• Bulletin of the Korean Chemical Society
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• v.34 no.2
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• pp.489-494
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• 2013

An improved method for the preparation of monomethine cyanine dyes with quinoline nucleus by one-pot three-component using 1-methyl-2-quinolinethione, quaternized 2- or 4-methylheterocyclic compounds and methyl p-toluenesulfonate as starting materials was described. Compared with the traditional methods, the new synthetic method reduced the reaction steps, shortened the reaction time, avoided the separation and purification of the intermediate and reduced cost. The dyes absorbed in the region 478.0-563.0 nm and had molar extinction coefficients of $1.3{\times}10^4-9.4 {\times}10^4L\;mol^{-1}\;cm^{-1}$. Their fluorescence maxima and Stokes shifts were in the range of 525.2-594.4 nm and 16.2-80.6 nm in different solvents, respectively. From the spectral properties of the dyes in different solvents, it could be found that the ${\lambda}_{max}$ of the dyes were shorter in protonic solvents, and showed hypsochromic shifts with the increase of polarity of the solvents.

• Clean Technology
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• v.22 no.4
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• pp.281-285
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• 2016

Cu wire catalyst was highly reactive toward catalytic wet peroxide oxidation of the highly refractory 1,4-dioxane. While complete removal of 1,4-dioxane could be achieved with the catalyst, the removed 1,4-dioxane could not totally mineralized into $CO_2$ and $H_2O$. In accordance with the disappearance of 1,4-dioxane, formaldehyde and oxalic acid were formed gradually with reaction time and they went through maxima. At around the time of maximum concentrations of these two intermediates acetaldehyde concentration was increased drastically and showed maximum value. With the disappearance of these three intermediates, formic acid together with ethylene glycol diformate began to increase gradually. The Cu wire catalyst was proved also to be highly stable against deactivation during the reaction.

• Journal of the Korean Chemical Society
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• v.17 no.4
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• pp.247-255
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• 1973

The self supported film specimen of Wyoming montmorillonite as a layer silicate saturated by cations,$Li^{+},\;Na^{+},\;K^{+},\;Ca^{2+},\;Ni^{2+},\;Al^{3+}$and$F^{3+}$ were allowed to contact acetone, methyl-ethyl ketone and diethyl ketone within the heatable gas cell. The i.r. spectra between $4000{\sim}1200cm^{-1}$ at different pressures of adsorbates indicated bond formation through carbonyl oxygen. Two types of carbonyl bond shift with maxima at $1713cm^{-1}$ and $1690cm^{-1}$ are attributed as coordinate bond formation of carbonyl with either surface hydroxyl or cationic hydroxyl group. The intensity of the vOH was analyzed and resonance form of cationic hydroxyl was proposed as an adsorption site. The tendency to form coordinate bond was in good agreement with calculated formal charge of carbonyl oxygen in an increasing order, acetone < methyl-ethyl ketone < diethyl ketone. As an additional mechanism of adsorption, weak hydrogen bonding of methyl hydrogen with surface oxygen was observed.

• Mycobiology
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• v.43 no.3
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• pp.288-296
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• 2015

Thailand is one of the largest citrus producers in Southeast Asia. Pathogenic infection by Phytophthora, however, has become one of major impediments to production. This study identified a pathogenic oomycete isolated from rotted roots of pomelo (Citrus maxima) in Thailand as Phytophthora nicotianae by the internal transcribed spacer ribosomal DNA sequence analysis. Then, we examined the in vitro and in vivo effects of Chaetomium globosum, Chaetomium lucknowense, Chaetomium cupreum and their crude extracts as biological control agents in controlling this P. nicotianae strain. Represent as antagonists in biculture test, the tested Chaetomium species inhibited mycelial growth by 50~56% and parasitized the hyphae, resulting in degradation of P. nicotianae mycelia after 30 days. The crude extracts of these Chaetomium species exhibited antifungal activities against mycelial growth of P. nicotianae, with effective doses of $2.6{\sim}101.4{\mu}g/mL$. Under greenhouse conditions, application of spores and methanol extracts of these Chaetomium species to pomelo seedlings inoculated with P. nicotianae reduced root rot by 66~71% and increased plant weight by 72~85% compared to that in the control. The method of application of antagonistic spores to control the disease was simple and economical, and it may thus be applicable for large-scale, highly effective biological control of this pathogen.

• YAKHAK HOEJI
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• v.31 no.5
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• pp.330-337
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• 1987

The weak UV absorbing ephedrine alkaloids such as ephedrine, pseudoephedrine, methylephedrine and norephedrine could be analyzed by charge-transfer spectrophotometric method. The results obtained are summarized as follows: (1) It was possible to determine a weak UV absorbing ephedrine alkaloids using the intense charge-transfer UV bands in chloroform. (2) This method was suitable for the spectrophotometric determination of ephedrine alkaloids in mixed pharmaceutical preparation. (3) Linear relationship was found between absorbance and concentration in the range of 1.0$\times$$10^{-5}M$~5$\times$$10^{-5}M$ of ephedrine ($\varepsilon$= 2.72$\times$$10^{4}LM^{-1}cm^{-1}$ and pseudoephedrine ($\varepsilon$=2.84$\times$$10^{4]LM^{-1}cm^{-1}$), 1.0$\times$$10^{-5}M$~5$\times$$10^{-5}$M of methylephdrine ($\varepsilon$=1.68$\times$$10^{4}LM^{-1}cm^{-1}$) and 1/3$\times$$10^{-4}M$~4/3$\times$$10^{-4}M$ of norephedrine ($\varepsilon$=0.74$\times$$10^{4}LM^{-1}cm^{-1}$. (4) CT- complex of ephedrine, pseudoephedrine and methylephedrine has absorption maxima at 293nm and norephedrine have absorption maximum at 253nm. (5) CT-complexes were formed in a 1:1 ratio between ephedrine alkaloids and iodine in chloroform. (6) By UV, IR, and $^1H$-NMR spectra, it could be inferred that CT-complexes were formed by interaction between the basic nitrogen of ephedrine alkaloids as electron (n) donor and iodine as electron ($\sigma$) acceptor.

