• Title/Summary/Keyword: Matrix Resin

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Friction and Wear Properties of Fiber Reinforced Composite (섬유보강 복합재의 마찰 및 마모특성)

  • Ju, Hyeok-Jong;Choe, Don-Muk;O, In-Seok;Hong, Myeong-Ho
    • Korean Journal of Materials Research
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    • v.4 no.7
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    • pp.733-740
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    • 1994
  • Oxidized-PAN fiber reinforced composite(OFRP), carbon fiber reinforced composite(CFRP), aramid fiber reinforced composite(AFRP), and glass fiber reinforced composite(GFRP) were fabricated with phenolic resin matrix by hot press molding. We tested the friction coefficient and wear rate varying with fiber weight fraction and observed the effect of fibers according to characteristics of individual reinforcement. When the amount of aramid fiber was 45wt%, average friction coefficient was maximum value of 0.353~0.383, where as, when the amount of pitch based carbon fiber was 45wt%, average friction coefficient was the lowest value of 0.164~0.190. The wear rate of AFRP and CFRP was low, but that of GFRP and OFRP increases drastically in the case of increasing of fiber weight fraction. Wear diagram of OFRP was unstable, but that of CFRP and AFRP was a bit stable. Through very unstable diagram of GFRP, we found that friction stability of GFRP was the lowest.

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Improving Smoothness of Hydrophilic Natural Polymer Coating Layer by Optimizing Composition of Coating Solution and Modifying Chemical Properties of Cobalt-Chrome Stent Surface (코팅 용액의 조성 최적화 및 코발트-크롬 금속스텐트의 화학적 표면개질을 통한 친수성 천연 고분자 코팅층의 표면 거칠기 개선)

  • Kim, Dae Hwan;Kum, Chang Hun
    • Journal of Chitin and Chitosan
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    • v.23 no.4
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    • pp.256-261
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    • 2018
  • Recently, the number of cardiovascular disease-related deaths worldwide has increased. Therefore, the importance of percutaneous cardiovascular intervention and drug-eluting stents (DES) has been highlighted. Despite the great clinical success of DES, the re-endothelialization at the site of stent implantation is retarded owing to the anti-proliferative effect from the coated drug, resulting in late thrombosis or very late restenosis. In order to solve this problem, studies have been actively carried out to excavate new drugs that promote rapid re-endothelialization. In this study, we introduced hydrophilic drug, tauroursodeoxycholate (TUDCA), that improves the proliferation of endothelial progenitor cells and promotes apoptosis of vascular smooth muscle cells. In addition, we utilized shellac, which is a natural resin from lac bug to coat TUDCA on the surface of the metal. When using conventional coating method including biodegradable polymers and organic solvents, phase separation between polymer and drug occurred in the coating layer that caused incomplete incorporation of drug into the polymer layer. However, when using shellac as a coating polymer, no phase separation was observed and drug was fully covered with the polymer matrix. In addition, by adjusting the composition of coating solution and modifying the hydrophilicity of the metal surface using oxygen plasma, the surface roughness decreased due to the increased affinity between coating solution and metal surface. This result provides a method of depositing a hydrophilic drug layer on the stent.

Effects of NaCl Concentration and Solution Temperature on the Galvanic Corrosion Between CFRP and A516Gr.55 Carbon Steel

  • Hur, Seung Young;Kim, Ki Tae;Kim, Young Sik
    • Corrosion Science and Technology
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    • v.18 no.4
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    • pp.129-137
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    • 2019
  • CFRP (Carbon Fiber Reinforced Plastics) is composed of carbon fiber and plastic resin, and is approximately 20 - 50% lighter than metallic materials. CFRP has a low density, higher specific stiffness, specific strength, and high corrosion resistance. Because of these excellent properties, which meet various regulation conditions needed in the industrial fields, CFRP has been widely used in many industries including aviation and ship building. However, CFRP reveals water absorption in water immersion or high humidity environments, and water absorption occurs in an epoxy not carbon fiber, and can be facilitated by higher temperature. Since these properties can induce volume expansion inside CFRP and change the internal stress state and degrade the chemical bond between the fiber and the matrix, the mechanical properties including bond strength may be lowered. This study focused on the effects of NaCl concentration (0.01 - 1% NaCl) and solution temperature ($30-75^{\circ}C$) on the galvanic corrosion between CFRP and A516Gr.55 carbon steel. When NaCl concentration increases 10 times, corrosion rate of a specimen was not affected, but that of galvanic coupled carbon steel increased by 46.9% average. However, when solution temperature increases $10^{\circ}C$, average corrosion rate increased approximately 22%, regardless of single or galvanic coupled specimen.

