• Bulletin of the Korean Chemical Society
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• v.15 no.5
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• pp.390-393
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• 1994

Details on the electrochemical formation of lead dioxide from aqueous plumbous ion are studied by measuring current-time behavior with potential step method at a rotating platinum electrode. A cubic law without induction period can be applied to the crystallization of lead dioxide in both acetate and nitrate media. In the course of the mechanistic study, the presence of a soluble intermediate during the nucleation step is clearly observed with a rotating ring-disk electrode. Decrease in the anodic ring current due to the reduction of soluble species formed during the anodic crystallization of lead dioxide at disk is detected.

• Bulletin of the Korean Chemical Society
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• v.10 no.6
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• pp.578-581
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• 1989

Two enantiomers of various 2-hydroxy acid esters have been resolved as the 3,5-dinitrophenyl carbamates on chiral stationary phases (CSPs) derived from ${\alpha}-arylalkylamines.$ Two CSPs, each of which contains the same type of chiral moiety, but shows different mode of connection to a silica support, have been found to show the contrasting resolution behaviors. From the contrasting resolution behaviours of two CSPs used in this study, two competing chiral recognition mechanisms are proposed.

• Bulletin of the Korean Chemical Society
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• v.19 no.3
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• pp.324-327
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• 1998

The mechanisms of Cu2+ adsorption onto goethite, hematite and kaolinite are different. Goethite and hematite showed a similar adsorption behavior (ionic-strength independent), but kaolinite gave somewhat different result (ionic-strength dependent). These experimenal results were successfully simulated using a surface complexation model, TLM, which defines the inner- or outer-sphere complex. The chemical nature of Cu2+ adsorption onto kaolinite was qualitatively identified by EPR spectroscopy.

• International Journal of Highway Engineering
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• v.19 no.5
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• pp.49-58
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• 2017

PURPOSES : The objective of this study is to develop a simple regression model in designing the asphalt concrete (AC) overlay thickness using the Mechanistic-empirical pavement design guide (MEPDG) program. METHODS : To establish the AC overlay design equation, multiple regression analyses were performed based on the synthetic database for AC thickness design, which was generated using the MEPDG program. The climate in Seoul city, a modified Hirsh model for determining dynamic modulus of asphalt material, and a new damaged master curve approach were used in this study. Meanwhile, the proposed rutting model developed in Seoul city was then used to calibrate the rutting model in the MEPDG program. The AC overlay design equation is a function of the total AC thickness, the ratio of AC overlay thickness and existing AC thickness, the ratio of existing AC modulus and AC overlay modulus, the subgrade condition, and the annual average daily truck traffic (AADTT). RESULTS : The regression model was verified by comparing the predicted AC thickness, the AADTT from the model and the MEPDG. The regression model shows a correlation coefficient of 0.98 in determining the AC thickness and 0.97 in determining AADTT. In addition, the data in Seoul city was used to validate the regression model. The result shows that correlation coefficient between the predicted and measured AADTT is 0.64. This indicates that the current model is more accuracy than the previous study which showed a correlation coefficient of 0.427. CONCLUSIONS:The high correlation coefficient values indicate that the regression equations can predict the AC thickness accurately.

• International Journal of Highway Engineering
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• v.8 no.3 s.29
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• pp.29-37
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• 2006

The primary objective of this study is to characterize traffic axle loadings that consider Korea specific traffic conditions for developing mechanistic-based pavement design method as a part of Korea Pavement Research Program(KPRP). Although the concept of equivalent single axle load(ESAL) has been generally used since the 1960s for the pavement design, the mechanistic-based pavement design procedure requires more accurate axle loading data on the specific pavement. In this study, axle loading data were collected according to vehicle type and highway functional classification. Axle-load spectrum was then standardized by cumulative density function(cdf), because the axle load spectrum could vary from the observed site, truck traffic volume, and truck type, Finally, this study presented the procedure and S-shaped exponential models for characterizing axle load spectra according to vehicle type and highway functional classification.

• International Journal of Highway Engineering
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• v.13 no.1
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• pp.33-40
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• 2011

The resilient modulus which is presented mechanical properties of compacted subbase material is the design parameter on the Mechanistic - Empirical pavement design guide. The compaction control method on the Mechanistic - Empirical pavement design guide will be the way to confirm whether the in-situ elastic modulus measured after the compaction meets the resilient modulus which is applied the design. The resilient modulus in this study is calculated by the neural network suggested by Korea Pavement Research Program, and degree of compaction as the existing compaction control test and plate bearing capacity test(PBT) was performed to confirm whether the in-situ elastic modulus is measured. The Light Falling Weight Deflectometer(LFWD) is additionally tested for correlation analysis between each in-situ elastic modulus and resilient modulus, and is proposed correlation equation and test interval which can reduced overall testing cost. Also, the subbase compaction control procedure based on the in-situ elastic modulus is proposed using the in-situ PBT and LFWD test result.

