• 제목/요약/키워드: Mass Balance Model

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Determining Groundwater-surface Water Interaction at Coastal Lagoons using Hydrogeochemical Tracers (수리화학적 환경 추적자를 이용한 강원도 석호지역에서의 지하수-지표수 상호작용에 대한 연구)

  • Dong-Hun Kim;Jung-Yun Lee;Soo Young Cho;Hee Sun Moon;Youn-Young Jung;Yejin Park;Yong Hwa Oh
    • Journal of Soil and Groundwater Environment
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    • v.28 no.2
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    • pp.1-11
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    • 2023
  • Groundwater-surface water interaction was evaluated using water quality parameters (temperature and electrical conductivity), distributions of stable water isotopes (δ2H and δ 18O), and Rn-222 in lagoon water, groundwater, and seawater at three coastal lagoons (Songji (SJ), Youngrang (YR), and Sunpo (SP) Lagoon) in South Korea. From the results of composition and distributions of δ2H and δ18O, it was found that groundwater fraction of lagoon water in YR Lagoon (76%) was slightly higher than those of SJ (42%), and SP (63%) Lagoon. Based on Rn-222 mass balance model, groundwater discharge into SJ Lagoon in summer 2020 was estimated to be (3.2±1.1)×103 m3 day-1, which showed a similar or an order of magnitude higher than the results of previous studies conducted in coastal lagoons. This study can provide advanced techniques to evaluate groundwater-surface water interaction in coastal lagoons, wetlands, and lakes, and help to determine the effects of groundwater on coastal ecosystems.

Dynamic Modeling of Gasification Reactions in Entrained Coal Gasifier (석탄 가스화 반응의 동적 거동 전산 모사)

  • Chi, Jun-Hwa;Oh, Min;Kim, Si-Moon;Kim, Mi-Young;Lee, Joong-Won;Kim, Ui-Sik
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.3
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    • pp.386-401
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    • 2011
  • Mathematical models for various steps in coal gasification reactions were developed and applied to investigate the effects of operation parameters on dynamic behavior of gasification process. Chemical reactions considered in these models were pyrolysis, volatile combustion, water shift reaction, steam-methane reformation, and char gasification. Kinetics of heterogeneous reactions between char and gaseous agents was based on Random pore model. Momentum balance and Stokes' law were used to estimate the residence time of solid particles (char) in an up-flow reactor. The effects of operation parameters on syngas composition, reaction temperature, carbon conversion were verified. Parameters considered here for this purpose were $O_2$-to-coal mass ratio, pressure of reactor, composition of coal, diameter of char particle. On the basis of these parametric studies some quantitative parameter-response relationships were established from both dynamic and steady-state point of view. Without depending on steady state approximation, the present model can describe both transient and long-time limit behavior of the gasification system and accordingly serve as a proto-type dynamic simulator of coal gasification process. Incorporation of heat transfer through heterogenous boundaries, slag formation and steam generation is under progress and additional refinement of mathematical models to reflect the actual design of commercial gasifiers will be made in the near futureK.

Modeling and Analysis of Dynamic Characteristic for Bundle Fluid System (집속체 유동계의 모델링과 운동 특성해석)

  • Kim, Jong-Sung;Heo, Yu;Kim, Yoon-Hyuk
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.1643-1646
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    • 2003
  • Drawing is a mechanical operation that attenuates thick material to an appropriate thickness for the next processing or end usage. When the input material has the form of a bundle or bundles made of very thin and long shaped wire or fibers, this attenuation operation is called "bundle drawing" or "drafting" Drafting is being used widely in manufacturing staple yarns. which is indispensable for the textile industry. However, the bundle processed by this operation undertake more or less defects in the evenness of linear density. Such irregularities cause many problems not only for the product quality but also for the efficiency of the next successive processes. Since long there have been many researches tying to find out factors affecting the irregularity of linear desity, to obtain optimal drafting conditions, to develop efficient measuring and analysis methods of linear density of bundle, etc., but there exists yet no fundamental equation describing the dynamic behavior of the flowing bundle during processing. In this research a mathematical model for the dynamic behavior of the bundle fluid is to be set up on the basis of general physical lows representing physical variables, i.e. linear density and velocity as the dynamic state of bundle. The conservation of mass and momentum balance was applied to the fluid field of bundle. while the movement of′ individual material was taken into account. The constitutive model relating the surface force and the deformation of bundle was introduced by considering a representative prodedure that stands for the bundle movement. Then a fundamental equations system could be simplified considering a steady state of the process. On the basis of the simplified model, the simulation was performed and the results could be confirmed by the experiments under various conditions.

