• Title/Summary/Keyword: Measurement aggregation

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Oil Absorbencies of Fibers of Biodegradable and Microbial Polymers Prepared by Electrospinning Method (전기방사에 의한 미생물 합성 생분해성 고분자 섬유의 Oil 흡수)

  • Jang, Ei-Sup;Lee, Won-Ki;Park, Chan-Young;Min, Sung-Kee;Jang, Seong-Ho
    • Journal of Environmental Science International
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    • v.22 no.2
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    • pp.243-249
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    • 2013
  • Fibers of microbial polyesters, poly(3-hydroxy butyrate) (PHB) and poly(3-hydroxy butyrate-co-3-hydroxy valerate) (HB-co-HV) were prepared by electrospinning method. The obtained fibers were evaluated by differential scanning calorimetry, scanning electron microscopy, and oil absorption. The formation of fibers was strongly dependent on a concentration of solution. At a low concentration, the fibers contained beads which is from aggregation of polymer due to short evaporation time. The fine fibers with $2-5{\mu}m$ diameter were obtained at 20 wt% concentration. The contact angle measurement showed that the fiber had higher water contact angle than the film due to the lotus-like effect. Oil absorbency showed that the fiber had higher than the film. Specially, the HB-co-HV fiber which was spinned from 20 wt% absorbed 65% oil which is much higher than that of a normal polypropylene-based oil paper.

Change in Spatial Dispersion of Daphnia magna(Cladocera: Daphniidae) Populations Exposed to Organophosphorus Insecticide, Diazinon (유기인계 살충제 (다이아지논)에 대한 물벼룩, Daphnia magna (Cladocera: Daphniidae) 개체군의 공간분산 변이)

  • Lee, Sang-Hee;Ji, Chang-Woo;Chon, Tae-Soo
    • Environmental Analysis Health and Toxicology
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    • v.24 no.3
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    • pp.231-240
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    • 2009
  • We explored collective behaviors of indicator species to elucidate the effect of the chemical stress. After the treatments of an insecticide, diazinon, at low concentrations (1.0 and 10.0 ${\mu}g/L$), spatial dispersion patterns of Daphnia magna were checked in a test chamber. The I-index was used to characterize the movement data before (0~1 h) and after (1~2 h) the treatments in laboratory conditions. The slopes of the frequency distribution of I-index in semi-log scale decreased significantly, and the test populations appeared to be more dispersed with a lower degree of aggregation after the treatments. The index was feasible in indicating decrease in the ability of the specimens to keep desirable distances with neighbor individuals under chemical stress and showed a possibility of monitoring presence of toxic chemicals in environment through group behavior measurement.

Transport behavior of PVP (polyvinylpyrrolidone) - AgNPs in saturated packed column: Effect of ionic strength and HA (포화 컬럼실험에서 이온강도 변화 및 유기물질 출현에 의한 PVP로 코팅된 은나노 입자의 거동 연구)

  • Heo, Jiyong;Han, Jonghun;Her, Namguk
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.3
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    • pp.263-270
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    • 2016
  • Recent Engineered nanoparticles were increasingly exposed to environmental system with the wide application and production of nanomaterials, concerns are increasing about their environmental risk to soil and groundwater system. In order to assess the transport behavior of silver nanoparticles (AgNPs), a saturated packed column experiments were examined. Inductively coupled plasma-mass spectrometry and a DLS detector was used for concentration and size measurement of AgNPs. The column experiment results showed that solution chemistry had a considerable temporal deposition of AgNPs on the porous media of solid glass beads. In column experiment, comparable mobility improvement of AgNPs were observed by changing solution chemistry conditions from salts (in both NaCl and $CaCl_2$ solutions) to DI conditions, but in much lower ionic strength (IS) with $CaCl_2$. Additionally, the fitted parameters with two-site kinetic attachment model form the experimental breakthrough curves (BTCs) were associated that the retention rates of the AgNPs aggregates were enhanced with increasing IS under both NaCl and $CaCl_2$ solutions.