Estimating Tensile Strengths of CFRP Laminates Having Various Stacking Sequences (다양한 적층을 갖는 CFRP 적층판의 인장강도 예측)

  • Park, Chan Yik;Lee, Myung-Keon;Kim, Sang-Yong;Jang, Se-Yong
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.50 no.5
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    • pp.309-316
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    • 2022
  • This paper presents nonlinear numerical analysis results which were compared with the tested tensile strengths of CFRP(Carbon Fiber Reinforced Plastic) laminates with 14 different stacking sequences. The composite laminate coupons were cured under an autoclave pressure using resin-impregnated unidirectional tapes. The nonlinearity of the matrix was considered for the analysis, which was obtained from lamina tests. The Hashin failure criteria and progressive failure analysis were used for the nonlinear finite element analysis. The comparison results show that the current approach is acceptable to predict the tensile strengths of the CFRP laminate coupons with various stacking sequences and no damage. However, it is not acceptable to predict the tensile strengths of the laminate specimens with a center hole.

Interfacial shear strength test by a hemi-spherical microbond specimen of carbon fiber and epoxy resin (탄소섬유/에폭시의 반구형 미소접합 시험편에 대한 계면강도 평가)

  • Park, Joo-Eon;Gu, Ja-Uk;Kang, Soo-Keun;Choi, Nak-Sam
    • Composites Research
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    • v.21 no.4
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    • pp.15-21
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    • 2008
  • Interfacial shear strength between epoxy and carbon fiber was analyzed utilizing a hemi-spherical microbond specimens adhered onto single carbon fiber. The hemi-spherical microbond specimen showed high regression coefficient and small standard deviation in the measurement of interfacial strength as compared with a droplet and an inverse hemi-spherical one. This seemed to be caused by the reduced meniscus effects and the reduced stress concentration In the region contacting with a pin-hole loading device. Finite element analysis showed that the stress distributions along the fiber/matrix interface in the hemi-spherical specimen had a stable shear stress distribution along the interface without any stress mode change. The experimental data was also different according to the kinds of loading device such as the microvise-tip and the pin-holed plate.

The Effects of Physical Aging of PSF/AS4 Laminate on Fatigue (PSF/AS4 복합재료의 가속노화가 피로강도에 미치는 영향)

  • Kim, Hyung-Won
    • Composites Research
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    • v.19 no.4
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    • pp.1-6
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    • 2006
  • The effects of aging on fatigue of PSF/AS4 laminates tvas studied using the new energy release rate analysis. The analysis by the variational mechanics has been useful in providing fracture mechanics interpretation of matrix microcracking in cross-ply laminates. This paper describes the changes of the critical energy release rate ${\Delta}Gmc$(microcracking toughness) about the variation of the aging period during fatigue loading. The master plot by modified Pans-law gives a characterization of a material system's resistance to microcrack formation. PSF/AS4 $[0/902]_s$ laminates were aged at four different temperatures based on the glass transition temperature for 60 days. At all temperatures, the toughness decreased with aging time. The decrease of the toughness at higher temperature was faster than at lower temperature. To assess the effects of aging on fatigue, the unaged laminates were compared with the laminates which were aged for 60 days at $170^{\circ}C$ near $180^{\circ}C\;T_g$. The slope of dD/dN versus A 6u, of the aged laminates was lower than that of the unaged laminates. There was a significant shift of the aged data to formation of microcracks at the lower values of ${\Delta}G_m$.

Natural Aging Effect on the Fiber Tensile Strength of Carbon Epoxy Pressure Vessel (자연 노화에 따른 카본 에폭시 압력용기의 섬유 인장 강도 변화)

  • Hwang, Tae-Kyung;Park, Jae-Byum;Kim, Hyoung-Geun;Doh, Young-Dae
    • Composites Research
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    • v.20 no.2
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    • pp.1-9
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    • 2007
  • To evaluate and investigate the aging characteristics and the structural service lifetime of the CFV(carbon fiber pressure vessel), natural aging tests were carried out using the CFVs, which had been placed and aged at outdoor and indoor laboratories for 10 and 15 years, respectively. To obtain the probabilistic characteristics of ageing characteristics in aged CFVs, inner pressure loading test was conducted with ring specimens taken from aged CFVs. And, to observe the interface morphology of aged CFVs, the micro-photographs were taken by SEM microscope and the fractured interfaces between the carbon fiber and the matrix resin were scrutinized. Based on the Weibull parameters of the tensile failure strain of aged CFVs, the degradation of the 10 and the 15 year aged CFV occur by 19% and 23%, respectively, and the effect of the placement, whether being placed inside the laboratory or not, is not so significant. However, the outer layer protection, such as painting, is found very advantageous to prevent CFV from aging.

