• 제목/요약/키워드: Mass conversion rate

검색결과 111건 처리시간 0.023초

수소 생산을 위한 수증기 개질기의 형상 변화와 작동 조건에 대한 수치해석 연구 (Numerical Study on Geometries and Operating Parameters of a Steam Reformer for Hydrogen Production)

  • 변강수;이재성;김호영
    • 한국연소학회지
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    • 제16권3호
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    • pp.1-11
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    • 2011
  • The main objective of this paper is to investigate characteristic of steam reformer at various geometries and operating conditions. In this paper, the steam reforming is studied by a numerical method and three dimensional simulations were used for effective analytical study. User - Defined Function (UDF) was used to simultaneously calculate reforming and combustion reaction. And the numerical model is validated with experimental results at the same operating conditions. In order to understand the relationship between operating conditions such as gas hourly space velocity(GHSV), mass flow rate of combustor inlet, various numerical investigations are carries out for various geometries. Numerical results show that cylindrical geometry is more effective than rectangular geometry for heat transfer to reactors and reforming efficiency. As mass flow rate of combustor inlet increase, reaction occurs more faster and temperature increase with each geometry. On the other hand, reaction and hydrogen conversion decrease as mass flow rate of reactor decreases.

Comparison of Immobilization Matrix for Ethanol Fermentation by Zymomonas mobilis and Saccharomyces cerevisiae

  • Ryu, Sang-Ryeol;Lee, Ke-Ho
    • Journal of Microbiology and Biotechnology
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    • 제7권6호
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    • pp.438-440
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    • 1997
  • A continuous fermentation system employing immobilized cells of Zymomonas mobilis and Saccharomyces cerevisiae was studied for the mass production of ethanol. Ethanol production by cells immobilized with Ca-alginate was better than those by cells immobilized with K-carrageenan. Maximum ethanol production employing a continuous system by cells immobilized with Ca-alginate was 77.5 $g.l^{-1}h^{-1}$ at a dilution rate of 1.85 $h^{-1}$ with 82% conversion rate for Z. mobilis while that was 40.2 $g.l^{-1}h^{-1}$ at a dilution rate of 0.92 $h^{-1}$ with 85% conversion rate for S. cerevisiae. These results suggest that Ca-alginate is a better cell immobilization matrix than K-carrageenan and that immobilized cells of Z. mobilis are more efficient than S. cerevisiae for ethanol production.

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열 방출률에 대한 마이크로 백금 촉매 연소기의 치수 설계 기준 (Design Criterion for the Size of Micro-scale Pt-catalytic Combustor in Respect of Heat Release Rate)

  • 이광구;스즈키 유지
    • 한국연소학회지
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    • 제19권4호
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    • pp.49-55
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    • 2014
  • Design criterion for the size of micro Pt-catalytic combustor is investigated in terms of heat release rate. One-dimensional plug flow model is applied to determine the surface reaction constants using the experimental data at stoichiometric butane-air mixture. With these reaction constants, the mass fraction of butane and heat release rate predicted by the plug flow model are in good agreement with the experimental data at the combustor exit. The relationship between the size of micro catalytic combustor and mixture flowrate is introduced in the form of product of two terms-the effect of fuel conversion efficiency, and the effect of chemical reaction rate and mass transfer rate.

PARAMETER DEPENDENCE OF STEAM EXPLOSION LOADS AND PROPOSAL OF A SIMPLE EVALUATION METHOD

  • MORIYAMA, KIYOFUMI;PARK, HYUN SUN
    • Nuclear Engineering and Technology
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    • 제47권7호
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    • pp.907-914
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    • 2015
  • The energetic steam explosion caused by contact between the high temperature molten core and water is one of the phenomena that may threaten the integrity of the containment vessel during severe accidents of light water reactors (LWRs). We examined the dependence of steam explosion loads in a typical reactor cavity geometry on selected model parameters and initial/boundary conditions by using a steam explosion simulation code, JASMINE, developed at Japan Atomic Energy Agency (JAEA). Among the parameters, we put an emphasis on the water pool depth that has significance in terms of accident mitigation strategies including cavity flooding. The results showed a strong correlation between the load and the premixed mass, defined as the mass of the molten material in low void zones (void fraction < 0.75). The jet diameter and velocity that comprise the flow rate were the primary factors to determine the premixed mass and the load. The water pool depth also showed a significant impact. The energy conversion ratio based on the enthalpy in the premixed mass was in a narrow range ~4%. Based on this observation, we proposed a simplified method for evaluation of the steam explosion load. The results showed fair agreement with JASMINE.

고정식 진동수주형 파력발전기에 관한 실험적 연구 (A Study for Fixed Type Wave Energy Conversion Device with Oscillating Water Column)

  • 김성근;박노식;박인규
    • 한국해양공학회지
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    • 제10권2호
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    • pp.136-145
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    • 1996
  • The theory is based on two thermodynamic equations for the air mass in the air column and bydrodynamic equation for the relation between the response of the air in the water column and the incident wave. The numerical model is experimented in a two dimensional water tank and the caisson model with sloped front wall is tested in the large towing tank.

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Living cationic polymerization of poly (isobutyl vinyl ether) and PVA derived therefrom

  • Mah, Soukil
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
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    • pp.1-2
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    • 2003
  • Some new synthetic routes for the preparation of poly (isobutyl vinyl ether) (P(IBVE)) having a controllable molar mass with narrow distribution via catalytic or photoinduced living cationic polymerization and their conversion to corresponding PVA have been developed. It was found that the combination of iodomethyl methyl ether (IMME)-zinc iodide is effective in the initiation of the catalytic and the various combinations of diphenyliodonium halides, well known photocationic initiators (DPIX) with zinc halides (ZnX$_2$) are also useful in photoinduced living cationic polymerization of isobutyl vinyl ether (IBVE). Polymerization both in the catalytic and photoinduced systems precede until the full consumption of the monomer and the rate of polymerization increases as the concentration of the catalyst or photoinitiator. The number average molar mass of the resulting polymer is proportional with % conversion, which is determined by the ratio of monomer consumed and the initial values of the catalyst or initiator. The living nature was also confirmed by subsequent monomer addition technique.

