• Title/Summary/Keyword: Mass Properties

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Development of Surface Coating Technology fey Metallic Bipolar Plate in PEMFC : I. Study on Surface and Corrosion Properties (PEMFCB금속분리판 코팅 기술 개발 : I. 표면 및 부식 특성 평가)

  • Chung, Kyeong-Woo;Kim, Se-Yung;Yang, Yoo-Chang;Ahn, Seung-Gyun;Jeon, Yoo-Taek;Na, Sang-Mook
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.348-351
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    • 2006
  • Bipolar plate, which forms about 50% of the stack cost, is an important core part with polymer electrolyte membrane in PEMFC. Bipolar plates have been commonly fabricated from graphite meterial having high electrical conductivity and corrosion resistance. Lately, many researchers have concentrated their efforts on the development of metallic bipolar plate and stainless steel has been considered as a potential material for metallic bipolar plate because of its high strength, chemical stability, low gas permeability and applicability to mass production. However, it has been reported that its inadequate corrosion behavior under PEMFC environment lead to a deterioration of membrane by dissolved metal ions and an increase in contact resistance by the growth of passive film therefore, its corrosion resistance as well as contact resistance must be improved for bipolar plate application. In this work, several types of coating were applied to 316L and their electrical conductivity and corrosion resistance were evaluated In the simulated PEMFC environment. Application of coating gave rise to low interfacial contact resistances below $19m{\Omega}cm^2$ under the compress force of $150N/cm^2$. It also made the corrosion potential to shift in the posit ive direct ion by 0.3V or above and decreased the corrosion current from ca. $9{\mu}A/cm^2$ to ca. $0.5{\mu}A/cm^2$ in the mixed solution of $0.1N\;N_2SO_4$ and 2ppm HF A coat ing layer under potentiostatic control of 0.6V and $0.75V_{SCE}$ for 500 hours or longer showed some instabilities, however, no significant change in coat Ing layer were observed from Impedance data. In addition, the corrosion current maintained less than $1{\mu}A/cm^2$ for most of time for potentiostatic tests. It indicates that high electrical conductivity and corrosion resistance can be obtained by application of coatings in the present work.

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Studies on the Aging Characteristics in Different Parts of Beeswax-treated Duplicates during Humidified Artificial Aging (습식 인공열화 시 밀랍본 복제품의 제책 부위별 열화특성)

  • Choi, Kyoung-Hwa;Cho, Jung Hye;Kang, Yeong Seok;Yang, Eun Jung;Jeong, Hye Young
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.5
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    • pp.72-79
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    • 2012
  • In this study, to understand the aging factor and mechanism in different partitions of the beeswax-treated volumes, the duplicated beeswax-treated volume was artificially aged at $80^{\circ}C$ of temperature and 65% of relative humidity and then a physical and optical properties of an aged volumes was analyzed. Also, the degraded components of the beeswax samples isolated from different partitions of aged volumes was measured using a gas chromatography/mass spectroscopy (GC/MS). In results, the surface of beeswax-treated volume which is primarily affected by a main aging factors such as light, oxygen, moisture was more deteriorated than the inside of that volume. However, unlike inside of the book volume which was made from paper, the inside of beeswax-treated volume wax was also considerably deteriorated. The inside of the beeswax-treated volume is largely unaffected by the oxygen and humidity during aging due to the water repellency and the air permeation resistance of beeswax. Therefore, it is confirmed that aging factors and mechanisms in the inside of the volume are different from thats of the outside of the volume. This fact was also verified by the results of GC/MS analysis of an beeswax samples which was sampled from different partitions of aged volumes. As result as GC/MS analysis of the beeswax extracted from the outside of the aged volume, the low molecular compounds with a carbon length of $C_9-C_{20}$ (fatty acid, etc) were increased and the compounds with a carbon length of above $C_{34}$ (ester, etc) were also increased. But the compounds with a chain length of $C_{21}-C_{36}$ (hydrocarbon, alcohol, etc) were decreased. In case of the aged beeswax of inside, the low molecular compounds with a carbon length of $C_9-C_{20}$ (fatty acid, etc) and the compounds with a chain length of $C_{21}-C_{36}$ (hydrocarbon, alcohol, etc) were increased. While, the compounds with a carbon length of above $C_{34}$ (ester, etc) were decreased.

