slag used in this study is controled by a air-jet method which rapidly cools substance melted at a high temperature. Rapid cooling prevents from generating of free-CaO in steel slag. In this study, it was investigated that steel slag manufactured by air-jet method affects on concrete in the freezing and thawing. As results of this study, concrete mixed with steel slag was worse in the freezing and thawing than concrete mixed with sand in spite of using air entraining agent. To obtain durability of concrete in the freezing and thawing, it is desirable to mix 50% of steel slag in concrete per unit weight of volume.

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Properties of Mortar Using Steel Slag Fine Aggregate (제강슬래그 잔골재를 사용한 모르타르 특성)

  • 조성현;한기석;박성우;권기주;오상윤;김진만
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.217-222
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    • 2003
  • The steel slag, a by-product which is produced during the manufacture of steel by refining pig iron, is mainly used as road materials after aging it. It is necessary to age steel slag for long time in air because the reaction with water and free-CaO in steel slag could make the expansion of volume. This problem prevents steel slag from being used as aggregate for concrete. But steel slag used in this study was controled by an air-jet method which rapidly cools substance melted at a high temperature. Rapid cooling prevents from generation of free-CaO in steel slag. In this study, properties of steel slag manufactured by air-jet method and mortar used it were investigated. As results of this study, free-CaO contents were controled under 1%. Mortar used this steel slag demanded to lower water contents, higher compressive strength and lower drying shrinkage than the basic mortar in the same condition.

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Study on the Remelting of Titanium Scrap by DC-ESR Process (DC-ESR법(去)을 이용한 타이타늄 스크랩의 재용융(再熔融)에 관한 연구(硏究))

  • Seo, Yeung-Deuk;Lee, Ho-Seong;Sohn, Ho-Sang
    • Resources Recycling
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    • v.16 no.4
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    • pp.33-39
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    • 2007
  • Titanium scrap was re-melted and refined by using a DC-ESR (Direct Current Electro Slag Remelting) apparatus. A graphite rod was used as an anode. The used slag was $CaF_2-TiO_2-CaO$ slag system. The effect of slag composition on the shape and oxygen content of re-melted ingot was studied. The titanium ingot was produced very well from the $CaF_2-TiO_2$ slag system, and the oxygen content of the ingot was less than that of titanium scrap. The addition of CaO into $CaF_2-TiO_2$ slag system made the bad shape of titanium ingot. The oxygen content of the ingot was also higher than that of titanium scrap.

Structure and Properties of Fe-29Ni-17Co Alloy Manufactured by Air Induction Melting and Electro-Slag Remelting (AIM 및 ESR 법에 의해 제조한 Fe-29Ni-17Co 합금의 조직 및 성질)

  • Lee, Jeong-Keun;Kim, Moon-Hyun;Joo, Dae-Heon;Kim, Myung-Ho
    • Journal of Korea Foundry Society
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    • v.22 no.4
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    • pp.160-166
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    • 2002
  • The structure and properties of Fe-29Ni-17Co alloy which had been melted using induction furnace in air atmosphere and than electroslag-remelted were investigated. The oxygen content was reduced to 0.03% when the ingot was refined from $0.09{\sim}0.12%$ of that air melted. The amounts of spheroidal oxides inclusions and gas porosities of ingot were markedly reduced by the ESR process. CTE of ESR ingot contained small amount of oxides and porosities was found to be lower than that of AIM ingot, and tensile properties of ESR ingot and plate were found to be superior than that of AIM ingot and plate.

Refining of Invar and Permalloy Fe-Ni Alloys by $Ar/Ar-H_2$ Plasma and Electron Beam Melting (Ar/Ar-$H_2$ 플라즈마 및 전자선 용해에 의한 인바 및 퍼멀로이 Fe-Ni 합금의 정련)

