• Journal of Applied Reliability
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• v.9 no.2
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• pp.71-80
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• 2009

This paper discusses the service life prediction methods for CFRP bar for concrete reinforcement using accelerated degradation tests. The relationship between performance degradation and the rate of a failure-causing chemical reaction is assumed for the temperature accelerated degradation tests. Methods of obtaining acceleration factors and predicting service life of the CFRP bar using the degradation model are presented.

• Journal of the Korean Ceramic Society
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• v.45 no.10
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• pp.625-630
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• 2008

In the bone cement composed of dense granules of $\beta-Ca_3(PO_4){_2}(\beta-TCP)$ and $Ca(H_2PO_4){_2}H_2O$, the compressive strength, setting time and temperature rise were measured to observe the degradation of cement with respect to the stored days before setting. Decreases of compressive strength and temperature rise were observed, while setting time increased with respect to the stored days. The similar trends were repeated with the increase of temperature of storage. Such a change virtually meant the fading of the character of cement and it took place only when the two starting materials were mixed during storage. The degradation could be mitigated taking advantage of granular $\beta$-TCP instead of powdery one. The formation of $CaHPO_4$, which resulted from reaction with ambient humidity, was attributed to the degradation observed during storage. Dependence of the degradation behavior on mixing and temperature during storage was discussed in terms of the driving force for reaction of cement.

• Corrosion Science and Technology
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• v.21 no.5
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• pp.327-339
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• 2022

The water-jet technique started by Bridgman can cut metal and alloys without harmful gas and fume. However, while this technique is convenient to cut metals and alloys, in the case of coated pipe, water jet induces the degradation of coatings on the pipes, and may facilitate structural failure, leakage, and loss of products. While there are many reports on the effect of water jet on cut metals and the damage of metallic materials, research on the effect of water impingement on the epoxy coatings has been little studied. In this work, we therefore control the velocity of water jet, distance between nozzle and specimen, and water temperature, and discuss the effect of water impingement on the epoxy coatings. Increasing water velocity and water temperature and reducing nozzle distance increased the degradation rates of three epoxy coatings were increased. Among three test parameters - water velocity, nozzle distance and water temperature, water temperature was relatively effective to increase the degradation rate of epoxy coatings.

• Nuclear Engineering and Technology
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• v.54 no.12
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• pp.4514-4521
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• 2022

In this study, the effects of heat and radiation on the degradation behaviour of fluoroelastomer under simulated normal operation and a severe accident environment were investigated using sequential testing of gamma irradiation and thermal degradation. Tensile properties and Shore A hardness were measured, and thermogravimetric analysis was used to evaluate the degradation behaviour of fluoroelastomer. Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy were used to characterize the structural changes of the fluoroelastomer. Heat and radiation generated in nuclear power plant break and deform the chemical bonds, and fluoroelastomer exposed to these environments have decreased C-H and functional groups that contain oxygen and double bonds such as C-O, C=O and C=C were generated. These functional groups were formed by auto oxidation by reacting free radicals generated from the cleaved bond with oxygen in the atmosphere. In this auto oxidation reaction, crosslinks were generated where bonded to each other, and the mobility of molecules was decreased, and as a result, the fluoroelastomer was hardened. This hardening behaviour occurred more significantly in the severe accident environment than in the normal operation condition, and it was found that thermal stability decreased with the generation of unstable structures by crosslinking.

• Journal of the Korean Society of Industry Convergence
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• v.25 no.6_3
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• pp.1239-1246
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• 2022

This paper introduces the effect of grease on the degradation characteristics of bearings used as key components of packaging equipment and automation systems. Bearings parts are installed to fix and support the rotating body of the system, and performance degradation of the bearings has a great effect on the life of the system too. When bearings are used in various devices and systems, the grease is applied to reduce friction and improve fatigue life. Determining the type of lubricant (grease) is important because it has a great influence on the operating environment and lifespan and ensures long lifespan of systems and facilities. However, studies that simultaneously compared and analyzed the change in mechanical degradation characteristics and the comparison of chemical degradation characteristics according to grease types under actual operating conditions are insufficient. In this paper, three types of small harmonic drive, high-load reducer, and low-load reducer grease used in power transmission joint modules are experimentally selected and finally injected into ball bearings with a load (19,500N) to improve bearing durability. Degradation characteristics were tested by attaching to test equipment. At this time, after the durability test under the same load conditions, the mechanical degradation characteristics, that is temperature, vibration according to the three greases types. In addition, the chemical degradation characteristics of the corresponding grease was compared to present the results of mutual correlation analysis.

