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Synthesis of Borosilicate Zeotypes by Steam-assisted Conversion Method (수증기 쪼임법에 의한 제올라이트형 보로실리케이트 제조방법)

  • Mansour, R.;Lafjah, M.;Djafri, F.;Bengueddach, A.
    • Journal of the Korean Chemical Society
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    • v.51 no.2
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    • pp.178-185
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    • 2007
  • Intermediate pentasil borosilicate zeolite-like materials have been crystallized by a novel method named steam-assisted conversion, which involves vapor-phase transport of water. Indeed, amorphous powders obtained by drying Na2O.SiO2.B2O3.TBA2O gels of various compositions using different boron sources are transformed into crystalline borosilicate zeolite belonging to pentasil family structure by contact with vapors of water under hydrothermal conditions. Using a variant of this method, a new material which has an intermediate structure of MFI/MEL in the ratio 90:10 was crystallized. The results show that steam and sufficiently high pH in the reacting hydrous solid are necessary for the crystallization to proceed. Characterization of the products shows some specific structural aspects which may have its unique catalytic properties. X-ray diffraction patterns of these microporous crystalline borosilicates are subjected to investigation, then, it is shown that the product structure has good crystallinity and is interpreted in terms of regular stacking of pentasil layers correlated by inversion centers (MFI structure) but interrupted by faults consisting of mirror-related layers (MEL structure). The products are also characterized by nitrogen adsorption at 77 K that shows higher microporous volume (0.160 cc/g) than that of pure MFI phase (0.119 cc/g). The obtained materials revealed high surface area (~600 m2/g). The infrared spectrum reveals the presence of an absorption band at 900.75 cm-1 indicating the incorporation of boron in tetrahedral sites in the silicate matrix of the crystalline phase.

Effect of Bleaching on Restorative Materials and Restorations-Review (치아미백제가 수복재와 수복물에 미치는 영향에 관한 고찰)

  • Shim, Youn-Soo;Choi, Jae-Yoon
    • Journal of dental hygiene science
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    • v.6 no.3
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    • pp.153-158
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    • 2006
  • Bleaching of vital and nonvital teeth is becoming a more commonly used treatment in the dental office and at home. To improve appearance and remove discoloration, the teeth of specific patients are treated with a variety of bleaching agents. The typical bleaching agents contains carbamide or hydrogen peroxide as the active component. The purpose of the review article was to summarize and discuss the available information concerning the effect of peroxide releasing bleaching agent on dental restorative materials and restorations. Information from all original scientific full papers or reviews listed in PubMed or ISI Web Science were included in the review. Bleaching may exert a negative influence on restorations and restorative materials. Advice is provided based on the current literature to minimize the impact of bleaching treatment on restorative materials and restorations.

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Characterization of interfacial chemistry on the coal bottom ash (저회의 계면 화학적 특성 규명)

  • Lee, Ki-Gang
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.2
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    • pp.92-97
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    • 2011
  • Landfill is the main treatment method for bottom-ash because it has not only an irregular particle size and ingredients but also not proper recycling treatment. The aim of this study is to raise recycling rate of bottom-ash(nonplasticity pulverulent) and for the purpose of alternatives of clay to investigate the properties of Bottom-ash (B/A)-Hard Clay (H/C) bodies with controlled interfacial chemistry properties. After investigating the sedimentation height of suspensions with controlled pH, it was discovered that there was no hetero-polar aggregation for mixed slips because hard clay and bottom-ash had similar interfacial chemistry properties. Also, bulk density, water absorption, and microstructure properties of each pellet was observed that made by silp casting method and manufactured at $50^{\circ}C$ intervals between $1000{\sim}1250^{\circ}C$. As a result, dispersed slip of clay and bottom ash are possible for slip casting and plastic forming process because they exhibit Bingham plastic behavior. Products that made by slip with dispersed clay and bottom ash are not only suitable for KS L 4201 and KS L 1001 at $1250^{\circ}C$ but it is also possible to apply for ceramic and sanitary ware because specific gravity was about 15 % lighter than general ceramic materials.

Electrochemical Characteristics of Ultra Battery Anode Material using the Nano Pb/AC for ISG (나노 납/활성탄을 사용한 ISG용 울트라 전지 음극소재의 전기화학적 특성)

  • Hwang, Jin Ung;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.55 no.5
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    • pp.593-599
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    • 2017
  • In order to enhance ultra battery performances, the electrochemical characteristics of nano Pb/AC anode composite was investigated. Through nano Pb adsorption onto activated carbon, nano Pb/AC was synthesized and it was washed under vacuum process. The prepared anode materials was analysed by SEM, BET and EDS. The specific surface area and average pore size of nano Pb/AC composite were $1740m^2/g$ and 1.95 nm, respectively. The negative electrode of ultra battery was prepared by nano Pb/AC dip coating on lead plate. The electrochemical performances of ultra battery were studied using $PbO_2$ (the positive electrode) and prepared nano Pb/AC composite (the negative electrode) pair. Also the electrochemical behaviors of ultra battery were investigated by charge/discharge, cyclic voltammetry, impedance and rate capability tests in 5 M $H_2SO_4$ electrolyte. The initial capacity and cycling performance of the present nano Pb/AC ultra battery were improved with respect to the lead battery and the AC-coated lead battery. These experimental results indicate that the proper addition of nano Pb/AC into the negative electrode can improve the discharge capacity and the long term cycle stability and remarkably suppress the hydrogen evolution reaction on the negative electrode.