Antifungal Activity of Lactobacillus plantarum Isolated from Kimchi (김치로부터 항진균 활성 Lactobacillus plantarum의 분리 및 특성 규명)

  • Yang, Eun-Ju;Chang, Hae-Choon
    • Microbiology and Biotechnology Letters
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    • v.36 no.4
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    • pp.276-284
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    • 2008
  • A lactic acid bacterium having antifungal activity was isolated from kimchi. It was identified as Lactobacillus plantarum based on its morphological and biochemical properties, and 16S rRNA sequence, and designated as Lb. plantarum AF1. This isolate inhibited the growth of Aspergillus flavus ATCC 22546, A. fumigatus ATCC 96918, A. petrakii PF-1, A. ochraceus PF-2, A. nidulans PF-3, Epicoccum nigrum KF-1, and Cladosporium gossypiicola KF-2 under a dual culture overlay assay. Also, the antimicrobial activity was found to be active against various species of Gram-positive and Gram-negative bacteria. The antifungal activity was found to be stable after heat ($121^{\circ}C$, 15 min) and proteolytic enzyme treatment, but it was unstable over pH 5.0. The antifungal compound(s) was estimated to have a low molecular mass (below 3,000 Da).

Binding Profiles of Oxomemazine to the Muscarinic Receptor Subtypes (Oxomemazine의 Muscarinic Receptor Subtypes에 대한 결합성질)

  • Lee, Shin-Woong;Kim, Jeung-Gu
    • The Korean Journal of Pharmacology
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    • v.30 no.1
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    • pp.49-57
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    • 1994
  • The binding properties of oxomemazine to muscarinic receptors using the ability of oxomemazine to inhibit $[^3H]QNB$ binding in membrane fractions of rat cerebrum and guinea pig ventricle and ileum were investigated. $[^3H]QNB$ bound to a single class of muscarinic receptors with a dissociation constant of approximately 60 pM in three tissue preparations. Pirenzepine and oxomemazine inhibited $[^3H]QNB$ binding in cerebrum with a Hill coefficient lower than unity, and the inhibition data were best described by a two-site model. The relative densities of the high $(M_1)\;and\;low\;(M_2)$ affinity sites for pirenzepine were 60 and 40%, with corresponding Ki values of 16 and 431 nM, and those $(O_H\;and\;O_L)$ for oxomemazine 40 and 60%, with corresponding Ki values of 80 and 1350 nM. However, the inhibition data of both drugs vs $[^3H]QNB$ in ventricle and ileum appeared to obey the law of mass-action (Hill coefficient close to 1). The apparent Ki values of pirenzepine were 850 and 250 nM, and those of oxomemazine 1460 and 570 nM in ventricle and ileum, respectively. Thus, oxomemazine like pirenzepine has high affinity for cerebrum, moderate affinity for ileum and low affinity for ventricle. These results suggest that oxomemazine could recognize the muscarinic receptor subtypes with a high affinity for the $M_1$ sites.

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[ HCO+ ]CLOUDS IN THE SGR B2 REGION (SGR B2 지역에 있는 HCO+ 분자운의 특성 연구)

  • Minh Y. C.
    • Journal of Astronomy and Space Sciences
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    • v.21 no.4
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    • pp.233-242
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    • 2004
  • The $HCO^+$ 1-0 transition line was observed toward the Sgr B2 region in our Galactic center. We found that there exist two large-scale velocity structures of $v_{lsr}\;{\sim}50\;and\;{\sim}100kms^{-1}$, which are thought to interact with each other. A new gas clump 'OF28 Cloud'('Odenwald & Fazio FIR 38' Cloud), showing different chemical and kinematical properties with the Sgr B2(M) cloud, was found in the $50kms^{-1}$ gas component. Toward the core of this component, we derive the $HCO^+$ total column density, $N(HCO^+)=(2-5){\times}10^{14}cm^{-2}$ and the mass $M=1{\times}10^6M_{\odot}$, by estimating its size, ${\sim}15pc$, from the half-power width of this component. We also found that there is a highly turbulent component in this region in the velocity range of about $100kms^{-1}$. The column density of this component is $N(HCO^+)=1{\times}10^{13}cm^{-2}$. The $HCO^+$ in this region may form effectively by the reaction between $C^+$ and OH, which are the elements whose abundances increase rapidly in shocked region.

