• Korean Chemical Engineering Research
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• 제55권4호
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• pp.561-566
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• 2017

폴리머 재질의 관을 융착 시키기 위해서는 버트 융착 공정을 거치는데, 최근 융착면에 굴곡을 주어 융착 강도를 높이고자 하는 시도가 있었다. 본 연구에서는 융착면의 굴곡이 폴리머의 열유체 거동 및 융착 강도에 어떠한 영향을 미칠 것인지 2차원 축대칭 평면에서 유한요소법을 사용하여 살펴보았으며, 고밀도폴리에틸렌 관을 대상으로 하였다. 열유화 단계에서 융착면의 형상을 따라 굴곡진 상경계면이 나타남을 확인할 수 있었다. 접합 단계에서는 굴곡진 상경계면과 융착면 사이에서의 멜트의 압착 흐름이 나타남을 확인할 수 있었으며, 굴곡융착부의 낮은 전단율은 관의 축과 수직 방향 배향을 완화시켜 융착부 강도 향상에 도움을 줄 수 있을 것으로 예상된다.

• Nuclear Engineering and Technology
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• 제55권8호
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• pp.3017-3029
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• 2023

In the late in-vessel phase of a nuclear reactor severe accident, the internal heat transfer and crust evolution during the debris bed melting process have important effects on the thermal load distribution along the vessel wall, and further affect the reactor pressure vessel (RPV) failure mode and the state of melt during leakage. This study coupled the phase change model and large eddy simulation to investigate the variations of the temperature, melt liquid fraction, crust and heat flux distributions during the debris bed melting process in the hypothetical severe accident of HPR1000. The results indicated that the heat flow towards the vessel wall and upper surface were similar at the beginning stage of debris melting, but the upward heat flow increased significantly as the development of the molten pool. The maximum heat flux towards the vessel wall reached 0.4 MW/m². The thickness of lower crust decreased as the debris melting. It was much thicker at the bottom region with the azimuthal angle below 20° and decreased rapidly at the azimuthal angle around 20-50°. The maximum and minimum thicknesses were 2 and 90 mm, respectively. By contrast, the distribution of upper crust was uniform and reached stable state much earlier than the lower crust, with the thickness of about 10 mm. Moreover, the sensitivity analysis of initial condition indicated that as the decrease of time interval from reactor scram to debris bed dried-out, the maximum debris temperature and melt fraction became larger, the lower crust thickness became thinner, but the upper crust had no significant change. The sensitivity analysis of in-vessel retention (IVR) strategies indicated that the passive and active external reactor vessel cooling (ERVC) had little effect on the internal heat transfer and crust evolution. In the case not considering the internal reactor vessel cooling (IRVC), the upper crust was not obvious.

• 대한치과재료학회지
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• 제45권4호
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• pp.311-320
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• 2018

본 연구의 목적은 서로 다른 온도 설정을 받았을 때 열가소성 가타퍼차의 흐름성 특성을 평가 해보고자 현재 임상에서 사용되는 가타퍼차 4개 제품을 연질, 중질, 경질로 분류하여 실험하였으며, 실험시편은 24시간 동안 $(23{\pm}2)^{\circ}C$, ($50{\pm}5$) % 상대습도 조건으로 하여 ISO 1133-1:2011의 제시에 따라 레오미터(Melt flow indexer MFI-10, DAVENPORT, England)로 측정했다. 가타퍼차 재료의 열화 온도는 $108^{\circ}C$, $160^{\circ}C$, $200^{\circ}C$의 온도로 하고 하중은 2.16 ㎏, 3.8 ㎏으로 설정했으며 시편은 레오미터 가압과정에 적합하도록 약 5 mm 단위로 잘랐으며, Preheating time 5 분, Cutting time은 5~240초, 샘플은 10 g 으로 하여 실험한 결과 $108^{\circ}C$, $160^{\circ}C$의 온도에서는 흐름성 성질에 변화가 없었으나 $200^{\circ}C$까지 열화하면 흐름성 성질이 변화되는 것으로 나타났다. 가압 하중은 2.16 ㎏과 3.8 ㎏으로 하여 측정한 결과 하중은 흐름성 특성에 영향을 미치지 않았으나 열가소성 가타퍼차의 흐름성 측정의 경우 온도와 Cut-off time의 설정이 매우 중요한 것으로 조사 되었다.

