• Title/Summary/Keyword: Mass conversion rate

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Analysis on Activation Energy Measurement and Application of Nuclear Equipment Non-metallic Materials (원전기기 비금속재료의 활성화에너지 측정 및 적용성 분석)

  • Bhang, Keug-Jin;Hong, Jun-Hee
    • Journal of Power System Engineering
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    • v.20 no.4
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    • pp.38-43
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    • 2016
  • Safety-related equipments of Nuclear Power Plants(NPP) have to perform environmental qualification test in accordance with IEEE-323 standards. However, non-metallic materials replace new one regularly instead of the test because they are considered as consumable parts. In this study, the seven kinds of non-metallic materials are selected and their activation energy was experimentally evaluated with uncertainty analysis by using thermogravimetric analyzer(TGA). In order to obtain activation energy of non-metallic materials, mass difference, temperature raising rate and conversion rate on the specimen are analyzed. It is postulated that the three experiment conditions are important to get a reliable activation energy. This postulate was experimentally confirmed using Arrhenius equation and Flynn-Wall-Ozawa analysis.

Mitigation of seismic responses of actual nuclear piping by a newly developed tuned mass damper device

  • Kwag, Shinyoung;Eem, Seunghyun;Kwak, Jinsung;Lee, Hwanho;Oh, Jinho;Koo, Gyeong-Hoi
    • Nuclear Engineering and Technology
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    • v.53 no.8
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    • pp.2728-2745
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    • 2021
  • The purpose of this study is to reduce seismic responses of an actual nuclear piping system using a tuned mass damper (TMD) device. A numerical piping model was developed and validated based on shaking table test results with actual nuclear piping. A TMD for nuclear piping was newly devised in this work. A TMD shape design suitable for nuclear piping systems was conducted, and its operating performance was verified after manufacturing. The response reduction performance of the developed TMD under earthquake loading on actual piping was investigated. Results confirmed that, on average, seismic response reduction rates of 34% in the maximum acceleration response, 41% in the root mean square acceleration response, and 57% in the spectral acceleration response were shown through the TMD application. This developed TMD operated successfully within the seismic response reduction rate of existing TMD optimum design values. Therefore, the developed TMD and dynamic interpretation help improve the nuclear piping's seismic performance.

Optimum Process Condition by Experimental Design Method for the Synthesis of Methylchlorosilanes(MCS) (실험계획법에 의한 메틸염화실란 합성의 최적공정조건)

  • Cho, Chul Kun;Han, Kee Do
    • Applied Chemistry for Engineering
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    • v.9 no.3
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    • pp.394-398
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    • 1998
  • An optimum synthetic condition was studied for the MCS used as a silicone monomer. The contact mixture was made from the four component catalyst system($CuCl/ZnCl_2/Sn/Cd$) and silicon particles. The contact mass was used for a series of experiments with methyl chloride, which were designed and done to explore the optimum condition for MCS synthesis by an experimental design method. The optimum temperature and MeCl flow rate, which were obtained using 50g contact mass at 60rpm and 1 atm, were in the range of $300-305^{\circ}C$ and of 70-80ccm. Also a continuous run was performed to confirm the conditions. The results showed that the average reaction rate and selectivity were 170(g-MCS/hr.kg-Si) and 0.05 respectively at 67% conversion of MeCl and 92% silicon utilization rate. Also the parameters of overall reaction rate equation and a total pressure were estimated on the basis of the results of the continuous run.

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Effects of Octacosanol Extracted from Rice Bran on the Laying Performance, Egg Quality and Blood Metabolites of Laying Hens