• Korean Journal of Food Science and Technology
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• v.8 no.3
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• pp.179-184
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• 1976

Properties of starch from three rice varieties in Korea, Indica types Tongil, Yusin and a Japonica type Jinheung were investigated. 1) Gelatinization temperatures of Tongil, Yushin and Jinheung rice were $72^{\circ}C,\;70^{\circ}C\;and\;68{\sim}69^{\circ}C$ respectively. Gelatinization temperature of Indica variety was higher than that of Japonica variety. 2) Blue values of Tongil, Yusin and Jinheung rice starch were 0.40, 0.39 and 0.35 respectively, in which differences among rice varieties were small. 3) Color intensity of three varieties of rice starch with iodine gave rise to absorption maxima at $610{\sim}625\;nm$. 4) Amylose contents of Tongil, Yusin and Jinheung rice starch were 23.2%, 21.3% and 20.6% respectively, which were lower than those of other cereals. Amylose content of Indica variety was higher than that of Japonica variety. 5) Alkali numbers of Tongil, Yusin and Jinheung rice starchs were 7.0, 7.0 and 6.8, respectively. The differences were negligible among rice varieties. Those values were higher than that of glutinous rice starch.

• Journal of KIISE:Databases
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• v.28 no.3
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• pp.324-333
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• 2001

In this paper we present a novel color image segmentation algorithm based on a Gaussian Mixture Model(GMM). It is introduced a Deterministic Annealing Expectation Maximization(DAEM) algorithm which is developed using the principle of maximum entropy to overcome the local maxima problem associated with the standard EM algorithm. In our approach, the GMM is used to represent the multi-colored objects statistically and its parameters are estimated by DAEM algorithm. We also develop the automatic determination method of the number of components in Gaussian mixtures models. The segmentation of image is based on the maximum posterior probability distribution which is calculated by using the GMM. The experimental results show that the proposed DAEM can estimate the parameters more accurately than the standard EM and the determination method of the number of mixture models is very efficient. When tested on two natural images, the proposed algorithm performs much better than the traditional algorithm in segmenting the image fields.

• Journal of the Korean institute of surface engineering
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• v.39 no.4
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• pp.160-165
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• 2006

Ni-SiC composite coating layers were prepared by electroplating method and their deposition rate, codeposition of SiC, morphology, surface roughness, hardness, wear and friction properties were investigated. It was found that the deposition rate and the codeposition of SiC in the composite coating layer increased with increasing concentration of SiC in the solution only at the early stage. Both of them reached certain maxima and then decreased with increasing concentration of SiC. Rough surface was obtained with increasing codeposition of SiC, which is probably due to the agglomeration of the SiC particle in the vicinity of surface. Vickers hardness increased with increasing codeposition of SiC and heat treatment at $300^{\circ}C$ in air for 1 hour. Wear volume decreased with increasing codeposition of SiC and friction coefficient increased with increasing codeposition of SiC at the early stage, and it became almost constant. Such wear and friction behaviors are desirable for the practical application.

• Proceedings of the KSRS Conference
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• 2002.10a
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• pp.366-366
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• 2002

Cloud-to ground lightning and total precipitation over Korean peninsula during the summer monsoon season are studied extensively with a special emphasis on the characteristics of convective precipitation. Ten years (1988-1997) lightning and rainfall data and a temporal and spatial scale of one month and 10$^2$ km$^2$ respectively are used to calculate the monthly number of CG lightning flash count. Monsoonal convective activity is higher over the west coast with maxima at two different regions, one in the northern part which increases nortwestward and the other is at the middle west coast of Korea increasing towards the west coast. East coast represents the minimum value of monsoonal convective activity. In the east coast of Korean peninsula, particularly in the region east of Tae-back mountain, the value of Rain yield, (which is defined as the ratio of total precipitation to CG flash count over a common area), is maximum with an average value of 3$\times$10$^{8}$ kg fl$^{-1}$, while the minimum value of rain yield is occurred in the west of Tae-back mountain, with an average value of 0.8$\times$10$^{8}$ kg fl$^{-1}$. Results show in the west coast stations, nearly 82% of the total rainfall is convective in nature, at the middle of the peninsula 53% of the total rain is convective while in the east coast stations 46% contribution from the convective rain is seen. Kanghwa receives the maximum convective rain while at Ulsan the convective rain is minimum. Correlation coefficient between the total precipitation and CG lightning during the summer monsoon season is 0.54.

• Korean Journal of Soil Science and Fertilizer
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• v.30 no.1
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• pp.41-45
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• 1997

This study was conducted to investigate methane production, emission and diffusion under organic matter application in paddy soil (Jeonbug Series). The rates of application of rice straw were 5,000kg/ha in combination with 110kg N/ha as chemical fertilizer. In seasonal variations of the $CH_4$ emission rates two maxima were found during the ear formation stage and the heading stage of the rice plant. Entrapped methane increased dining the early growing season, declined thereafter and especially increased during the heading stage. Methane concentration in the soil solution was the higest at 5cm depth, but decreased with upper and lower depth. The gas diffusion rate of $CH_4$ was very slow in the liquid phase. Eh of soil solution varied from -150~-160mV and methane prodution rate was highly correlated with Eh.