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Methane emission from municipal solid waste dumpsites: A case study of Chennai city in India

  • Srinivasan, Pavithrapriya;Andimuthu, Ramachandran;S.N., Ahamed Ibrahim;Ramachandran, Prasannavenkatesh;Rajkumar, Easwari;Kandasamy, Palanivelu
    • Advances in environmental research
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    • v.9 no.2
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    • pp.97-107
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    • 2020
  • The indiscriminate growth in global population poses a threat to the world in handling and disposal of Municipal solid waste. Rapid urban growth increases the production, consumption and generation of Municipal solid waste which leads to a drastic change in the environment. The methane produced from the Municipal Solid waste accounts for up to 11% global anthropogenic emissions, which is a major cause for global warming. This study reports the methane emission estimation using IPCC default, TNO, LandGEM, EPER and close flux chamber from open dump yards at Perungudi and Kodungaiyur in Chennai, India. The result reveals that the methane emission using close flux chamber was in the range of 8.8 Gg/yr-11.3 Gg/yr and 6.1Gg/yr to 9.1 Gg/yr at Kodungaiyur and Perungudi dump yard respectively. The per capita waste generation was estimated based on waste generation and population. The waste generation potential was projected using linear regression model for the period 2017-2050. The trend of CH4 emission in the actual field measurement were increased every year, similarly the emission trend also increased in IPCC default method (mass balance approach), EPER Germany (zero order decay model) where as TNO and Land GEM (first order decay model) were decreased. The present study reveals that Kodungaiyur dump yard is more vulnerable to methane emission compared to Perungudi dump yard and has more potential in waste to energy conversion mechanisms than compare to Perungudi dump yard.

Evaluation of natural and anthropogenic impact on sediment yield using RUSLE and WATEM/SEDEM sediment delivery equation (RUSLE과 WATEM/SEDEM 유사이동식을 활용한 인간활동과 기후변화로 인한 유사량 평가)

  • Kim, Wonjin;Woo, Soyoung;Jang, Wonjin;Kim, Yongwon;Kim, Seongjoon
    • Proceedings of the Korea Water Resources Association Conference
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    • 2022.05a
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    • pp.80-80
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    • 2022
  • 본 연구는 한강유역 (35,770 km2)을 대상으로 RUSLE (Revised Universal Soil Loss Equation)과 WATEM/SEDEM (The Water and Tillage Erosion Model and Sediment Delivery Model)의 유사이동식을 활용하여 인간활동과 기후변화로 인한 유사량을 평가하였다. 대상유역에 영향을 주는 16곳의 기상관측소에서 제공하는 분 단위 누적강수량 (2000-2019), 농촌진흥청 토양도, 국토지리정보원 DEM (Digital Elevation Model), 환경공간정보서비스 (EGIS) 2020년 세분류 토지이용도를 활용하여 RUSLE과 WATEM/SEDEM 유사이동식에 필요한 강우침식인자(R), 토양침식인자 (K), 지형인자 (L·S), 식생피복인자 (C), 그리고 보전관리인자 (P)를 구축하였으며, SWAT (Soil and Water Assessment Tool)으로 모의한 표준유역 단위 연도별(2000-2019) 유사량 결과를 기준으로 WATEM/SEDEM 유사량 계수 (KTC)를 검·보정하였다. 토양침식 산정 입력자료 중 강우량으로 산정하는 강우침식인자는 기후변화를 보여주는 인자, 토지피복에 따라 다른 식생피복인자와 보전관리인자는 인간활동을 나타내는 인자로 설정하였다. 강우침식인자는 2010년대 평균값을 활용하여 현재의 유사량을 평가하였으며, 분 단위 자료가 없는 과거의 경우 직접적인 계산에 어려움이 있어, 연평균 강수량과의 관계로 추정한 1980년대 평균값을 활용하여 기후변화로 인한 영향을 평가하였다. 식생피복인자와 보전관리인자는 1980년대 토지이용도를 활용하여 산정한 결과로 인간활동에 의한 유사량 평가에 사용되었다. 대상유역의 유사량은 RUSLE 모형의 토양침식량과 WATEM/SEDEM 유사이동량을 mass balance로 분석하며, 다른 인자들은 고정한 상태로 과거 강우침식인자, 식생피복인자와 보전관리인자를 적용하여 인간활동과 기후변화로 인한 유사량 변화를 분석하고자 한다.

