• Title/Summary/Keyword: Mean Porosity

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The Preparation of Porous Silica Glass by the Sol-Gel Method -Change of Properties of Gel by Addition of Fromamide- (졸-겔법에 의한 다공질 실리카 유리의 제조에 관한 연구 -Formamide 첨가에 의한 겔의 성질 변화-)

  • 서정민;신대용;최성일;한상목
    • Journal of the Korean Ceramic Society
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    • v.30 no.3
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    • pp.169-174
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    • 1993
  • The porous silica glass prepared by the sol-gel method from the mixed solution of Si(OCH3)4, H2O, HCl and CH3OH with HCONH2 as a DCCA (Drying Control Chemical Additives). For investigation the characteristics of gels and glasses, we examined gels and glasses using TG-DTA, XRD, IR, SEM and porosimeter. The more content of formamide in the mixed solution increased, the more pore size and porosity of gel increased. In the excess formamide added gel, the properties of pore of gel were not so changed. The porous silica glass was prepared from the dry gel after heat treatment at 75$0^{\circ}C$. Porosity and mean pore size of the porous silica glass was 17~25% and 40~60$\AA$ relatively.

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Fabrication of Fe-Cr-Al Porous Metal with Sintering Temperature and Times (소결 온도와 유지 시간에 따른 Fe-Cr-Al 다공성 금속의 제조)

  • Koo, Bon-Uk;Lee, Su-In;Park, Dahee;Yun, Jung-Yeul;Kim, Byoung-Kee
    • Journal of Powder Materials
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    • v.22 no.2
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    • pp.100-104
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    • 2015
  • The porous metals are known as relatively excellent characteristic such as large surface area, light, lower heat capacity, high toughness and permeability. The Fe-Cr-Al alloys have high corrosion resistance, heat resistance and chemical stability for high temperature applications. And then many researches are developed the Fe-Cr-Al porous metals for exhaust gas filter, hydrogen reformer catalyst support and chemical filter. In this study, the Fe-Cr-Al porous metals are developed with Fe-22Cr-6Al(wt) powder using powder compaction method. The mean size of Fe-22Cr-6Al(wt) powders is about $42.69{\mu}m$. In order to control pore size and porosity, Fe-Cr-Al powders are sintered at $1200{\sim}1450^{\circ}C$ and different sintering maintenance as 1~4 hours. The powders are pressed on disk shapes of 3 mm thickness using uniaxial press machine and sintered in high vacuum condition. The pore properties are evaluated using capillary flow porometer. As sintering temperature increased, relative density is increased from 73% to 96% and porosity, pore size are decreased from 27 to 3.3%, from 3.1 to $1.8{\mu}m$ respectively. When the sintering time is increased, the relative density is also increased from 76.5% to 84.7% and porosity, pore size are decreased from 23.5% to 15.3%, from 2.7 to $2.08{\mu}m$ respectively.

Effect of build orientation on the accuracy and internal porosity of removable partial denture metal frameworks (적층 빌드 방향이 가철성 국소의치 금속 구조물의 정확도와 내부 다공성에 미치는 영향)

  • Geon Hee Ham;Ji-Hwan Kim
    • Journal of Technologic Dentistry
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    • v.46 no.3
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    • pp.73-83
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    • 2024
  • Purpose: This study aimed to investigate whether the accuracy and internal porosity of removable partial denture frameworks differ depending on the build direction in the selective laser melting method. Methods: A partially edentulous maxillary study model was scanned, and the anterior-posterior palatal bar was then digitally designed. The angles formed between the z-axis and the path of the insertion and removal were divided into five groups: -60°, -30°, 0°, 30°, and 60°. For each group, three removable partial denture metal frameworks were fabricated and used as specimens. The inner surface of each sample was scanned and superimposed on the design file to obtain the root mean square (RMS) value, and the average RMS value of each group was measured. One sample was randomly selected from each group, and the equivalent diameter and sphericity of the pores were analyzed using industrial X-ray three-dimensional computed tomography. To compare statistical differences between groups, the Kruskal-Wallis test of SPSS Statistics ver. 27.0 (IBM) was used (α=0.05). Results: The average RMS values of the whole inner surface accuracy of the specimens were in the order of -60°<0°<-30°<30°<60° (p<0.05). The equivalent diameter and sphericity of internal pores were significantly different among groups (p<0.001). Conclusion: The build orientation of the selective laser melting method influences the accuracy and internal porosity of removable partial denture frameworks.

