• Title/Summary/Keyword: Maximum absorption rate

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Ultrasonic Relaxation for Complexation Reaction Between β-Cyclodextrin and Butanoic Acid in Aqueous Solution (사이크로덱스트린과 부탄산의 복합체 형성반응에 의한 초음파 완화)

  • Bae, Jong-Rim
    • The Journal of the Acoustical Society of Korea
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    • v.31 no.2
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    • pp.100-106
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    • 2012
  • The aim of this work was to reveal the effect of butanoic acid in its dissociated form and undissociated form as a guest molecule on the kinetic parameters in an inclusion reaction with ${\beta}$-cyclodextrin (${\beta}$-CD). Ultrasonic absorption measurements in the frequency range from 0.2 to 45 MHz were carried out for ${\beta}$-CD solutions with butanoic acid at $25^{\circ}C$ by ultrasonic relaxation method. The rate and the equilibrium constants were obtained from the guest concentration dependence of the relaxation frequency, and the standard volume change of the complexation reaction were obtained from the maximum absorption per wavelength. A single relaxational absorption was observed, and the cause of the relaxation was attributed to a perturbation of the chemical equilibrium associated with a complexation reaction between ${\beta}$-CD and butanoic acid. These results were compared with those in solutions containing both ${\beta}$-CD and different guest molecules. It was found that the hydrophobicity of guest molecules played an important role in the formation of the inclusion complex and also that the charge on the carboxylic group had a considerable effect on the kinetic characteristics of the complexation reaction.

A Study on Characteristics of Fluid Flow on Direct Absorption Receiver from Solar Energy (태양(太陽)에너지의 직접흡수식(直接吸收式) 수열판상(受熱板上)의 유체유동특성(流體流動特性)에 관(關)한 연구(硏究))

  • Pak, Ee-Tong
    • Solar Energy
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    • v.4 no.2
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    • pp.13-28
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    • 1984
  • Direct Absorption Receiver and Thermal Storage System is a complex problem. This paper describes only characteristic of fluid flow on the receiver. The fluid thicknesses of Molten Salts (Melting Point : $397^{\circ}C$) flowing on the receiver of modified protopype ($10m{\times}10m$) were calculated theorectically, changing the receiver slope from 60 degree to 85 degree (5 steps). The receiver temperatures were $430^{\circ}C$ at the top part and $950^{\circ}C$ at the low part. The flow thickness of the Molten Salts at the top part of the receiver are around 1.9mm in the case of maximum insolution ($50{\times}10^6$juoule/sec; 58.898kg/sec of flow rate) and 2.0mm at the low part. In the case of 3/10 of maximum insolation (flow rate = 17.669kg/sec) the flow thickness at the top part are around 0.9mm and 0.4mm at the low part, and in the case of 1/10 of maximum insolation (flow rate = 5.889 kg/see) the flow thickness at the top part are around 0.6mm and 0.3mm at the low part. From experimental measurements of a normal fresh water thickness flowing on the model plate ($12.7cm{\times}111.76cm$), around 0.8mm at the top part of the plate and around 0.7mm at the low part were obtained in the case of maximum insolation (flow rate = 0.12496 kg/see). In the case of 3/10 (flow rate = 0.03748 kg/see) and 1/10 (flow rate = 0.012496 kg/see) of maximum insolation, around 0.5mm and 0.4mm at the top part, and around 0.3mm and 0.2mm at the low part were obtained respectively. The reason why the thickness of the Molten Salts increase at the low part of the receiver only in case of maximum insolation is that decreasing rate of the viscosity of the Molten Salts is larger than decreasing rate of the density of the Molten Salts during temperature increase from the top to the low receiver plate and decrease of the fluid velocity in accordance with continuity principle. In all cases without the above maximum insolation, the thickness of the Molten Salts and the fresh water decreased at the low part of the plate because of gravity force effects rather than friction effects and of continuity principle. All simillar flow patterns were obtained through all cases of the insolation making an exception of only maximum insolation.

