• Title/Summary/Keyword: Material Resistance

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Improvement of Electrochemical Properties and Thermal Stability of a Ni-rich Cathode Material by Polypropylene Coating

  • Yoo, Gi-Won;Son, Jong-Tae
    • Journal of Electrochemical Science and Technology
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    • v.7 no.2
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    • pp.179-184
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    • 2016
  • The interface between the surface of a cathode material and the electrolyte gives rise to surface reactions such as solid electrolyte interface (SEI) and chemical side reactions. These reactions lead to increased surface resistance and charge transfer resistance. It is consequently necessary to improve the electrochemical characteristics by suppressing these reactions. In order to suppress unnecessary surface reactions, we coated cathode material using polypropylene (PP). The PP coating layer effectively reduced the SEI film that is generated after a 4.3 V initial charging process. By mitigating the formation of the SEI film, the PP-coated Li[(Ni0.6Co0.1Mn0.3)0.36(Ni0.80Co0.15Al0.05)0.64)]O2(NCS) electrode provided enhanced transport of Li+ ions due to reduced SEI resistance (RSEI) and charge transfer resistance (Rct). The initial charge and discharge efficiency of the PP-coated NCS electrode was 96.2 % at a current density of 17 mA/g in a voltage range of 3.0 ~ 4.3 V, whereas the efficiency of the NCS electrode was only 94.7 %. The presence of the protective PP layer on the cathode improved the thermal stability by reducing the generated heat, and this was confirmed via DSC analysis by an increased exothermic peak.

Assesment of Renewable Energy (신재생 에너지 고찰)

  • Lee, Sang-Heon;Koo, Kyoung-Whan
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.2071-2072
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    • 2011
  • Withstand voltage characteristics of the nanocomposites, as a material with excellent abrasion resistance and water resistance, low shrinkage upon curing with moisture even in very good adhesion, workability is not lost. In this study, the fusion of nanoparticles and the high functionality epoxy nano-composite material produces the electricity. Degeneration of the unit based on this power structure and breakdown characteristics, efficiency and cross-measurement system as closely related organisms that can be applied to the power plant electrical efficiency of the nano-composite material is designed to develop skills.

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Electrical characteristics of RGB OLED (RGB OLED의 전기적 특성 분석)

  • Yoo, Ji-Hong;Han, Jay-Ho;Choi, Byoung-Deog
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.281-281
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    • 2009
  • Electrical analysis of red, green and blue (RGB) organic light emitting diode (OLED), which were measured at various temperatures from 230K to 370K by steps of 20K, were investigated using current-voltage(I-V) characteristics. Ideality factor and series resistance were obtained from the thermionic emission theory. Experimental results showed that the ideality factors were 2.12 for red, 3.80 for green, and 6.03 for blue OLED at 290K, respectively. The series resistance were 1960, 2190, 2630$\Omega$ for red, green and blue OLED at the same temperature. It was found that the OLED ideality factors were much higher than near unity for well-behaved silicon diodes, because of the organic material and multi-layer fabrication diode. In addition, the series resistance was near 2k$\Omega$ range. More researches are required to reduce both ideality factors and series resistance to increase the efficiency of OLEDs.

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Study on the Welding Parameters of Steel Pipes for Higher Sulfide Stress Corrosion Cracking Resistance for Field Application

  • Baek, Kwang Ki;Lee, Ho il;Lee, Chul Hwan
    • Corrosion Science and Technology
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    • v.3 no.4
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    • pp.154-160
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    • 2004
  • The Sulfide Stress Corrosion Cracking (SSCC) resistance of structural steels is one of the critical concerns for the operators, material designers, and fabricators of oil-field equipment, especially treating sour gas (H2S) containing fluids. As far as its fabricators concerned, the systematic care of welding parameters should be taken to obtain comparable SSCC resistance of their weldment to that of its base material. In this respect, every different type of welding joint design for this use should be verified to be SSCC-proof with relevant test procedures. In this study, the welding parameters to secure a proper SSCC resistance of steel pipe's weldments were reviewed on the Welding Procedure Qualification Records (WPQR), which had been employed for actual fabrication of an offshore structure for oil and gas production. Based on this review, a guideline of welding parameters, such as, heat input, welding consumable for Y.S. 65 ksi class steel pipe material is proposed in terms of the NACE criteria for SSCC resistance.

