• Title/Summary/Keyword: Melamine resin

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Preparation of melamine-formaldehyde microcapsule by surfactants (안정화제에 따른 멜라민-포름알데히드 마이크로캡슐의 제조)

  • Oh, Seong-Dae;Choi, Seong-Ho;Lee, Se-Hee;Lee, Kwang-Pill;Kim, Sang-Ho
    • Analytical Science and Technology
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    • v.18 no.2
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    • pp.97-103
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    • 2005
  • The various size and morphology microcapsules were prepared to produce smell sweet by heating condensation reaction of melamine and formaldehyde using 5-types of surfactants such as the laurylbenzenesulfonic acid sodium salt (SDS), polyvinylpyrrolidon (PVP), polyvinyl alcohol (PVA), Span-80 and 2-acrylamido-2-methyl-1-1 propanesulfonic acid (AMP). As result it was found that the size and morphology of microcapsule is intimately associated with a kind of surfactants. In order to prepare microcapsule with antibacterial, the silver nanoparticle was prepared by gamma-irradiation. microcapsule with silver nanoparticle was prepared.

Curing Reaction and Physical Properties of Acrylic High-Solid Coatings (아크릴계 하이솔리드 도료의 경화반응과 도막물성)

  • Park, Hyong-Jin;Kim, Sung-Rae;Jung, Choong-Ho;An, Chong-Il;Park, Hong-Soo;Kim, Tae-Ok
    • Journal of the Korean Applied Science and Technology
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    • v.18 no.4
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    • pp.261-272
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    • 2001
  • An ACR/HMMM film was prepared by blending high-solid ACR with curing agent, hexamethoxymethyl melamine (HMMM). An active curing reaction was observed at $170^{\circ}C$. The dynamic viscoelastic $T_{g}$ of the final film increased with the static viscoelastic $T_{g}$ of the film. The log damp value, which means a viscoelastic ratio, decreased with the increase in the curing temperature of the film. Physical properties of the films were within a suitable range for films, and by an accelerated weathering resistance test the films were proved weather resistible ones.

A Study on the Durable Press Finish by Wet-Fixation Processes for Rayon Fabrics (I) - One Bath and Two Bath Processes - (레이온 직물의 Wet-Fixation에 의한 DP가공에 관한 연구(I) - 일욕법과 이욕법의 비교 -)

  • Hu Yoon Sook;Kim Eun Ae
    • Journal of the Korean Society of Clothing and Textiles
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    • v.13 no.3 s.31
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    • pp.242-251
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    • 1989
  • The purpose of this study was to investigate the changes in easy-care and strength properties of the wet fixation processed viscose rayon fabrics. Rayon fabrics were treated with mixed resins of melamine formaldehyde (MF) and DMDHEU by one bath and two bath wet fixation processes. The MF/DMDHEU mixed resin concentrations were 50/100, 50/150, 100/100, 100/150 and 150/100(g/1). Magnasium chloride was used as a catalyst. Treated fabrics were evaluated by nitrogen content, DP rating, wrinkle recovery angle, breaking strength, tearing strength and abrasion resistance. The properties were compared to the fabrics treated by conventional Pad-Dry-Cure (PDC) method. Wet fixation processed fabrics showed DP ratings of higher than 3 and higher than 275 degrees of wrinkle recovery angles in all the mixed resin concentrations. Wet fixation processed fabrics showed increase in breaking strength and tearing strength but decrease in abrasion resistance. However, the decrease in abrasion resistance was much less than the conventional PDC treated fabrics. The one bath wet fixation processed fabrics showed better physical properties than the two bath processed fabrics in general. The optimum treatment condition was the mixed resin concentration of MF/DMDHEU, 100/100 g/l in one bath wet fixation process.

