• Journal of Korea Foundry Society
• /
• v.21 no.1
• /
• pp.7-14
• /
• 2001

The research on new DRA(discontinuous reinforced alloy) and CRA(continous reinforced alloy) composites has been carried out to improve the properties of ceramic fiber and particle reinforced metal matrix composites(MMCs). Effects of alloying elements and aging conditions on the microstructures and aging behavior of Al-Si-Cu-Mg-(Ni)-SiCp composite have been examined. The specimens used in this study were manufactured by duplex process. The first squeeze casting is the process to make precomposite and the second squeeze casting is the process to make final composite. The hardening behavior was accelerated with decreasing the size of SiCp particle in the composites. It is considered that the dislocation density increased with increasing SiCp size, due to the different thermal deformation between Al matrix and SiCp during quenching after the solution treatment. Peak aging time to obtain the maximum hardness in 3 ${\mu}m$ SiCp reinforced Al composite was reduced than that in large size(5, 10 ${\mu}m$) of SiCp because of difference in dislocation density. Aging hardening responce(${\Delta}H$ = $H_{Max}.-H_{S.T}$) of composites was greater than that of unreinforced Al alloy because of higher density of second phases in matrix.

• Composites Research
• /
• v.17 no.5
• /
• pp.54-60
• /
• 2004

A new three-dimensional model for predicting the relationship between the prestrain of the composite and the amount of phase transformation of shape memory alloy inducing shape memory effect has been proposed by using Eshelby's equivalent inclusion method with Mori-Tanaka's mean field theory. The model composite is aluminum matrix reinforced with short TiNi fiber shape memory alloy, where the matrix is work-hardening material of power-law type. The analytical results predicted by the current model show that most of the prestrain is induced by the plastic deformation of the matrix, except the small prestrain region. The strengthening mechanism of the composite by the shape memory effect should be explained by excluding its increase of yield stress due to the work-hardening effect of the matrix.

• Korean Journal of Materials Research
• /
• v.16 no.4
• /
• pp.241-247
• /
• 2006

Structural studies have been performed on precipitation hardening discovered in $L1_2-ordered\;Ni_3(Al,Cr)$ containing 0.2 to 3.0 mol% of carbon using transmission electron microscopy (TEM). Fine octahedral precipitates of $M_{23}C_6$ appeared in the matrix by aging at temperatures around 973 K after solution treatment at 1423 K. TEM examination revealed that the $M_{23}C_6$ phase and the matrix lattices have a cube-cube orientation relationship and keep partial atomic matching at the {111} interface. After prolonged aging or by aging at higher temperatures, the $M_{23}C_6$ precipitates then adopt a rod-like morphology elongated parallel to the <100> directions. Deformation at temperature below 973 K, typical Orowan loops were observed surrounding the $M_{23}C_6$ particles. At higher deformation temperatures, the Orowan loops disappeared and the morphology of dislocations at the particle-matrix interfaces suggested the existence of attractive interaction between dislocations and particles. The change of the interaction modes between dislocation and particles with increasing deformation temperature can be considered as a result of strain relaxation at the interface between matrix and particles.

• Journal of the Korean Society for Heat Treatment
• /
• v.22 no.6
• /
• pp.345-353
• /
• 2009

The precipitates of $L2_1$-type $Ni_2AlHf$ phase in B2-ordered NiAl system has been observed by using transmission electron microscope (TEM). The hardness of as-quenched NiAl-Hf alloys is high due to the larger strengthening. However, age hardening of this alloy is not main effect to increase hardness compared to the large microstructural variations during aging. At the beginning of aging, the $L2_1$-type $Ni_2AlHf$ precipitates keep a lattice coherency with the NiAl matrix. The orientation relationship between the $Ni_2 AlHf$ precipitate and the NiAl matrix is <100>$_{Ni2AlHf}$//<100>$_{NiAl}$, {001}$_{Ni2AlHf}$//{001}$_{NiAl}$. By aging treatment for long time $Ni_2AlHf$ precipitates lost their coherency and change their morphology to the spherical ones surrounded by misfit dislocations. The orientation relationship between the NiAl matrix and the $Ni_2AlHf$ precipitates, however, has been kept even after longer aging time. The lattice misfit between the $Ni_2AlHf$ precipitate and the NiAl matrix has been calculated by the selected electron diffraction patterns, and the spacings of misfit dislocations is about 4.5% at 1173 K.

• Korean Journal of Metals and Materials
• /
• v.49 no.9
• /
• pp.692-698
• /
• 2011

The thermo-chemical treatment (TCT) process was applied to achieve surface hardening of CP titanium. The following three different surface modification conditions were tested so that the best surface hardening process could be selected:(a) PVD, (b) TCT+PVD, and (c) TCT+Aging+PVD. These specimens were tested and analyzed in terms of surface roughness, wear, friction coefficient, and the gradient of hardening from the surface of the matrix. The three test conditions were all beneficial to improve the surface hardness of CP titanium. Moreover, the TCT treated specimens, that is, (b) and (c), showed significantly improved surface hardness and low friction coefficients through the thickness up to $100{\mu}m$. This is due to the functionally gradient hardened surface improvement by the diffused interstitial elements. The hardened surface also showed improvement in bonding between the PVD and TCT surface, and this leads to improvement in wear resistance. However, TCT after aging treatment did not show much improvement in surface properties compared to TCT only. For the best surface hardening on CP titanium, TCT+PVD has advantages in surface durability and economics.

