• 제목/요약/키워드: Medium chemical analysis

검색결과 321건 처리시간 0.021초

키토산을 첨가한 저지방 기능성 소시지의 향미 성분 분석과 냉장 저장 중의 이화학적인 특성 (Flavor Compounds and Physicochemical Properties of Low-fat Functional Sausages Manufactured with Chitosans during Refrigerated Storage)

  • 박성용;진구복;유승석
    • 한국축산식품학회지
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    • 제25권3호
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    • pp.285-294
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    • 2005
  • 본 연구는 기능성 육제품 개발로 키토산이 육제품 내에서 어떠한 조직적인 특성을 나타내는지 알아보기 위해 저지방 소시지에 키토산을 첨가한 기능성 소시지를 제조하여 향미를 분석하였고 저장기간에 따른 이화학적 특성의 변화를 조사하였다. 돈육 후지로부터 추출한 염용성 단백질에 키토산을 첨가하여 pH와 점도를 측정한 결과 중분자 키토산 처리구의 pH는 대조구에 비해 첨가량이 증가할수록 증가하는 경향이며, 점도는 이와는 반대로 저분자 키토산 처리구는 첨가량에 따라 차이를 보이지 않았으나(p>0.05) 중분자 및 고분자의 경우 첨가량이 증가할수록 점도 값이 증가하는 경향을 나타냈다(p<0.05). 대조구와 유의적 차이를 보인 처리구는 중분자 그리고 고분자 키토산을 $0.6\%$ 첨가한 처리구로 특정 분자량의 키토산이 일정수준 첨가되면 점성이 증가되는 것을 알 수 있었다. 이는 조직감 검사에서도 볼 수 있듯이 중분자와 고분자 키토산을 첨가한 소시지가 저지방 대조구에 비해 대부분의 조직감에서 높은 값을 나타내었다. 가열 전 반죽의 pH, 가열 후 소시지의 pH, 가열 감량, 진공 감량 그리고 보수력에서는 저지방 대조구와 비교해서 키토산 첨가 효과는 나타나지 않았다. 향미 성분 분석 결과 저지방과 고지방의 경우 차이를 보일 뿐 대조구와 비교하여 키토산 첨가에 따른 향미의 효과는 없었으며 저분자 키토산을 $0.6\%$ 첨가한 처리구가 유화형 대조구와 유사한 향미 특성을 나타내는 것을 알 수 있었다.

Chemical synthesis of processable conducting polyaniline derivative with free amine functional groups

  • Kar, Pradip
    • Advances in materials Research
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    • 제3권2호
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    • pp.117-128
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    • 2014
  • Processable conducting polyaniline derivative with free amine functional groups was successfully synthesized from the monomer o-phenylenediamine in aqueous hydrochloric acid medium using ammonium persulfate as an oxidative initiator. The synthesized poly(o-phenylenediamine) (PoPD) in critical condition was found to be completely soluble in common organic solvents like dimethyl sulfoxide, N,N-dimethyl formamide etc. From the intrinsic viscosity measurement, the optimum condition for the polymerization was established. The polymer was characterized by ultraviolet visible spectroscopy, Fourier transform infrared spectroscopy, proton magnetic resonance spectroscopy ($^1HNMR$) and thermogravimetric (TGA) analyses. The weight average molecular weights of the synthesized polymers were determined by the dynamic light scattering (DLS) method. From the spectroscopic analysis the structure was found to resemble that of polyaniline derivative with free amine functional groups attached to ortho/meta position in the phenyl ring. However, very little ladder unit was also present with in the polymer chain. The moderate thermal stability of the synthesized polymer could be found from the TGA analysis. The average DC conductivity of $2.8{\times}10^{-4}S/cm$ was observed for the synthesized polymer pellet after doping with hydrochloric acid.

Rib-eye의 조리기구 및 조리방법에 따른 물성 연구 (A Study on Rheology of the Rib-eye Cooked by Cooking Method and Cooking Utensil)

  • 박진수;최민경
    • 한국가정과학회지
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    • 제7권1호
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    • pp.21-31
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    • 2004
  • This study was carried out to investigate the physico-chemical properties during the rib-eye preperation while cooked rib-eye and fine sensory evaluation by various cooked utensil (oven, fry-pan and microwave). 1) Change of moisture contents of sauce-pan boiling cooker was lower than boiling by preasure cooker and fat content of sauce-pan boiling was higher than preasure cooker boiling. 2) Degree of cholesterol of cooker meat was not change for content of cholesterol during the boiling preperation but progressively decreased in order of well-done steak < medium steak < rare steak measured by cholesterol analysis. 3) Sensory evaluation conducted by fine graduate as panelists showed that oven steak and fry-pan steak had higher score of sensory evaluation. While microwave steak had the lowest score all sensory profile score.

