• Title/Summary/Keyword: Material recovery

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Recycling of end-of-life LiNixCoyMnzO2 batteries for rare metals recovery

  • Sattar, Rabia;Ilyas, Sadia;Kousar, Sidra;Khalid, Amaila;Sajid, Munazzah;Bukhari, Sania Iqbal
    • Environmental Engineering Research
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    • v.25 no.1
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    • pp.88-95
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    • 2020
  • An investigation of rare metals recovery from LiNixCoyMnzO2 cathode material of the end-of-life lithium-ion batteries is presented. To determine the influence of reductant on the leach process, the cathode material (containing Li 7.6%, Co 20.4%, Mn 19.4%, and Ni 19.3%) was leached in H2SO4 solutions either with or without H2O2. The optimal process parameters with respect to acid concentration, addition dosage of H2O2, temperature, and the leaching time were found to be 2.0 M H2SO4, 4 vol.% H2O2, 70℃, and 150 min, respectively. The yield of metal values in the leach liquor was > 99%. The leach liquor was subsequently treated by precipitation techniques to recover nickel as Ni(C4H7N2O2)2 and lithium as Li2CO3 with stoichiometric ratios of 2:1 and 1.2:1 of dimethylglyoxime:Ni and Na2CO3:Li, respectively. Cobalt was recovered by solvent extraction following a 3-stage process using Na-Cyanex 272 at pHeq ~5.0 with an organic-to-aqueous phase ratio (O/A) of 2/3. The loaded organic phase was stripped with 2.0 M H2SO4 at an O/A ratio of 8/1 to yield a solution of 114 g/L CoSO4; finally recovered CoSO4.xH2O by crystallization. The process economics were analyzed and found to be viable with a margin of $476 per ton of the cathode material.

The effectiveness of Ceravida recovery technology on sleeping factors in bedding : Quantitative evaluation (Ceravida recover 기술이 적용된 침구류의 수면요인 효과분석 : 정량적평가)

  • Kim, Jong-Geun;Kim, Ji-Young;Lee, Young-Ik
    • The Journal of the Convergence on Culture Technology
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    • v.9 no.6
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    • pp.273-280
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    • 2023
  • The purpose of this study is to investigate the effect of functional bedding of ceravida recovery materials on muscle fatigue, brain waves, and heat in the cervical spine before and after sleep. The subjects of the study were 12 women in their 50s or older in D Metropolitan City who complained of insomnia due to sleep disorders and cervical pain. The results of this study first showed that functional bedding lowered muscle tension. Second, the skin temperature of cervical spine increased statistically significantly for both functional and general bedding. Third, there was a statistically significant difference in EEG(alpha, beta, theta, delta) of functional bedding. Through these results, it is considered that functional bedding of ceravida recovery material has sufficient effect on sleep recovery technology.

An Experimental Study on Crack Self-Healing and Mechanical Recovery Performance of Cement Composites Materials Using Encapsulated Expandable Inorganic Materials based Solid Healing Materials (캡슐화된 팽창성 무기재료 기반 고상 치유재 활용 시멘트 복합재료의 균열 자기치유 및 역학적 회복성능에 관한 실험적 연구)

  • Choi, Yun-Wang;Nam, Eun-Joon;Kim, Cheol-Gyu;Oh, Sung-Rok
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.1
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    • pp.92-100
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    • 2022
  • In this paper, to evaluate the effect of SC on the crack self-healing performance and mechanical recovery performance of cement composites, encapsulated intumescent inorganic material-based solid healing materials were prepared. SC was mixed with cement composite materials to evaluate the basic properties, permeability test, and load reload test. SC slightly improved the flow of cement composites, and the compressive strength decreased by about 10 %. Also, the flexural strength decreased by about 30 %. It was found that when SC was mixed with the cement composite material by 5 %, the crack self-healing rate of Plain was improved by about 𝜟10 %. As a result of the load reload test, it was found that the mechanical recovery rate of Plain was improved by about 𝜟20 %. In addition, as a result of analyzing the correlation between the crack self-healing rate and the mechanical recovery rate by the load reload test, it is judged that the healing area of the Plain can be increased due to SC.