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The Study on the Development of Environmental-friendly Surface Material Using Condensed Tannin (축합형 탄닌을 이용한 친환경 건축마감재 개발에 관한 연구)

  • Jo, Jae-Min;Park, Moon-Soo;Chung, Kyung-Ho
    • Elastomers and Composites
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    • v.45 no.3
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    • pp.199-205
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    • 2010
  • Medium-density fiberboard (MDF) is widely used as an indoor building materials. However, formaldehyde resins, commonly used to bind MDF together, emit formaldehyde and other volatile organic compounds that cause health risk at sufficient concentration. In this study, condensed tannin having formaldehyde absorption ability was used to solve the problem of formaldehyde emission generated from surface material. The synthesis of melamine-formaldehyde resin and reaction of melamine-formaldehyde and condensed tannin were analyzed by FT-IR spectrum. Also surface properties, such as shear force, impact strength, tape adhesion, pencil hardness and gloss retention were measured. Free formaldehyde analysis was performed to analyze remaining unreacted formaldehyde. According to the results, the optimum shear force and impact strength could be obtained by 10 wt.% usage of condensed tannin. In cases of pencil hardness and gloss retention, the optimum properties could be obtained at 20 wt.% of condensed tannin. The amounts of formaldehyde emission of surface material containing 20 wt.% of condensed tannin was 59 ${\mu}g/m^2{\cdot}h$. The amounts of formaldehyde emission could be reduced 3 times by using 20 wt.% of condensed tannin.

The study about the property of flame retardant of Red Phosphorus (홍인의 방염성에 관한연구)

  • Han, Yeon-Sun;Gu, Gang
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2008.04a
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    • pp.31-33
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    • 2008
  • The study related that Red Phosphorus is surface coated by Al(OH)$_3$ using the proportion 1:1, 1:3, 1:5 respectively, and then take the coated red phosphorus as the core material, at the same time, use Melamine-Formaldehyde resin as the capsule materials for microcapsule processing. According to the TG analysis, the coated red phosphorus with the proportion 1:3 has the tiptop temperature of thermal decomposition, it reaches 376.20^{\circ}C$$. The same to the ratio of burning incomplete carbon it reaches 26.5%. The lowest moisture absorption ratio of the red phosphorus that used coated red phosphorus for microcapsule processing can reach 0.5% with the condition that thermal decomposition temperature decline 3.6%.

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A Study on Physical Properties of Epoxy Adhesives Modified with Polybutadiene Rubber (Polybutadiene 고무 변성 에폭시 접착제의 물성에 관한 연구)

  • Hong, Suk-Pyo;Choi, Sang-Goo
    • Elastomers and Composites
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    • v.26 no.3
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    • pp.193-201
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    • 1991
  • Epoxy resin and CTBN(carboxyl terminated butadiene acrylonitrile) rubber were reacted at $150^{\circ}C$. Epoxy mixtures containing reactant in a ratio $0{\sim}75%(wt%)$ of total liquid component were with dicyandiamide(DICY) at $130{\sim}200^{\circ}C$. Cure, thermal and adhesive properties were investigated in relation to rubber content, cure temperature, hardner content and promoter content. $CTBN{\times}13$ showed better properties in miscibility, curing time and adhesive strength. 2PZ-CNS was more excellent in Tg, and melamine was in adhesive strength. Adhesive strength represented best at rubber content $12{\times}15%$.

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Low Hysteresis Organic Thin Film Transistors with Modified Photocrosslinkable Poly (4-vinylphenol)

  • Kim, Doo-Hyun;Kim, Hyoung-Jin;Kim, Byung-Uk;Kim, We-Yong;Kim, Ho-Jin;Hong, Mun-Pyo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.563-565
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    • 2009
  • We introduce the new modification approaches of photocrosslinkable poly (4-vinylphenol) (PVP) for low hysteresis organic thin film transistors (OTFTs). The dielectric layers were composed of different PVP resin, low molecular melamine, and halogen free photo-initiator. The low hysteresis OTFT from one of the organic gate dielectrics has been realized. The electrical performance of low hysteresis OTFT with photocrosslinkable PVP exhibited a field-effect mobility of 0.2 cm2/Vs, a threshold voltage of - 0.04V, hysteresis of 0.4V.