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Mechanics of nonlocal advanced magneto-electro-viscoelastic plates

  • Ebrahimi, Farzad;Barati, Mohammad Reza;Tornabene, Francesco
    • Structural Engineering and Mechanics
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    • 제71권3호
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    • pp.257-269
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    • 2019
  • This paper develops a nonlocal strain gradient plate model for damping vibration analysis of smart magneto-electro-viscoelastic nanoplates resting on visco-Pasternak medium. For more accurate analysis of nanoplate, the proposed theory contains two scale parameters related to the nonlocal and strain gradient effects. Viscoelastic effect which is neglected in all previous papers on magneto-electro-viscoelastic nanoplates is considered based on Kelvin-Voigt model. Governing equations of a nonlocal strain gradient smart nanoplate on viscoelastic substrate are derived via Hamilton's principle. Galerkin's method is implemented to solve the governing equations. Effects of different factors such as viscoelasticity, nonlocal parameter, length scale parameter, applied voltage and magnetic potential on damping vibration characteristics of a nanoplate are studied.

Identification of Dammarane-type Triterpenoid Saponins from the Root of Panax ginseng

  • Lee, Dong Gu;Lee, Jaemin;Yang, Sanghoon;Kim, Kyung-Tack;Lee, Sanghyun
    • Natural Product Sciences
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    • 제21권2호
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    • pp.111-121
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    • 2015
  • The root of Panax ginseng, is a Korea traditional medicine, which is used in both raw and processed forms due to their different pharmacological activities. As part of a continued chemical investigation of ginseng, the focus of this research is on the isolation and identification of compounds from Panax ginseng root by open column chromatography, medium pressure liquid chromatography, semi-preparative-high performance liquid chromatography, Fast atom bombardment mass spectrometric, and nuclear magnetic resonance. Dammarane-type triterpenoid saponins were isolated from Panax ginseng root by open column chromatography, medium pressure liquid chromatography, and semi-preparative-high performance liquid chromatography. Their structures were identified as protopanaxadiol ginsenosides [gypenoside-V (1), ginsenosides-Rb1 (2), -Rb2 (3), -Rb3 (4), -Rc (5), and -Rd (6)], protopanaxatriol ginsenosides [20(S)-notoginsenoside-R2 (7), notoginsenoside-Rt (8), 20(S)-O-glucoginsenoside-Rf (9), 6-O-[$\alpha$-L-rhamnopyranosyl(1$\rightarrow$2-$\beta$-D-glucopyranosyl]-20-O-$\beta$-D-glucopyranosyl-$3\beta$,$12\beta$, 20(S)-dihydroxy-dammar-25-en-24-one (10), majoroside-F6 (11), pseudoginsenoside-Rt3 (12), ginsenosides-Re (13), -Re5 (14), -Rf (15), -Rg1 (16), -Rg2 (17), and -Rh1 (18), and vinaginsenoside-R15 (19)], and oleanene ginsenosides [calenduloside-B (20) and ginsenoside-Ro (21)] through the interpretation of spectroscopic analysis. The configuration of the sugar linkages in each saponin was established on the basic of chemical and spectroscopic data. Among them, compounds 1, 8, 10, 11, 12, 19, and 20 were isolated for the first time from P. ginseng root.

Kinetic Study on Michael-type Reactions of 1-Phenyl-2-propyn-1-one with Alicyclic Secondary Amines: Effect of Medium on Reactivity and Mechanism

  • Hwang, So-Jeong;Park, Youn-Min;Um, Ik-Hwan
    • Bulletin of the Korean Chemical Society
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    • 제29권10호
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    • pp.1911-1914
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    • 2008
  • Second-order rate constants (kN) have been measured for Michael-type addition reactions of a series of alicyclic secondary amines to 1-phenyl-2-propyn-1-one (2) in MeCN at 25.0 ${\pm}$ 0.1 ${^{\circ}C}$. All the amines studied are less reactive in MeCN than in $H_2O$ although they are more basic in the aprotic solvent by 7-9 p$K_a$ units. The Bronsted-type plot is linear with $\beta_{nuc}$ = 0.40, which is slightly larger than that reported previously for the corresponding reactions in $H_2O$ ($\beta_{nuc}$ = 0.27). Product analysis has shown that only E-isomer is produced. Kinetic isotope effect is absent for the reactions of 2 with morpholine and deuterated morpholine (i.e., $k^H/k^D$ = 1.0). Thus, the reaction has been concluded to proceed through a stepwise mechanism, in which proton transfer occurs after the rate-determining step. The reaction has been suggested to proceed through a tighter transition state in MeCN than in H2O on the basis of the larger $\beta_{nuc}$ in the aprotic solvent. The nature of the transition state has been proposed to be responsible for the decreased reactivity in the aprotic solvent.