• Journal of Welding and Joining
• /
• v.15 no.5
• /
• pp.92-103
• /
• 1997

The purpose of this study is to improve the wear resistance and hardness of Al alloy by making a formation of the thick surface hardening layers. The thick surface hardening layers were formed by PTAW(Plasma Transferred Arc Welding), with the addition of metal powders (Cu), ceramics powders (NbC, TiC), and mixture powders (Cu+NbC) in Al alloy (A1050, A5083). Mechanical properties of overlaid layers (wear resistance, hardness) were investigated in relation to the microstructure. The results obtained are summarized as follows: The depth of penetration was increased with increasing powder feeding rate. It is considered that these increase were due to the thermal pinch effect by the addition of powders, especially, for the Cu powders, were due to the heat of reaction with the matrix. The hardness and wear resistance of overlaid layers were improved with increasing powder feeding rate. For the Cu powders, it is considered that these increase were due to the increase of the formation of ${\theta}(CuAl_2)$ phase with increasing feeding rate of Cu powers.

• Journal of Welding and Joining
• /
• v.18 no.6
• /
• pp.102-107
• /
• 2000

It was attempted to improve the wear resistance of Al alloy under the load condition by making a formation of the thick surface hardening alloy layers. The thick surface hardening alloy layers were formed on 6061 Al alloys overlayed by MIG welding process with WC-12%Co powder addition. Effects of the dispersion of WE-12%Co powders on hardness and wear characteristics of alloys were investigated. The following results were obtained. Most of WE-12%Co powders are dispersed nearly uniform as unmelted particles in the matrix alloy. A part of WC-12%Co powders are melted in the molten pool, and during solidification {TEX}$Al_{9}Co_{2}${/TEX} appeared. With increasing addition of WC-12%Co powders, the hardness and specific wear resistance of the overlay weld alloys increased and reached Hv450 at WC-12%Co powder addition rate of 54g/min. It is considered that excellent wear resistance of the overlayed alloys was due to dispersed WC-12%Co powders and increased 10 times at WC-12%Co powder addition rate of 54 g/min than that of the WC-free overlaying layers.

• Laser Solutions
• /
• v.18 no.2
• /
• pp.1-4
• /
• 2015

This study is related to the surface hardening treatment to spheroidal graphite cast iron for die by using high power diode laser. Laser device used in this experiment is capable of real-time laser power control. This is because the infrared temperature sensor (two color pyrometer) attached to the optical system measures the surface temperature of specimen and adjusts the laser power in real time. The surface treatment was carried out with the change of heat treatment temperature at the beam travel speed 3 mm/sec. Hardened width and depth was measured and hardened zone was analyzed by micro vickers hardness test in order to research the optimum condition of heat treatment. The changes in microstructure of the hardened zone also was examined. As a result of hardness measurement and observations on microstructure of hardened zone, hardness increased over three times as compared with base metal because the martensite was formed on the matrix structure.

• Journal of Mechanical Science and Technology
• /
• v.20 no.7
• /
• pp.1002-1011
• /
• 2006

In this study, we describe the conventional hot pressing (CHP) of layered $Al-B_4C$ composites and their characterization. The matrix alloy Al-5 wt.%Cu was prepared from elemental powder mixtures. The metal and B4C powders were mixed to produce either $Al-Cu-10vol.%B_4C$ or $Al-Cu-30vol.%B_4C$ combinations. Then, these powder mixtures were stacked as layers in the hot pressing die to form a two-layered composite. Hot pressing was carried out under nitrogen atmosphere to produce $30\times40\times5mm$ specimens. Microstructural features and age hardening characteristics of composites were determined by specimens cut longitudinally. The flexural strength of both layered composites and their monolithic counterparts were investigated via three point bending tests. In the case of layered specimens of both $10vol.%B_4C$ and $30vol.%B_4C$ containing layers were loaded for three-point test. The results show that a homogeneous distribution of $B_4C$ particles in the matrix alloy which is free of pores, can be obtained by CHP method. The ageing behavior of the composites was found to be influenced by the reinforced materials, i.e. higher hardness values were reached in 8 hrs for the composites than that for the matrix alloy. Flexural strength test showed that two-layered composites exhibited improved damage tolerance depending on layer arrangement. Microstructural investigation of the fracture surfaces of the bending specimens was performed by means of scanning electron microscope (SEM). While layer with lower reinforcement content exhibited large plastic deformation under loading, the other with higher reinforcement content exhibited less plastic deformation.

• Composites Research
• /
• v.20 no.2
• /
• pp.21-26
• /
• 2007

This paper summarizes the design procedure and constructibility of an ECC (Engineered Cementitious Composite), which is a synthetic fiber-reinforced composite produced with the Portland cement-based mortar matrix. This study employs a stepwise method to develop useful ECC in construction field, which possesses different fluid properties to facilitate diverse types of processing (i.e., self-consolidating or spray processing). To control the rheological properties of the composite, the aggregates and reinforcing fibers were initially selected based on micromechanical analysis and steady-state cracking theory. The stability and consequent viscosity of the suspensions were then mediated by optimizing the dosage of the chemical and mineral admixtures. The rheological properties altered through this approach were revealed to be effective in obtaining ECC-hardened properties, represented by pseudo strain-hardening behavior in uniaxial tension, allowing the readily achievement of the desired function of the fresh ECC.