A Study on the Method and System for Organization's Name Authorization of Korean Science and Technology Contents (국내 과학기술콘텐츠 전거데이터 구축을 위한 소속기관명 식별 방법과 시스템에 관한 연구)

  • Kim, Jinyoung;Lee, Seok-Hyong;Suh, Dongjun;Kim, Kwang-Young
    • Journal of Digital Contents Society
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    • v.17 no.6
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    • pp.555-563
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    • 2016
  • Science and technology contents (research papers, patents, reports) are the most common reference material for researchers involved in research and development in the fields of science and technology. Based on various search elements (title, abstract, keyword, year of publication, name of journal, name of author, publisher, etc.), many services are available for users to search science and technology contents and bibliographic information owned by libraries. Authority data on organization name can be useful as an element for author identification and as an element to search for results produced by specific organizations. However, organization name is not taken into account by current search services for domestic academic information and bibliographic records. This study analyzes organization name data contained in the metadata of science and technology contents, which are the basis of the establishment of authority data, and proposes a method and system based on string containment and exact string matching.

Optimal Sensor Placement of Boundaries and Robustness Analysis for Chemical Release Detection and Response of Near Plant (주변 사업장의 화학물질 확산 감지와 대응을 위한 경계면의 센서배치 최적화 및 강건성 분석)

  • Cho, Jaehoon;Kim, Hyunseung;Kim, Tae-Ok;Shin, Dongil
    • Journal of the Korean Institute of Gas
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    • v.20 no.5
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    • pp.104-111
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    • 2016
  • Recently, the quantities of chemical material are increasing in chemical industries. At that time, release accident is increasing due to aging of equipment, mechanical failure, human error, etc. and industrial complexes found community properties in a specific area. For that matter, chemical release accident can lead to hight probability of large disaster. There is a need to analyze the boundaries optimal sensor placement calculated by selecting release scenarios through release condition and wether condition in a chemical process for release detection and response. This paper is to investigate chlorine release accident scenarios using COMSOL. Through accident scenarios, a numerical calculation is studied to determine optimized sensor placement with weight of detection probability, detection time and concentration. In addition, validity of sensor placement is improved by robustness analysis about unpredicted accident scenarios. Therefore, this verifies our studies can be effectively applicable on any process. As mention above, the result of this study can help to place mobile sensor, to track gas release based concentration data.

The Prediction of tong-Term Creep Behavior of Recycled PET Polymer Concrete (단기 크리프 실험을 이용한 PET 재활용 폴리머콘크리트의 장기 크리프거동 예측)

  • Jo Byung-Wan;Tae Ghi-Ho;Kim Chul-Hwan
    • Journal of the Korea Concrete Institute
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    • v.16 no.4 s.82
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    • pp.521-528
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    • 2004
  • In general, polymer concrete has more excellent mechanical properties and durability than Portland cement concrete, but very sensitive to heat and has large deformations. In this study, the long-term creep behaviors was predicted by the short-term creep test, and then the characteristic of creep of recycled-PET polymer concrete was defined by material and experimental variables. The error in the predicted long-term creep values is less than 5 percent for all polymer concrete systems. The filler carry out an important role to restrict the creep strains of recycled PET Polymer concrete. The creep strain and specific on using the $CaCO_3$ were less than using fly-ash. The creep increases with an increase in the applied stress, but not proportional the rate of stress increase ratio. The creep behavior of polymer concrete using recycled polyester resin is not a linear viscoelastic behavior.