Preparation and Characterization of poly(ethylene-co-vinyl acetate)/Magnesium Hydroxide Composites by Electron Beam Crosslinking (전자빔 가교에 의한 폴리(에틸렌-co-초산 비닐)/수산화 마그네슘 복합재료의 제조 및 평가)

  • Si-Hyeong Lee;Byoung-Min Lee;Hyun-Rae Kim;Sangwon Park;Jong-Seok Park;Yong Seok Kim;Sungmin Park;Jae-Hak Choi
    • Journal of Radiation Industry
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    • v.17 no.3
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    • pp.225-232
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    • 2023
  • In this study, poly(ethylene-co-vinyl acetate)/magnesium hydroxide (EVA/MDH) composites were prepared by electron beam crosslinking. EVA as a matrix resin and MDH as a flame retardant were melt-blended and compression molded to prepare EVA/MDH composites. The prepared EVA/MDH composites were electron beam-irradiated at various absorbed doses of 50~200kGy. The effects of electron beam irradiation on the gel content, tensile strength, elongation-at-break, thermal properties, and flame retardancy of the composites were investigated. The gel content and tensile strength increased, while the elongation-at-break decreased with an increase in the absorbed dose due to the formation of crosslinked network structures. In addition, the thermal stability and flame retardancy improved as the absorbed dose increased. Therefore, the EVA/MDH composites prepared in this study can be used as an insulation material for flame-retardant and heat-resistant wires and cables.

Chios gum mastic enhance the proliferation and odontogenic differentiation of human dental pulp stem cells

  • Hyun-Su Baek;Se-Jin Park;Eun-Gyung Lee;Yong-Il Kim;In-Ryoung Kim
    • The Korean Journal of Physiology and Pharmacology
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    • v.28 no.5
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    • pp.423-433
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    • 2024
  • Dental pulp stem cells (DPSCs) are a type of adult stem cell present in the dental pulp tissue. They possess a higher proliferative capacity than bone marrow mesenchymal stem cells. Their ease of collection from patients makes them well-suited for tissue engineering applications, such as tooth and nerve regeneration. Chios gum mastic (CGM), a resin extracted from the stems and leaves of Pistacia lentiscus var. Chia, has garnered attention for its potential in tissue regeneration. This study aims to confirm alterations in cell proliferation rates and induce differentiation in human DPSCs (hDPSCs) through CGM treatment, a substance known for effectively promoting odontogenic differentiation. Administration of CGM to hDPSC cells was followed by an assessment of cell survival, proliferation, and odontogenic differentiation through protein and gene analysis. The study revealed that hDPSCs exhibited low sensitivity to CGM toxicity. CGM treatment induced cell proliferation by activating cell-cycle proteins through the Wnt/β-catenin pathway. Additionally, the study demonstrated that CGM enhances alkaline phosphatase activation by upregulating the expression of collagen type I, a representative matrix protein of dentin. This activation of markers associated with odontogenic and bone differentiation ultimately facilitated the mineralization of hDPSCs. This study concludes that CGM, as a natural substance, fosters the cell cycle and cell proliferation in hDPSCs. Furthermore, it triggers the transcription of odontogenic and osteogenic markers, thereby facilitating odontogenic differentiation.

CHEMICAL DEGRADATION OF VARIOUS COMPOMERS IN NaOH (콤포머의 NaOH 용액 내에서의 화학적 분해)

  • Park, Mi-Ran;Choi, Nam-Ki;Lee, Young-Jun;Kim, Seon-Mi;Yang, Kyu-Ho
    • Journal of the korean academy of Pediatric Dentistry
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    • v.31 no.2
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    • pp.144-152
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    • 2004
  • The aim of this study was to evaluate the resistance to degradation of three commercial compomers in an alkaline solution. Dyract(Dentsply), Elan(Kerr) and F-2000(3M) polyacid modified resin composites(compomers) were used in this study. The resistance to degradation was evaluated on the basis of mass loss(%), degradation $depth({\mu}m)$ and Si, Al, Ba loss(ppm). The results were as follows : 1. The mass loss of each brand was $1.42%{\sim}2.14%$ and there was no statistically significant difference of mass loss among Dyract, F2000 and Elan. 2. The degradation layer depth of each brand was $182.92{\sim}227.7{\mu}m$ and there was no statistically significant difference of degradation layer depth among Dyract, F2000 and Elan. 3. There was statistically significant differences in Si-loss and Al-loss among three compomers (p<0.05). Si loss was the highest value in Dyract and Al loss was the highest value in F2000. 4. There was statistically significant correlation between mass loss and degradation layer depth (r=0.60, p<0.05). 5. In SEM finding, there was some destruction of compomer matrix-filler interface in post-exposure specimen to NaOH solution. As the matrix decreased, the filler particles distinguished and the periphery of the filler particles appeared whitish color due to degradation.

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