Recovery of Silver from Artificial Photographic Wastewater by Continuous Flow Electrolytic Process (순환공정법(循環工程法)을 적용(適用)한 인공(人工) 사진폐액(寫眞廢液)으로부터의 전해채취(電解採取)에 의한 은(銀)의 회수(回收))

  • Chung, Won-Ju;Kim, Dong-Su
    • Resources Recycling
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    • v.16 no.1 s.75
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    • pp.68-72
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    • 2007
  • The influences of reduction time, potential difference and ionic concentration flow rate have been investigated on the electrolytic recovery of silver from artificial photographic wastewater in continuous flow reactor system. As the initial concentration of silver ion and applied potential were increased, the amount of silver recovered was observed to be raised. Also, the electrolytically recovered material from artificial wastewater was proved to be pure silver based on the qualitative analyses by EPMA and XRD.

Study on Current Limiting Characteristics of YBCO Thin-Film Wire with Insulation Layer

  • Doo, Seung-Gyu;Du, Ho-Ik;Jeon, An-Gyoon
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.1
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    • pp.20-23
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    • 2013
  • When applying superconducting wire to power machines, an investigation needs to be carried out on the characteristics of wire phase changes in connection with the insulating layer. This study examined trends in the increase of the wire's resistance and the characteristics of its recovery from quenching by a current-applied cycle at temperatures of 90 K, 180 K, and 250 K. The procedure was conducted based on the thickness and presence (or absence) of the insulating wire layers. To achieve this, YBCO thin-film wires with the same critical temperatures were prepared with copper and stainless steel stabilizing layers. At levels (-one, three, and five-), with superior performance, polyimide pressure-sensitive adhesive tape was attached to the wires at a very low temperature. The eight prepared test samples were wound around the linear frames. The wire's voltage and current created from the phase change characteristics were measured at the wire's prescribed temperature, using the four-point probe method. The wire's resistance and recovery characteristics were examined for each cycle at temperatures of 90 K, 180 K, and 250 K.

A Study on the Way to Improve Efficiency of a Waste Heat Recovery System for an Automotive Engine (자동차 엔진용 폐열 회수 시스템의 효율 향상방안에 관한 연구)

  • Cha, Won-Sim;Choi, Kyung-Wook;Kim, Ki-Bum;Lee, Ki-Hyung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.4
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    • pp.76-81
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    • 2012
  • In recent, there are tremendous efforts to apply co-generation concept in automobile to improve its thermal efficiency. The co-generation is basically a simple Rankine Cycle that uses the waste heat from the engine exhaust and coolant for heat source. In spite of developed nano technology and advance material science, the bulky co-generation system is still a big concern in automotive application. Therefore, the system should be effectively designed not to add much weight on the vehicle, but the capacity of the waste heat recovery should be still large. With such a goal in mind, the system thermal efficiency was investigated in terms of the system operation condition and working fluid. This paper provides a direction for the optimal design of the automotive co-generation system.

EAF Dust Recycling Technology in Japan

  • Sasamoto, Hirohiko;Furukawa, Takeshi
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.9-18
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    • 2001
  • 1. EAF Dust in Japan - Generation and Characteristics. The quantity of dust generated from EAF shops in Japan was estimated to be 520,000 tons/year in 1999. Extremely fine dust (or fume) is formed in the EAF by metal vaporization. Its characteristics such as chemical compositions, phases, particle size, leaching of heavy metal are mentioned. 2. EAF Dust Treatment Methods in Japan. In 1999, 61% of EAF dust was treated by regional zinc recovery processing routes, 25% went to landfill disposal, 4% was reused as cement material, and 10% was treated by on-site processing routes. The problems of EAF dust treatment methods in Japan are: (1) very high treatment cost, and (2) heavy environmental load (leaching of heavy metal, emission of dioxins, depletion of disposal sites, etc). It has been much hoped for that new dust management technology would be developed. 3. New technology of EAF dust treatment in Japan. In Japan, some new technologies of EAF dust treatment have been developed, and some others are in the developing stages. Following five processes are mentioned:. (1) Smelting reduction process by Kawasaki Steel, (2) DSM process by Daido Steel, (3) VHR process by Aichi Steel, (4) On-site dust direct recycling technology, and (5) Process technology of direct separation and recovery of iron and zinc metals contained in high temperature EAF off gas by the Japan Research and Development Center fur Metals.