Particle Size, Morphology and Color Characteristics of C.I. Pigment Red 57:1 : 2. Effect of Salt Milling Process

  • Seo, Hee Sung;Lee, Hyun Kyung;Yoo, Eui Sang
    • Textile Coloration and Finishing
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    • v.27 no.4
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    • pp.245-260
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    • 2015
  • The effect of salt milling process on the crystal size, morphology, and color characteristics of C.I. Pigment Red 57:1 was studied. The primitive morphology and color properties of the pigment after synthesis were studied in the former series work. The size and morphology of primary particles and the second aggregation features should be considered because they are very important to determine pigment quality. We compared the primary morphology of pigment particles before drying with the secondary aggregated morphology of pigment particles after drying and salt milling process. Morphological properties were investigated by particle size analysis, X-ray diffraction, and scanning electron microscopy and color measurement was carried out. Significant reduction in particle size as well as enhanced crystallite size after salt milling process was observed. This result might give a difference in color of the pigment, turning into brighter and more blue-toned red color. It was revealed that synthesis condition affect the morphology and color of the pigment even after milling. Increase in HCl concentration in the synthesis process enhanced crystal size and quality forming bluer-red pigments but an increase in $CaCl_2$ concentration resulted in more amorphous crystals forming darker-red pigments after salt milling.

Effect of γ-Irradiation on the Physicochemical Properties of Zein Films

  • Lee, Sehee;Lee, Myoungsuk;Song, Kyung-Bin
    • Preventive Nutrition and Food Science
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    • v.8 no.4
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    • pp.343-348
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    • 2003
  • To elucidate the effect of gamma-irradiation on the physicochemical properties of zein films, the molecular and mechanical properties of the films were examined after irradiation at various irradiation doses. Gamma-irradiation of zein solutions caused the disruption of the ordered structure of the zein molecules, as well as degradation, cross-linking, and aggregation of the polypeptide chains based on an SDS-PAGE study. Gamma-irradiation increased the solubility of zein and decreased the viscosity due to cleavage of the polypeptide chains. Protein solubility of the zein films in urea/2-mercaptoethanol also increased with increasing irradiation doses. Alterations of the zein molecules by irradiation decreased water vapor per-meability by 12% and increased the elongation of zein films. However, mean tensile strength of the zein films was decreased by gamma-irradiation treatment. Measurement of Hunter color values indicated that irradiation caused a destructive effect on yellow pigments, resulting in a significant decrease in Hunter b values. The microstructure as observed by scanning electron microscopy showed that irradiated zein film had a smoother and glossier surface than the non-irradiated films.

A Field Application Case of Direct Ice Slurry Transporting System for District Cooling (지역냉방용 직접순환식 아이스슬러리 시스템의 현장적용 사례)

  • Yoo, Ho-Seon;Lee, Sang-Hoon;Lee, Yoon-Pyo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.21 no.9
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    • pp.496-504
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    • 2009
  • In order to investigate the feasibility of a direct ice slurry transporting system for the purpose of district cooling, a case study of field application is performed. The research aims include the field measurement of ice packing factor, the performance of coldness delivery, and the branching characteristics of ice slurry. Two representative types of pipe branch are dealt with in this work. For the slurry flow with ice volume fraction of 0.16 or less, the pipe blocking due to aggregation is not observed. Based on the time-wise variation of temperature in the storage tank, a calculating method of ice packing factor is newly developed, which seems to be useful when the brine concentration is unknown. It is confirmed that the mass flow rate of ice slurry per unit cooling load is markedly reduced with increasing the ice content. The pumping power also decreases, but remains unchanged for high ice fractions. The distribution of ice particle before and after branching shows a good uniformity within the range of 5% difference, but yields a unique trend depending on the flow rate.

Pulsatility Index of Blood Echogenicity of the Human Radial and Common Carotid Arteries: Relation with Age and Stroke (인체 요골동맥과 경동맥의 혈액에코박동지수: 나이 및 뇌졸중과의 관계)

  • Bok, Tae-Hoon;Kong, Qi;Nam, Kweon-Ho;Choi, Jay Chol;Paeng, Dong-Guk
    • Journal of the Korean Society for Nondestructive Testing
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    • v.32 no.5
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    • pp.494-501
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    • 2012
  • In the present paper, the ultrasound blood images were measured at both the human radial artery(RA) and common carotid artery(CCA), depending on the age, and the pulsatility index of blood echogenicity(PIBE) was analyzed. In addition, the ultrasound blood images were measured at both RA and CCA of both the stroke patients and the control group, and PIBE was compared. PIBE of RA for the young group was similar with that for the old group ($0.13{\pm}0.11$ and $0.16{\pm}0.03$). PIBE of CCA for the young group, however, was larger than that for the old group ($0.70{\pm}0.21$ and $0.32{\pm}0.01$), and was more variable depending on the subject. Similarly, the fibrinogen concentrations of the patients ($336{\pm}61$ and $340{\pm}126mg/dl$) were more than that of the control group ($264{\pm}38$ and $257{\pm}43mg/dl$), for both RA and CCA. The results indicate the possibility of the ultrasonic test on the correlation between erythrocyte aggregation and stroke, and it is expected that the in-vivo EA measurement would be clinically useful.

