• 제목/요약/키워드: Mass bias

검색결과 169건 처리시간 0.033초

Isotope Measurement of Uranium at Ultratrace Levels Using Multicollector Inductively Coupled Plasma Mass Spectrometry

  • Oh, Seong-Y.;Lee, Seon-A.;Park, Jong-Ho;Lee, Myung-Ho;Song, Kyu-Seok
    • Mass Spectrometry Letters
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    • 제3권2호
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    • pp.54-57
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    • 2012
  • Mass spectrometric analysis was carried out using multicollector inductively coupled plasma mass spectrometry (MC-ICP-MS) for the precise and accurate determination of the isotope ratios of ultratrace levels of uranium dissolved in 3% $HNO_3$. We used the certified reference material (CRM) 112-A at a trace level of 100 pg/mL for the uranium isotopic measurement. Multiple collectors were utilized for the simultaneous measurement of uranium isotopes to reduce the signal uncertainty due to variations in the ion beam intensity over time. Mass bias correction was applied to the measured U isotopes to improve the precision and accuracy. Furthermore, elemental standard solution with certified values of platinum, iridium, gold, and thallium dissolved in 3% $HNO_3$ were analyzed to investigate the formation rates of the polyatomic ions of $Ir^{40}$ $Ar^+$, $Pt^{40}$ $Ar^+$, $Tl^{40}$ $Ar^+$, $Au^{40}$ $Ar^+$ for the concentration range of 50-400 pg/mL. Those polyatomic ions have mass-to-charge ratios in the 230-245 m/z region that it would contribute to the increase of background intensity of uranium, thorium, plutonium, and americium isotopes. The effect of the polyatomic ion interference on uranium isotope measurement has been estimated.

High redshift clusters of galaxies

  • Kim, Jae-Woo;Im, Myungshin;Lee, Seong-Kook;Jeon, Yiseul;Hyun, Minhee
    • 천문학회보
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    • 제38권2호
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    • pp.69.2-69.2
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    • 2013
  • A galaxy cluster is an important laboratory to study the large scale structure in the Universe and the galaxy evolution. In order to identify candidate galaxy clusters at z~1, we have used deep and wide optical-NIR datasets based on IMS, UKIDSS DXS and CFHTLS wide covering ${\sim}20deg^2$ in the SA22 field. We measure the angular two-point correlation function of the candidate clusters and investigate the star formation activity of the member galaxies. Based on bias factor and halo mass function, candidate clusters have the average halo mass of > $10^{14}h^{-1}M_{\odot}$. At z~1, the star formation rate of cluster galaxies is similar to that of field galaxies, which indicates the environmental quenching is not so significant at z~1 as the local Universe.

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THE GALAXY-BLACK HOLE CONNECTION IN THE LOCAL UNIVERSE

  • Schawinski, Kevin;Fellow, Einstein
    • 천문학논총
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    • 제25권3호
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    • pp.77-82
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    • 2010
  • Recent results from large surveys of the local universe show that the galaxy-black hole connection is linked to host morphology at a fundamental level and that there are two fundamentally different modes of black hole growth. The fraction of early-type galaxies with actively growing black holes, and therefore the AGN duty cycle, declines significantly with increasing black hole mass. Late-type galaxies exhibit the opposite trend: the fraction of actively growing black holes increases with black hole mass. Issues of AGN selection bias and prospects for near-future efforts with high redshift data are discussed.

Periodontal health status, oral microbiome, white-spot lesions and oral health related to quality of life-clear aligners versus fixed appliances: A systematic review, meta-analysis and meta-regression

  • Ana Sandra Llera-Romero;Milagros Adobes-Martin;Jose Enrique Iranzo-Cortes;Jose Maria Montiel-Company;Daniele Garcovich
    • 대한치과교정학회지
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    • 제53권6호
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    • pp.374-392
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    • 2023
  • Objective: Assess and evaluate the different indicators of oral health-related quality of life (OHRQoL) among patients treated with clear aligners (CAs) versus those treated with conventional fixed orthodontics (FAs). Methods: An electronic search was performed on the database is Web of Science, Scopus, and Embase databases. Randomized and non-randomized control trials, cross-sectional, prospective cohort and retrospective trials were included. Quality was assessed with risk of bias tool and risk of bias in non-randomised studies. Meta-analyses were performed with random effects models, estimating the standardized and non-standardized mean differences, odds ratio and risk ratio as the measure of effect. The effect on time was determined using a meta-regression model. Results: Thirty one articles were included in the qualitative synthesis and 17 in the meta-analysis. CAs had a significantly lower negative impact on QoL, with an "important" effect size, while the influence of time was not significant. Periodontal indicators plaque index (PI), gingival index (GI), probing depth (PD), and bleeding on probing show significantly better values in patients treated with CAs, with moderate to large effect sizes. PI and GI have a significant tendency to improve over time. In microbiological indicators, CAs present a lower biofilm mass without differences in the percentage of patients with high counts of Streptococcus mutans and Lactobacilli bacteria. The risk of white spot lesion onset is ten times lower in carriers of CAs. Conclusions: Patients wearing CAs show better periodontal indicators, less risk of white spot development, less biofilm mass and a better QoL than patients with FAs.

