• Journal of the Korean Wood Science and Technology
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• v.32 no.2
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• pp.65-72
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• 2004

A melamine-urea-formaldehyde (MUF) resin, based on 5 percent melamine addition of the resin solids weight, was synthesized in the laboratory for particleboard (PB) manufacture. Laboratory PBs were made with the MUF resin at three press times (3, 4, 5 min) and two resin application rates (6, 8 percent). Enclosed caul system was used for collecting the exhaust gases materials generated during the hot-pressing of PBs. Exhaust gases materials generated inside the enclosed caul during the hot-pressing of PBs were collected in a controlled air stream. Formaldehyde from the exhaust gases collected was determined per a chromotropic method of the National Institute of Occupational Safety and Health Method 3500. The measurement results showed that formaldehyde emissions during the hot-pressing of PB significantly increased with increasing press time, and MUF resin application rates. PB' performance test results showed that internal bond (IB) of PB made with 3-minute press time exceeded the minimum requirement for KS F 3104 PB type 8.0.

• Molecular & Cellular Toxicology
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• v.5 no.3
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• pp.243-249
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• 2009

Melamine, which is used to produce melamine resin for various industrial applications, has a high nitrogen content by mass. For this reason, it has been illegally added to foods to increase their apparent protein content. In the present investigation, melamine-induced oxidative damage of human lymphocyte DNA was evaluated by Comet assay. The in vitro oxidative DNA damage caused by melamine increased in a dose-dependent manner. This DNA damage was significantly inhibited by treatment with ascorbate. Moreover, the traditional Korean medicinal herb, named Acanthopanax, red ginseng and green tea markedly reduced the DNA damage. Various edible plant extracts also inhibited melamine-induced oxidative DNA damage in vitro. Melamine enhanced intracellular ROS generation, and this effect was suppressed by treatment with various antioxidants.

• Journal of Korean Society of Forest Science
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• v.94 no.6
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• pp.476-480
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• 2005

Agricultural straws such as rice and barley were used as partial replacement of raw materials for particleboard (PB) manufacture. A melamine-urea-formaldehyde (MUF) resin, based on 5 percent melamine addition of the resin solids weight, was synthesized in the laboratory for the bonding of PB. PBs were made using two straw particles based on 10, 20, 30, 40% oven dry weight addition with MUF resin. PBs were tested for physical and mechanical properties, and water soak dimensional stability. The results indicated that as rice and barley straws addition level were increased, the properties of IB, MOR and dimensional stabilities such as thickness swell and water absorption were decreased. Overall, the agricultural straws can be used at 15% substitution of raw materials for PB manufacture.

• Journal of the Korean Wood Science and Technology
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• v.33 no.2 s.130
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• pp.29-39
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• 2005

Formaldehyde emissions from wood-based panels bonded with pine and wattle tannin-based adhesives, urea-formaldehyde resin (UF), melamine-formaldehyde resin (MF), and co-polycondensed resin of urea-melamine-formaldehyde (UMF) were measured by the Japanese standard method using a desiccator (JIS A 1460) and the EN 120 (European Committee For Standardization, 1991) method using the perforator value. In formaldehyde emission, all particleboards made using the wattle tannin-based adhesive with three different hardeners, paraformaldehyde, hexamethylenetetramine, and tris(hydroxyl)nitromethan (TN), satisfied the requirements of grade $E_1$. But only those made using the pine tannin-based adhesive with the hexamine as hardener met the grade $E_1$ requirements. Hexamine was effective in reducing formaldehyde emission in tannin-based adhesives when used as the hardener. While the UF resin showed a desiccator value of $7.1mg/{\ell}$ and a perforator value of 12.1 mg/100 g, the MF resin exhibited a desiccator value of $0.6mg/{\ell}$ and a perforator value of 2.9 mg/100 g. According to the Japanese Industrial Standard and the European Standard, the formaldehyde emission level of the MDF panels made with UF resin in this study came under grade $E_2$. The formaldehyde emission level was dramatically reduced by the addition of MF resin. The desiccator and perforator methods produced proportionally equivalent results. Gas chromatography, a more sensitive and advanced method, was also used. The samples for gas chromatography were gathered during the experiment involving the perforator method. The formaldehyde contents measured by gas chromatography were directly proportional to the perforator values.

• Journal of the Korean Society of Clothing and Textiles
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• v.2 no.1
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• pp.125-131
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• 1978

This study was intended to clarify (1) the release of free formaldehyde (2) transfer of free formaldehyde to the contacted fabrics during storing, and (3) the removal effect of free formaldehyde by washing from resin finished fabrics. The results of this study were as follow; 1. The decrease rate of free formaldehyde content in fabrics was higher during storing in open air, poly bag, and glass tube in descending order and the content of free formaldehyde in fabrics was decreased in glyoxal resin finished but, increased in Melamine M-3 resin finished when the fabrics was stored in polybag and in glass tube. 2. Increased amount of formaldehyde transfer to contacted fabrics was noted with Melamine M-3 resin finished than that of glyoxal resin finished. Increased amount of formaldehyde transfer as well as more free formaldehyde were noted in cotton fabrics than in polyester/ cotton blend. 3. The effect of removing free formaldehyde from the fabrics was better in case of solid alkaline soap, synthetic alkaline powdered detergents, neutral detergents in descending order. The romoval of free formaldehyde was marked after the 1st washing and almost no increase in free formaldehyde was found after three times of washing. 4. After first washing, the content of formaldehyde in Melamine M-3 resin finished fabrics increased more rapidly than that of glyoxal resin finished fabrics in condition of closed storing.

