• Transactions of the Korean Society of Mechanical Engineers A
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• v.35 no.1
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• pp.33-37
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• 2011

In the fields of display, optics, and energy, it is important to improve micropattern-machining technology for achieving small patterns, large surface areas, and low cost. Unlike flat molds, roll molds have the following advantages: they can be manufactured within a short time, larger surface areas can be obtained, and continuous molding can be achieved. In this study, we aim to investigate the causes for errors in the shapes for a micropattern-machining process, and we show that by compensating the dynamic balance of roll molds, the dimensional accuracy of machined parts can be improved. The experimental results show that dynamic-balance compensation for a roll mold reduced the mass unbalance and the vibrations of the roll mold, and as a result, the dimensional accuracy of machined micropatterns has been improved.

• Microbiology and Biotechnology Letters
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• v.16 no.2
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• pp.85-91
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• 1988

Energy efficiency of bacterial cell mass and product formation from cellulose using Ruminococcus albus and Ruminococcus flavefaciens with application of available electron balance were discussed. Values of true growth yield, η$_{max}$ and η$^{max}_{th}$ and maintenance coefficient, m$_{e}$, were estimated us-ing experimental data, and the results were compared with estimates obtained from theoretical ap-proach. Experimental values were similar in magnitude to theoretical values in $Y^{max}_{ATP}$= 10.5 g cells/ mole ATP. Therefore, $Y^{max}_{ATP}$ values of Ruminococcus albus and Ruminocoecus flavefaciens were considered similar to 10.5 g cells/mole ATP.

• Mass Spectrometry Letters
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• v.5 no.1
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• pp.30-33
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• 2014

A solid phase extraction (SPE) method was optimized for the quantitative analysis of perfluorooctanoic acid (PFOA) in serum using hydrophilic-lipophilic balance SPE and LC-MS/MS. Fetal bovine serums spiked with $^{13}C_8$-PFOA before or after SPE were used as test samples for evaluation of the SPE efficiency. Simultaneous evaluation of matrix effects and absolute SPE recovery for $^{13}C_8$-PFOA in serum using different sample pre-treatments and SPE conditions allowed optimization of SPE process efficiency with minimal matrix effect and decent SPE recovery. Introduction of protein precipitation as a sample pre-treatment procedure for serum samples before SPE generally decreased matrix effect in LC-MS/MS analysis and provided more stable recovery of PFOA.

• Membrane Journal
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• v.12 no.4
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• pp.226-239
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• 2002

A process simulation model of pervaporation process has been developed as a design tool to analyse and optimize the dehyhration of organic solvents through a commercial scale of pervaporative plate-and-frame modules that contain a stack of membrane sheets. In the simulation model, the mass balance, the heat balance and the concentration balance are integrated in a finite elements-in-succession method to simulate the overall process. In the integration method, a feed channel between membrane sheets in the modules was taken as differential unit element volume to simplify calculation procedure and shorten computing time. Some of permeation parameters used in the simulation model, were quantified directly from the dehydration experiment of ethanol through $AzeoSep^{TM}$-2002 membrane which is a commercial pervaporation membrane. The simulation model was verified by comparing the simulated values with experimental data. Using the model, continuous and batch pervaporation processes were simulated, respectively, to acquire basic data for analysing and optimizing in the dehydration of ethanol through the membrane. Based on the simulation results, a comparison between the continuous and the batch pervaporation processes would be discussed.

• Korean Journal of Chemical Engineering
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• v.35 no.12
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• pp.2327-2335
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• 2018

Fluid catalytic cracking (FCC) is an important chemical process that is widely used to produce valuable petrochemical products by cracking heavier components. However, many difficulties exist in modeling the FCC process due to its complexity. In this study, a dynamic process model of a FCC process is suggested and its structural observability is analyzed. In the process modeling, yield function for the kinetic model of the riser reactor was applied to explain the product distribution. Hydrodynamics, mass balance and energy balance equations of the riser reactor and the regenerator were used to complete the modeling. The process model was tested in steady-state simulation and dynamic simulation, which gives dynamic responses to the change of process variables. The result was compared with the measured data from operating plaint. In the structural analysis, the system was analyzed using the process model and the process design to identify the structural observability of the system. The reactor and regenerator unit in the system were divided into six nodes based on their functions and modeling relationship equations were built based on nodes and edges of the directed graph of the system. Output-set assignment algorithm was demonstrated on the occurrence matrix to find observable nodes and variables. Optimal locations for minimal addition of measurements could be found by completing the whole output-set assignment algorithm of the system. The result of this study can help predict the state more accurately and improve observability of a complex chemical process with minimal cost.

