• 대한기계학회논문집A
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• 제36권10호
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• pp.1283-1288
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• 2012

수소를 대량으로 생산하기 위한 원자력수소생산시스템에서 공정열교환기는 초고온가스로로부터 생성된 초고온 열을 화학반응공정으로 전달하는 핵심기기이다. 한국원자력연구원에 구축되어 있는 소형 가스루프에서 $Hastelloy^{(R)}$-X 로 제작된 중형 공정열교환기 시제품에 대한 성능시험이 계획되어 있다. 본 연구에서는 중형 공정열교환기의 고온구조건전성을 파악하기 위한 선행 연구로서 소형가스루프 시험조건하에서 중형 공정열교환기 시제품의 고온구조해석을 이전 연구에서 확립된 경계조건을 적용하여 수행하였다. 해석결과는 소형가스루프에서의 중형 공정열교환기 시제품에 대한 성능시험 결과와 비교할 예정이다.

• 대한화학회지
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• 제44권3호
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• pp.207-211
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• 2000

Tween80 미셀용액에서 착화제로서 APDC틀 이용하여 Ni(II)를 정량하는 방법에 대해 연구하였다. Ni(PDC)$_2$ 착물의 홉수 스펙트럼 chloroform에서 보다는 Tween80에서 더 좋은 모양과 더 좋은 감도를 보여 주었다. Ni(PDC)$_2$ 착물은 pH 7.0에서 그리고 100분 정도까지 매우 안정하였으며, APDC를 Ni(II)의 몰수의 10배 이상 넣어 주면 정량적으로 착물이 형성되었다. Tween80의 농도는 0,1%가 적절하였고,0.1% Tween80 용액에서 Ni(PDC)$_2$ 착물의 검정곡선은 좋은 직선성(R2=0.9955)을 보여주었다. 이 분석법의 검출한계와 정량한계는 각각 0.09 ${\mu}g$/mL와 0.28${\mu}g$/mL이었으며, 강물시료에 적용한 회수율은 100% 보다 조금 크게 나타났다. 비록 여러 금속이온들이 방해를 하지만, 실제시료에 들어있는 Ni(II)을 정량하는데 이용할 수 있을 것이다.

• Mycobiology
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• 제48권4호
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• pp.326-329
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• 2020

Valuable natural compounds produced by a variety of microorganisms can be used as lead molecules for development of new agrochemicals. Furthermore, high-throughput in vitro screening systems with specific modes of action can increase the probability of discovery of new fungicides. In the current study, a rapid assay tested with various microbes was developed to determine the degree of respiratory inhibition of Saccharomyces cerevisiae in two different liquid media, YG (containing a fermentable carbon source) and NFYG (containing a non-fermentable carbon source). Based on this system, we screened 100 fungal isolates that were classified into basidiomycetes, to find microbial secondary metabolites that act as respiratory inhibitors. Consequently, of the 100 fungal species tested, the culture broth of an IUM04881 isolate inhibited growth of S. cerevisiae in NFYG medium, but not in YG medium. The result is comparable to that from treatment with kresoxim-methyl used as a control, suggesting that the culture broth of IUM04881 isolate might contain active compounds showing the inhibition activity for respiratory chain. Based on the assay developed in this study and spectroscopic analysis, we isolated and identified an antifungal compound (-)-oudemansin A from culture broth of IUM04881 that is identified as Oudemansiella venosolamellata. This is the first report that (-)-oudemansin A is identified from O. venosolamellata in Korea. Taken together, the development of this assay will accelerate efforts to find and identify natural respiratory inhibitors from various microbes.

• 한국균학회지
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• 제23권3호통권74호
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• pp.197-201
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• 1995

느타리버섯 재배에 있어서 배지재료로 제지부산물의 사용 가능성을 검토한 결과 배지재료별 화학특성은 제지부산물이 폐면, 볏짚, 왕겨보다 CaO는 많았고, T-C, T-N, $P_2O_5$, MgO는 비슷하였으며 $K_2O$는 현저히 적었다. 균사생장은 혼합처리가 폐면단용보다 생장이 다소 빠르거나 비슷한 경향이었다. 초발이소요일수는 폐면단용보다 혼합처리가 비슷하거나 $1{\sim}2$일 정도 빠른 경향이었다. 배지종류별 수량은 폐면단용에 비해 폐면 10+왕겨 20+제지부산물 70% 처리를 제외하고는 증수되었으며, 특히 계면+제지부산물 30% 혼합처리가 21% 증수되어 가장 우수하였다. 경제성분석결과 폐면단용보다 폐면+제지부산물 30% 혼합처리에서 소득지수가 50% 높게 나타났다.

• 한국세라믹학회지
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• 제51권2호
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• pp.121-126
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• 2014

The influence of a liquid medium duringa wet-milling process in the grinding and oxidation of silicon powder was investigated. Distilled water, dehydrated ethanol and diethylene glycol were used as the liquid media. The applied grinding times were 0.5, 3, and 12 h. Ground silicon powder samples were characterized by means of aparticle size analysis, scanning electron microscopy(SEM), x-ray powder diffraction (XRD), FT-IR spectroscopy and by a chemical composition analysis. From the results of the characterization process, we found that diethylene glycol is the most efficient liquid medium when silicon powder is ground using a wet-milling process. The FT-IR results show that the Si-O band intensity in an unground silicon powder is quite strongbecause oxygen becomes incorporated with silicon to form $SiO_2$ in air. By applying deionized water as a liquid medium for the grinding of silicon, the $SiO_2$ content increased from 4.12% to 31.7%. However, in the cases of dehydrated ethanol and diethylene glycol, it was found that the $SiO_2$ contents after grinding only changed insignificantly, from 4.12% to 5.91% and 5.28%, respectively.