  • Peng, Kai;Long, Lei;Wang, Yuxi;Wang, Shunxi
    • Asian-Australasian Journal of Animal Sciences
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    • v.29 no.10
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    • pp.1458-1463
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    • 2016
  • A 42-d study with 384 Hy-line brown laying hens was conducted to assess the effects of dietary octacosanol supplementation on laying performance, egg quality and blood metabolites of laying hens. Hens were randomly allocated into 4 dietary groups of 8 cages each, which were fed basal diet supplemented with 0 (Control), 9 (OCT9), 18 (OCT18), and 27 (OCT27) mg/kg diet of octacosanol isolated from rice bran, respectively. The experiment was conducted in an environmental controlled house and hens were fed twice daily for ad libitum intake. Laying performance was determined over the 42-d period, and egg quality as well as blood metabolites were estimated on d 21 and d 42. Diets in OCT18 and OCT27 increased (p<0.05) laying rate, egg weight, egg mass, egg albumen height, Haugh unit and eggshell strength on d 42, but decreased (p<0.05) feed conversion rate and levels of total cholesterol, triglyceride and low density lipoprotein cholesterol in the serum as compared to those of Control. Feed intake, yolk color, yolk diameter, eggshell thickness and high density lipoprotein cholesterol were similar (p>0.05) among treatments. Results demonstrate that supplementing 18 to 27 mg/kg diet of rice bran octacosanol can improve laying rate and egg quality and reduce blood lipid of laying hens.

Optimization of Cell Concentration and Dilution Rate in Cell Recycled Ethanol Fermentation (세포재순환 에탄올 발효에서 세포농도와 희석률의 최적화)

  • 이재우;유영제
    • KSBB Journal
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    • v.7 no.4
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    • pp.258-264
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    • 1992
  • The rheological characteristics of the ethanol fermentation broth were pseudoplastic when the yeast concentration was above 150g/L. From the viewpoint of rheological properties, the cell concentration below 150g/L was recommended for ethanol fermentation. Since the cell floc was formed at the cell concentration of 100 g/L, yeast cells were not much plugged in the pores of the membrane. The cell concentration above 100g/L was desirable when considering the permeability of the membrane. Since ethanol productivity was the highest when the cell concentration was 130 g/L in cell recycled ethanol fermentation. The optimal dilution rate was determined at 1.3 h-1 at constant cell mass of 130g/L. At this dilution rate, the ethanol productivity and glucose conversion ratio ware 80 g/L$\cdot$h and 0.94, respectively.

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Can we estimate forest gross primary production from leaf lifespan? A test in a young Fagus crenata forest

  • Koyama, Kohei;Kikuzawa, Kihachiro
    • Journal of Ecology and Environment
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    • v.33 no.3
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    • pp.253-260
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    • 2010
  • It has been well established that leaf longevity is linked to the carbon economy of plants. We used this relationship to predict leaf lifetime carbon gains from leaf lifespan, and estimated the gross primary production (GPP) of a young deciduous forest of Japanese beech (Fagus crenata) located in central Japan. The light-saturated photosynthetic rates of the leaves were measured repeatedly during the growing season. We used the leaf lifespan to calculate the conversion coefficient from the light-saturated photosynthetic rate into the realized leaf lifetime carbon gain under field conditions. The leaf turnover rate was estimated using litter traps. GPP was estimated as the product of lifetime carbon gain per unit of leaf mass, and the annual leaf turnover rate. The GPP of the forest in 2007 was estimated to be $1.2{\times}10^3gCm^{-2}y^{-1}$, which was within the range of previously reported GPP values of beech forests in Japan, and was close to the GPP of a European beech forest, as estimated by eddy flux measurements.

A Study on Heat Storage System Using Calcined Dolomite - Numerical Analysis of Heat Transfer in Calcined Dolomite Hydration Pocked Bed - (소성Dolomite 수화물계의 축열시스템에 관한 연구 - 소성Dolomite 수화반응층의 전열해석 -)

  • Park, Young-Hae;Kim, Jong-Shik
    • Journal of the Korean Solar Energy Society
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    • v.22 no.1
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    • pp.9-21
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    • 2002
  • To develope chemical heat pump using available energy sources, solar heat and other kinds of waste thermal energy, we have studied the heat transfer rate in cylindrical bed reactor packed with calcined Dolomite. Two dimensional (radial and circumferential) Partial differential equations, concerning heat and mass transfer in packed bed of calcined Dolomite, are solved numerically to describe the characteristics of the reaction of calcined Dolomite and heat transfer. The results obtained by numerical analysis about two dimensional profiles of temperature and conversion of reactant in the packed bed reactor and the amount of exothermic heat released from the reactor are follows. It was found that all of calcined Dolomite packed bed kept the reaction temperature of about 750K throughout the entire part of the bed, immediately after the steam was introduced exothermic reaction of hydration was proceeded from the packed bed inpu to output and from wall side to center. The rate of thermochemical reaction depends on the temperature and concentration and it is also governed by the boundary conditions and heat transfer rate in the particle packed bed.