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Dynamic tensile behavior of SIFRCCs at high strain rates

  • Kim, Seungwon;Park, Cheolwoo;Kim, Dong Joo
    • Computers and Concrete
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    • v.26 no.3
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    • pp.275-283
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    • 2020
  • Reinforced concrete (RC) does not provide sufficient resistance against impacts and blast loads, and the brittle structure of RC fails to protect against fractures due to the lack of shock absorption. Investigations on improving its resistance against explosion and impact have been actively conducted on high-performance fiber-reinforced cementitious composites (HPFRCCs), such as fiber-reinforced concrete and ultra-high-performance concrete. For these HPFRCCs, however, tensile strength and toughness are still significantly lower compared to compressive strength due to their limited fiber volume fraction. Therefore, in this study, the tensile behavior of slurry-infiltrated fiber-reinforced cementitious composites (SIFRCCs), which can accommodate a large number of steel fibers, was analyzed under static and dynamic loading to improve the shortcomings of RC and to enhance its explosion and impact resistance. The fiber volume fractions of SIFRCCs were set to 4%, 5%, and 6%, and three strain rate levels (maximum strain rate: 250 s-1) were applied. As a result, the tensile strength exceeded 15 MPa under static load, and the dynamic tensile strength reached a maximum of 40 MPa. In addition, tensile characteristics, such as tensile strength, deformation capacity, and energy absorption capacity, were improved as the fiber volume fraction and strain rate increased.

Varietal Difference in Water Absorption Characteristics of Milled Rice, and Its Relation to the Other Grain Quality Components

  • Hae Chune, Choi;Jeong Hyun, Chi;Soo Yeon, Cho
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.44 no.3
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    • pp.288-295
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    • 1999
  • Nineteen japonica and Tongil-type rices were selected from seventy nine Korean and Japanese rice cultivars grown in 1989 based on the water uptake behavior of milled rice under the room temperature and boiling conditions. The selected rice cultivars were investigated for water absorbability and some physicochemical characteristics of milled rice, proper water amount for cooking and sensory evaluation of cooked rice. The relationships among the tested grain properties were also examined. The highest varietal variation of water uptake rate was observed at twenty minutes after soaking in water. The maximum water uptake of milled rices at room temperature occurred mostly at about eighty minutes after soaking in water. Newly harvested rices showed a significantly lower water uptake rate of milled rice at 20 minutes after soaking, a relatively higher maximum water absorption ratio under the room temperature, and the less water uptake and volume expansion of boiled rice compared with the one-year old rice samples. The water uptake rate and the maximum water absorption ratio showed significantly negative correlations with the K/Mg ratio and alkali digestion value(ADV) of milled rice. The rice materials showing the higher amount of hot water absorption exhibited the larger volume expansion of cooked rice. The harder rices with lower moisture content revealed the higher rate of water uptake at twenty minutes after soaking and the higher ratio of maximum water uptake under the room temperature condition. These water uptake characteristics were not associated with the protein and amylose contents of milled rice ansd the palatability of cooked rice. The water/rice ratio(in w/w basis) for optimum cooking was averaged to 1.52 in dry milled rices (12% wet basis) with varietal range from 1.45 to 1.61 and the expansion ratio of milled rice after proper boiling was averaged to 2.63(in v/v basis). The water amount needed for optimum cooking was the lowest in Cheongcheongbyeo (Tongil-type rice) and the highest in Jinbubyeo, and the amount could be estimated with about 70% fittness by the multiple regression formula based on some water uptake characteristics, ADV and amylose content of milled rice as the independent variables. Nineteen rice cultivars were classified into seven groups based on scatter diagram projected by principal component analysis using eight properties related to water uptake and gelatinization of milled rice.