A Cyclophilin from Griffithsia japonica Has Thermoprotective Activity and Is Affected by CsA

  • Cho, Eun Kyung;Lee, Yoo Kyung;Hong, Choo Bong
    • Molecules and Cells
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    • v.20 no.1
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    • pp.142-150
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    • 2005
  • Members of the multifunctional Cyp family have been isolated from a wide range of organisms. However, few functional studies have been performed on the role of these proteins as chaperones in red alga. For studying the function of cDNA GjCyp-1 isolated from the red alga (Griffithsia japonica), we expressed and purified a recombinant GjCyp-1 containing a hexahistidine tag at the amino-terminus in Escherichia coli. An expressed fusion protein, $H_6GjCyp-1$ maintained the stability of E. coli proteins up to $50^{\circ}C$. For a functional bioassay for recombinant $H_6GjCyp-1$, the viability of E. coli cells overexpressing $H_6GjCyp-1$ was compared with that of cells not expressing $H_6GjCyp-1$ at $50^{\circ}C$. After high temperature treatment for 1 h, E. coli overexpressing $H_6GjCyp-1$ survived about three times longer than E. coli lacking $H_6GjCyp-1$. Measurement of the light scattering of luciferase (luc) showed that GjCyp-1 prevents the aggregation of luc during mild heat stress and that the thermoprotective activity of GjCyp-1 is blocked by cyclosporin A (CsA), an inhibitor of Cyps. Furthermore, the Cyp-CsA complex inhibited the growth of E. coli under normal conditions. The results of the GjCyp-1 bioassays as well as in vitro studies strongly suggest that Cyp confers thermotolerance to E. coli.

Viscosity and Density Studies on the Second CMC of the Aqueous Solution of Dodecyl Pyridinium Chloride (粘性度 및 密度測定에 依한 Dodecyle Pyridinium Chloride 水溶液의 第二 CMC에 關한 硏究)

  • Young Won Youn;Kun Moo Lee
    • Journal of the Korean Chemical Society
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    • v.19 no.5
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    • pp.289-293
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    • 1975
  • According to the viscosity and density studies of an aqueous solution of dodecyl pyridinium chloride (DPC) it was shown that the 2nd critical micelle concentration (2nd cmc) existed in the solution in addition to the 1st cmc. The volume fraction ${\phi}_m$ of the hydrated micelle was calculated by using the following equation: ${\Pi}_{rm}=1+2.5{\phi}_m+14.1{\phi}_m^2$ It has been found that the increment of ${\phi}_m$ in the ${\phi}_m$ vs. $C_m$ curve decreased at near the 2nd cmc. And the partial specific volume ($\={v}$) of DPC obtained from the density measurement also decreased rapidly at near the 2nd cmc and remains constant value above the 2nd cmc. This may be attributed to a change in the micelle structure at the 2nd cmc caused by a variation in the type of aggregation and by a decrease in the counterion binding by the micelle.

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The Complexity of the Static Structures of Object-Oriented Systems by Analyzing the Class Diagram of UML (UML 클래스 다이어그램의 분석에 의한 객체지향 시스템의 정적 구조 복잡도 연구)

  • Chung, Hong;Hong, Dong-Kwon
    • Journal of the Korean Institute of Intelligent Systems
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    • v.14 no.6
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    • pp.793-799
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    • 2004
  • Many researches and validations for the complexity metrics of the object-oriented systems have been studied. Most of them are aimed for the measurement of the partial aspects of the systems, for example, the coupling between objects, the complexity of inheritance structures, the cohesion of methods, and so on. But the software practitioners want to measure the complexity of overall system, not partial. We studied the complexity of the overall structures of object-oriented systems by analyzing the class diagram of UML. The class diagram is composed of classes and their relations. There are three kinds of relations, association, generalization, and aggregation, which are making the structure of object-oriented systems to be difficult to understand. We proposed a heuristic metric to measure the complexity of object-oriented systems by putting together the three kinds of the relations. This metric will be helpful to the software developers for their designing tasks by evaluating the complexity of the structures of object-oriented system and redesigning tasks of the system.