Preliminary Study on Chlorination Reaction of Lithium Carbonate for Carbon-Anode-Based Oxide Reduction Applications

  • Jeon, Min Ku;Kim, Sung-Wook;Choi, Eun-Young
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.2
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    • pp.225-231
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    • 2021
  • The reaction between Li2CO3 and Cl2 was investigated to verify its occurrence during a carbon-anode-based oxide reduction (OR) process. The reaction temperature was identified as a key factor that determines the reaction rate and maximum conversion ratio. It was found that the reaction should be conducted at or above 500℃ to convert more than 90% of the Li2CO3 to LiCl. Experiments conducted at various total flow rate (Q) / initial sample weight (Wi) ratios revealed that the reaction rate was controlled by the Cl2 mass transfer under the experimental conditions adopted in this work. A linear increase in the progress of reaction with an increase in Cl2 partial pressure (pCl2) was observed in the pCl2 region of 2.03-10.1 kPa for a constant Q of 100 mL·min-1 and Wi of 1.00 g. The results of this study indicate that the reaction between Li2CO3 and Cl2 is fast at 650℃ and the reaction is feasible during the OR process.

Methane-Steam Reforming Simulation for a High Temperature Solar Chemical Reactor (고온 태양열 화학 반응기에서의 메탄-수증기 개질반응 시뮬레이션)

  • Ko, Jo-Han;Seo, Tae-Beom
    • Journal of the Korean Solar Energy Society
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    • v.29 no.1
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    • pp.44-49
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    • 2009
  • Steam reforming of methane in the high temperature solar chemical reactor bas advantage in its heating method. Using concentrated solar energy as a heating source of the reforming reaction can reduce the $CO_2$ emission by 20% compared to hydrocarbon fuel. In this paper, the simulation result of methane-steam reforming on a high temperature solar chemical reactor(SCR) using Fluent 6.3.26 is presented. The high temperature SCR is designed for the Inha Dish-1, a Dish type solar concentrator installed in Songdo city. Basic SCR performance factors are referred to the former researches of the same laboratory. Inside the SCR porous metal is used for a receiver/reactor. The porous metal is carved like a dome shape on the incident side to increase the heat transfer. Also, ring-disc set of baffle is inserted in the porous metal region to increase the path length. Numerical and physical models are also used from the former researches. Methane and steam is mixed with the same mole fraction and injected into the SCR. The simulation is performed for a various inlet mass flow rate of the methane-steam mixture gas. The result shows that the average reactor temperature and the conversion rate change appreciably by the inlet mass flow rate of 0.0005 kg/s.

A numerical analysis of the degradation of VOC in the photocatalytic microreactors with different inner geometries (광촉매 마이크로 반응기의 내부 형상에 따른 VOC 분해특성에 관한 수치해석적 연구)

  • Yong, Jung-Kwon;Kim, Chang-Nyung;Youm, Min-Qou
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2896-2900
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    • 2007
  • A numerical analysis was carried out to investigate the degradation of Volatile Organic Compounds (VOC) in photocatalytic microreactors with different inner geometries. Two different cases of microreactor were considered, namely, one microreactor has bump on the channel and the other has no bump on the channel. The removal efficiency of VOC has been calculated by the Langmuir-Hinshelwood reaction rate equation that was obtained from the experimental results. From the numerical calculations, it was observed that the conversion ratio of VOC for the microchannel with bump is about 4.5% greater than the microchannel without bump. And the mass transfer characteristics in the microreactor are also shown in numerical results. These results can be used effectively for the photocatalytic numerical analysis.

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