Effect of Nuruks and Crude Amylolytic Enzyme on Free Amino Acid and Volatile Components of Brown Rice Vinegar Prepared by Static Culture (누룩 및 조효소제가 정치배양 현미식초의 유리아미노산과 휘발성분에 미치는 영향)

  • Lee, Su-Won;Yoon, Sung-Ran;Kim, Gui-Ran;Kyung, Hyun-Kyu;Jeong, Yong-Jin;Yeo, Soo-Hwan;Kwon, Joong-Ho
    • Korean Journal of Food Science and Technology
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    • v.43 no.5
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    • pp.570-576
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    • 2011
  • The effect of nuruks and crude amylolytic enzyme on free amino acid and volatile components of brown rice vinegar prepared by static cultures was investigated. Five groups consisted of AV (100% nuruk without crude amylolytic enzyme), BV (75% nuruk; 25% crude amylolytic enzyme), CV (50% nuruk; 50% crude amylolytic enzyme), DV (25% nuruk; 75% crude amylolytic enzyme) and EV (100% crude amylolytic enzyme without nuruk). Free amino acid content in AV vinegar (132.06 mg%) was lower than the others (184.56-191.22 mg%). Acetic acid, 3-methyl butyl acetate, acetoin and isoamyl alcohol were major volatile components as analyzed using gas chromatography-mass spectrometry after headspace solid-phase microextraction. Acetic acid in AV and EV samples represented 67.56% and 55.53% of total GC peak area, respectively. E-nose provided different patterns in each case showing variation in sensory properties.

An Analysis of the Characteristics of Aerosol Light Scattering Coefficients at Seoul and Baengnyeongdo (서울과 백령도의 에어로솔 산란계수 특성 분석)

  • Eun, Seung-Hee;Nam, Hyoung-Gu;Kim, Byung-Gon;Park, Jin-Soo;Ahn, Jun-Young;Lee, Seok-Jo
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.3
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    • pp.264-274
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    • 2013
  • This study investigates long-term trends and characteristics of aerosol light scattering coefficient at Seoul and Baengnyeongdo in order to understand aerosol optical and radiative properties around Korea. The analysis period is limited to one year of 2011. First, the aerosol scattering coefficients (${\sigma}_{sp}$) of both sites show strong linear dependence on the $PM_{2.5}$ mass concentrations with significant correlations between both. Further, correlations and sensitivity between ${\sigma}_{sp}$ and $PM_{2.5}$ increase with relative humidity, implying both relationships are strongly dependent upon moisture amounts in the atmosphere. This study applied 3-step careful quality control procedures to the analysis of ${\sigma}_{sp}$ for the insurance of data confidence. For the relationship analysis of extinction coefficients (${\sigma}_{ext}$) to visibility and aerosol optical depth, ${\sigma}_{sp}$ observed at 3 p.m. have been used with help of aerosol absorption coefficients (${\sigma}_{ap}$) in order to remove its dependence upon relative humidity, and also those of rainy period have been excluded. As expected, ${\sigma}_{ext}$ estimated are inversely proportional to visibility observation by eye. Finally, aerosol extinction coefficients have been vertically integrated with an assumption of nearly well-mixed within an e-folding height to determine aerosol optical depth, and compared with those retrieved from sunphotometer. The results show a reasonable agreement in spite of an inherent difference of each definition. We expect these findings would help to eventually understand aerosol radiative forcing and its effect on the regional climate change around Korea.

