• Elastomers and Composites
• /
• v.47 no.4
• /
• pp.355-363
• /
• 2012

A series of poly(hydroxyamide)s (PHAs) having trifluoromethyl group were prepared by direct polycondensation of aromatic diimide-dicarboxylic acids with 2,2-bis(3-amino-4-hydroxyphenyl)hexafluoropropane by thionyl chloride and triethyl amine in N-methyl-2-pyrrolidinone (NMP). The PHAs exhibited inherent viscosity in the range of 0.54-0.96 dL/g at $35^{\circ}C$ in DMAc solution. All PHAs were readily soluble in a variety of organic solvents, whereas the polybenzoxazoles (PBOs) were quite insoluble except partially soluble in sulfuric acid. PHAs were converted to PBOs by thermal cycling reaction with heat of endotherm. The maximum weight loss temperature of the PHAs occurred in the range of $559-567^{\circ}C$. The PBOs showed relatively high char yields in the range of 47-59%. Pyrolysis Combustion Flow Calorimeter (PCFC) results of the PBOs showed 12-19 W/g heat release rate (HRR), and 2.7-3.6 kJ/g total heat release (total HR). The HRR of PBO 1 showed the lowest value of 12 W/g, which was 37% lower than that of PBO 3 (19 W/g).

• Korean Journal of Remote Sensing
• /
• v.24 no.4
• /
• pp.359-367
• /
• 2008

TRMM TMI data were used to investigate a relationship between physical parameters from microwave sensor and typhoon intensities from June to September, 2004. Several data such as 85GHz brightness temperature (TB), polarization corrected temperature (PCT), precipitable water, ice content, rain rate, and latent heat release retrieved from the TMI observation were correlated to the maximum wind speeds in the best-track database by RSMC-Tokyo. Correlation coefficient between TB and typhoon intensity was -0.2 - -0.4 with a maximum value in the 2.5 degree radius circle from the center of tropical cyclone. The value of correlation between in precipitable water, rain, latent heat, and typhoon intensity is in the range of 0.2-0.4. Correlation analysis with respect to storm intensity showed that maximum correlation is observed at 1.0-1.5 degree radius circle from the center of tropical cyclone in the initial stage of tropical cyclone, while maximum correlation is shown in 0.5 degree radius in typhoon stage. Correlation coefficient was used to produce regressed intensities and adopted for typhoon Rusa (2002) and Maemi (2003). Multiple regression with 85GHz TB and precipitable water was found to provide an improved typhoon intensity when taking into account the storm size. The results indicate that it may be possible to use TB and precipitable water from satellite observation as a predictor to estimate the intensity of a tropical cyclone.

• Journal of Korean Tunnelling and Underground Space Association
• /
• v.23 no.1
• /
• pp.47-60
• /
• 2021

Hydrogen is a next-generation energy source, and according to the roadmap for activating the hydrogen economy, it is expected that industries to stably produce, store, and transport of hydrogen as well as the supply of hydrogen fuel cell vehicles will be made rapidly. Accordingly, safety measures for accidents of hydrogen vehicles in confined spaces such as tunnels are required. In this study, as part of a study to ensure the safety of hydrogen fuel cell vehicles in road tunnels, a basic investigation and research on the risk of fire and explosion due to gas leakage and hydrogen tank rupture among various hazards caused by hydrogen fuel cell vehicle accidents in tunnels was conducted. The following results were obtained. In the event of hydrogen fuel cell vehicle accidents, the gas release rate depends on the orifice diameter of TPRD, and when the gas is ignited, the maximum heat release rate reaches 3.22~51.36 MW (orifice diameter: 1~4 mm) depending on the orifice diameter but the duration times are short. Therefore, it was analyzed that there was little increase in risk due to fire. As the overpressure of the gas explosion was calculated by the equivalent TNT method, in the case of yield of VCE of 0.2 is applied, the safety threshold distance is analyzed to be about 35 m, and number of the equivalent fatalities are conservatively predicted to reach tens of people.

