• Title/Summary/Keyword: Material specific

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Electrochemical Capacitance of Activated Carbons Regenerated using Thermal and Chemical Activation

  • Park, Jung Eun;Lee, Gi Bbum;Hwang, Sang Youp
    • Journal of Electrochemical Science and Technology
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    • v.12 no.3
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    • pp.339-345
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    • 2021
  • Spent activated carbons (SACs) collected from a water treatment plant were regenerated and then adopted as electrochemical material in capacitors. The SACs used in this study were regenerated via two steps, namely thermal and chemical activation. However, during the activation process, the adsorbates were converted into ashes, which caused pore blockage and decreased specific surface area. The regenerated SACs were washed with acid solutions with different levels of acidity (strong: HCl, mild: H3PO4, and weak: H2O2) to remove the ashes. The regenerated SACs washed with HCl exhibited the highest specific surface area, although their capacitance was not the highest. Conversely, the specific surface area of regenerated SACs washed using H3PO4 was slightly lower than that of HCl, but exhibited higher capacitance and electrochemical stability. Although the strong acid removed the generated ashes in the pores efficiently, it could adversely affect their structural stability, which would lead to lower capacitance.

A New Way to Prepare MoO3/C as Anode of Lithium ion Battery for Enhancing the Electrochemical Performance at Room Temperature

  • Yu, Zhian;Jiang, Hongying;Gu, Dawei;Li, Jishu;Wang, Lei;Shen, Linjiang
    • Journal of Electrochemical Science and Technology
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    • v.7 no.2
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    • pp.170-178
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    • 2016
  • Composited molybdenum oxide and amorphous carbon (MoO3/C) as anode material for lithium ion batteries has been successfully synthesized by calcining polyaniline (PANI) doped with ammonium heptamolybdate tetrahydrate (AMo). The as prepared electrode material was characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and field emission scanning electron microscopy (FE-SEM). The electrochemical performance of the anode was investigated by galvanostatic charge/discharge, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The MoO3/C shows higher specific capacity, better cyclic performance and rate performance than pristine MoO3 at room temperature. The electrochemical of MoO3/C properties at various temperatures were also investigated. At elevated temperature, MoO3/C exhibited higher specific capacity but suffered rapidly declines. While at low temperature, the electrochemical performance was mainly limited by the low kinetics of lithium ion diffusion and the high charge transfer resistance.

N.M.for the Effect of P.T. on Resicual Stress Relaxation (잔류응력 완화에 미치는 상변태의 수치적 모델링)

  • 장경복;손금렬;강성수
    • Journal of Welding and Joining
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    • v.17 no.6
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    • pp.84-89
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    • 1999
  • Most of ferrous b.c.c weld materials may experience martensitic transformation during rapid cooling after welding. It is well known that volume expansion due to the phase transformation could influence on the relaxation of welding residual stress. To apply this effect practically, it is a prerequisite to establish a numerical model which is able to estimate the effect of phase transformation on residual stress relaxation quantitatively. For this purpose, the analysis is carried out in two regions. i.e., heating and cooling, because the variation of material properties following a phase transformation in cooling is different in comparison with the case in heating, even at the same temperature. The variation of material properties following phase transformation is considered by the adjustment of specific heat and thermal expansion coefficient, and the distribution of residual stress in analysis is compared with that of experiment by previous study. consequently, in this study, simplified numerical procedures considering phase transformation, which based on a commercial finite element package was established through comparing with the experimental data of residual stress distribution by other researcher. To consider the phase transformation effect on residual stress relaxation, the transition of mechanical and thermal property such as thermal expansion coefficient and specific heat capacity was found by try and error method in this analysis.