Development and Characterization of an Anti-Acne Gel Containing Siamese Crocodile (Crocodylus siamensis) Leukocyte Extract

  • Phupiewkham, Weeraya;Lu, Qiumin;Payoungkiattikun, Wisarut;Temsiripong, Threeranan;Jangpromma, Nisachon;Lai, Ren;Klaynongsruang, Sompong
    • Journal of Microbiology and Biotechnology
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    • v.28 no.5
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    • pp.707-717
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    • 2018
  • Leukocytes are reportedly the first line of the innate immune defense and essential for the control of common bacterial infections. Therefore, in this work, the antibacterial activity of crocodile leukocyte extract against Propionibacterium acnes was evaluated, and we also characterized the related activity of skin infection. The leukocyte extract showed the minimum inhibitory concentration to be $100{\mu}g/ml$ to P. acnes. SEM imaging demonstrated that the leukocyte extract adversely affected P. acnes cell permeability in a concentration-dependent manner. Furthermore, the crocodile leukocyte extract could significantly reduce proinflammatory markers and decrease inflammatory signs in infected mouse ears. The crude leukocyte extract was further purified using FPLC and RP-HPLC. The resulting fraction F5 was indicated as the anti-acne peptide-containing fraction. The molecular mass of the peptide contained in F5 was calculated to be 4,790.5 Da. N-Terminal sequencing revealed the amino acid sequence as GPEPVPAIYQ, which displays similarities to immunoglobulin A and leucine-rich repeat neuronal protein. This is the first reported amino acid sequence of a crocodile leukocyte extract that possesses anti-acne activity. To attempt to use it in a prototype cosmetic, an anti-acne gel containing crude crocodile leukocyte extract was formulated, resulting in seven gel formulations (G1, G2, G3, G4, G5, G6, and G7). The formulations G5, G6, and G7 exhibited 2-fold higher anti-acne activity than G1-G4. Investigation of accelerating stability studies of anti-acne gel formulations G5, G6, and G7 demonstrated that a low storage temperature ($4^{\circ}C$) is suitable for maintaining the physical properties and biological activity of the anti-acne gel products.

Production and Application of Domestic Input Data for Safety Assessment of Disposal (처분안전성평가를 위한 국내고유 입력자료의 확보와 적용)

  • Park, Chung-Kyun;Lee, Jae-Kwang;Baik, Min-Hoon;Lee, Youn-Myoung;Ko, Nak-Youl;Jeong, Jong-Tae
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.3
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    • pp.161-170
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    • 2012
  • To provide domestic values of input parameters in a safety assessment of radioactive waste disposal under domestic deep underground environments, various kinds of experiments have been carried out under KURT (KAERI Underground Research Tunnel) conditions. The input parameters were classified, and some of them were selected for this study by the criteria of importance. The domestic experimental data under KURT environments were given top priority in the data review process. Foreign data under similar conditions to KURT were also gathered. The collected data were arranged and the statistical calculations were processed. The properties and distribution of the data were explained and compared to foreign values in view of their validity. The following parameters were analysed: failure time and early time failure rate of a container, solubility of nuclides, porosity and density of the buffer, and distribution coefficients of nuclides in the geomedia, hydraulic conductivity, diffusion depth of nuclides, groundwater flow rate, fracture aperture, length of internal fracture, and width of faulted rock mass in the host rock.

A Prediction of Thermal Expansion Coefficient for Compacted Bentonite Buffer Materials (압축 벤토나이트 완충재의 열팽창계수 추정)

  • Yoon, Seok;Kim, Geon-Young;Baik, Min-Hoon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.3
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    • pp.339-346
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    • 2018
  • A geological repository system consists of a disposal canister with packed spent fuel, buffer material, backfill material, and intact rock. The buffer is indispensable to assure the disposal safety of high-level radioactive waste. Since the heat generated from spent nuclear fuel in a disposal canister is released to the surrounding buffer materials, the thermal properties of the buffer material are very important in determining the entire disposal safety. Especially, since thermal expansion can cause thermal stress to the intact rock mass in the near-field, it is very important to evaluate thermal expansion characteristics of bentonite buffer materials. Therefore, this paper presents a thermal expansion coefficient prediction model of the Gyeongju bentonite buffer materials which is a Ca-bentonite produced in South Korea. The linear thermal expansion coefficient was measured considering heating rate, dry density and temperature variation using dilatometer equipment. Thermal expansion coefficient values of the Gyeongju bentonite buffer materials were $4.0{\sim}6.0{\times}10^{-6}/^{\circ}C$. Based on the experimental results, a non-linear regression model to predict the thermal expansion coefficient was suggested and fitted according to the dry density.