• Title/Summary/Keyword: Material Decomposition

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Effects of $Fe_{3}O_{4}$ Addition on Spinel Phase $LiMn_{2}O_{4}$ for $CO_{2}$ Decomposition (($CO_{2}$ 분해용 스피넬상 $LiMn_{2}O_{4}$에 대한 $Fe_{3}O_{4}$ 첨가효과)

  • Yang, Chun-Mo;Rim, Byung-O;Kim, Seung-Ho;Kim, Soon-Tae
    • Journal of the Korean Applied Science and Technology
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    • v.18 no.3
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    • pp.167-173
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    • 2001
  • The spinel $LiMn_{2}O_{4}$ powders were synthesized at $480^{\circ}C$ for 12 h in air by a sol-gel method using manganese acetate and lithium hydroxide as starting material and the $Fe_{3}O_{4}$ powders were synthesized by the precipitation method using $0.2M-FeSO_{4}{\cdot}H_{2}O$ and 0.5M-NaOH. The synthesized $Fe_{3}O_{4}$ powders were mixed at portion of 5, 10, 15 and 20 wt% about $LiMn_{2}O_{4}$ powders through ball-milling followed by drying at room temperature for 48 h in air. The mixed catalysts were reduced at $350^{\circ}C$ for 3 h by hydrogen and the decomposition rate of carbon dioxide was measured at $350^{\circ}C$ using the reduced catalysts. As the results of $CO_{2}$ decomposition experiments, the decomposition rates of carbon dioxide were 85% in all catalysts but the initial decomposition rates of $CO_{2}$ were slightly high in the case of the $5%-Fe_{3}O_{4}$ added catalyst.

Effect of Electrode Process Variables in case of Decomposition of $NO_x$ by SPCP (연면방전에 의한 질소산화물의 분해시 전극 공정변수에 대한 영향)

  • 안형환;강현춘
    • Proceedings of the Safety Management and Science Conference
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    • 1999.11a
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    • pp.543-563
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    • 1999
  • For hazardous air pollutants(HAP) such as NO and $NO_2$ decomposition efficiency, power consumption, and applied voltage were investigated by SPCP(surface induced discharge plasma chemical processing) reactor to obtain optimum process variables and maximum decomposition efficiencies. Decomposition efficiency of HAP with various electric frequencies(5~50 kHz), flow rates(100~1,000 mL/min) initial concentrations(100~1,000 ppm), electrode materials(W, Cu, Al), electrode thickness(1, 2, 3 mm) and number of electrode windings(7, 9, 11) were measured. Experimental results showed that for the frequency of 10 kHz, the highest decomposition efficiency of 94.3% for NO and 84.7% for $NO_2$ were observed at the poser consumptions of 19.8 and 29W respectively and that decomposition efficiency decreased with increasing frequency above 20 kHz. Decomposition efficiency was increased with increasing residence times and with decreasing initial concentration of pollutants. Decomposition efficiency was increased with increasing thickness of discharge electrode and the highest decomposition efficiency was obtained for the electrode diameter of 3mm in this experiment. As the electrode material, decomposition efficiency was in order : tungsten(W), copper(Cu), aluminum(Al).

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CSG-based Representation for Free-form Heterogeneous Object Modeling (임의 형상의 복합재 모델링을 위한 CSG 기반 표현)

  • Shin, K.H.;Lee, J.K.
    • Korean Journal of Computational Design and Engineering
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    • v.11 no.4
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    • pp.235-245
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    • 2006
  • This paper proposes a CSG-based representation scheme for heterogeneous objects including multi-material objects and Functionally Graded Materials (FGMs). In particular, this scheme focuses on the construction of complicated heterogeneous objects guaranteeing desired material continuities at all the interfaces. In order to create various types of heterogeneous primitives, we first describe methods for specifying material composition functions such as geometry-independent, geometry-dependent functions. Constructive Material Composition (CMC) and corresponding heterogeneous Boolean Operators (e.g. material union, difference, intersection. and partition) are then proposed to illustrate how material continuities are dealt with. Finally, we describe the model hierarchy and data structure for computer representation. Even though the proposed scheme alone is sufficient for modeling all sorts of heterogeneous objects, the proposed scheme adopts a hybrid representation between CSG and decomposition. That is because hybrid representation can avoid the unnecessary growth of binary trees.