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Microwave Drying of Sawdust for Pellet Production: Kinetic Study under Batch Mode

  • Bhattarai, Sujala;Oh, Jae-Heun;Choi, Yun Sung;Oh, Kwang Cheol;Euh, Seung Hee;Kim, Dae Hyun
    • Journal of Biosystems Engineering
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    • v.37 no.6
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    • pp.385-397
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    • 2012
  • Purpose: Drying characteristics of sawdust was studied under batch mode using lab scale microwave dryer. The objective of this study was to investigate the effect of material load and microwave output power on drying characteristics of sawdust. Methods: Material load and microwave output power were varied from 23 to 186 g and 530 to 370 W respectively. Different kinetic models were tested to fit the drying rates of sawdust. Similarly, the activation energy was calculated by employing the Arrhenius equation. Results: The drying efficiency increased considerably, whereas the specific energy consumption significantly decreased with increase in material load and microwave output power. The cumulative energy efficiency increased by 9%, and the specific energy consumption decreased by 8% when the material load was increased from 23 to 186 g. The effective diffusivity increased with decrease in material load and increase in microwave output power. The previously published model gave the best fit for data points with $R^2$ and RMSE values of 0.999 and 0.01, respectively. Conclusions: The data obtained from this study could be used as a basis for modeling of large scale industrial microwave dryers for the pellet production.

Electrical Characteristics and Fabrication of NiCr/NiCrSi Alloy Film for High Precision Thin Film Resistors (고정밀급 박막저항을 위한 NiCr/NiCrSi박막의 제조 및 전기적 특성)

  • Lee, Boong-Joo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.6
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    • pp.520-526
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    • 2007
  • In order to acquire fundamental informations to fabricate high precision thin film resistors, NiCr/NiCrSi alloy films were prepared using Ni and Cr targets. Effect of composition on the electrical properties of the NiCr/NiCrSi alloy film were then investigated. Considering the effect of Si doping on the electrical and material characteristics, the lower TCR (temperature coefficient of resistance) values could be achieved for samples with Ni/Cr ratio of $0.8{\sim}1.5$ (in a range of relative higher specific resistivity and Cr composition of $40\;wt%{\sim}55\;wt%$) and with Si doping. Consequently, the sample prepared using a DC power showed a good TCR of $-25\;ppm/^{\circ}C$, which implies that increase of specific resistivity and decrease of TCR would be achieved more efficiently not for Ni-Cr binary material but for Si doped Ni-Cr ternary material, and not using RF power but using DC power in the sputtering process.

Development of New Bimetal Material for Home Appliances by Using the Rolling Process (압연공정을 이용한 가전용 신 바이메탈재의 개발)

  • Park, S.S.;Lee, J.H.;Bae, D.H.;Bae, D.S.
    • Transactions of Materials Processing
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    • v.16 no.5 s.95
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    • pp.375-380
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    • 2007
  • The bimetals of home appliances are mainly manufactured by cladding process and these are almost consisted with Cu alloy and Ni alloy. But it is very difficult to clad these alloys, because the brittle $Cu_3O_4$ oxide film formed easily on Cu alloy surface during cladding process. Clad rolling and heat treatment processes were applied for the development of bimetals by using the Ni alloy and the 3 types of Cu alloys. Optical microstructure, micro-hardness, specific resistance, and deflection and line profile of newly processed bimetals specimens were observed and measured in this paper. Inter-diffusion was observed between Cu and Ni element in the interface of heat treated Cu alloy and Ni alloy clad material. The C1220 and Invar36 clad material showed the best property of deflection among the 3 kind of clad materials.

A Study on the Chip Shapes Properties of the Fiber Reinforced Plastics by High Speed Drilling Process (복합재료의 고속드릴링 가공시 칩형태에 관한 연구)

  • Sung In-Sik;Lim Se-Hwan;Kim Joo-Hyun
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2005.05a
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    • pp.168-173
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    • 2005
  • Composite material is combined with two or more chemical ingredient and different components. FRP has been widely used for the structure of aircraft, ships, automobiles, sporting goods and other machines because of their high specific strength, high specific stiffness and excellent fatigue strength. Recently, the development of machine tool and cutting tool greatly relies on high speed process to satisfy high precision, high efficient machining, shortened process time to maximize material removal rate (MRR) through high cutting speed and feed speed. The research molded CFRP, GFRP as stacking sequence methods of two direction (orientation angle $0^{\circ}\;and\;0^{\circ}/9^{\circ}$) hand lay-up, drilled molded plates using cemented carbide drill and examined chip shapes, surface roughness properties.