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Porosity and Abrasion Resistance of Concrete Coated by Surface enhanced type Water Repellent (표면강화형흡수방지재 적용 콘크리트의 기공률 및 내마모성 특성)

  • Park, Myungju;Noh, Jaeho;Lee, Byungjae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.4
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    • pp.31-36
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    • 2019
  • Concrete is a material generally used to build structures and it is exposed to various environment conditions. In particular, a medium such as water lets noxious factors flow into concrete, causing a lot of damage. Therefore, different kinds of materials are being developed to increase the durability of concrete. Among such materials, silane and siloxane compound are known to have a high utilization as an absorption inhibitor. However, if aged or deteriorated reinforced concrete is treated with those compounds, they easily come off the concrete and lose their function since the basic material is weak. This study conducted an experiment to provide concrete with both an absorption-inhibiting effect and surface strengthening by using melamine-formaldehyde resins that are surface-treated with siloxane compound. In addition, a study on the porosity and surface hardness characteristics of a concrete was conducted to check the absorption-inhibiting effect and surface strengthening.

Preparation and application of the functionalized Shampoo with core-shell microcapsule (코아-쉘 마이크로 캡슐을 이용한 기능성 샴푸의 제조 및 응용)

  • Seo, Mi-Young;Kim, Eun-Ji;Kim, In-Kyoung;Choi, Seong-Ho
    • Journal of Advanced Technology Convergence
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    • v.1 no.1
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    • pp.7-13
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    • 2022
  • In this study, we prepared the functionalized Shampoo with three-type functionalized microcaples which were synthesized by microcapsulation, respectively. In detail, the functionalized microcapsule was included such as (1) the functionalized microcapsule with core-menthol and shell-melamine resin and (2) the functionalized microcapsule with core-menthol and shell-lecithin, and (3) the functionalized microcapsule with core-cinnamon oil and shell-lecithin, respectively. The size and morphology of the prepared microcapsules was evaluated via Optical Microscopy (OM), Scanning Electron Microscopy (SEM) and Dynamic Light Scattering (DLS). From these results, the prepared microcapsules with size of 0.1~0.2 ㎛ and spherical morphology was confirmed. Furthermore, we applied the prepared Shampoo to treat hair. As results we confirmed that the scalp temperature was decreased about 3~4 ℃ compared to no treatment. This result may be considered that the core compounds are vaporize when the functionalized Shampoo is treated on scalp. We will determine the change of scalp pore, diameter of hair, and etc during treatment of the functionalized Shampoo.

Cryogenic Mechanical Characteristics of Laminated Plywood for LNG Carrier Insulation System (LNG운반선 방열시스템에 적용되는 적층형 플라이우드의 극저온 기계적 특성 분석)

  • Kim, Jeong-Hyeon;Park, Doo-Hwan;Choi, Sung-Woong;Lee, Jae-Myung
    • Journal of Ocean Engineering and Technology
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    • v.31 no.3
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    • pp.241-247
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    • 2017
  • Plywood, which is created by bonding an odd number of thin veneers perpendicular to the grain orientation of an adjacent layer, was developed to supplement the weak points such as contraction and expansion of conventional wood materials. With structural merits such as strength, durability, and good absorption against impact loads, plywood has been adopted as a structural material in the insulation system of a membrane type liquefied natural gas (LNG) carrier. In the present study, as an attempt to resolve recent failure problems with plywood in an LNG insulation system, conventional PF (phenolic-formaldehyde) resin plywood and its alternative MUF (melamine-urea-formaldehyde) resin bonded plywood were investigated by performing material bending tests at ambient ($20^{\circ}C$) and cryogenic ($-163^{\circ}C$) temperatures to understand the resin and grain effects on the mechanical behavior of the plywood. In addition, the failure characteristics of the plywood were investigated with regard to the grain orientation and testing temperature.