• Korean Journal of Materials Research
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• v.24 no.6
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• pp.326-337
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• 2014

The use of solar energy generation is steadily increasing, and photovoltaic modules are connected in series to generate higher voltage and power. However, solar panels are exposed to high-voltage stress (up to several hundreds of volts) between grounded module frames and the solar cells. Frequent high-voltage stress causes a power-drop in the modules, and this kind of degradation is called potential induced degradation (PID). Due to PID, a significant loss of power and performance has been reported in recent years. Many groups have suggested how to prevent or reduce PID, and have tried to determine the origin and mechanism of PID. Even so, the mechanism of PID is still unclear. This paper is focused on understanding the PID of crystalline-silicon solar cells and modules. A background for PID, as well as overviews of research on factors accelerating PID, mechanisms involving sodium ions, PID test methods, and possible solutions to the problem of PID, are covered in this paper.

• Journal of the Korean Ceramic Society
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• v.46 no.1
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• pp.1-9
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• 2009

Activated carbon modified with nickel (Ni-AC) was employed the for preparation of Ni-activated carbon/$TiO_2$ (Ni-AC/$TiO_2$) composites. The $N_2$ adsorption data showed that the composites had a decreased surface area compared with pristine AC. This indicated blocking of the micropores on the surface of the AC, which was further supported by observation via SEM. XRD results showed that the Ni-AC/$TiO_2$ composite contained a mixed anatase and rutile phase while the untreated AC/$TiO_2$ contained only a typical single and clear anatase phase. EDX results showed the presence of C, O, and Ti with Ni peaks on the composites of Ni-AC/$TiO_2$. Subsequently, the photocatalytic effects on methylene blue (MB) were investigated. The improved decomposition of MB showed the combined effects of adsorptions and photo degradation. In particular, composites treated with Ni enhanced the photo degradation behaviors of MB.

• Bulletin of the Korean Chemical Society
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• v.33 no.12
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• pp.4122-4126
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• 2012

Cellulose-graft-poly (L-lactide) (cellulose-g-PLLA) was successfully prepared via ring-opening polymerization (ROP) by using 4-dimethylaminopyridine (DMAP) as an organic catalyst in an ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl). The structure and morphology of the polymer was characterized by nuclear magnetic resonance (NMR) and transmission electron microscope (TEM). From wide-angle X-ray powder diffraction (WAXD) and degradation test (by acid, alkaline, PBS and enzyme solution), changes in the crystalline structure as a result of degradation was also investigated. The results indicated that materials which have low degree of crystallinity showing higher degradability, however, in acid liquor, enzyme solution, alkaline liquor and PBS system, the degradation rate of the polymer decreased by the above sequence. Moreover, with the further increase of graft degree of this material, its degradation degree decreased.

• Korean Journal of Metals and Materials
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• v.46 no.5
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• pp.276-282
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• 2008

Material degradation of Cr steels in boiler tubes was accompanied by the microstructural changes including carbide behavior and crack formation. The microstructural change and the mechanical behavior of hardness and creep properties in accelerated heat-treatments were studied in order to identify the material degradation of the X20 Cr steel. The degradation behavior was occurred in the hardness increasing followed by decreasing due to carbide dissolution and precipitation.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.17 no.6
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• pp.46-52
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• 2018

Nondestructive evaluation for mechanical degradation of ultrasuper-critical (USC) heat-resistance steel, which is attractive to the next generation of power plants is studied by magnetic reversible permeability. The interrelationship between reversible permeability and high-temperature mechanical degradation has been investigated by precise measurement of permeability nondestructively. Also, the effects of microstructural variation on reversible permeability are discussed. Isothermal aging was observed to coarsen the tempered carbides ($Cr_{23}C_6$), generated the intermetallic phases ($Fe_2W$), and grow rapidly during aging. The dislocation density also decreases steeply within lath interior. The peak to peak interval (PPI) of reversible permeability profile decreased drastically during the initial 500 h aging period, and was thereafter observed to decrease only slightly. The variation in PPI is closely related to the decrease in the number of pinning sites and the degradation in tensile strength.