Biological Treatment of Two-Phase Olive Mill Wastewater (TPOMW, alpeorujo): Polyhydroxyalkanoates (PHAs) Production by Azotobacter Strains

  • Cerrone, Federico;Sanchez-Peinado, Maria Del Mar;Juarez-Jimenez, Belen;Gonzalez-Lopez, Jesus;Pozo, Clementina
    • Journal of Microbiology and Biotechnology
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    • 제20권3호
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    • pp.594-601
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    • 2010
  • Azotobacter chroococcum H23 (CECT 4435), Azotobacter vinelandii UWD, and Azotobacter vinelandii (ATCC 12837), members of the family Pseudomonadaceae, were used to evaluate their capacity to grow and accumulate polyhydroxyalkanoates (PHAs) using two-phase olive mill wastewater (TPOMW, alpeorujo) diluted at different concentrations as the sole carbon source. The PHAs amounts (g/l) increased clearly when the TPOMW samples were previously digested under anaerobic conditions. The MNR analysis demonstrated that the bacterial strains formed only homopolymers containing $\beta$-hydroxybutyrate, either when grown in diluted TPOMW medium or diluted anaerobically digested TPOMW medium. COD values of the diluted anaerobically digested waste were measured before and after the aerobic PHA-storing phase, and a clear reduction (72%) was recorded after 72 h of incubation. The results obtained in this study suggest the perspectives for using these bacterial strains to produce PHAs from TPOMW, and in parallel, contribute efficiently to the bioremediation of this waste. This fact seems essential if bioplastics are to become competitive products.

중규모 하천 생물 서식처의 특성 분석 -복하천을 중심으로- (An Analysis of Ecological Habitat Characteristics in Medium-scale Stream -A Case of the Bokha Stream-)

  • 안홍규;우효섭
    • 한국조경학회지
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    • 제32권2호
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    • pp.102-119
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    • 2004
  • This study investigates the relation between the location of a habitat and the ecological connections according to the habitat type in the riparian zone at the Bokha stream. Stream habitat is classified into nine types for the aquatic insects and fish. For vegetation and birds, habitat is classified into five types of medium-scale streams, including both physical and chemical streams are analyzed accordingly. The major results of this study are as follows: 1) A pool connected to the main stream has a certain water depth (about 80 cm) and is disturbed at least 5 to 6 times a year. Although the pool has a somewhat bad water quality, it provides a habitat for various types of young fish. 2) A meander riffle is about 15 cm deep, the flow velocity in the region is about 75 cm/s. This region does not have large structures to which aquatic insects can attach, so it cannot be used as a spawning ground. 3) A rock type pool is about 60 cm deep, the flow velocity in the meander riffle is about 25 cm/s. In this region, many aquatic insects attached to large structures appear. Due to various riparian vegetation, the rock type pool is used as a habitat for aquatic insects. 4) A pool which is only connected to the main stream during floods has a bad water quality. Despite of its relatively small size, it has a high population density of aquatic insects. faculty.

MgO 매개층을 이용하여 제작된 유량센서의 특성 (The Characteristics of Flow Sensor Fabricated by MgO Medium Layer)

  • 홍석우;장수;이종춘;정귀상
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 G
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    • pp.3319-3321
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    • 1999
  • Pt-RTD and Micro Heater was fabricated by using MgO as medium layer in order to improve adhesion of Pt thin-films to $SiO_2$ layer, MgO layer improved adhesion of Pt thin-films to $SiO_2$ layer without any chemical reactions to Pt thin-films under high annealing temperatures, In the analysis of properties of Pt-RTD, TCR value had 3927 $ppm/^{\circ}C$ and liner in the temperature range of $25-400^{\circ}C$. The temperature of Pt micro-heater had up to $400^{\circ}C$ with 1.5watts of the heating power. In investigating output characteristics of flow sensors output voltages increased as gas flow rate and its conductivity increased due to increase of heat-loss from sensor to external. Output voltage was 82 mV at $N_2$ flow rate of 2000sccm, heating power of 1.2W.

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방사성 오염 토양의 효율적 복원을 위한 처리기술 평가 연구 (A Study on The Assessment of Treatment Technologies for Efficient Remediation of Radioactively-Contaminated Soil)

  • 송종순;신승수;김선일
    • 방사성폐기물학회지
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    • 제14권3호
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    • pp.245-251
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    • 2016
  • 발전소 해체 및 핵종누출 시 원자력 관련 시설 주변의 방사성오염 토양은 주민의 거주 및 공업용지로의 재사용을 위해 토양제염이 불가피하다. 본 논문에서는 기존 토양복원 기술을 생물학적, 물리/화학적, 열적 처리로 분류하고 각 기술의 원리 및 처리 물질을 분석 및 조사를 통해 방사성물질로 오염된 토양에 적용 가능한 기술을 선정하였다. 선정된 기술을 평가하기 위해 경제성, 적용성, 기술성을 고려하였다. 또한 High, Medium, Low로 가중치를 적용하여 평가하였다. 이에 따른 결과값을 바탕으로 방사성물질로 오염된 토양에 가장 적합한 토양제염 방법을 제시하고자 한다.