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Opportunities and Challenges in Metals Recovery from Secondary Sources - US Perspective

  • Han, Kenneth N.
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.3-8
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    • 2001
  • The mineral industry of the United States is going through a challenging time. The US as an industrial nation faces with increasing demand in raw materials to fuel various industrial sectors but, at the same time, meeting environmental constraints associated with excavating and extracting these raw materials. In addition, gradual depletion of material resources. and the necessity of handling more complex forms of resources of primary origin have led to a decline in her resource productivity, once a strategic advantage of the U.S. As a result. the United States currently relies heavily upon foreign importation of various materials such as precious and strategic metals. However, since the US is the major consumer of most of these materials, the recovery of these values from scrap would help renew her position as a resource-producing nation, and ultimately help spur its domestic economy. Furthermore. recycling would also help maintain a clean environment and reduce energy consumption. In this paper. the author attempts to discuss opportunities and challenges lied ahead of the US mineral in relation to recovering their much-needed resources from secondary sources. The need and demand in various metals in the US will be reviewed and discussed. The implication of resource recovery from secondary sources will also be discussed. Extraction methods treating secondary sources are inherently different from those for primary sources. There is a need for new technologies which are metallurgically efficient and environmentally benign in treating secondary sources. Ways to meet such a need will be examined and key factors to be considered in approaching these challenges will be discussed.

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Performance Prediction of Heat Exchanger for Waste Heat Recovery from Humid Flue Gases (습증기를 포함한 연소가스의 폐열회수를 위한 열교환기 성능 예측)

  • Jeong, Dong-Woon;Lee, Sang-Yong;Lee, Han-Ju
    • Proceedings of the KSME Conference
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    • 2000.04b
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    • pp.276-281
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    • 2000
  • A simulation program using the mass transfer correlation was constructed to analyze 1-D simplified condensing flow across the tube bank. Higher efficiency was anticipated by reducing the flue gas temperature down below the dew point where the water vapor in the flue gas is condensed at the surface of the heat exchanger; that is, the heat transfer by the latent heat is added to that by the sensible heat. Thus, there can be an optimum operating condition to maximize the heat recovery from the flue gas. The temperature rises of the flue gas and the cooling water between the inlet and the outlet of the tube bank were compared with the experimental data reported previously. The predicted results agree well with the experimental data. Using this simulation program, the parametric studies have been conducted fur various operating conditions, such as the velocities and temperatures of the vapor/gas mixture and the cooling water, the number of the rows, and the conductivity of the wall material.

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Research on Technique of Gold Powder Painting and Conservation Process for White Porcelain Bottle with Phoenix and Peony Design Poly Chrome (백자채색봉황모란문병 보존처리와 금채장식 기법 연구)

  • Lee, Dahae;Hwang, Hyunsung
    • Conservation Science in Museum
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    • v.12
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    • pp.25-34
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    • 2011
  • This study examined conservation process of white porcelain bottle with phoenix and peony design poly chrome, recovery of golden powder painted porcelain being damaged and colored, and recovery material and conservation methods by using a variety of experiments. Not only traditional method but also modern method can recover golden powder painted area being damaged and/or peel off, and suitable recovery was found out by using experiments. The golden powder paint of pattern edge was recovered not by traditional method but by modern method of golden powder paint with acrylic paint and binder.