Accurate Measurement of Arsenic in Laver by Gravimetric Standard Addition Method Combined with High Resolution Inductively Coupled Plasma Mass Spectrometry

  • Lee, Kyoung-Seok;Kim, Hyeon-Ji;Yim, Yong-Hyeon;Kim, Jeongkwon;Hwang, Euijin
    • Mass Spectrometry Letters
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    • 제5권2호
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    • pp.57-61
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    • 2014
  • A gravimetric standard addition method combined with internal standard calibration has been successfully developed for the accurate analysis of total arsenic in a laver candidate reference material. A model equation for the gravimetric standard addition approach using an internal standard was derived to determine arsenic content in samples. Handlings of samples, As standard and internal standard were carried out gravimetrically to avoid larger uncertainty and variability involved in the volumetric preparation. Germanium was selected as the internal standard because of its close mass to the arsenic to minimize mass-dependent bias in mass spectrometer. The ion signal ratios of $^{75}As^+$ to $^{72}Ge^+$ (or $^{73}Ge^+$) were measured in high resolution mode ($R{\geq}10,000$) to separate potential isobaric interferences by high resolution ICP/MS. For method validation, the developed method was applied to the analysis of arsenic content in the NMIJ 7402-a codfish certified reference material (CRM) and the result was $37.07mg{\cdot}kg^{-1}{\pm}0.45mg{\cdot}kg^{-1}$ which is in good agreement with the certified value, $36.7mg{\cdot}kg^{-1}{\pm}1.8mg{\cdot}kg^{-1}$. Finally, the certified value of the total arsenic in the candidate laver CRM was determined to be $47.15mg{\cdot}kg^{-1}{\pm}1.32mg{\cdot}kg^{-1}$ (k = 2.8 for 95% confidence level) which is an excellent result for arsenic measurement with only 2.8 % of relative expanded uncertainty.

새만금호 3차원 수리.수질모델(EFDC)의 수치격자 민감도 분석 (A Sensitivity Analysis on Numerical Grid Size of a Three-Dimensional Hydrodynamic and Water Quality Model (EFDC) for the Saemangeum Reservoir)

  • 전지혜;정세웅
    • 한국물환경학회지
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    • 제28권1호
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    • pp.26-37
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    • 2012
  • Multi-dimensional hydrodynamic and water quality models are widely used to simulate the physical and biogeochemical processes in the surface water systems such as reservoirs and estuaries. Most of the models have adopted the Eulerian grid modeling framework, mainly because it can reasonably simulate physical dynamics and chemical species concentrations throughout the entire model domain. Determining the optimum grid cell size is important when using the Eulerian grid-based three-dimensional water quality models because the characteristics of species are assumed uniform in each of the grid cells and chemical species are represented by concentration (mass per volume). The objective of this study was to examine the effect of grid-size of a three dimensional hydrodynamic and water quality model (EFDC) on hydrodynamics and mass transport in the Saemangeum Reservoir. Three grid resolutions, respectively representing coarse (CG), medium (MG), and fine (FG) grid cell sizes, were used for a sensitivity analysis. The simulation results of numerical tracer showed that the grid resolution affects on the flow path, mass transport, and mixing zone of upstream inflow, and results in a bias of temporal and spatial distribution of the tracer. With the CG, in particular, the model overestimates diffusion in the mixing zone, and fails to identify the gradient of concentrations between the inflow and the ambient water.

