• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.11 no.3
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• pp.414-421
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• 1999

Falling film rectification involves simultaneous heat and mass transfer between vapor and liquid interface. In the present work, the adiabatic rectification process of ammonia-water vapor on the vertical plate was investigated. The continuity, momentum, energy and diffusion equations for the solution film and vapor mixture were formulated in integral forms and solved numerically. The model could predict the film thickness, the pressure gradient, and the mass transfer rate. The effects of Reynolds number and ammonia concentration of solution and vapor mixture, rectifier length, and the enhancement of mass transfer in each phases were investigated. The stripping of water in vapor mixture occurred new the entrance of ammonia solution, which imposed the proper size of an adiabatic rectifier. Rectifier efficiency increased as film Reynolds number increased and as vapor mixture Reynolds number decreased. The improvement of rectifier efficiency was significant with the enhancement of mass transfer in falling film.

• International Journal of Air-Conditioning and Refrigeration
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• v.8 no.2
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• pp.69-79
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• 2000

Falling film rectification involves simultaneous heat and mass transfer between vapor and solution film. In the present work, the adiabatic rectification process of ammonia-water vapor by the falling solution film on the vertical plate was investigated. The continuity momentum, energy and diffusion equations for the solution film and the vapor mixture were formulated in integral forms and solved numerically, The model could predict the film thickness, the pressure gradient, and the mass transfer rate. The effects of Reynolds number and ammonia concentration of solution and vapor mixture, rectifier length, and the enhancement of mass transfer coefficient in each phases were investigated. The stripping of water in vapor mixture occurred near the entrance of ammonia solution, which imposed the proper size of an adiabatic rectifier. Rectifier efficiency increased as film Reynolds number increased and as vapor mixture Reynolds number decreased. The improvement of rectifier efficiency was significant with the enhancement of mass transfer coefficient in falling film.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.1
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• pp.102-111
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• 2000

A numerical model which simulates the simultaneous heat and mass transfer within a vertical tube GAX absorber was developed. The ammonia vapor and the solution liquid are in counter-current flow, and the hydronic fluid flows counter to the solution liquid. The film thickness and the velocity distribution of the liquid film were obtained by matching the shear stress at the liquid-vapor interface. Two-dimensional diffusion and energy equations were solved in the liquid film to give the temperature and concentration, and a modified Colburn-Drew analysis was used for the vapor phase to determine the heat and mass fluxes at the liquid-vapor interface. The model was applied to a GAX absorber to investigate the absorption rates, temperature and concentration profiles, and mass flow rates of liquid and vapor phases. It was shown that the mass flux of water was negligible compared with that of ammonia except the region near the liquid inlet. Ammonia absorption rate increases rapidly near the liquid inlet and decrease slowly. Both the absorption rate of ammonia vapor and the desorption rate of water near the liquid inlet increase as the vapor mass flow rate increases, but the mass fluxes of the ammonia and the water near the liquid outlet decrease as the mass flow rate of the vapor increases.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.2
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• pp.99-103
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• 2010

A new analytic solution was derived for the diffusion into or from an immobile zone of a rectangular 2-D pore. For a long time, the new solution converges to a traditional mobile-immobile zone (MIM) model, but only if the latter is used with an apparent initial concentration that is smaller by almost 20% than the true one. This is the tradeoff for using a simple MIM model instead of an exact model based on the diffusion equation. The mass-transfer coefficient was found to be constant for a sufficiently long time; it was proportional to the molecular diffusion and inversely proportional to the square of the pore depth. The mass-transfer coefficient was time-dependent for a sufficiently short time and may be significantly larger than its asymptotic value.

• Proceedings of the KSME Conference
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• 2004.04a
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• pp.1546-1551
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• 2004

This paper presents a mathematical model to predict the frost properties and heal and mass transfer within the frost layer formed on a cold plate. The laminar flow equations for the air-side are analyzed. and the empirical correlations of local frost properties are employed in order to predict the frost layer growth. The correlations of local frost density and effective thermal conductivity of frost layer, obtained from various experimental conditions, are derived as functions of various frosting parameters (Reynolds number, frost surface temperature, absolute humidity and temperature of moist air, cooling plate temperature, and frost density). The numerical results are compared with experimental data and the results of various models to validate the present model, and agree well with experimental data within a maximum error of 10%. The heat and mass transfer coefficients obtained from the numerical analyses are presented, as the results, it is found that the model for frost growth using the correlation of heat transfer coefficient without solving air flow have a limitation in its application.