• Macromolecular Research
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• 제17권2호
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• pp.110-115
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• 2009

The electrical, morphological and rheological properties of melt and dry mixed composites of poly ethylene (PE)/graphite (Gr), polypropylene (PP)/Gr and PP/nickel-coated carbon fiber (NCCF) were investigated as a function of filler type, filler content and processing temperature. The electrical conductivities of dry mixed PP/NCCF composites were increased with decreasing processing temperature. For the melt mixed PP/NCCF composites, the electrical conductivities were higher than those of the melt mixed PE/Gr and PP/Gr composites, which was attributed to the effect of the higher NCCF aspect ratio in allowing the composites to form a more conductive network in the polymer matrix than the graphite does. From the results of morphological studies, the fillers in the dry mixed PP/NCCF composites were more randomly dispersed compared to those in the melt mixed PP/NCCF composites. The increased electrical conductivities of the dry mixed composites were attributed to the more random dispersion of NCCF compared to that of the melt mixed PP/NCCF composites. The complex viscosities of the PP/Gr composites were higher than those of the PP/NCCF composites, which was attributed to the larger diameter of the graphite particles than that of the NCCF. Furthermore, the fiber orientation in the 'along the flow' direction during melt mixing was attributed to the decreased complex viscosities of the melt mixed PP/NCCF composites compared those of the melt mixed PP/Gr composites.

• Design & Manufacturing
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• 제6권2호
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• pp.31-36
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• 2012

Now days CAE has been used for almost all injection molding designs in order to find the best injection conditions. Almost all CAE use 2-D mesh, but the CAE with 2-D mesh can't indicate such as jetting, flow-mark and filling imbalance in multi cavity mold. In this study, we suggested a new 3D meshing. the method which can indicate the filling imbalance in geometrically balanced runner system with Mold Flow MPI 6.1 and we found out that the calculation times are saved. As a feasibility study, we verified that Melt Flipper, RC Pin etc appeared the balanced filling behaviors. of geometrically balanced runner system and Melt Flipper, filling imbalance was indicated more accurately.

• 한국금형공학회:학술대회논문집
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• 한국금형공학회 2008년도 하계 학술대회
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• pp.121-127
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• 2008

Nowdays CAE has been used for almost all injection molding designs in order to find the best injection conditions. Almost all CAE use 2-D mesh, but the CAE with 2-D mesh can't indicate such as jetting, flow-mark and filling imbalance in multi cavity mold. In this study, we suggested a new 3D meshing. the method which can indicate the filling imbalance in geometrically balanced runner system with Mold Flow MPI 6.1 and we found out that the calculation times are saved. As a feasibility study, we verified that Melt Flipper, RC Pin etc appeared the balanced filling behaviors. of geometrically balanced runner system and Melt Flipper, filling imbalance was indicated more accurately.

• 대한기계학회논문집B
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• 제35권4호
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• pp.425-429
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• 2011

원자로의 노심 손상에 따른 노심 용융물의 노외 유출시 코어캐처라고 불리는 설비를 통해 용융물을 억제하고 냉각시키게 된다. 이 때 노외 노심용융물의 거동은 희생물질과의 반응을 포함한 복잡한 물리적, 화학적 현상에 의해 결정된다. 이 연구는 기존의 용융물 거동 실험결과에 대해 용융물의 유동과 열전달의 세부적인 특성을 상용코드를 이용해 해석하여 검증함으로써 코어캐처의 설계에 활용할 수 있도록 하기 위한 것이다. 단순화된 채널에서 시간에 따른 용융물과 공기의 이상유동과 복사열전달을 VOF 모델과 구분종좌법을 적용하여 비정상상태에서 해석한 결과, 열전달에 따른 용융물 내부의 온도 변화 및 이에 따른 점성 변화 등을 예측할 수 있음을 확인하였다. 이러한 접근방식을 기초로 향후 용융물의 조성, 유량 및 용도 등의 조건에 따른 용융물의 거동에 대한 자세한 평가가 필요하다.