  • Park, Byung-Sam;Baik, Hong-Koo
    • Journal of Korea Foundry Society
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    • v.15 no.2
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    • pp.175-183
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    • 1995
  • It is difficult to remove such interstitial impurities as sulfur, oxygen, hydrogen and carbon in Fe-Ni alloys. Thermodynamic and kinetic studies were carried out on the behavior of hydrogen gas, oxygen gas, Si, Al and slag, and the reaction time by the $Ar/Ar-H_2$ plasma and electron beam melting. After the addition of Al, Si, they were melted by Ar plasma with reaction time changed. 80%Ni-Fe alloys showed a better deoxidation than 36%Ni-Fe alloys. At $Ar-H_2$ plasma melting, the deoxidation was significant. In the case of the electron beam melting, the residual oxygen was higher than in Ar plasma melting because electron beam melting temperature was lower than that of Ar plasma. For the decaburization, it was melted by $Ar-O_2$ plasma melting, which could remove effectively carbon by activated oxygen in plasma. We added slag to Fe-Ni alloys for the desulfurization. As the result of this experiments, the amount of residual sulfur was not changed according to the slag ratio and reaction time.

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An Experimental Study on the fluidity properties of Polymer Concrete According to Replacement Ratio of Rapidly-Chilled Steel Slag and polymer resin (급냉 제강 슬래그 대체율과 폴리머 수지에 따른 폴리머 콘크리트의 유동특성에 관한 실험적 연구)

  • Choi, Duck-Jin;Kim, Jae-Won;Sun, Joung-Soo;Kim, Ha-Suk;Hwang, Eui-Hwan;Kim, Jin-Man
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2007.11a
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    • pp.75-78
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    • 2007
  • The steel slag, a by-product which is produced by refining pig iron during the manufacture of steel, is mainly used as road materials after aging. It is necessary to age steel slag for long time in air because the reaction with water and free-CaO in steel slag could make the expansion of volume. This problem prevents steel slag from being used as aggregate for concrete. However, steel slag used in this study was controled by a air-jet method which rapidly cools substance melted at a high temperature. The rapidly-chilled method would prevent from generation of free-CaO in steel slag. Also, Molten steel slag rapidly-chilled by air in high speed becomes a fine aggregate of nearly spherical shape. This study dealt with the influence of the using rate of rapidly-chilled steel slag and polymer resin on fluidity of polymer concrete, as a results Since RCSS has spherical shape and high density, up to replacement ratio of 100%, increases concrete fluidity under same polymer content and decrease polymer content in order to secure the same fluidity

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A Study on the Replacement of a Light Burnt Dolomite with a Waste MgO-C Refractory Material for a Steel-Making Flux in Electric Arc Furnace (폐 MgO-C계 내화재의 전기로(EAF) 제강 Flux용 경소돌로마이트 대체 사용 연구)

  • Hyun-Jong Kim;Jong-Deok Lim;Hang-Goo Kim;Jei-Pil Wang
    • Resources Recycling
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    • v.31 no.6
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    • pp.44-51
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    • 2022
  • In the steelmaking process using an electric arc furnace (EAF), light-burnt dolomite, which is a flux containing MgO, is used to protect refractory materials and improve desulfurization ability. Furthermore, a recarburizing agent is added to reduce energy consumption via slag foaming and to induce the deoxidation effect. Herein, a waste MgO-C based refractory material was used to achieve the aforementioned effects economically. The waste MgO-C refractory materials contain a significant amount of MgO and graphite components; however, most of these materials are currently discarded instead of being recycled. The mass recycling of waste MgO-C refractory materials would be achievable if their applicability as a flux for steelmaking is proven. Therefore, experiments were performed using a target composition range similar to the commercial EAF slag composition. A pre-melted base slag was prepared by mixing SiO2, Al2O3, and FeO in an alumina crucible and heating at 1450℃ for 1 h or more. Subsequently, a mixed flux #2 (a mixture of light-burnt dolomite, waste MgO-C based refractory material, and limestone) was added to the prepared pre-melted base slag and a melting reaction test was performed. Injecting the pre-melted base slag with the flux facilitates the formation of the target EAF slag. These results were compared with that of mixed flux #1 (a mixture of light-burnt dolomite and limestone), which is a conventional steelmaking flux, and the possibility of replacement was evaluated. To obtain a reliable evaluation, characterization techniques like X-ray diffraction (XRD) analysis and X-ray fluorescence (XRF) spectrometry were used, and slag foam height, slag basicity, and Fe recovery were calculated.