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A Mathematical Model on the Absorption Rate of Carbon-Dioxide in Mixed Gas During the Transient State of Rotary Type Absorbers (과도상태의 회전형 흡수기에서 혼합기체 중 이산화탄소 흡수량 계산 모델)

  • Paik, Hyun-Jong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.12
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    • pp.1729-1737
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    • 2002
  • A mathematical model for the prediction of carbon-dioxide absorption rate during the transient state of rotary type absorber is developed. The rotary type absorber operates using a fast rotating porous structure and clean water. The model for the transient state rotary type absorbers is based on the steady state model of packed tower absorber. The paper manipulates the operating data of an arbitrary quasi-steady state condition of rotary type absorber for the determination of the coefficients involved in the model developed. The prediction accuracy is evaluated from the measured data of rotary type absorber operated under fast transient state. The measured data include the mole fraction of carbon dioxide in mixed gas and the pressure of absorber. The relative error in carbon dioxide prediction is estimated to be 20% at maximum. The model is successfully applied for the prediction of the behavior of a closed cycle diesel engine.

Drug Interaction of Cimetidine and Cyclosporine in Human (정상지원자에서 Cimetidine과 Cyclosporine의 약물상호작용)

  • Choi, In;Choi, Jun Shik
    • Korean Journal of Clinical Pharmacy
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    • v.7 no.2
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    • pp.51-63
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    • 1997
  • The effect of cimetidine administration on the pharmacokinetic parameters of cyclosporine were determined in healthy voluteers. This study was performed in 10 volunteers of age ranged 22-48 years and body weight 48-62 kg. This study was performed with cross-over design. Mono cyclosporine and cyclosporine metabolites was extracted from whole blood analysed by fluororescence polarization immune assay (TDX-FLX, Abbott). After coadministration of cimetidine (300 mg) with cyclosporine (300 mg) orally, maximum concentration of mono cyclosporine was significantly increased $1221{\pm}143\;ng/ml\;to\;1562{\pm}184\;ng/ml$ (P<0.05), area under the time curve of cyclosporine (12 hr) also was significantly increased $7478{\pm}829\;ng/ml{\cdot}hr\;to\;9721{\pm}879\;ng/ml{\cdot}hr$ (P<0.05) and absolute baioavailability of cyclosporine was increased $50\pm5.6\%\;to\;57.6\pm6.1\%\;(P<0.05)$ compared to control group. The blood concentrations of cyclopsorine metabolites were significantly decrased (P<0.05) after coadministration of cimetidine. In cimetidine pretreated group, blood mono cyclosporine concentrations were increased significan시y $1220.0\pm203.00\;ng/ml\;to\;1510.0\pm204.00\;ng/ml$ compared with control group (P<0.05). In the mono cyclosporine pharmacokinetic parameter after oral administration absorption rate and maximum concentration were significantly higher in cimetidine coadministered and pretreated group than control group (P<0.05). The ratio of metabolites and mono cyclosporine concentrations was decreased significantly from $70.8\%\;in\;control\;to\;34.8\%$ in coadministration of cimetidine orally. As matter of facts these reults are considered to inhibition of cyclosporine hepatic metabolism and increasing of cyclosporine absorption rate in gastrointestinal tract because of maintaining cyclosporine stability in elevated gastric pH by cimetidine. We considered, it appeares that cimetidine increase bioavailability of cyclosporine by increasing oral absorption and by decreasing hepatic clearance. But the absorption and clearance of cyclosporine was highly variable individually, and therefore we consider that cyclosporine blood level monitoring would be essential in patients with cimetidine co-administration.

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A Study on the COP Improvement of Absorption Chillers by Recovering Heat from the Condenser (응축기 배열회수에 의한 흡수식 냉동기의 고효율화에 관한 연구)

  • Park, Chan-Woo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.18 no.9
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    • pp.738-744
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    • 2006
  • In order to utilize the condensation heat of refrigerants in condenser on the absorption chiller system, the solution cooled condenser (SCC) was proposed using the weak solution of absorber as a cooling medium. The increase of COP with the increase of UA of the solution cooled condenser was approximately 0.009 in maximum with single effect one, and is about maximum 0.008 in occasion of double effect one with series flow compared to that without. In the case of heat exchanger, effectiveness is about 0.85, it's increments are 0.008 and 0.0072, respectively. And solution cooled condenser is more effective device in the single effect absorption system than double effect system for the principle of operation. On the other hand, as the solution split ratio increases when the value of UA is fixed, COP is increased and as the solution split ratio increases when the value of UA is fixed, COP is increased. If the flow rate of cooling water or the value of UA is reduced in order to increases the heat recovery of solution cooled condenser, heat recovery of solution cooled condenser is increased a little but COP is decreased as the system pressure is increased.