• 대한기계학회논문집B
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• 제20권3호
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• pp.988-1004
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• 1996

The characteristics of flow and oxygen concentration are numerically studied in Czochralski 8" silicon crystal growing process considering radiative heat transfer. The analysis of net radiative heat flux on all relevant surfaces shows growing crystal affects the heater power. Furthermore, the variation of the radiative heat flux along the crystal surface in the growing direction is confirmed and should be a cause of thermal stress and defect of the crystal. The calculated distributions of temperature and, heat flux along the wall boundaries including melt/crystal interface, free surface and crucible wall indicate that the frequently used assumption of the thermal boundary conditions of insulated crucible bottom and constant temperature at crucible side wall is not suitable to meet the real physical boundary conditions. It is necessary, therefore, to calculate radiative heat transfer simultaneously with the melt flow in order to simulate the real CZ crystal growth. If only natural convection is considered, the oxygen concentration on the melt/crystal interface decreases and becomes uniform by the application of a cusp magnetic filed. The heater power needed also increases with increasing the magnetic field. For the case of counter rotation of the crystal and crucible, the magnetic field suppresses azimutal flow produced by the crucible rotation, which results in the higher oxygen concentration near the interface.

• Elastomers and Composites
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• 제48권1호
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• pp.39-45
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• 2013

Haake Rheocorder로 각종 과산화물 개시제를 사용하여 ethylene-propylene-diene terpolymer (EPDM)에 단량체 citraconic acid (CCA)을 용융 그라프트 중합을 하여 그라프트 중합물 CCA-g-EPDM을 얻었으며, 이때 효율적인 그라프트 정도와 우수한 성능을 지닌 그라프트 중합물을 얻기 위해서 최적의 반응조건과 최적의 단량체/개시제 농도를 찾는 것은 매우 중요하다. 따라서 본 연구에서는 반응조건과 단량체 및 개시제 함량이 CCA-g-EPDM의 그라프트 정도, 그라프트 효율, 가교정도 (겔화도), 용융흐름지수(MI) 및 기계적 물성 등에 미치는 영향에 초점을 맞추었다. 그라프트 정도와 가교도가 증가함에 따라서 인장강도는 상당히 증가한 반면, 파괴신도 및 MI는 감소하였다. 개시제 중에서 2,5-dimethyl-2,5-di(tert-butyl peroxy)-hexane (T-101)가 가장 우수한 그라프트 정도 (2.31%)를 나타내었으며, CCA와 T-101의 함량이 증가함에 따라 그라프트 정도가 크게 증가하였다. 그리고 그라프트 정도는 반응(혼합)온도 및 반응시간이 증가함에 따라 역시 증가하다가 어느 온도/시간 이상에서는 안정화 혹은 약간 감소하는 경향을 나타내었다. 이러한 영향으로 결과로부터 최적의 단량체/개시제 농도는 5/0.05 wt%이었으며, 최적의 반응온도/시간은 $180^{\circ}C$/15분인 것을 알 수 있었다.

• 한국세라믹학회지
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• 제46권3호
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• pp.229-233
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• 2009

This study has focused on manufacturing technique of powder injection molding of watch case made from zirconia powder. A series of computer simulation process was applied to prediction of the flow pattern in the inside of the mould to clarifying the change of sintering shrinkage depended on flow direction. The material properties of melted feedstock inclusive of the PVT graph and thermal viscosity flowage properties were measured for obtaining the input data in computer simulation. Also, molding experiment was conducted and the results of experiment showed that good agreement with simulation results for flow pattern and weld line location. On the other hand, gravity and inertia effect have an influence on velocity of melt front because of high density of ceramic powder particles in powder injection molding against the polymer injection molding process. In the experiment, the position of melt front was compared with upper gate and lower gate position. The gravity and inertia effect could be confirmed in the experimental results.