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A Study on the Source Profile Development for Diesel and Gasoline-Powered Vehicles (디젤 및 가솔린자동차 배출원의 구성물질 성분비 개발에 관한 연구)

  • Kang, Byung-Wook;Cho, Min-Shik;Lee, Seung-Bok;Bae, Gwi-Nam;Lim, Cheol-Soo;Na, Kwang-Sam;Lee, Hak-Sung
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.3
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    • pp.318-329
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    • 2010
  • The purpose of this study was to develop the $PM_{2.5}$ source profiles for diesel and gasoline-powered vehicles, which contained mass abundances in terms of mass fraction of $PM_{2.5}$ of chemical species. Seven diesel-powered vehicles and nine gasoline-powered vehicles were sampled from a chassis dynamometer exhaust dilution system. The species measured were water-soluble ions, elements, elemental carbon (EC), and organic carbon (OC). From this study, the large abundances of EC (54.5%), OC (26.0%), ${SO_4}^{2-}$ (1.5%), ${NO_3}^-$ (0.8%), and S (0.6%) were observed from the diesel-powered vehicle exhaust showing that carbons were dominant species. The gasoline-powered vehicle exhaust emitted large abundances of OC (38.3%), EC (4.2%), ${SO_4}^{2-}$ (3.6%), ${NH_4}^+$ (3.5%), and ${NO_3}^-$ (3.0%). The abundances of ${SO_4}^{2-}$, ${NH_4}^+$, and ${NO_3}^-$ from gasoline vehicle were greater than those of diesel vehicle. The emissions of P, S, Ca, Fe, and Zn among trace elements for the gasoline vehicle were greater than 1% of the $PM_{2.5}$ mass unlike those for the diesel vehicle. Particularly, the fraction of Zn was five times higher from the gasoline vehicle than that from the diesel vehicle. The source profiles developed in this work were intensively examined by applying chemical mass balance model.

Livestock Manure Nutrients Flow Analysis of Integrated Crop-Livestock Farming Model Reflecting the Regional Characteristics (지역특성을 고려한 경축순환농업 모형의 가축분뇨 양분 흐름분석)

  • Lee, Joon Hee;Choi, Hong Lim
    • Journal of the Korea Organic Resources Recycling Association
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    • v.23 no.2
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    • pp.36-46
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    • 2015
  • Integration of crop-livestock farming has been a problem-solving mode for abatement of environmental pollution and recovery of resources in recent years. The objectives of this study were 1) to suggest the customized integration of crop-livestock farming model reflecting the regional characteristics through in-depth analysis of case study and 2) to analyze the livestock nutrients flow in terms of three primary elements as nitrogen(N), phosphorous(P), and potassium(K). The personal interview and survey were carried out in 2012 for a total of 161 farms from four different regions(NS, NW, JJ, YC) in South Korea. The mass balance analysis was used to suggest and evaluate the models for two sites(JJ and YC). The results showed that NS and NW sites produced relatively more livestock manure than the sites of YC and JJ because of the regional differences in livestock numbers and urbanization. The models were suggested for the site JJ and site YC, and 'two track model(energy and resource recovery)' and 'dispersal type model' were assigned respectively. For the nutrient flows, the releasing P and K with new models had increased up to 7%, while N release had decreased down to 15% in both YC and JJ sites compared to the present treatment system. Estimated value showed that there was oversupply of N (719 ton/yr) and $P_2O_5$ (1,269 ton/yr) in YC and deficiency of N (671 ton/yr) and excessive $P_2O_5$ (32 ton/yr) in JJ respectively. Therefore, P runoff has to be considered an eutrophication occurs in rural small stream when an integration of crop-livestock farm system is applied into both sites.