• Journal of the Korean Society of Combustion
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• v.23 no.1
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• pp.44-54
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• 2018

Heat and mass balance process modeling has been conducted for a coal-firing power plant to be used as a testbed facility for development of various plant systems and equipment. As the material and design of the boiler tube bundle and fuel conversion to the biomass have become major concerns, the process modeling is required to incorporate those features in its calculation. The simulation cases for two different generation load show the satisfying results compared to the operational data from the actual system. Based on the established process conditions, the hypothetical case using wood pellet has also been simulated. Additional calculations for the tube bundle has been conducted regarding the changes in the tube material and design.

• 제어로봇시스템학회:학술대회논문집
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• 1987.10b
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• pp.664-666
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• 1987

In this study, the computation of optimum operating conditions for catalytic oxidation of sulfur dioxide to sulfur trioxide in CONVERTER which determines the yield ultimately in sulfuric acid plant is performed on an IBM/XT computer. The process simulator of rigorous converter model including mass & energy balance equations and supporting equations is linked to optimizer, which produces the desired results successfully.

• Corrosion Science and Technology
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• v.5 no.6
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• pp.206-212
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• 2006

The effects of sub-ppm levels of $H_2S$ and the adsorbed water on the atmospheric corrosion of silver were studied with In situ weight balance to study the effect of the adsorbed water on the kinetic behavior and to determine the rate-controlling step, with XPS to analyze the tarnish film, and with calculation of phase equilibrium to predict the stable solid phase, the concentrations of dissolved species ($Ag^-$, $H^+$, $S^{2-}$, $HS^-$) and the equilibrium potentials ($E_{Ag^+/Ag}$, $E_{H^+/H_2}$, $E_{O_2/O^{2-}$). The results of weight measurements showed that oxygen was required for the sulfidation of silver in 100 ppb $H_2S$ and humidified environments enhanced the tarnished rate and oxidizing power. In addition, the rate determining step for tarnishing silver was shown to be changed to transport though the tarnish film.

• Journal of the Korean Ceramic Society
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• v.32 no.11
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• pp.1246-1254
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• 1995

A numerical model for fabrication and deposition of ultrafine SiO2 particles were proposed in the simplified horizontal MCVD apparatus using tube furnace reactor. The model equations such as energy and mass balance equations and the 0th, 1st and 2nd moment balance equations of aerosols were considered in the reactor. The phenomena of SiCl4 chemical reaction, SiO2 particle formation and coagulation, diffusion and thermophoresis of SiO2 particles were included in the aerosol dynamic equation. The profiles of gas temperature, SiCl4 concentration and SiO2 particle volume were calculated for standard conditions. The concentrations, sizes and deposition efficiencies of SiO2 particles were calculated, changing the process conditions such as tube furnace setting temperature, total gas flow rate and inlet SiCl4 concentration.

• Journal of the Korea Organic Resources Recycling Association
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• v.29 no.4
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• pp.77-86
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• 2021

In this study, to use as basic data for the organic waste resource energy incentive system, the energy efficiency is evaluated through the mass balance and energy balance calculation results of the anaerobic digester where food waste, food waste leachate and various organic wastes are treated. As a result of the mass balance analysis for 11 biogasification facilities, it was confirmed that 21.1% of process water and 25.7% of tap water were input in large amounts, excluding organic waste. Accordingly, it accounted for 87.6% of the total effluent of linked treated water. In addition, considering that 15.7% of the total input volume is converted to biogas and the average total solids (TS) is 22%, an average material conversion rate of 75% was confirmed. As a result of the energy balance analysis, the energy conversion rate was confirmed to be 78.5% on average by analyzing the biogas calorific value compared to the potential energy of the influent. The average biogas production efficiency including external energy sources for biogas production was 69.4%, and the biogas plant efficiency to which unused effluent energy was applied was 58.9% on average.