• 제목/요약/키워드: Material diffusion

검색결과 1,097건 처리시간 0.026초

Ba-페라이트/$SiO_2$ 자성박막에서 ${\alpha}-Al_2O_3$ buffer 층의 역할 (Role of ${\alpha}-Al_2O_3$ buffer layer in $Ba-ferrite/SiO$ magnetic thin films)

  • 조태식;정지욱;권호준
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
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    • pp.267-270
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    • 2003
  • We have studied the interfacial diffusion phenomena and the role of ${\alpha}-Al_2O_3$ buffer layer as a diffusion barrier in the $Ba-ferrite/SiO_2$ magnetic thin films for high-density recording media. In the interface of amorphous Ba-ferrite ($1900-{\AA}-thick)/SiO_2$ thin film during annealing, the interfacial diffusion started to occur at ${\sim}700^{\circ}C$. As the annealing temperature increased up to $800^{\circ}C$, the interfacial diffusion abruptly proceeded resulting in the high interface roughness and the deterioration of the magnetic properties. In order to control the interfacial diffusion at the high temperature, we introduced ${\alpha}-Al_2O_3$ buffer layer ($110-{\AA}-thick$) in the interface of $Ba-ferrite/SiO_2$ thin film. During the annealing of $Ba-ferrite/{\alpha}-Al_2O_3/SiO_2$ thin film even at ${\sim}800^{\circ}C$, the interface was very smooth. The smooth interface of the film was also clearly shown by the cross-sectional FESEM. The magnetic properties, such as saturation magnetization 3nd intrinsic coercivity, were also enhanced, due to the inhibition of interfacial diffusion by the ${\alpha}-Al_2O_3$ buffer layer. Our study suggests that the ${\alpha}-Al_2O_3$ buffer layer act as a useful interfacial diffusion barrier in the $Ba-ferrite/SiO_2$ thin films.

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열확산 프로세스에 의한 초전도 벌크 합성 (Fabrication of the Bulk Superconductor by Thermal Diffusion Process)

  • 이상헌
    • 한국전기전자재료학회논문지
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    • 제34권6호
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    • pp.461-465
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    • 2021
  • A diffusion heat treatment process for YBa2Cu3O7-y bulk superconductor in a Gd2O3 powder was attempted. As a result of measuring the critical temperature of the superconducting bulk, there was no change in the superconducting transition temperature as the Gd particles diffused into the YBa2Cu3O7-y lattice, resulting in dense microstructure. As a result of measuring the critical current, the critical current density (Jc) of the superconducting bulk having treated by the Gd thermal diffusion treatment at 0 T increased to 3×104 A/cm2 at 0 T, which was higher than that of the superconducting bulk without thermal diffusion treatment. The surface magnetic force of the superconducting bulk with Gd thermal diffusion treatment was observed at the center of the superconducting bulk with the maximum trapped magnetic force (Hmax) of 1.51 kG. This result means that the Gd thermal diffusion treatment contributes to improving the critical current density Jc of YBa2Cu3O7-y, and it is believed that Gd particles migrating into the superconducting bulk through thermal diffusion either fill the surface pores of YBa2Cu3O7-y superconductors or act as a flux pinning center.

불포화 압축 벤토나이트에서의 수확산 및 재포화 (Water Diffusion and Resaturation in Unsaturated Compacted Bentonite)

  • 고은옥;이재완;조원진;현재혁;전관식
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 1998년도 공동 심포지엄 및 추계학술발표회
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    • pp.216-220
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    • 1998
  • Experimental studies were carried out to investigate water diffusion in unsaturated compacted bentonite for a landfill of hazardous wastes. Water content distributions were measured and water diffusion coefficients were determined when the dry densities of compacted bentonite were in the range of 1.4 - 1.8 g/㎤. Resaturation times were also calculated to analyze the ability of the compacted bentonite to retard water movement. The results obtained were as follows: Diffusion model described properly the water migration in unsaturated compacted bentonite. Water diffusion coefficients ranged from 4.30$\times$10$^{-6}$ $\textrm{cm}^2$/sec to 1.93$\times$10$^{-6}$ $\textrm{cm}^2$/sec, and decreased with increasing the dry density. The dry density of compacted bentonite was found to be an important factor to control the resaturation time by water. This study suggests that the domestic compacted bentonite should be a good barrier material against water movement in a landfill of hazardous wastes.