Models of Wastewater Treatment by Rotating Discs (회전원판접촉법(回轉圓板接觸法)에 의한 폐수처리(廢水處理)의 모형(模型)에 관한 연구(研究))

  • Chung, Tai Hak;Park, Chung Hyun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.2 no.2
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    • pp.39-46
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    • 1982
  • A model of substrate removal by rotating discs has been developed for a better understanding of the process, and the performance of the system has been evaluated under steady and unsteady state. The model was constructed based upon mass transfer of the substrate from the bulk solution to the biofilm and a simultaneous removal of the substrate by the biomass. The model is composed of a few sets of differential equations representing mass balance within the elements of a liquid film and a biofilm, and in the bulk solution. Substrate removal efficiency of the process is largely dependent on a diffusion coefficient of the substrate within the biofilm and a maximum rate of substrate removal of the biomass. The efficiency is affected to a greater extent when the substrate concentration is low and the maximum substrate removal rate is high. The efficiency increases proportionally with increasing film depth when the biofilm is shallow, however, the rate of increase gradually decreases with an increase of the film depth. As the film reaches a limiting depth, the efficiency remains constant. Unlike the steady state, the effluent quality is affected by the tank volume under dynamic state. Increasing tank volume decreases peak concentration of the effluent under peak loading. Additional tank volume provides a buffer capacitya.gainst a peak loading and the holding tank behaves like an equalization tank.

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Numerical Analysis of Integrated Fuel Processing System Considering Thermo-Chemical Energy Balance (열/화학적 에너지 평형을 고려한 통합 연료 개질 시스템의 수치적 연구)

  • Noh, Junghun;Jung, Hye-Mi;Jung, Un-Ho;Yoon, Wang-Lai;Um, Sukkee
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.111.1-111.1
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    • 2010
  • This paper focuses on a systematic configuration of steam reforming fuel processor, particularly designed for small and medium sized hydrogen production application. In a typical integration of the fuel processor, there exist significant temperature gradients over the entire system which has negative effect on both catalyst life-time and system performance. Also, the volumetric inefficiency should be avoided to obtain the possible compactness for the commercial purpose. In the present work, the computational analysis will be performed to gain the fundamental insight on the transport phenomena and chemical reactions in the reformer consisting of preheating, steam reforming (SR), and water gas shift (WGS) reaction beds in the flow direction. Also, the fuel processing system includes a top-fired burner providing necessary thermal energy for endothermic catalytic reactor. A fully two-dimensional numerical modeling for a integrated fuel processing system is introduced for in-depth analysis of the heat and mass transport phenomena based on surface kinetics and catalytic process. In the model, water gas shift reaction and decomposition reaction were assumed to be at equilibrium. A kinetic model was developed and then computational results were compared with the experimental data available in the literature. Finally, the case study was done by considering the key parameters, i.e. steam to carbon (S/C) ratio and temperature. The computer-aided models developed in this study can be greatly utilized for the design of advanced fast-paced compact fuel processors research.

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Characterization of Volatile Organic Compounds in New Residential Buildings Before Moving-in

  • Shin, Seung-Ho;Jo, Wan-Kuen
    • Journal of Environmental Science International
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    • v.21 no.1
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    • pp.11-21
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    • 2012
  • This study investigated the characteristics of selected volatile organic compounds(VOCs) in newly-finished residential buildings, before the occupants moved in. This investigation was carried out by measuring the indoor and outdoor concentrations of selected VOCs before the occupants moved in and by utilizing an indoor mass balance model. Among 25 target VOCs, five aromatics(benzene, ethyl benzene, toluene, m,p-xylene, and o-xylene) were detected in all samples of both indoor and outdoor air. Toluene was most abundant VOC in the indoor air of new apartments, with a median value of 168 mg $m^{-3}$. Unlike other VOCs, halogenated compounds would not be significantly emitted from building materials. The indoor air concentrations of all selected VOCs, except for 1,3,5-trimethyl benzene, exhibited significant correlations each other, while for outdoor air concentrations, five aromatics only were significantly correlated between them. The emission rate of toluene was higher for the current study(median value, 76.8 mg $m^{-2}\;h^{-1}$) than for a previous study, while the emission rates of limonene, a-pinene and b-pinene(geometric means of 2.4, 13.8 and 9.6 mg $m^{-2}\;h^{-1}$, respectively) were lower and the emission rates of m,p-xylene and 2-butanone(geometric means of 10.9 and 21.3 mg $m^{-2}\;h^{-1}$, respectively) were similar. Although there were a few exceptions, the emission strengths are likely proportional to indoor temperature, and appear to reversely proportional to air exchange rate.