A study on the Characteristics of the High Efficiency absorption Chiller by Heat Recovering from Condenser (응축기 배열 회수에 의한 흡수식 냉동기의 고효율화에 관한 연구)

  • Park, Chan-Woo
    • Proceedings of the SAREK Conference
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    • 2006.06a
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    • pp.46-51
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    • 2006
  • In order to utilize the refrigerants condensation heat of condenser on the absorption chiller system, the solution cooling condenser(SCC) were proposed, which weak solution of absorber outlet use as a cooling water. As the UA of the solution cooling condenser increased, increasement of COP is about maximum 0.09 in occasion of single effect and is about maximum 0.08 in occasion of double effect series flow. In the case of heat exchanger efficiency is about 0.85, it's increments are 0.08 and 0.072, each. And solution cooling condenser is a more effective device in the single effect absorption system more than double effect system for the principle of operation. In order to increases the heat of solution cooling condenser, if reduce the flow rate of cooling water or the value of UA, it makes COP increase a little, but it brought COP decrease because of increasing the pressure of system.

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Experimental research on dynamic response of red sandstone soil under impact loads

  • Wang, Tong;Song, Zhanping;Yang, Jianyong;Wang, Junbao;Zhang, Xuegang
    • Geomechanics and Engineering
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    • v.17 no.4
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    • pp.393-403
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    • 2019
  • The cycling impact test of red sandstone soil under different axial pressure and different impact loads are conducted to reveal the mechanical properties and energy consumption mechanism of red sandstone soil with static-dynamic coupling loading. The results show that: Under the action of different axial pressure and different impact loads, the peak stress of the specimen increases, and then tends to be stable with the times of impact. With the increase of impact times, the specific energy absorption value of the red sandstone soil specimen is increased first and then gentle development trend. When the impact loads are certain, the larger the axial pressure is, the smaller the peak value of energy absorption, which indicates that the energy utilization rate is not high under the condition of large axial pressure. Through the analysis of energy utilization, it is found that the smaller the impact load, the higher the energy utilization rate. The greater the axial pressure, the lower the energy utilization rate. when the axial pressure is large, the impact loads corresponding to the maximum values of reflectivity, transmissivity and absorptivity are the same. The relationship between reflectivity and transmissivity is negatively correlated.

Primary Productivity and Matter Economy of a Maize Plant Population. III. Phosphorus Economy in Relation to Dry Matter Production (옥수수 개체군의 일차생산성과 물질경제. 3. 건물생산과 인경제)

  • Huque, M. Anwarul;Seung-Dal Song
    • Journal of Plant Biology
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    • v.24 no.1
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    • pp.1-12
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    • 1981
  • Phosphorus dynamics in terms of specific absorption rate, inflow and outflow rates. turnover rate, demand and supply, and utility index of a high yield Zea mays L. cv. Bokgyo field were evaluated using an analysis of successive production structures. The analysis was adopted for measuring quantitative changes in the population by stratified clip technique on every two weeks during the growing season. The seasonal trends of specific absorption rate (2. 4 mg P/g/day in maximum) and specific absorption efficiency (0. 03) closely correlated with that of relative growth rate of the population. The overall inflow and outflow of phosphorus was 3.41 g P/$m^2$/yr showing the maximum inflow of 2.99 g P/$m^2$/month in July. While the maximum phosphorus standing crop was 1.4 g P/$m^2$ showing the maximum turnover rate of 178% in late June. The accumulation of phosphorus along plant height declined monotonically in stems and roots but increased in foliage after heading. The proportions of the total annual demand of phosphorus were 24.4% for leaves, 22.5% for stems, 49.6% for fruits and 3.5% for roots. These demands were met with internal (18.2 %) and external (81.8 %) supplies. The seasonal highest phosphorus utility index was 1,091 in early June, while the average value was 655.

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