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Modeling of sulfate ionic diffusion in porous cement based composites: effect of capillary size change

  • Gospodinov, Peter N.
    • Computers and Concrete
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    • 제4권2호
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    • pp.157-166
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    • 2007
  • The paper considers a theoretical model to study sulfate ion diffusion in saturated porous media - cement based mineral composites, accounting for simultaneous effects, such as filling micro-capillaries (pores) with ions and chemical products and liquid push out of them. Pore volume change and its effect on the distribution of ion concentration within the specimen are investigated. Relations for the distribution of the capillary relative radius and volume within the composite under consideration are found. The numerical algorithm used is further completed to consider capillary size change and the effects accompanying sulfate ion diffusion. Ion distribution within the cross section and volume of specimens fabricated from mineral composites is numerically studied, accounting for the change of material capillary size and volume. Characteristic cases of 2D and 3D diffusion are analyzed. The results found can be used to both assess the sulfate corrosion in saturated systems and predict changes occurring in the pore structure of the composite as a result of sulfate ion diffusion.

Magnetic Effects of La0.67Sr0.33MnO3 on W-C-N Diffusion Barrier Thin Films

  • Song, Moon-Kyoo;So, Ji-Seop;Shim, In-Bo;Lee, Chang-Woo
    • 한국자기학회지
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    • 제15권2호
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    • pp.133-136
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    • 2005
  • In the case of contacts between semiconductor and metal in semiconductor devices, they tend to be unstable because of thermal budget. To prevent these problems we deposited W-C-N diffusion barrier for preventing the interdiffusion between metal and semiconductor. The thickness of the barrier is $1,000{\AA}$ and the pressure is 3 mTorr during the deposition. In this work we coated LSMO (CMR material) on W-C-N diffusion barrier and then we studied the interface effects between LSMO layer and W-C-N diffusion barrier. We got results that the magnetic characteristics of LSMO thin film are still maintained after annealing at $800^{\circ}C$ for 3 hr because W-C-N thin diffusion barrier was prevented the diffusion of oxygen between LSMO and Si substrate.

Cultural Diffusion, Adoption and Adaptation - Motifs and Patterns in Indonesian Textiles -

  • Hann, Michael A.
    • The International Journal of Costume Culture
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    • 제12권1호
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    • pp.85-92
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    • 2009
  • The objectives of the research are to explain the nature of cultural diffusion and its associated theoretical concepts, to review the nature of traditional Indonesian textiles and to focus particular attention on the origin, evolution and diffusion of motifs and patterns associated with the decoration of two important categories of Indonesian textiles: batiks and ikats. Cultural diffusion refers to the process by which cultural traits, material objects, ideas, inventions, innovations or patterns of behaviour are spread from one social or geographical context to another. Examining the decoration on traditional textiles produced across the Indonesian archipelago, certain motifs and patterns are shown to have been retained from ancient times, and others have been adopted from elsewhere. There is great cultural diversity across the archipelago and ample evidence of cultural diffusion.

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열간 프레스 성형공정 적용을 위한 극저탄소강의 탄소확산에 미치는 결정립 크기의 영향 (Effects of Grain Size on Carbon Diffusion in an Ultra-Low Carbon Steel for Hot Press Forming)

  • 강수영
    • 대한금속재료학회지
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    • 제50권12호
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    • pp.883-889
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    • 2012
  • Carbon diffusion of ultra low carbon steel treated at $880^{\circ}C$ and $930^{\circ}C$ for 10, 30, 60 and 120 minutes was investigated using optical microscopy, SAM, EPMA, and Micro Vickers. The martensite patterns of the specimens treated at $880^{\circ}C$ and $930^{\circ}C$ were different. Martensite in the ferrite region was found in the specimen treated at $880^{\circ}C$ because of grain boundary diffusion. Such phenomena is explained by a carbon diffusion model.