• Proceedings of the KSME Conference
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• 2003.11a
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• pp.308-313
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• 2003

Thermal mass flow meters (TMFMs) are most widely used for measuring mass flow rates in the semiconductor industry. A TMFM should have a short response time in order to measure the time-varying flow rate rapidly and accurately. Therefore it is important to study transient heat transfer phenomena in the sensor tube of a TMFM that is the most critical part in the TMFM. In the present work, a simple numerical model for transient heat transfer phenomena of the sensor tube of a TMFM is presented. Numerical solutions for the tube and fluid temperatures in a transient state are obtained using the proposed model and compared with experimental results to validate the proposed model. Based on numerical solutions, heat transfer mechanism in a transient state in the sensor tube is explained. Finally, a correlation for predicting the response time of a sensor tube is presented. The correlation is verified by experimental results.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2000.11a
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• pp.171-176
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• 2000

Bioremediation of hazardous hydrophobic organic compounds, such as polycyclic aromatic hydrocarbons (PAHs), is a major environmental concern due to their toxic and carcinogenic properties. Due to their hydrophobicity, the hydrophobic organic compounds are mainly associated with the soil organic matter or nonaqueous-phase liquids. A major question concerns the relationships between biodegradation and sorption. This work develops and utilizes a non- steady state model for evaluating the interactions between sorption and biodegradation of phenanthrene, a 3-ring PAH compound, in soil-slurry systems. The model includes sorption/desorption of a target compound, its utilization by microorganisms as a primary substrate existing in the dissolved phase and/or the sorbed phase in biomass and soil, oxygen transfer, and oxygen utilization as an electron acceptor. Biodegradation tests with phenanthrene were conducted in liquid and soil-slurry systems. The soil-slurry tests were performed with very different mass transfer rate: fast mass transfer in a flask test at 150 rpm, and slow mass transfer in a roller-bottle test at 2 rpm. In the slurry tests, phenanthrene was degraded more rapidly than in liquid tests, but with a similar rate in both slurry systems. Modeling analyses with several hypotheses indicate that a model without biodegradation of compound sorbed to the soil was not able to account for the rapid degradation of phenanthrene, particularly in the roller bottle slurry test. Reduced mass-transfer resistance to bacteria attached to the soil is the most likely phenomenon accounting for rapid sorbed-phase biodegradation.

• Membrane and Water Treatment
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• v.3 no.3
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• pp.151-168
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• 2012

Gas sparging is one of the techniques used to control the concentration polarization during ultrafiltration. In this work, the effects of gas sparging in stratified flow regime were investigated during gel layer controlling cross flow ultrafiltration in a rectangular channel. Synthetic solution of pectin was used as the gel forming solute. The liquid and gas flow rates were selected such that a stratified flow regime was prevalent in the channel. A mass transfer model was developed for this system to quantify the effects of gas flow rates on mass transfer coefficient (Sherwood number). The results were compared with the case of no gas sparging. Gas sparging led to an increase of mass transfer coefficient by about 23% in this case. The limitation of the developed model was also evaluated and it was observed that beyond a gas flow rate of 20 l/h, the model was unable to explain the experimental observation, i.e., the decrease in permeate flux with flow rate.

• Journal of Soil and Groundwater Environment
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• v.18 no.4
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• pp.8-18
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• 2013

Biocarrier beads with dead biomass, Bacillus drentensis, immobilized in polymer polysulfone were synthesized to remove heavy metals from wastewater. To identify the sorption mechanisms and theoretical nature of underlying processes, a series of batch experiments were carried out and a mathematical model was developed to quantify the biosorption of Pb(II) by the biocarrier beads. A series of mass balance equations for representing mass transfer of metal sorbents in biocarrier beads and surrounding solution were established. Major model parameters such as external mass transfer coefficient and maximum sorption capacity, etc. were determined from pseudo-first-order kinetic models and Langmuir isotherm model based on kinetic and equilibrium experimental measurements. The model simulation displays reasonable representations of experimental data and implied that the proposed model can be applied to quantitative analysis on biosorption mechanisms by porous granular beads. The simulation results also confirms that the biosorption of heavy metal by the biocarrier beads largely depended on surface adsorption.

• KIEAE Journal
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• v.7 no.5
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• pp.53-58
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• 2007

In order to predict the indoor air pollutant, the VOCs emission rate is used through small chamber in the design process. However, the small chamber method has limitations as the convective mass transfer coefficient, the most important factor when predicting VOCs contamination of indoor air, is different between the small chamber result and the measured data in the actual building. Furthermore, the existing studies which analyzed mass transfer coefficient in the small chamber were directed on the small chambers developed at the time and FLEC(Field and Laboratory Emission Cell), thus, are different from the current small chamber which has been changed with improvements. The purpose of this study is to determine the emission rate of pollutant in multi-layered building materials, and predict the indoor pollutant concentration through the CFD(Computational of Fluid Dynamics) and CRIAQ2 based on the mass transfer coefficient on singled-layered building material by using the current small chamber widely used in Korea. Futhermore, this study used the new convective mass transfer coefficient(hm') which indicates the existing convective mass transfer coefficient(hm) including VOC partition coefficient(k). Also, formaldehyde was selected as target pollutant.