• Fire Science and Engineering
• /
• v.27 no.2
• /
• pp.62-69
• /
• 2013

In this study, a full scale experiment was carried out to analyze the heat and smoke movement. The experiment was conducted a kindergarten that is scheduled to reconstruction. The kindergarten is a two-story building and the area of each floor is 252 $m^2$. 36 l heptane was used as a fuel and heptane was burned in a 0.8 m square steel pool. Maximum heat release rate was 1.7 MW at natural condition. Smoke movement and temperature variation were measured during the experiment. In the first floor corridor, smoke was moved downward about 1.4 m at 1 minute after a fire. Corridor was filled with smoke at 4 minutes after a fire. In the second floor, temperature was maintained at $70^{\circ}C$ or less. But, second floor rooms were filled with smoke.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.9 no.5
• /
• pp.548-554
• /
• 1985

This research is to find a means of reducing diesel engine combustion noise with none or minimum sacrifice of engine performance by investigating the influence of Cylinder Pressure Level(CPL). For this purpose, modified Wiebe's combustion function, considering the heat release curve as a combustion of both premixed and diffusive combustion portion, was exclusively used to obtain the indicator diagram and computer coeds were developed for the numerical analysis. Following are the results of this research. (1) CPL increases almostly with lag of ignition timing increasing .alpha. and decreasing. theta.$_{d}$, but at the crank angle with the maximal efficiency, CPL is independent of .alpha. and .theta.$_{d}$ with constant value of 200 dB especially at the low frequency. (2) For the constant ignition timing, the effects of .alpha. and .theta.$_{d}$ on CPL were the most significant at the frequency of about 1KHz and 300Hz respectively. (3) For the constant value of .alpha. and .theta.$_{d}$, CPL increases linearly with load but thermal efficiency increase very rapidly with maximum value of load Q$_{T}$=30-40 MJ/Kmol, then starts to decrease slowly. (4) The most effective way of reducing combustion noise without sacrificing thermal efficiency, is to decrease .alpha.. In the case of constant .alpha., there always exists a optimum value of .theta.$_{d}$ with respect to the various compression ratio.o..atio.o..

• International Journal of Automotive Technology
• /
• v.8 no.4
• /
• pp.421-428
• /
• 2007

This paper investigates the combustion and emission characteristics of a compression ignition engine fueled with neat and blended Shell's gas-to-liquid (GTL) fuel, which was derived from natural gas through the Fischer-Tropsch process. The experiments were conducted in a 6-cylinder DI diesel engine with pump timing settings of $6^{\circ},\;9^{\circ}\;and\;12^{\circ}$crank angle before TDC over ECE R49 and US 13-mode cycles separately and compared to a conventional diesel fuel. The results show that GTL exhibited almost the same power and torque output, improved fuel economy and effective thermal efficiency. It was found that GTL displayed lower peak in-cylinder combustion pressure and maximum heat release rate (HRR), the timings of the peak pressure and the maximum HRR were generally delayed, and the combustion durations were almost equivalent for diesel and GTL under the same speed-load condition. The results also indicate that, compared to diesel fuel, GTL blends showed a trend forward decreasing four regulated emissions simultaneously and a higher GTL fraction in blends contributing to further reductions in the emissions. In particular and on average, neat GTL significantly reduced HC, CO, NOx and PM by 16.4%, 17.8%, 18.3% and 32.4%, respectively, for all cases.

• Journal of Power System Engineering
• /
• v.5 no.2
• /
• pp.22-29
• /
• 2001

This paper represents axial mean velocity, turbulent kinetic energy and swirl number based on momentum flux measured in the X-Y plane and Y-Z plane respectively of a cone type gas swirl burner by using X-probe from the hot-wire anemometer system. This experiment is carried out at flow rates 350 and $450{\ell}/min$ respectively, which are equivalent to the combustion air flow rate necessary for heat release 15,000 kcal/hr in gas furnace, in the test section of a subsonic wind tunnel. Axial mean velocities and turbulent kinetic energies show that their maximum values exist centering around narrow slits situated radially on the edge of and in the forefront of a burner until $X/R{\fallingdotseq}1.5$, but they have a peculiar shape like a starfish diffusing and developing into inward and outward of a burner by means of the mixing between flows ejected from narrow slits, an inclination baffle plate and swirl vanes respectively according to downstream regions. Moreover, they show a relatively large value in the inner region of 0.5$S_m$ obtained by integration of velocity profiles shows a characteristic that has an inflection point composing of the maximum and minimum value until X/R<3, but shows close agreement with the geometric swirl number after a distance of X/R=3.

