A Study on the Photoisomerization of Functional Polyimide Monolayers

기능성 폴리이미드 단분자막의 광이성화 현상에 관한 연구

  • 박근호 (창원대학교 공업화학과) ;
  • 강동완 (창원대학교 공업화학과) ;
  • 김성일 (창원대학교 공업화학과) ;
  • 박태곤 (창원대학교 공업화학과)
  • Published : 2000.07.01

Abstract

Maxwell displacement current(MDC) was generated when the area per molecule was about 140${\AA}$$^2$and 100${\AA}$$^2$. MDC were investigated in connection with monolayer compression cycles. It was found that the maximum of MDC appeared at the molecular area just before the initial rise of surface pressure in compression cycles. The absorption spectra of polyamic acid containing p-methoxyazobenzene in a mixture of N,N-dimethylacetamide(DMAc) and benzene(1:1 by volume) solution was induced photoisomerization by UV and visible light irradiation. The precursor LB film was heated in a vacuum dry oven at 120$^{\circ}C$ in order to convert it into the LB film of polyimide. The absorption spectra of LB films were also induced photoisomerization by UV and visible light irradiation.

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