A Study on the Symbolic Meaning of the Costume Colours (복색 상징적 의미에 관한연구)

  • 이순홍
    • Journal of the Korean Society of Costume
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    • v.30
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    • pp.85-99
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    • 1996
  • This study has been made to examine the symbolic meaning of our traditional costume colours based on the theory of yin-yang Wu-hsing the interaction of yin and yang with the rotation of the five agents wood firt earth metal and waters. Presenting the spirt and the life of our race the costume culture has been keep-ing its own systematic symbol. Being sensible the colour has to be under-stood as the colour sense therefore the cos-tume colour has begun to have the symbolic meaning with the feeling or the mental value. According to the theory of yin-yang wu-hsing the costume colour has presented our racial sprit way of thinking and way of life for a long time and it has become the tra-ditional culture at last. Based on the doctrine of cosmic harmony through the motion of yin and yang or the passive and active elements are their five agents form the material force of everything. The order of nature has its counterpart in five symbolic costume colours wood-blue ; fire-red: earth-yellow; metal-white: water-black. The five colours are called the primary colours. which produce the next compound colours. Accepted in the social system as well as the social stats the costume colour has set up systematically. The theory of Yin-yang Wu-hsing has given the five colours the symbolic meanings and its mainstream has been the function of Sangsaeng and Sangeuk which are genera-ted by the power of virture. The former is mu-tually beneficial while the latter destructive. The colour as a costume colour has been made distinction between the colour of the up-per classes and the colour of the middle and lower classes and the specific colour has presented the symbolic meanings. The yeollow the red and the purple have been regarded as the colour of king queen and upper classes Being the colour recognition the costume colour has been established by the society and the race generally Implied the spiritual elements the colour recognition could select the lucky colour in accordance with one's des-tiny. Besides the colour recognition has begun to appear as the racial costumes to protect the society and to pray for good fortune. According to the theory of Yin-yang Wu-hsing the costume colour has been forming through our long history and has become our costume culture. Therefore the colour of the costume has signified not only the colour sense but also the important symbolic meanings.

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Effects of Supplemental Asterias amurensis Extract in the Experimental Diets on Growth, Blood Chemistry and Superoxide Production of Kidney Phagocytes of Sebastes schlegeli (불가사리(Asterias amurensis) 추출물을 첨가한 사료의 급이가 조피볼락(Sebastes schlegeli)의 성장, 혈액성상 및 식세포 활성산소 생산에 미치는 효과)

  • Park, Hee-Yeon;Lim, Chi-Won;Kim, Yeon-Kye;Choi, Tae-Jin;Yoon, Ho-Dong;Lee, Ka-Jung;Seo, Yeon-Kyung;Kim, Ji-Yeong;Park, Ki-Eui
    • Applied Biological Chemistry
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    • v.50 no.4
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    • pp.362-366
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    • 2007
  • This study was conducted to examine the effects of Asterias amurensis prethanol extract on growth performance, serum traits, and superoxide production of phagocytes in Sebastes schlegeli. The effects of Asterias amurensis extract on growth performance, specific growth rate (SGR), feed concentration ratio (FCR), coefficient of fatness (CF), and survival rate (SR) of fish fed diets containing various concentrations of Asterias amurensis extract were measured. There were no significant differences in SGR, FCR, CF, and SR among the experimental groups. This result was produced because experimental diets were coated to prevent repellent action of fish. To investigate the effects of Asterias amurensis extract on the metabolism, the contents of glucose, glutamic oxaloacetic transaminase (GOT), and total cholesterol in serum were measured. The contents of glucose and total cholesterol in serum increased dose-dependently and serum GOT content showed no significant difference among the experimental groups, suggesting that Asterias amurensis extract was non-toxic material. To confirm the effects of Asterias amurensis extract on the immune system of fish, superoxide production of phagocytes was measured. Asterias amurensis extract caused a dose-dependent increase of superoxide production of phagocytes. When considering these results, Asterias amurensis extract could be utilized as an additive to augment immune function in diets.

Properties of Unsaturated Polyester Mortar Using Expanded Polystyrene as a Shrinkage-Reducing Additive (발포 폴리스티렌 수지를 수축저감제로 이용한 불포화 폴리에스테르 모르타르의 특성)

  • 조영국;최낙운;소양섭
    • Journal of the Korea Concrete Institute
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    • v.13 no.1
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    • pp.30-37
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    • 2001
  • Generally, polymer mortar made with unsaturated polyester(UP) resin has a high curing shrinkage. This is an inadequate as repair material and construction products that have been widely used for years recently. To overcome these problems, polymer researchers and engineers have used shrinkage-reducing additives, which are usually specific thermoplastic polymers. The objective of this study is to evaluate the effects of shrinkage-reducing additive on the curing shrinkage and strengths of UP mortar. UP mortars are prepared with expanded polystyrene(EPS) ratio in styrene monomer(SM), (EPS/PS, PS=EPS+SM), and the ratio of total polystyrene resin(PS) to UP resin, (PS/UP). And it is tested for viscosity of UP resin, slump-flow, working life, flexural and compressive strengths, and curing shrinkage tests. From the test results, viscosity of resin for UP mortar increases with increasing PS content. Curing shrinkage of UP mortar is considerably smaller than that of plain UP mortar, nevertheless, reduction in the strengths is not recognized according to adding PS resin. In this study, we can obtain the optimum mix proportions of UP mortar using PS resin which made of waste expanded polystyrene.