The Effect of Potassium Hydroxide on the Porosity of Phenol Resin-based Activated Carbon Fiber

  • Jin, Hang-Kyo
    • Carbon letters
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    • v.7 no.3
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    • pp.161-165
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    • 2006
  • Activated carbon fiber could be prepared at 973 K by catalytic activation using potassium hydroxide. Phenol resin fiber (Kynol) was impregnated with potassium hydroxide ethanol solution, carbonized and activated at 973 K, resulting in activated carbon fibers with different porosities. The potassium hydroxide accelerated the activation of the fiber catalytically to form narrow micropore preferentially in carbon dioxide atmosphere. The narrow micropore volume of 0.3~0.4 cc/g, total pore volume of 0.3~0.8 cc/g, mean pore width of 0.5~0.7 nm was obtained in the range of 20~50% burnoff.

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Control of Pore Characteristics of Porous Glass in the $ZrO_2.SiO_2$ System Prepared by the Sol-Gel Method (졸-겔법으로 제조한 $ZrO_2.SiO_2$다공질유리의 세공제어)

  • 신대용;한상목
    • Journal of the Korean Ceramic Society
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    • v.30 no.6
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    • pp.485-491
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    • 1993
  • Porous glass in the ZrO2.SiO2 system containning up to 30mol% zirconia were prepared by the sol-gel method from metal alkoxides and their pore characteristics with reaction parameters were investigated. The gels were made by hydrolyzing and condensation of the mixed metla alkoxides and were converted into the porous glass by heating up to $700^{\circ}C$. As a results, the mean pore radius became larger with increasing contents of HCl, H2O and hydrolysis temperature, and an alcohol with a large molecular weight for making the porous glass. In the case of 20ZrO2.80SiO2 porous glass with heated at $700^{\circ}C$, HCl and H2O content was 0.3mol and 4mol, the specific surface area was 284$m^2$/g, average mean pore radius was about 19.4$\AA$, porosity was 22.55% and pore characteristics depended on heating temperature.

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Preparation of Porous Inorganic Materials by Foaming Slurry (슬러리 발포에 의한 연속성 무기질 다공체의 제조)

  • 박재구;이정식
    • Journal of the Korean Ceramic Society
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    • v.35 no.12
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    • pp.1280-1285
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    • 1998
  • Foaming method is presented the preparation of porous materials from high-concentrated kaolin silica and flyash slurries. The slurries were foamed dried and sintered respectively. The porosity of sintered ma-terials was about 70-75% Mean pore-size was the range of 70-150$\mu\textrm{m}$ and pore structure was continuous Sodium lauryl sulfate anionic surfactant was used as a foaming agent. The foaming ability and the froth sta-bility were increased with increasing the concentration of the foaming agent. But the size of the constituent bubble of froth after foaming process was not affected by the concentration of the foaming agent. These results showed that the mean pore-size of sintered materials was closely related to the froth stability which is related to the change of bubble-size during the drying process.

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Wind Engineering Study on the Surface-Pressure Characteristic of a Triangular Prism Located Behind a Porous Fence (다공성 방풍펜스 후방에 놓인 삼각프리즘의 표면압력특성에 관한 풍공학적 연구)

  • Park, Cheol-U;Lee, Sang-Jun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.11
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    • pp.1496-1508
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    • 1997
  • The effects of porous wind fence on the pressure characteristics around a 2-dimensional prism model of triangular cross-section were investigated experimentally. The fence and prism model were embedded in a neutral atmospheric surface boundary layer over the city suburb. In this study, various fences of different porosity, back fence, inclination angle of prism and location of additional back prisms were tested to investigate their effects on the pressure and wall shear stress of the prism surface. The fence and prism had the same height of 40 mm and Reynolds number based on the model height was Re=3.9*10$^{4}$. The porous fence with porosity 40% was found to be the best wind fence for decreasing the mean and pressure fluctuations on the prism surface. By installing the fence of porosity 40%, the wall shear stress on the windward surface of prism was largely decreased up to 1/3 of that without the fence. This indicates that the porous fence is most effective to abate the wind erosion. Pressure fluctuations on the model surface were decreased more than half when a back fence was located behind the prism in addition to the front fence. With locating several back prisms and decreasing the inclination angle of triangular prism, the pressure fluctuations on the model surface were increased on the contrary.