• Fire Science and Engineering
• /
• v.24 no.4
• /
• pp.69-78
• /
• 2010

In this study, Fire Hazards were evaluated through computer simulation using FDS program for an apartment fire accident. The results of fire simulation showed that the maximum heat release rate in the case of no sprinklers activation was 7,700 kW which was about 16 times of that in the case of sprinklers activation, 497 kW and there was a very high fire hazard due to the backdraft phenomenon when the door of fire room was forced to open. Regarding the hazard time of fire room temperature and detection time of detectors, available evacuation time was 32.5 seconds of minimum to 53.5 seconds of maximum. In the case of sprinklers activation, fire hazard in the apartment was showed to be very low due to the fire control by the spray cooling of sprinklers. This study shows that what a important function for fire safety is the activations of fire sprinkler system and emergency alarm system and what a large loss can cause if these systems don’t activate in fire accidents.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.25 no.2
• /
• pp.225-234
• /
• 2001

This paper represents the vector fields, three dimensional mean velocities, the turbulent intensities, the turbulent kinetic energy, and the Reynolds shear stresses in the X-Y plane of gas swirl burner with a cone type baffle plate measured by using X-probe from hot-wire anemometer system. This experiment is carried out at flow rates 350 and 450ℓ/min respectively, which are equivalent to the combustion air flow rate necessary for heat release 15,000 kcal/hr in gas furnace, in the test section of subsonic wind tunnel. The vector plot shows that the maximum axial mean velocity component exists in the narrow slits situated radially on the edge of gas swirl burner, for that reason, there is some entrainment phenomena of ambient air in the outer region of burner. Moreover, mean velocities in the initial region are largely distributed near the outer region of burner at Y/R≒0.97, but they diffuse and develop into the center flow region of burner according to the increase of axial distance. The turbulent intensities and the turbulent kinetic energy due to large inclination of mean velocity and swirl effect show that the maximum value in the initial region of burner is formed in the narrow slits situated radially on the edge of gas swirl burner and large values are mainly formed in the entire region of burner after X/R=2.4358, hence, the combustion reaction is anticipated to occur actively near this region. And the Reynolds shear stresses are also largely distributed from slite to vanes of gas swirl burner in the intial region, but their values largely disappear after X/R=3.2052.

• Fire Science and Engineering
• /
• v.25 no.6
• /
• pp.168-177
• /
• 2011

The combustion test for real box of AC outdoor unit has been performed in this study in order to estimate the fire hazard in multi-system type of AC outdoor unit which is currently used for commercial use. The result showed that in test, there was explosion inside of AC outdoor unit, and flame erupted and fire spread through upper side grill. And then this fire burnt the combustibles such as wires, electronic control board, heat exchange copper plate and plastics etc inside the unit, refrigerant gas pipe was burst due to fire, and accelerated the explosion and flame eruption to outside while the refrigerant was erupting. It is found in this test that the maximum heat release rate of AC outdoor unit is 5,830 kW, the maximum internal temperature measured with infrared camera and thermocouple is $1,201^{\circ}C$, maximum ambient temperature is $881^{\circ}C$, and flame rose higher than about 5 m. It is concluded that the fire in AC outdoor unit cause fire to combustibles around the unit, and may give big damage by generating the secondary fire. It is expected that the result obtained from the test on the real object may be applied to fire realization of AC outdoor unit and estimation of fire spreading to the combustibles around in the future computer simulation.