• Title/Summary/Keyword: Maxwell displacement current (MDC)

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Measurement of Maxwell Displacement Current of Polyamic Acid Containing p-Cyanoazobenzene of the Water Surface (p-Cyanoazobenzene을 함유한 Polyamic Acid의 수면상의 Maxwell 변위 전류 측정)

  • Park, Keun-Ho;Shon, Byung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.14 no.3
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    • pp.55-61
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    • 1997
  • Maxwell displacement current(MDC) measuring technique has been applied on the study of monolayers of polyamic acid containing p-cyanoazobenzene. The displacement current was generated from monolayers on the water surface by monolayer compression and expansion. Displacement current was generated when the area per molecule was about $140{\AA}^2$ and $100{\AA}^2$. Maxwell displacement currents were investigated in connection with monolayer compression cycles. It was found that the maximum of MDC appeared at the molecular area just before the initial rise of surface pressure in compression cycles.

A Study on the Electrical Properties of Organic Miked Films (유기혼합막의 전기특성에 관한 연구)

  • 조수영;이경섭
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.503-506
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    • 2000
  • Molecular switching in azobenzene mixed monolayers on a water surface was investigated by means of Maxwell displacement current(MDC) measurement. It was found that the change in the vertical component of the dipolemoment of the mixed monolayer during visible light irradiation was almost the same as that flowing during UV light irradiation. Also MDC was generated but it depended on the molar ratio. As a result. It's phtoisomerization progressed by 8A5H in mixed films.

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A Study on the Langmuir-Blodgett Films of Polyamic Acid Monolayer Containing p-Nitroazobenzene (p-Nitroazobenzene을 함유한 Polyamic Acid 단분자층의 Langmuir-Blodgett 막에 관한 연구)

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.2
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    • pp.213-218
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    • 2011
  • Displacement current measuring technique has been applied on the study of polyamic acid monolayer containing p-nitroazobenzene. The displacement current was generated from monolayer on the water surface by monolayer compression and expansion. Maxwell displacement current(MDC) was generated when the area per molecule was about $200{\AA}^2$ and $70{\AA}^2$. Maxwell displacement currents were investigated in connection with monolayer compression cycles. It was found that the maximum of MDC appeared at the molecular area just before the initial rise of surface pressure in compression cycles. The monolayer surface morphology of the LB film have been measured by Atomic Force Microscope(AFM). As a result, we confirmed that the microscopic properties of LB film by AFM showed the good orientation of monolayer molecules and the thickness of monolayer was 3.5-4.1nm.

A Study on the Photoisomerization of Langmuir-Bledgett Films of Fatty Acid (지방산 Langmuir-Bledgett막의 광이성화에 관한 연구)

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.16 no.3
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    • pp.193-198
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    • 1999
  • Maxwell displacement current(MDC) measuring technique has been applied on the study of monolayers of fatty acid. The displacement current was generated from monolayers on the water surface by monolayer compression and expansion. Displacement current was generated when the area per molecule was about $130{\AA}^2$. MDCs were investigated in connection with monolayer compression cycles. It was found that the current pulses were generated over the entire range of molecular area, and the maximum of MDC appeared at the molecular area just before the initial rise of surface pressure in compression cycles. We investigated the change in absorption spectra of the fatty acid(8A5H) monolayer LB film due to cis-trans photoisomerization. It was found that the absorption spectrum of the 8A5H LB film was induce to photoisomerization by alternate irradiation with UV and visible light irradiation.

The Measurement of Maxwell Displacement Current of Phospholipid Monolayers on the Water Surface

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.14 no.2
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    • pp.35-40
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    • 1997
  • The organization of phospholipid monolayers and their monolayers mixed with fatty acid containing azobenzene on the water surface was investigated by means of the displacement current measurement method. The phase transition from the gaseous phase to the gaseous-fluid phase which accompanies the polar ordering of phospholipid molecules was detected in the range of immeasurably low surface pressure. The molecular area which gives the onset of the transition was determined for phospholipid monolayers. The Maxwell displacement current(MDC) pulses were generated across mixed monolayers due to the photoisomerization of fatty acid containing azobenzene by alternating irradiation of ultraviolet and visible light, because the condensation of pure azobenzene monolayers was loosened by the introduction of phospholipids into the monolayers. The displacement currents generated during light irradiation were also investgated in connection with monolayer compression cycles. It was found that the maximum of MDC appeared at the molecular area just before the initial rise of surface pressure in compression cycles.