THE EFFECT OF SPRUE DESIGN ON THE MARGINAL REPRODUCIBILITY OF CAST TITANIUM CROWNS (주입선 형태가 티타늄 주조관의 변연재현성에 미치는 영향)

  • Park Jae-Kyoung;Jeong Chang-Mo;Jeon Young-Chan
    • The Journal of Korean Academy of Prosthodontics
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    • v.40 no.4
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    • pp.352-364
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    • 2002
  • There has been a great interest in the use of titanium for fixed and removable prostheses in recent because of its excellent biocompatibility. However the high melting temperature and chemical reactivity of titanium necessitates casting systems different from those used in conventional casting. The current titanium casting systems are based on an electric-arc design for melting the metal in an argon atmosphere and its exclusive investment. Despite the new developments in Ti casting systems, inadequate mold filling and internal porosity are frequently observed casting defects. Therefore, the study on the fabrication technique including sprue design to solve these casting defects is still necessary. In this study to evaluate the effect of sprue design on the castability of simulated cast titanium crowns, 10 cylindrical cast crowns for each group with four different sprue design(Single group. Double group, Runner bar group. Reservoir group) were fabricated. An impression of the entire casting margin was made and cut at $90^{\circ}$ intervals, and the sections were photographed in a microscope at $100{\times}$ magnification to record marginal discrepancy. The internal porosities of the cast crowns were disclosed by radiographs. Within the limits of this study. the following conclusions were drawn. 1. The overall mean marginal discrepancies for each group were as follows: Double group, $43.65{\mu}m$; Reservoir group, $50.27{\mu}m$; Single group, $54.17{\mu}m$; Runner bar group, $58.90{\mu}m$ (p<0.05). 2. The mean of marginal discrepancies for wax patterns was $10.65{\mu}m$. 3 The numbers of internal porosity showed the most in Runner bar group followed by Single group, Reservoir group, and Double group.

Effects of Nickel Supports on Hydrogen Permeability of Vanadium based Membrane (니켈 지지체를 이용한 바나듐기 분리막의 수소 투과특성)

  • Cho, Kyoungwon;Choi, Jaeha;Jung, Seok;Kim, Raymundk.I.;Hong, Taewhan;Ahn, Joongwoo
    • Journal of Hydrogen and New Energy
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    • v.24 no.3
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    • pp.200-205
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    • 2013
  • The separation of hydrogen depends on porosity, diffusivity and solubility in permeation membrane. Dense membrane is always showing a solution diffusion mechanism but porous membrane is not showing. Therefore, porous membrane has a good hydrogen flux due to pore is carried out transferred media. This mechanism is named as the Knudsen diffusion. Hydrogen molecules or hydrogen atoms are diffused along pore that is a mean free path. In this study, complex layer hydrogen permeation membrane was fabricated by hot press process. And then, it was evaluated and calculated to relationship between hydrogen permeability and membrane porosity.

Analysis of Non-Darcy Flour in Tide Embankment (호안제체에서 Non-Darcy 흐름해석)

  • Choi, Hung-Sik
    • Journal of Korea Water Resources Association
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    • v.37 no.2
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    • pp.87-96
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    • 2004
  • The simulation results using i- V relationship of non-Darcy flow through tide embankment by Li et al.(1998) agree well to the observed data. The use of i- V relationship is applicable to the engineering practice and the correct input of porosity is necessary. The non-Darcy flow based on the pipe flow and Taylor's definition for mean hydraulics radius in rockfill material is applicable to the block and caisson materials. The correct calculation of flow through tide embankment enables the accurate calculation of velocity at final closing gap and the prediction of inner water level after tide embankment construction as well.