Analysis of Surface Tracking of Micro and Nano Size Alumina Filled Silicone Rubber for High Voltage AC Transmission

  • Loganathan, N.;Chandrasekar, S.
    • Journal of Electrical Engineering and Technology
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    • v.8 no.2
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    • pp.345-353
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    • 2013
  • This paper discusses the experimental results in an effort to understand the tracking and erosion resistance of the micro and nano size $Al_2O_3$ filled silicone rubber (SIR) material which has been studied under the AC voltages, with ammonium chloride as a contaminant, as per IEC 60587 test procedures. The characteristic changes in the tracking resistance of the micro and nano size filled specimens were analyzed through leakage current measurement and the eroded masses were used to evaluate the relative erosion and tracking resistance of the composites. The fundamental, third and fifth harmonic of the leakage current during the tracking study were analyzed using moving average current technique. It was observed that the harmonic components of leakage current show good correlation with the tracking and erosion resistance of the material. The thermogravimetry-derivative thermo gravimetric (TG-DTG) studies were performed to understand the thermal degradation of the composites. The physical and chemical studies were carried out by using scanning electron microscope (SEM), Energy Dispersive X-ray analysis (EDAX) and Fourier Transform Infra-red (FTIR) Spectroscopy. The obtained result indicated that the performance of nano filled SIR was better than the micro filled SIR material when the % wt. of filler increased.

Efficiency Estimation of Toxicity Free Eire Resistance Cable

  • Yoon, Hun-Ju;Hon, Jin-Woong
    • Transactions on Electrical and Electronic Materials
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    • v.3 no.3
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    • pp.34-38
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    • 2002
  • In this paper, efficiency estimation of toxicity fee fire resistance cable experiments was measured smoke density of toxicity free fire resistance polyolefin insulation material and electric field dependence of tree shape in low density polyethylene (LDPE). One of the most serious causes of failure in high-voltage cables, can be an electrical discharge across an internal gab or void in the insulating material. Treeing due to partial discharge is one of the main causes of breakdown in the insulating materials and reduction of the insulation life. Therefore the necessity for establishing a method to diagnose the aging of insulation materials and to predict the breakdown of insulation and research of the fire resistance character has become important. First, we have studied on electric field dependence of tree shape in LDPE about treeing phenomena occurring on the high electrical field. Second, the measurement method is the attenuation quantity of irradiation by smoke accumulating with in a closed chamber due to non-flaming heat decomposition and flaming combustion. A main cause of fire-growth and generating toxic gas when, it bums, should be dealt with great care in life. safety design. The fire gases were occurred carbon monoxide and decomposition than in polyolefin due to incomplete combustion of PVC, which has high content of carbon in chemical compound.

Fracture resistance of CAD-CAM all-ceramic surveyed crowns with different occlusal rest seat designs

  • Chaturvedi, Saurabh;Alqahtani, Turki;Alsolami, Saleh;Alqahtani, Abdulbari;Das, Gotam;Alsubaiy, Ebrahim
    • The Journal of Advanced Prosthodontics
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    • v.13 no.1
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    • pp.36-45
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    • 2021
  • Purpose. To investigate the fracture resistance of monolithic CAD-CAM all-ceramic surveyed crowns with two different occlusal rest seat designs. Materials and Methods. Two maxillary first premolar were prepared for all-ceramic surveyed crowns with wide (2/3rd of buccolingual width of an unprepared tooth) or narrow (1/3rd of buccolingual width of an unprepared tooth) disto-occlusal rest seat (ORS) designs. Eighty monolithic CAD-CAM all-ceramic surveyed crowns were prepared and divided into 4 groups - Group CR, Composite resin material as a control; Group LDS, Lithium disilicate based material; Group ZIPS, zirconia-material (IPS ZirCAD); and Group ZLHT, zirconia- material (CeramillZolidht+). Crowns were cemented on an epoxy resin die with adhesive resin cement. The fracture resistance of crowns was tested with the universal machine. Univariate regression analysis was used. Results. The mean ± standard deviation of maximum failure force values varied from 3476.10 ± 285.97 N for the narrow ORS subgroup of group ZIPS to 687.89 ± 167.63 N for the wide ORS subgroup of group CR. The mean ± standard deviation of maximum force was 1075 ± 77.0 N for group CR, 1309.3 ± 283.9 N for group LDS, 3476.1 ± 285.97 N for group ZIPS, and 2666.7 ± 228.21 N for group ZLHT, with narrow occlusal rest seat design. The results of the intergroup comparison showed significant differences in fracture strength with various material groups and occlusal rest seat designs (P<.001). Conclusion. The zirconia-based all-ceramic surveyed crowns fractured at more than double the load of Lithium disilicate based crowns. The crowns with narrow base occlusal rest seat design had statistically significantly higher fracture resistance than surveyed crowns with wide occlusal rest seat design. The use of narrow occlusal rest seat design in CAD-CAM all ceramic surveyed crowns provides higher fracture resistance, and therefore narrow occlusal rest design can be used for providing esthetics with high strength.