Characterization of an In2Se3 Passivation Layer for CIGS Solar Cells with Cd-free Zn-containing Atomic-layer-deposited Buffers

  • Kim, Suncheul;Lee, Ho Jin;Ahn, Byung Tae;Shin, Dong Hyeop;Kim, Kihwan;Yun, Jae Ho
    • Current Photovoltaic Research
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    • 제9권3호
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    • pp.96-105
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    • 2021
  • Even though above 22% efficiencies have been reported in Cd-free Cu(In,Ga)Se2 (CIGS) solar cell with Zn-containing buffers, the efficiencies with Zn-containing buffers, in general, are well below 20%. One of the reasons is Zn diffusion from the Zn-containing buffer layer to CIGS film during buffer growth. To avoid the degradation, it is necessary to prevent the diffusion of Zn atoms from Zn-containing buffer to CIGS film. For the purpose, we characterized an In2Se3 film as a possible diffusion barrier layer because In2Se3 has no Zn component. It was found that an In2Se3 layer grown at 300℃ was very effective in preventing Zn diffusion from a Zn-containing buffer. Also, the In2Se3 had a large potential barrier in the valence band at the In2Se3/CIGS interface. Therefore, In2Se3 passivation has the potential to achieve a super-high efficiency in CIGS solar cells that employ Cd-free ALD processed buffers containing Zn.

해양투기물질의 확산 특성에 관한 연구 (A Study on Characteristic of Diffusion of the Ocean Dumping Material)

  • 홍도웅;류청로
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2001년도 춘계학술대회 논문집
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    • pp.180-185
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    • 2001
  • In order to regulate the physical characteristics of an ocean dumping material in the south-eastern East Sea, the diffusion characteristics with the observation, hydraulic experiment and numerical experiment data are investigated. The main results are as follows; (1) Spying CTD observation result of the area of Jung in the East Sea, the ocean dumping area had influenced the Tsushima warm current of high temperature and salinity. Horizontal turbulent diffusivity is 1.913${\times}$10$^{7}$ $\textrm{cm}^2$/sec by drogue tracking. (2) From the experiment of settling, the initial settling velocity of each material is 1.0∼2.7 cm/sec according to the specific gravity and initial concentration. In the pycnocline, particles didn't settle under the pycnocline any more and accumulated. It is signified that calculation of the sedimentation rate of the ocean dumping material including of vertical diffustion must be regard the pycnocline in the ocean area have well-developed pycnocline. (3) Vertical turbulent diffusivity were 2.219${\times}$10$^{-8}$∼8,874${\times}$10$^{-4}$ $\textrm{cm}^2$/sec from the experiment of settling. And, the pycnocline influenced the vertical turbulent diffusivity. (4) From the result of diffusion simulation in the East Sea, the co-concentration line of 0.05 ppm and 0.1 ppm are limited at dumping area after 200 days. The constant concentration line of 0.01 ppm is distributed to the vicinity of Ulleungdo and Tokdo, but isn't distributed to the coastal area of East Sea and southern area of Jung in the East Sea.

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CFD 해석을 이용한 PEMFC 용 기체확산층의 특성평가 (The Characteristics Evaluation of the Gas Diffusion Layer for a PEM Fuel Cell by Computational Fluid Dynamics)

  • 김병희;최종필;전병희
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2005년도 춘계학술대회 논문집
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    • pp.207-210
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    • 2005
  • In this paper, a two-dimensional cross-channel model was applied to investigate influence of the gas diffusion layer(GDL) property and flow field geometry in the anode side for proton exchange membrane fuel cell(PEMFC). The GDL is made of a porous material such as carbon cloth, carbon paper, or metal wire mesh. To the simplicity, the GDL is represented as a block of material containing numerous pathways through which gaseous reactants and liquid water can pass. The purpose of present work was to study the effect of the GDL thickness and the porosity, and flow field geometry by computational fluid dynamics(CFD)

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