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동력학-전달 모델을 활용한 식품 폐기물 감량 해석 (Simulative Calculations of Food Waste Reduction Using Kineto-transport Models)

  • 조선주;김태욱;권성현;조대철
    • 한국환경과학회지
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    • 제30권6호
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    • pp.429-439
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    • 2021
  • Food waste is both an industrial and residential source of pollution, and there has been a great need for food waste reduction. As a preliminary step in this study, waste reduction is quantitatively modeled. This study presents two models based on kinetics: a simple kinetic model and a mass transport-shrinking model. In the simple kinetic model, the smaller is the reaction rate constant ratio k1, the lower the rate of conversion from the raw material to intermediate products. Accordingly, the total elapsed reaction time becomes shorter. In the mass transport-shrinking model, the smaller is the microbial decomposition resistance versus the liquid mass transfer resistance, the greater is the reduction rate of the radius of spherical waste particles. Results showed that the computed reduction of waste mass in the second model agreed reasonably with that obtained from a few experimantal trials of biodegradation, in which the microbial effect appeared to dominate. All calculations were performed using MATLAB 2020 on PC.

화강암 풍화토의 토량 변화율 추정을 위한 인공신경망 적용 (Application of Artificial Neural Network to the Estimation of Mass Conversion Rate in Weathered Granite Soils)

  • 김영수;정성관;임안식;김병탁
    • 한국지반공학회논문집
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    • 제17권2호
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    • pp.73-83
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    • 2001
  • 본 연구에서는 전국 4개 지구의 화강암 풍화토를 연구대상으로 현장 및 실내시험을 수행하고 토량 변화율을 노상과 노체에 대하여 결정하였다. 그리고, 본 연구에서는 인공 신경망 중 오류 역전파 학습 알고리즘을 도입하여 토량 변화율 C 값을 추정하고 신경망의 적용성에 대한 검증을 수행하였다. 화강암 풍화토에 대한 실내 및 현장시험 결과에서 얻어진 토량 변화율 C 값은 노상과 노체 구분 없이 최소 0.7에서 최대 1.2정도의 넓은 범위로 나타났다. 토지공사에서 제안하는 C값의 산정식과 본 연구 결과를 비교한 결과, 토지공사의 산정식에 의한 결과가 과대 평가될 가능성이 큰 것으로 나타났다. 비중, 자연 함수비, 자연상태의 습윤단위중량, #200 통과율 그리고 균등계수의 입력변수를 갖는 $I_{5-1}$$H_{30-30}$$O_1$의 신경망에서 다른 신경망 구조들보다 잦은 지역 최소점에 수렴하는 결과를 보였다. 본 연구에서 사용한 모든 신경망 구조에서 시험결과와 신경망 결과의 상관계수는 0.9이상으로 나타나 높은 상관성을 나타내었다. 특히, 인공 신경망에 의한 예측결과는 다양한 영향인자들 중에서 비중, 자연 함수비, 자연상태의 습윤단위중량 그리고 #200 통과율의 4개 변수만으로도 C값을 예측할 수 있었으며, 상관계수는 0.96으로 나타났다.다.

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상용 극저온 냉동기를 예냉기로 채택한 수소액화 시스템의 성능 해석 (Performance Analysis of a Hydrogen Liquefaction System using Commercial Cryogenic Refrigerators for Precooling)

  • 김승현;장호명;강병하
    • 한국수소및신에너지학회논문집
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    • 제9권2호
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    • pp.53-64
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    • 1998
  • Thermal analysis on a Linde-Hampson hydrogen liquefaction system using cryogenic refrigerators as precooling has been carried out. Three commercially available models of cryogenic refrigerators, such as CTI l020CP, CVI CGR009 and CVI CGR011, are considered in the performance analysis. The effect of ortho-para conversion process during hydrogen liquefaction is also studied in detail. The results obtained indicate that the optimal hydrogen mass flow rate and the optimal compressed pressure exist for the maximum hydrogen liquefaction rate. The optimal compressed pressure is increased in the range of 80 - 120 bar with an increase in the hydrogen mass flow rate. It is also found that better performance could be obtained with a cryogenic refrigerator, which produces high cooling capacity at precooling temperature in the range of 80 - 100 K.

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자동차 냉각수 폐열회수 열전발전 시스템의 성능에 관한 연구 (An Experimental Study on Thermoelectric Generator Performance for Waste Coolant Recovery Systems in Vehicles)

  • 이대웅
    • 설비공학논문집
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    • 제26권7호
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    • pp.329-334
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    • 2014
  • This study indicated the possibility of energy regeneration from waste coolant heat, by using thermoelectric generation integrated with heat pipe. The internal combustion engine rejects more than 60% wasteful energy to the atmosphere by heat. The thermoelectric generator has recently been studied, to convert the energy from engine waste heat into electricity. For coolant waste heat recovery, a thermoelectric generator was investigated, to find out the possibility of vehicular application. Performance characteristics were conducted with various test conditions of coolant temperature, coolant mass flow rate, air temperature, and air velocity, with the thermoelectric generator installed either horizontally or vertically. Experimental results show that the electric power and conversion efficiency increases according to the temperature difference between the hot and cold side of the thermoelectric generator, and the coolant flow rate of the hot side heat exchanger. Performance improvement can be expected by optimizing the heat pipe design.