A Study on the Damage by Burning Characteristics of Insulating Materials of RCD (누전차단기 절연재료의 소손 특성에 관한 연구)

  • Lee, Chun-Ha;Kim, Shi-Kuk;Ok, Kyung-Jae;Jee, Seung-Wook
    • Fire Science and Engineering
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    • v.23 no.2
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    • pp.62-66
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    • 2009
  • In this study, we study the damage by burning characteristics of insulating material of RCD (Residual Current Device) used in Korea. The insulating materials of RCD manufactured by three manufacturers are used as the sample. We compare and analyze the thermal decomposition characteristics, combustion characteristics and tracking characteristics of samples. The TGA and Mass Loss Calorimeter meeting the requirements for the ISO5660 (Fire tests-Reaction to Fire, part 1) are used for analyzing the thermal decomposition characteristics and combustion characteristics respectively. In addition, the tracking characteristics are analyzed according to standard of KSC IEC 60112 known as the test used for measuring the resistance tracking and comparison tracking indexes. The study results show that the resistance tracking property of insulating material provided by A Company is highest. Also, the test results show that the resistance tracking property of insulating material provided by B Company is lowest. However, the thermal stability of insulating material provided by this company is excellent at high temperature of above $350^{\circ}C$. In addition, the test results show that the thermal stability of insulating material provided by C Company is highest at temperature of below $400^{\circ}C$.

A study on the Identification of Sources for Benzene Detected in the Casting Process (주조공정에서의 벤젠 발생원 규명에 관한 연구)

  • Oh, Doe Suk;Lee, Seong Min;Lee, Byoung Jae;Kim, Young Ju
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.16 no.1
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    • pp.27-35
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    • 2006
  • The aim of this study was to identify the sources of benzene detected in airborne of casting workplace where benzene was not used as raw material. We have identified benzene by GC/FID and GC/MSD. In this pilot test, small size iron chamber(diameter 30 cm, height 20 cm) was used. As the raw materials, new sand, recovered sand, and mixed casting sand(new sand + solidifying agent + organic resin + coating material) was tested, respectively. In the new sand benzene was not detected, but in the recovered sand and the mixed casting sand was detected. Xylenesulfonic acid(solidifying agent), one of the mixed casting sand ingredients was thought to product benzene by thermal decomposition above $400^{\circ}$..., but the other raw materials(organic resin and coating material) were thought not to product benzene. In this experiment, the most of benzene by thermal decomposition was produced within 1 hour after pouring the iron solution($1560^{\circ}$...) in small size iron chamber. When the mixed casting sand with coating material was used, the concentration of the produced benzene was average 2.91 ppm(range 1.98~3.72 ppm), and without coating material, benzene concentration was average 0.11 ppm(range 0.08~0.14 ppm).

Understanding the Material Removal Mechanisms of Abrasive Water Jet Drilling Process by Acoustic Emission Technique

  • Kwak, Hyo-Sung;Kovacevic, Radovan
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 1998.03a
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    • pp.40-52
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    • 1998
  • Among the non-traditional machining methods, Abrasive waterjet machining process shows big promise in drilling difficult-to-machine materials due to its numerous advantages such as absence of heat affect zone and thermal distortion. Acoustic emission signal technique is used to understand about material removal mechanisms during abrasive waterjet drilling process. More information about the drilling process is derived through frequency decomposition of auto regressive moving average modeling representing acoustic emission signals.

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Single Wall Carbon Nanotube - a catalyst support for PEMEC

  • Rajalakshmi N.;Ryu Hojin;Shaijumon M.M.;Ramaprabhu S.
    • 한국전기화학회:학술대회논문집
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    • 2003.07a
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    • pp.183-187
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    • 2003
  • Carbon nanotubes, prepared by the catalytic decomposition of acetylene at $700^{\circ}C$ over a Mm based $AB_5$ hydrogen storage alloy hydride catalysts, have been used as a support for platinum electrocatalysts. The performance of this electrocatalyst In proton exchange membrane fuel cells has been studied and discussed.