• International Journal of Highway Engineering
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• v.8 no.1 s.27
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• pp.15-23
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• 2006

Criteria of the current asphalt mix design, Marshall method, includes the stability and flow which are not related with field performance of HMA mixture, together with the air void, Void filled with asphalt (VFA) and/or Void of mineral Aggregate(VMA). In addition, the limits of stability and flow are satisfied in most cases, the Optimum asphalt content (OAC) is determined based on volumetric properties, such as the air void and/or VFA and/of VMA. Therefore, many researchers have sought mechanistic properties which can replace the stability and flow, making the designed mixture having potential for better field performance. This study initiated to develope a mix design by introducing two performance-related mechanistic properties, the deformation strengh and fracture energy, in place of the stability and flow of the Marshall method. The deformation strength $(S_D)$ from the Kim Test has a high correlation with rutting property and the fracture energy(FE) from the indirect tensile test represents the fatigue cracking property of asphalt mixture. Four types of asphalt mixture were prepared for examining possibility of using the suggested mix design method in comparison with current methods. The results showed that mechanical properties were reflected in determination of OAC with this suggested mix design, unlike the existing Marshall method.

• Journal of the Korean Geotechnical Society
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• v.19 no.5
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• pp.189-197
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• 2003

The treatment and hauling of surplus soils which occur from construction activity are costly and have been demanding a reasonable recycling method. This study presents laboratory test results regarding the mechanistic properties of asphalt stabilized soils. The foamed asphalt equipment which generates the asphalt bubble was used to mix the soil. The marshall stability, indirect tensile test, resilient modulus, creep test and triaxial test(UU) were conducted to find out the performance of the asphalt stabilized soil. The test results were compared with the samples that fabricated in different conditions(the samples without asphalt and the reinforced samples using 2% cement). The inclusion of the asphalt in the soil has improved the marshall stability, resilient modulus and moisture susceptibility, and the addition of the 2% cement has even more increased these properties. The amount of the fines and the optimum moisture contents for mixing affects the mechanistic properties and important parameters for mix design.

• Proceedings of the Korean Society of Crop Science Conference
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• 2017.06a
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• pp.37-37
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• 2017

Mechanistic studies of halophytes are urgent areas of agricultural research due to the increase in saline-contaminated and irrigated land worldwide. The halophyte Suaeda glauca (S. glauca) has advantages in terms of biomass and saline elimination due to its large mass and well-developed phenotype on seashores, although its mechanistic features and growing specificities still require systematic investigation. In this study, S. glauca was cultivated under various saline concentrations (0-400 mM) in Hoagland's solution in the absence or presence of indole derivatives to elucidate physiological features. The results confirmed the optimal growth and development of S. glauca in 50 mM NaCl, and morphologies such as the number of branches, shoot length, and fresh and dry weights were improved by indole-3-carboxylic acid (ICA) treatment. The cation concentrations in roots, shoots and leaves were investigated to examine the ionic imbalances in response to saline treatment, and the results demonstrated that sodium ions accumulated to high concentrations in leaves. The levels of calcium and potassium ions in roots were maintained or slightly decreased in the presence of 50 mM NaCl and proline concentration was increased significantly in roots at optimal concentrations. These results demonstrate that the concentrations of ions and metabolites are key regulators of optimal growth by regulating the physiology of halophytes.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.30 no.5D
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• pp.505-512
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• 2010

Generally, the repeated traffic loading condition should be considered to predict the long-term deformation on road foundations or foundation systems. However, it is not easy to estimate long-term deformation on multi-layered system like roads and railways. For more quantitative analysis, mechanistic-empirical approach requires proper analytical tool, material's model, and material properties of foundation geomaterials under both traffic and environmental loadings. In this study, therefore, laboratory data from the long-term repeated load triaxial tests were used to predict accumulated deformation on pavement foundations and the results were analyzed based on the nonlinear models and stress state considered. All these results are presented and verified on laboratory based scale using the finite element analysis with the deformation characteristics of foundation geomaterials at various stress states.