A Study on the Photoisomerization of Fatty Acid and Polyamic Acid Mixture (지방산과 폴리아미드산 혼합물의 광이성질화 현상에 관한 연구)

  • 박근호;박태곤
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.8
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    • pp.695-701
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    • 2002
  • Maxwell displacement current (MDC) measuring technique has been applied on the study of monolayers of fatty acid and polyamic acid mixture. The displacement current was generated from monolayers on the water surface by monolayer compression and expansion. Displacement current was generated when the area per molecule was about 132 $^2$and 115 $^2$just before the initial rise of the surface pressure during the 1st and 2nd mixed monolayer compressions cycle, respectively. Maxwell displacement currents were investigated in connection with mixed monolayer compression cycles. It was found that the maximum of MDC appeared at the molecular area just before the initial rise of surface pressure in compression cycles. Ultra thin film of fatty acid and polyamic acid mixture was prepared on the hydrophilic quartz plate by Langmuir-Blodgett (LB) method. The precursor LB film was heated in a vacuum dry oven at 12$0^{\circ}C$ in order to convert it into the LB film of polyimide. The absorption spectra of LB films were also induced photoisomerization by UV and visible light irradiation.

A Study on the Maxwell Displacement Current in Monolayer of L-α-Dilauryl phosphatidylcholine on the Water Surface (수면상에서 L-α-Dilauryl phosphatidylcholine 단분자층의 맥스웰 변위전류에 관한 연구)

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.3
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    • pp.522-527
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    • 2015
  • We applied a displacement current measurement technique for the study of L-${\alpha}$-dilauryl phosphatidylcholine (DLPC) monolayer. Displacement current was generated at the DLPC monolayer on the water surface, while induced by compression and expansion of the monolayer. Generation of Maxwell displacement current (MDC) was observed when surface areas per DLPC molecule were approximately $200{\AA}^2$ and $40{\AA}^2$. We investigated MDC for monolayer compression cycles, and found that MDC reached the maximum at the molecular area, which was measured right before surface pressure began to increase during compression cycles. The monolayer surface morphology of Langmuir-Blodgett (LB) films was characterized using atomic force microscope (AFM). As a result, we measured the result from the microscopic properties shown in the AFM images of LB films that molecules in the monolayer were in good orientations and the thickness of the monolayer ranged from 5 to 10 nm.

Generation of Maxwell Displacement Current Across Single monolayers due to Phase transition

  • Mitsumasa Iwamoto;Wu, Chen-Xu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.6.1-10
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    • 1996
  • Starting from the Debye theory of rotational Brownian motion equation, we derive an expression for explaining the generation of Maxwell displacement current (MDC) across single monolayers on a material surface. The orientational order parameter and the dielectric relaxation the of monolayers are derived. Based on fille analyses developed here, we examine the MDC across phospholipid monolayers with thermal stimulation due to the change in the spontaneous polarization, and the generation of MDC from 4-cyano-4\`-5-alkayl-biphenyl(5CB) Langmuir-film at the onset of transition by monolayer compression

A Study on the Photoisomerization of Functional Polyimide Monolayers (기능성 폴리이미드 단분자막의 광이성화 현상에 관한 연구)

  • 박근호;강동완;김성일;박태곤
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.475-478
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    • 2000
  • Maxwell displacement current(MDC) was generated when the area per molecule was about 140${\AA}$$^2$and 100${\AA}$$^2$. MDC were investigated in connection with monolayer compression cycles. It was found that the maximum of MDC appeared at the molecular area just before the initial rise of surface pressure in compression cycles. The absorption spectra of polyamic acid containing p-methoxyazobenzene in a mixture of N,N-dimethylacetamide(DMAc) and benzene(1:1 by volume) solution was induced photoisomerization by UV and visible light irradiation. The precursor LB film was heated in a vacuum dry oven at 120$^{\circ}C$ in order to convert it into the LB film of polyimide. The absorption spectra of LB films were also induced photoisomerization by UV and visible light irradiation.

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Characteristics of Ultrathin Film Prepared through Nano-Sized Langmuir Blodgett Monolayer of Functionalized Polyimide

  • Park, Keun-Ho;Lee, Soo
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.2
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    • pp.224-231
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    • 2009
  • Techniques measuring Maxwell displacement current (MDC) and LB films surface measuring technique have been applied to the study of monolayers of polyamic acid containing azobenzene. MDCs was generated from monolayers on the water surface by monolayer compression and expansion. It was generated when the area per molecule was about $103{\AA}^2\;and\;78{\AA}^2$ just before the initial rise of the surface pressure during the 1st and 2nd mixed monolayer compressions cycle, respectively. It was the maximum of MDCs appeared at the molecular area just before the initial rise of surface pressure in compression cycles, and we have found that the increase of aggregations causes the noticeable increase of the surface roughness.