• Title/Summary/Keyword: Mass Transport

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Xenon in molten salt reactors: The effects of solubility, circulating particulate, ionization, and the sensitivity of the circulating void fraction

  • Price, Terry J.;Chvala, Ondrej;Taylor, Zack
    • Nuclear Engineering and Technology
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    • v.52 no.6
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    • pp.1131-1136
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    • 2020
  • Xenon behaves differently in molten salt reactors (MSRs) compared to solid fuel reactors. This behavior needs exploring due to the large reactivity effect of the 135Xe isotope, given the current interest in MSR power plant development for commercial deployment. This paper focuses on select topics in xenon transport, reviews relevant past works, and proposes specific research questions to advance the state of the art in each of the focus areas. Specifically, the paper discusses the issue of xenon solubility in MSRs, the behavior of particulates circulating in MSR fuel salt and its influence on the xenon transport, the possibility of ionization of xenon atoms which changes its effective size and thus affects its mass transport, and finally the issue of circulating void fraction and how it is measured. This work presents specific recommendations for MSR designers to research the limits of Henry's law validity, circulating particulate scrubbers, validity of mass transport coefficients in high radiation fields, and the effects of pump speed on circulating void fraction.

An Experiment on Evaporating Heat Transfer of HCFC-22 for Transport Refrigeration System (HCFC-22 냉매사용 차량냉동시스템의 증발 열전달에 관한 실험)

  • Oh, M.D.;Kim, S.C.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.6 no.2
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    • pp.166-174
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    • 1994
  • An experimental study has been performed to identify the evaporation characteristics of HCFC-22 for transport refrigeration system. Heat transfer coefficients were measured in a horizontal, smooth evaporating tube with an inner diameter of 10.7mm and a length of 2.8m. The refrigerant was heated electrically by surface-wrapped heaters and uniform power is applied along the tube. The entire tube was divided into 7 sections. Surface temperatures of tube and refrigerant temperature in each test section were measured. Pressure drops in each section and the inlet pressure were also measured. The mass flowrate of the refrigerant was controlled and measured. A single tube evaporation test was conducted for different ranges of mass flux of refrigerant, heat flux of evaporator and condensing temperature of transport refrigeration system. The evaporation heat transfer coefficients of HCFC-22 were compared with predictions from the well known Chen's correlations. Averaged heat transfer coefficients in this experiment range from $2kW/m^2/^{\circ}C$ to $3kW/m^2/^{\circ}C$. Most of the experimental results differ from the predicted ones by less than ${\pm}30%$.

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Long-term Stability of Perovskite Solar Cells with Inhibiting Mass Transport with Buffer Layers (물질이동 억제 버퍼층 형성을 통한 페로브스카이트 태양전지 장기 안정성 확보)

  • Bae, Mi-Seon;Jeong, Min Ji;Chang, Hyo Sik;Yang, Tae-Youl
    • Journal of the Microelectronics and Packaging Society
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    • v.28 no.3
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    • pp.17-24
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    • 2021
  • Perovskite solar cells (PSCs) can be fabricated through solution process economically with variable bandgap that is controlled by composition of precursor solution. Tandem cells in which PSCs combined with silicon solar cells have potential to reach high power conversion efficiency over 30%, however, lack of long-term stability of PSCs is an obstacle to commercialization. Degradation of PSCs is mainly attributed to the mass transport of halide and metal electrode materials. In order to ensure the long-term stability, the mass transport should be inhibited. In this study, we confirmed degradation behaviors due to the mass transport in PSCs and designed buffer layers with LiF and/or SnO2 to improve the long-term stability by suppressing the mass transport. Under high-temperature storage test at 85℃, PSCs without the buffer layers were degraded by forming PbI2, AgI, and the delta phase of the perovskite material, while PSCs with the buffer layers showed improved stability with keeping the original phase of the perovskite. When the LiF buffer and encapsulation were applied to PSCs, superior long-term stability on 85℃-85% RH dump heat test was achieved; efficiency drop was not observed after 200 h. It was also confirmed that 90.6% of the initial efficiency was maintained after 200 hours of maximum power tracking test under AM 1.5G-1SUN illumination. Here, we have demonstrated that the buffer layer is essential to achieve long-term stability of PSCs.