Determination of Clotiazepam in the Plasma Using Gas Chromatography/Mass Spectrometry with an Ion-Trap Detector and its Application to Pharmacokinetics in Healthy Volunteers

  • Kwon, Oh-Seung;Kim, Seung-Yong;Chung, Youn-Bok
    • Journal of Pharmaceutical Investigation
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    • 제36권2호
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    • pp.123-129
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    • 2006
  • A method determining the plasma concentration of clotiazepam was developed by using gas chromatography/mass spectrometry with an ion-trap detector and was validated for applying pharmacokinetics to human volunteers orally taken 5 mg dose of clotiazepam. The detection limit was 1 ng/ml and the limit of quantitation was 5 ng/mt. Intraday reproducibility and accuracy bias % were less than 8.2 and 10.2% with inter-day variations for those being within 7.0 and 13.8%, respectively. The recovery of clotiazepam was higher than 87%. The principal pharmacokinetic parameters were determined from the plasma concentration-time plot by non-compartmental or two-compartmental analysis. In non-compartmental analysis, the elimination half-life of 10.4 hr and the area under the curve of 651.3 ng hr/ml were determined, and the maximal concentration (158.6 ng/ml) in the plasma was obtained at 0.56 hr post-dose. The developed method can be appropriate to apply pharmacokinetics and bioequivalence of clotiazepam.

Modeling the tidal connection between in and around galaxy clusters

  • 송현미;이정훈
    • 천문학회보
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    • 제36권2호
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    • pp.53.1-53.1
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    • 2011
  • We analyze the halo and galaxy catalogs from the Millennium simulations at redshifts z=0, 0.5, 1 to determine the alignment profiles of cluster galaxies in terms of the matter density correlation coefficient and discuss a cosmological implication our result has for breaking parameter degeneracies. For each selected cluster, we measure the alignment between the major axes of the pseudo inertia tensors from all satellites within cluster's virial radius and from only those satellites within some smaller radius. Then we average the measured values over the similar-mass sample to determine the cluster galaxy alignment profile as a function of top-hat scale difference at each redshift. It is shown that the alignment profile of cluster galaxies is well approximated by a power-law of the nonlinear density correlation coefficient that is independent of the power spectrum normalization and bias factor. The alignment profile of cluster galaxies is found to have higher amplitude and lower power-law index when averaged over the larger-mass sample and to have rather weak redshift-dependence. This result is consistent with the picture that the satellite galaxies retain the memory of the external tidal fields right after merging and infalling into the clusters but they gradually lose the initial alignment tendency as the cluster's relaxation proceeds. Demonstrating that the nonlinear density correlation coefficient varies sensitively with the density parameter and neutrino mass fraction, we discuss a potential power of the cluster galaxy alignment profile as an independent probe of cosmology.

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Cosmological Tests using Redshift Space Clustering in BOSS DR11

  • Song, Yong-Seon;Sabiu, Cristiano G.;Okumura, Teppei;Oh, Minji;Linder, Eric V.
    • 천문학회보
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    • 제40권1호
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    • pp.43.3-44
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    • 2015
  • We analyze the clustering of large scale structure in the Universe in a model independent method, accounting for anisotropic effects along and transverse to the line of sight. A large sample of 690,000 galaxies from The Baryon Oscillation Spectroscopy Survey Data Release 11 are used to determine the Hubble expansion H, angular distance D_A, and growth rate GT at an effective redshift of z=0.57. After careful bias and convergence studies of the effects from small scale clustering, we find that cutting transverse separations below 40 Mpc/h delivers robust results while smaller scale data leads to a bias due to unmodelled nonlinear and velocity effects. The converged results are in agreement with concordance LCDM cosmology, general relativity, and minimal neutrino mass, all within the $68{\backslash}%$ confidence level. We also present results separately for the northern and southern hemisphere sky, finding a slight tension in the growth rate -- potentially a signature of anisotropic stress, or just covariance with small scale velocities -- but within $68{\backslash}%$ CL.

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Wafer Level Vacuum Packaged Out-of-Plane and In-Plane Differential Resonant Silicon Accelerometers for Navigational Applications

  • Kim, Illh-Wan;Seok, Seon-Ho;Kim, Hyeon-Cheol;Kang, Moon-Koo;Chun, Kuk-Jin
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제5권1호
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    • pp.58-66
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    • 2005
  • Inertial-grade vertical-type and lateral-type differential resonant accelerometers (DRXLs) are designed, fabricated using one process and tested for navigational applications. The accelerometers consist of an out-of-plane (for z-axis) accelerometer and in-plane (for x, y-axes) accelerometers. The sensing principle of the accelerometer is based on gap-sensitive electrostatic stiffness changing effect. It says that the natural frequency of the accelerometer can be changed according to an electrostatic force on the proof mass of the accelerometer. The out-of-plane resonant accelerometer shows bias stability of $2.5{\mu}g$, sensitivity of 70 Hz/g and bandwidth of 100 Hz at resonant frequency of 12 kHz. The in-plane resonant accelerometer shows bias stability of $5.2{\mu}g$, sensitivity of 128 Hz/g and bandwidth of 110 Hz at resonant frequency of 23.4 kHz. The measured performances of two accelerometers are suitable for an application of inertial navigation.