A Study on Improvement of the low temperature flex resistance test method about high waterproof materials (고기능성 투습방수 소재의 저온굴곡 시험방법 개선 연구)

  • Lee, Minhee;Moon, Sunjeong;Ko, Hyeji;Hong, Seongdon
    • Journal of Korean Society for Quality Management
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    • v.46 no.3
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    • pp.425-440
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    • 2018
  • Purpose: This study is aimed at developing of the flex resistance testing process at low temperature with the waterproof fabric to suit the military environment, and is designed to fit for the purpose of the waterproof materials in order to optimize the test method by finding out matters to improve from existing the test method and through previous studies. Methods: The test method, which has been applied to flex resistance of existing water-repellent materials, was improved and consequently, differentiated test results could be obtained according to the test temperature, sample size, and flexing method. Results: The testing of the total of 8 samples revealed that performance of the military requirement could hardly be met just by presenting the materials or 2~3 layers when the quality criteria for high functional water repellent fabrics were applied. PTFE(Polytetrafluoroethylene) is preferred to PU(Polyurethane) to be used in the extremely low-temperature environment, but durability under the low-temperature environment may be varied depending on film thickness or laminating technique even if the materials of waterproof films are identical. Therefore, in addition to the material or texture, the test method capable of reflecting durability under the low-temperature environment shall be suggested, and the newly designed test method proposed in this study was shown to suggest differentiated quality criteria by the material. Conclusion: The water resistance measurement and the test method following flex resistance with expanded range of flex will enable the differentiable test of the samples according to the number of repetition. This study is meaningful in that it suggests a differentiable test method capable of establishing a basis of deciding suitable material when selecting military goods made of water repellent material by properly improving the test method.

The Effect of Surface Protective Material on the Impact Resistance in Filament Wound Composite Pressure Vessel (필라멘트 와인딩 복합재 압력용기의 충격저항성에 미치는 표면 고무 보호재료의 영향)

  • Kang, Ki-Weon;Kim, Young-Soo;Lee, Mee-Hae;Choi, Rin
    • Journal of the Korean Society of Safety
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    • v.20 no.4 s.72
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    • pp.14-19
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    • 2005
  • One area in which composites have been used rather extensively is for fabricating pressure vessel. These structures can be readily manufactured by filament winding, which is, as far as composite fabrication techniques are concerned, a relatively inexpensive method for producing composite structures. Unfortunately, the higher strength material and fabrication costs are not the only disadvantages of fiber-reinforced polymer composites when they are compared to metals. Additionally, these materials tend to exhibit brittle behavior. This is of particular concern when they are subjected to a low-velocity impact during routine handling a significant amount of structural damage can be introduced into the composites. The goals of this paper are to understand the impact damage behavior and identify the effect of surface coating materials on impact resistance in filament wound composite pressure vessels. For these, a series of low velocity impact tests was performed on specimens cutting from the full scale pressure vessel by the instrumented impact testing machine. The specimens are classified into two types with and without surface protective material. The visualization for impact damage is made by metallurgical microscope. Based on the impact force history and damage, the resistance parameters were employed and its validity in identifying the damage resistance of pressure vessel was reviewed. As the results, the impact resistance of the filament wound composites and its dependency on the protective material were evaluated quantitatively.

A Study on Material Characterization of SMC (SMC의 물성치 평가에 관한 연구)

  • 정진호;한영원;임용택
    • Transactions of Materials Processing
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    • v.4 no.3
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    • pp.245-256
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    • 1995
  • SMC(Sheet Molding Compound), a thermoset composite material which consists of unsaturated polyester resin, fiberglass strands, fillers, and various chemical additives for curing agent, has been widely used in fabrication of structural components. The mechanical properties of molded SMS parts are strongly dependent on material flow results during compression molding process, while such flow in molds is affected by material characteristics. For numerical simulation of SMC molding process, estimation of material property of SMC must be accomplished. In this study, flow resistance of SMC was estimated through a simple compression test using a lubricant with grease oil under the constant strain rate condition at various temperatures and the result was compared with other material data available in the literature. The accuracy of the experimentally determined flow resistance was tested by finite element analyses of compression molding of SMC. Simulation results were compared with experimental results under the plane strain condition.

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