• Elastomers and Composites
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• v.29 no.5
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• pp.436-443
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• 1994

Melamine resin was mixed with polybutadiene rubber or wood flour in the ranges of $5{\sim}75%(wt.%)$. For mixtures, physical and thermal properties were tested experimentally. Physical properties were mainly influenced on the dispersed states of rubber or wood flour. The highest flexural and impact strength were obtained at wood flour content $65{\times}67%$. Rubber was homopolymerized by hardner, or partially copolymerized with melamine resin. At rubber content $3{\sim}6%$, cured products represented lower modulus without decreasing mechanical strength.

• Journal of Korean Society of Forest Science
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• v.48 no.1
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• pp.40-50
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• 1980

This research was carried out to examine the substitutional feasibility of low-priced materials produced in waste of forest instead of wheat flour which is extended for plywood adhesives. Wheat, pine bark, wood flour and pine foliage of coniferous trees or poplar foliage of hardwood species were selected and pulverized into 60-100 mesh minute powder after they were dried at $100-105^{\circ}C$ during 24 hours in the drying oven. The prepared particles as above were added to urea formaldehyde resin, urea-melamine copolymer resin and water soluble phenol formaldehyde resin in the ratio of 10, 20, 30 and 50%. After plywoods were processed by the above extending ratios, shear strength of extended plywoods were analyzed and discussed. The results obtained at this study were summarised as follows; 1. In the case of urea formaldehyde resin, both dry and wet shear strength of plywoods extended by wheat flour were shown the highest value. 2. Dry shear strength of urea-melamine copolymer resin was better than that of urea formaldehyde resin on the whole, while plywoods extended by wheat flour were shown excellent results. 3. Among 10% and 20% extensions of urea-melamine copolymer resin, the best results were shown by poplar leaves powder, wheat powder and wood flour. They had no significant difference statistically. 4. In the case of water soluble phenol formaldehyde resin, although dry shear strength of pine leaves powder was higher than that of wheat flour in the ratio of 10%, there was no significant difference between them in the ratio of 10 and 20%. 5. Among 20, 30 and 50% extensions of water soluble phenol formaldehyde resin, wet shear strength of wood flour and bark powder was higher than that of wheat flour. Wet shear strength of wood flour in the ratio of 10% was shown the same tendency as above.

• Biotechnology and Bioprocess Engineering:BBE
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• v.11 no.4
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• pp.332-336
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• 2006

In this study, melamine-formaldehyde microcapsules were prepared via in situ polymerization using peppermint oil as a core material, melamine-formaldehyde as the wall material, Tween 20 as the emulsifier, and poly (vinyl alcohol) as a protective colloid. The melamine-formaldehyde microcapsules prepared in this study were then evaluated with regard to their structures, thermal properties, particle size distributions, morphologies, and release behaviors.

• Journal of the Korean Wood Science and Technology
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• v.43 no.3
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• pp.327-333
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• 2015

To measure the dimensional stability of three softwoods by vacuum pressurization of water soluble melamine-formaldehyde (MF) resin impregnation process, properties of resin treated compressed woods (compregs) were measured after impregnating the water soluble MF resin into three coniferous wood species for different impregnation times and resin concentrations. As the resin concentration was higher and impregnation time was longer, coefficients of volumetric shrinkage and anti-volumetric swelling efficiency increased, but coefficients of volumetric swelling, anti-volumetric swelling efficiency and absorption decreased. Also, weight percent gain increased remarkably as the resin concentration was high, but there was no uniform relationship with impregnation time.

• Journal of the Korean Wood Science and Technology
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• v.43 no.5
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• pp.672-681
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• 2015

As a part of abating the formaldehyde emission of amino resin-bonded wood-based composite panels, this study was conducted to investigate hydrolytic stability of urea-melamine-formaldehyde (UMF) resin depending on various hydrolysis conditions and hardener types. Commercial UMF resin was cured and ground into a powdered form, and then hydrolyzed with hydrochloric acid. After the acid hydrolysis, the concentration of liberated formaldehyde in the hydrolyzed solution and mass loss of the cured UMF resins were determined to compare their hydrolytic stability. The hydrolysis of cured UMF resin increased with an increase in the acid concentration, time, and temperature and with a decrease in the smaller particle size. An optimum hydrolysis condition for the cured UMF resins was determined as $50^{\circ}C$, 90 minutes, 1.0 M hydrochloric acid and $250{\mu}m$ particle size. Hydrolysis of the UMF resin cured with different hardener types showed different degrees of the hydrolytic stability of cured UMF resins with a descending order of aluminum sulfate, ammonium chloride, and ammonium sulfate. The hydrolytic stability also decreased as the addition level of ammonium chloride increased. These results indicated that hardener types and level also had an impact on the hydrolytic stability of cured UMF resins.