Design and Performance Evaluation of the Precision Pressure Control System for the High Vacuum Transport Module (고진공 운송계에서의 정밀 압력제어장치의 설게 및 성능시험)

  • Jang, W.I.;Jang, K.H.;Lee, J.H.
    • Journal of the Korean Society for Precision Engineering
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    • v.12 no.7
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    • pp.92-98
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    • 1995
  • In the cluster tool, it is necessary to precisely control the vacuum pressure for the wafer transportation between transport module and cassette or process modules with the range of 1*10$^{-4}$ to 5*10$^{-5}$ torr. So we have designed the pressure control system for the transport module of the cluster tool and have evaluated its performance. Digital PID is utilized with the weighted sum of both three previous errors and one current error. The feedback signal is put into the nitrogen mass flow controller using the transport module controller. This pressure control system can prevent the transport module from the particle generation and backstreaming of hazardous process gases of the process chamber.

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Dynamic Model of a Passive Air-Breathing Direct Methanol Fuel Cell (수동급기 직접 메탄올 연료전지의 동적 모델)

  • Ha, Seung-Bum;Chang, Ikw-Hang;Cha, Suk-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.33-36
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    • 2008
  • The transient behavior of a passive air breathing direct methanol fuel cell (DMFC) operated on vapor-feeding mode is studied in this paper. It generally takes 30 minutes after starting for the cell response to come to its steady-state and the response is sometimes unstable. A mathematical dynamic one-dimensional model for simulating transient response of the DMFC is presented. In this model a DMFC is decomposed into its subsystems using lumped model and divided into five layers, namely the anodic diffusion layer, the anodic catalyst layer, the proton exchange membrane (PEM), the cathodic catalyst layer and the cathodic diffusion layer. All layers are considered to have finite thickness, and within every one of them a set of differential-algebraic governing equations are given to represent multi-components mass balance, such as methanol, water, oxygen and carbon dioxide, charge balance, the electrochemical reaction and mass transport phenomena. A one-dimensional, isothermal and mass transport model is developed that captures the coupling between water generation and transport, oxygen consumption and natural convection. The single cell is supplied by pure methanol vapor from a methanol reservoir at the anode, and the oxygen is supplied via natural air-breathing at the cathode. The water is not supplied from external source because the cell uses the water created at the cathode using water back diffusion through nafion membrane. As a result of simulation strong effects of water transport were found out. The model analysis provides several conclusions. The performance drop after peak point is caused by insufficiency of water at the anode. The excess water at the cathode makes performance recovery impossible. The undesired crossover of the reactant methanol through the PEM causes overpotential at the cathode and limits the feeding methanol concentration.

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Numerical and statistical analysis of Newtonian/non-Newtonian traits of MoS2-C2H6O2 nanofluids with variable fluid properties