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Fracture Characteristic of Double Cantilever Beam Specimen Using Lightweight Material at Sliding Mode (미끄러짐 모드에서의 경량 재료를 이용한 이중외팔보 시험편의 파손 특성)

  • Kim, Jae-Won;Cho, Jae-Ung
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.3
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    • pp.16-23
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    • 2021
  • The fracture characteristic of the bonded interface under the application of a sliding load to a double cantilevered specimen manufactured using lightweight material was examined. Inhomogeneously bonded materials such as Al6061-T6, CFRP, and CFRP-Al were employed. In the experiment, the specimen was loaded on both directions by applying a shearing load to the bonding interface. The experimentally obtained stress, specific strength and energy release rate values were examined. CFRP exhibited excellent specific strength. The experimental results demonstrated that the inhomogeneous bonded material CFRP-Al exhibited an overall high performance in comparison with the single materials.

Topology Optimization Through Material Cloud Method (재료조각법을 이용한 위상최적설계)

  • Chang Su-Young;Youn Sung-Kie
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.29 no.1 s.232
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    • pp.22-29
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    • 2005
  • A material cloud method, which is a new topology optimization method, is presented. In MCM, an optimal structure can be found out by manipulating sizes and positions of material clouds, which are lumps of material with specified properties. A numerical analysis for a specific distribution of material clouds is carried out using fixed background finite element mesh. Optimal material distribution can be element-wisely extracted from material clouds' distribution. In MCM, an expansion-reduction procedure of design domain for finding out better optimal solution can be naturally realized. Also the convergence of material distribution is faster and well-defined material distribution with fewer intermediate densities can be obtained. In addition, the control of minimum-member sizes in the material distribution can be realized to some extent. In this paper, basic concept of MCM is introduced, and formulation and optimization results of MCM are compared with those of the traditional density distribution method(DDM).

Specific Heat and Thermal Conductivity of XLPE Insulator and Semiconductive Materials for 154kV Power Cable (154kV 전력케이블용 XLPE 절연체와 반도전 재료의 비열 및 열전도)

  • Lee, Kyoung-Yong;Yang, Jong-Seok;Choi, Yong-Sung;Park, Dae-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.05b
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    • pp.19-24
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    • 2005
  • To improve mean-life and reliability of power cable, we have investigated specific heat (Cp) and thermal conductivity of XLPE insulator and semiconductive materials in 154kV underground power transmission cable. Specimens were respectively made of sheet form with EVA, EEA and EBA added 30wt%, carbon black, and the other was made of sheet form by cutting XLPE insulator in 154kV power cable. Specific heat (Cp) and thermal conductivity were· measured by DSC (Differential Scanning Calorimetry) and Nano Flash Diffusivity. Specific-heat measurement temperature ranges of XLPE insulator were from 20[$^{\circ}C$] to 90[$^{\circ}C$], and the heating rate was 1[$^{\circ}C$/min]. And the measurement temperatures of thermal conductivity were 25[$^{\circ}C$}], 55[$^{\circ}C$] and 90[$^{\circ}C$]. In case of semiconductive materials, the measurement temperature ranges of specific heat were from 20[$^{\circ}C$] to 60[$^{\circ}C$], and the heating rate was 1[$^{\circ}C$/min]. And the measurement temperatures of thermal conductivity were 25[$^{\circ}C$] and 55[$^{\circ}C$]. From these experimental results, both specific heat and thermal conductivity were increased by heating rate because volume of materials was expanded according to rise in temperature.

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