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Electrical Properties of Nickel Polycide Gate (니켈 폴리사이드 게이트의 전기적 특성)

  • 정연실;김시중;김주연;배규식
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.449-452
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    • 1999
  • NiSi were formed from either Ni monolayer or Ni/Ti bilayer and the SADS method was applied to fabricated PMOSFET with Ni-polycide gate electrodes. PMOSFET made from Ni monolayer showed thermal stability unto 300~40$0^{\circ}C$ for 600sec., and excellent C-V characteristics for long time of drive-in anneal than PMOSFET made from Ni/Ti bilayer. This was attributed to easier decomposition and subsequent Ni diffusion to SiO$_2$ layer, probably due to the presence of Ti unreducing process

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Domain Decomposition Strategy for Pin-wise Full-Core Monte Carlo Depletion Calculation with the Reactor Monte Carlo Code

  • Liang, Jingang;Wang, Kan;Qiu, Yishu;Chai, Xiaoming;Qiang, Shenglong
    • Nuclear Engineering and Technology
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    • v.48 no.3
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    • pp.635-641
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    • 2016
  • Because of prohibitive data storage requirements in large-scale simulations, the memory problem is an obstacle for Monte Carlo (MC) codes in accomplishing pin-wise three-dimensional (3D) full-core calculations, particularly for whole-core depletion analyses. Various kinds of data are evaluated and quantificational total memory requirements are analyzed based on the Reactor Monte Carlo (RMC) code, showing that tally data, material data, and isotope densities in depletion are three major parts of memory storage. The domain decomposition method is investigated as a means of saving memory, by dividing spatial geometry into domains that are simulated separately by parallel processors. For the validity of particle tracking during transport simulations, particles need to be communicated between domains. In consideration of efficiency, an asynchronous particle communication algorithm is designed and implemented. Furthermore, we couple the domain decomposition method with MC burnup process, under a strategy of utilizing consistent domain partition in both transport and depletion modules. A numerical test of 3D full-core burnup calculations is carried out, indicating that the RMC code, with the domain decomposition method, is capable of pin-wise full-core burnup calculations with millions of depletion regions.

In Situ Measurement of Diel Periodicity in Urea Decomposition in a Reed Zone of Lake Biwa, Japan

  • Tachibana, Junji;Kondo, Kunio;Seike, Yasushi;Osamu, Mitamura
    • Korean Journal of Ecology and Environment
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    • v.38 no.spc
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    • pp.31-38
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    • 2005
  • Diel change in urea decomposition activity of epiphytic algae on Phragmites stems and phytoplankton in a shallow littoral reed zone in the south basin of Lake Biwa was investigated with an in situ technique using $^{14}C$-labelled urea. The daily rates of urea decomposition (sum of urea carbon incorporation rate and $CO_2$ liberation rate) by epiphytic and planktonic algae were calculated as 180 ${\mu}$ mole urea surface shoot area $m^{-2}\;day^{-1}$ and 210 ${\mu}$ mole urea $m^{-3}\;day^{-1}$. The chlorophyll a specific urea decomposition rates of epiphytic and planktonic algae were 4.7 to 6.4 and 4.4 to 6.2 ${\mu}$ mole urea mg chl. $a^{-1}$ incubation $time^{-1}$ in daytime and 4.2 to 5.7 and 2.4 to 3.5 ${\mu}$ mole urea mg chl. $a^{-1}\;time^{-1}$ in nighttime, respectively. High values were obtained during 12:00 ${\sim}$ 18:00 and low values during 00:00 ${\sim}$ 06:00 for both epiphytic and planktonic algal communities. A clear diel periodicity in the urea decomposing activity of the planktonic algae was observed. The activity of the epiphytic algae, on the other hand, showed no destinctive variation during a day. The present results indicate that epiphytic algae are one of the significant urea decomposers in a reed zone, and that the diel patterns are quite difference between both algal communities.