• Journal of Microbiology and Biotechnology
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• 제9권5호
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• pp.593-603
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• 1999

Poly(3-hydroxybutyrate) (PHB) production by fermentation was examined under both restricted- and ample-oxygen supply conditions in a single fed-batch fermentation. Recombinant Escherichia coli transformed with the PHB production plasmid pSYLl07 was grown to reach high cell density (227 g/l dry cell weight) with a high PHB content (78％ of dry cell weight), using a glucose-based minimal medium. A simple flux model containing 12 fluxes was developed and applied to the fermentation data. A superior closure (95％) of the carbon mass balance was achieved. When the data were put into use, the results demonstrated a surprisingly large excretion of formate and lactate. Even though periods of severe oxygen limitation coincided with rapid acetate and lactate excretion, PHB productivity and carbon utilization efficiency were not significantly impaired. These results are very positive in reducing oxygen demand in an industrial PHA fermentation without sacrificing its PHA productivity, thereby reducing overall production costs.

• 대한방사선기술학회지:방사선기술과학
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• 제43권4호
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• pp.273-280
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• 2020

In this study, the P contrast agent of Iopamidol, which is a nonionic iodide contrast agent most commonly used as a vascular contrast agent in medical institutions, and the O contrast agent of Ioversol, were studied. The physicochemical changes according to the temperature change were compared and analyzed using the Bruker Avance 500MHz Nuclear Magnetic Resonance Spectrometer owned by the Korea Basic Science Institute (KBSI). There was no physical or chemical change in the O contrast medium of Ioversol formulation in temperature change. However, in the P contrast agent of Iopamidol, a doublet peak began to appear in the 1.1 ppm region of the sample at 60℃, and the doublet peak was clearly observed in the sample at 80℃. As a result of this study, 1H-NMR analysis revealed that the P contrast agent of the Iopamidol formulation was dissociated from chemical bonds as it rose to a high temperature of 60℃ or higher, resulting in the formation of foreign substances. It was evaluated that the O contrast agent of Ioversol formulation had physico-chemical stability than the P contrast agent of Iopamidol formulation. As shown in this study, it is necessary to analyze the physical and chemical changes of contrast agents according to various environmental factors.

• 한국측량학회지
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• 제34권1호
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• pp.79-90
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• 2016

본 논문에서는 지진 등으로 인해 발생하는 절대 지각변위 추정에 GPS 상시관측망의 동적기선해석 기법의 적용 가능성을 실험을 통해 정확도와 정밀도 측면에서 분석하였다. 국내 관측소의 절대좌표 추정을 위해 국외 관측소가 데이터처리에 포함 할 필요가 있어 실험 네트워크는 관측점 사이 거리가 수 백 ∼ 약 1,000km에 달하는 중기선으로 구성하였다. 따라서 대상 관측점의 동적 거동특성을 매개변수 추정단계에 반영하는 일련의 절차를 적용하여 GPS 동적 중기선해석 실험을 수행하였다. 이를 통하여 GPS 동적 중기선해석을 통해 센티미터 수준의 정확도와 그 이상의 정밀도로 GPS 상시관측소의 절대좌표를 동적모드로 추정할 수 있음을 확인하였다. 또한 본 논문은 위성궤도력, 관측데이터양 그리고 동적좌표 추정의 초기좌표 구속범위와 같은 기선해석 조건들이 동적좌표 추정 정확도와 정밀도에 미치는 영향을 분석하고 그 결과를 요약하고 있다.

• 한국산림과학회지
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• 제99권5호
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• pp.706-710
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• 2010

Understanding of chemical composition and energy contents in tree is important to develope strategies of renewable energy policy to cope with climate change. Residual biomass as renewable energy source was evaluated and focused on the bark-containing branches. Chemical analysis studies were conducted for different part of yellow poplar (Liriodendron tulipifera), which were partitioned to inner bark, outer bark, small branches, medium branches, big branches and trunk. The variations in hydrophobic extractives, hydrophilic extractives, lignin, carbohydrate compositions, energy contents (higher heating value) and the ash content were determined. The inner and outer bark had higher ash content, hydrophobic and hydrophilic extractives content, and higher energy content than those of tree trunk. Polysaccharides content in inner and outer bark was quite lower than those of stem or branches. Based on the energy content of residual biomass, replacement of fossil fuel and greenhouse gas emission abatement were calculated.

• Bulletin of the Korean Chemical Society
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• 제24권3호
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• pp.384-388
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• 2003

The emission and excitation spectra of $cis-[Cr(cyclam)(NCS)_2]NCS$ (cyclam = 1,4,8,11-tetraazacyclotetradecane) taken at 77 K are reported. The infrared and visible spectra at room temperature are also measured. The vibrational intervals due to the electronic ground state are extracted from the far-infrared and emission spectra. The ten pure electronic origins due to spin-allowed and spin-forbidden transitions are assigned by analyzing the absorption and excitation spectra. Using the observed transitions, a ligand field analysis has been performed to determine the bonding properties of the coordinated ligands in the title chromium(Ⅲ) complex. According to the results, it is found that nitrogen atoms of the cyclam ligand have a strong σ-donor character, while the NCS ligand has medium σ- and π-donor properties toward chromium(Ⅲ) ion.