  • Manoj C Kumar;Jasmine A Benazir
    • Advances in nano research
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    • v.16 no.4
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    • pp.341-352
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    • 2024
  • This study investigates the heat and mass transfer characteristics of a MoS2 nanoparticle suspension in ethylene glycol over a porous stretching sheet. MoS2 nanoparticles are known for their exceptional thermal and chemical stability which makes it convenient for enhancing the energy and mass transport properties of base fluids. Ethylene glycol, a common coolant in various industrial applications is utilized as the suspending medium due to its superior heat transfer properties. The effects of variable thermal conductivity, variable mass diffusivity, thermal radiation and thermophoresis which are crucial parameters in affecting the transport phenomena of nanofluids are taken into consideration. The governing partial differential equations representing the conservation of momentum, energy, and concentration are reduced to a set of nonlinear ordinary differential equations using appropriate similarity transformations. R software and MATLAB-bvp5c are used to compute the solutions. The impact of key parameters, including the nanoparticle volume fraction, magnetic field, Prandtl number, and thermophoresis parameter on the flow, heat and mass transfer rates is systematically examined. The study reveals that the presence of MoS2 nanoparticles curbs the friction between the fluid and the solid boundary. Moreover, the variable thermal conductivity controls the rate of heat transfer and variable mass diffusivity regulates the rate of mass transfer. The numerical and statistical results computed are mutually justified via tables. The results obtained from this investigation provide valuable insights into the design and optimization of systems involving nanofluid-based heat and mass transfer processes, such as solar collectors, chemical reactors, and heat exchangers. Furthermore, the findings contribute to a deeper understanding of stretching sheet systems, such as in manufacturing processes involving continuous casting or polymer film production. The incorporation of MoS2-C2H6O2 nanofluids can potentially optimize temperature distribution and fluid dynamics.

A Study on Mixture Preparation in a Port Fuel Injection Sl Engine During Engine Starting (흡기포트 분사방식의 가솔린 엔진에서 냉시동시 혼합기 형성에 관한 연구)

  • 황승환;이종화;민경덕
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.4
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    • pp.15-22
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    • 2002
  • As the emission regulations on the automobiles have been increasingly stringent, precise control of air/fuel ration is one of the most important issues on the gasoline engines. Although many researches have been carried out to identify the fuel transport phenomena in the port fuel injection gasolines, mixture preparation in the cylinder has not been fully understood due to the complexity of fuel film behavior, In this paper, the mixture preparation during cold engine start is studied by using a Fast Response Flame ionization Detector.(FRFID) In order to estimate the transportation of injected fuel from the intake port into cylinder, the wall wetting fuel model was used. The two coefficient($\alpha$,$\beta$) of the wall-wetting fuel model was determined from the measured fuel mass that was inducted into the cylinder at the first cycle after injection cut-in. $\alpha$( ratio of directly inducted fuel mass into cylinder from injected fuel mass) and $\beta$ (ratio of indirectly inducted fuel mass into cylinder from wall wetted fuel film on the wall) was increased with increasing cooling water temperature. To reduce a air/fuel ratio fluctuation during cold engine start, the appropriate fuel injection rate was obtained from the wall wetting fuel model. Result of air/fuel ratio control, air/fuel excursion was reduced.

The Importance of Dry Deposition : Dry Deposition Fluxes of Heavy Metals In Seoul, Korea During Yellow-Sand Events

  • Yi, Seung-Muk
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2003.06a
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    • pp.76-85
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    • 2003
  • Mass and elemental dry deposition fluxes and ambient particle size distributions were measured using dry deposition plates and a cascade impactor, from March to November 1998 in Seoul, Korea. During the spring sampling period several yellow sand events characterized by long range transport from China and Mongolia impacted the area. During these events the mass fluxes were statistically the same as during springtime non-yellow-sand events. However, most elemental fluxes were higher. In general, the flux ratios of both crustal (Al, Ca, Mn) and anthropogenic elements (Ni, Pb) to total mass measured during the daytime yellow-sand events were substantially higher than those measured in spring daytime during non-yellow-sand time periods. During all seasons the average measured daytime fluxes were about two times higher than at nighttime. The flux of primarily anthropogenic metals (Cu, Ni, Pb, Zn) and Mn was on average one to two orders of magnitude lower than the flux of the crustal metals Al and Ca. As is typically found two modes, fine (0.1∼l.0 $\mu\textrm{m}$) and coarse (1.0∼10.0 $\mu\textrm{m}$) were present in the measured size distributions (<10 $\mu\textrm{m}$). The particles in the coarse mode constitute a major portion of the measured mass size distribution during the yellow-sand events possibly due to the long-range transport of those particles from China.

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