• Title/Summary/Keyword: Mass Balance Model

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Estimation of Nitrogen Dioxide Source Generation and Ventilation Rate in Residence Using Multiple Measurements in Korea

  • Chung, Moon-Ho;Yang, Won-Ho
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2004.12a
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    • pp.45-50
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    • 2004
  • Indoor air quality can be affected by indoor sources, ventilation, decay and outdoor levels. Alt hough technologies exist to measure these factors, direct measurements are often difficult. The purpose of this study was to develop an alternative method to characterize indoor environmental factors by multiple indoor and outdoor measurements. Daily indoor and outdoor NO2 concentrations were measured for 30 consecutive days in 28 houses in Brisbane, Australia, and for 21 consecutive days in 37 houses in Seoul, Korea. Using a mass balance model and regression analysis, penetration factor (ventilation rate divided by the sum of ventilation rate and deposition constant) and source strength factor (source strength divided by the sum of ventilation rate and deposition constant) were calculated using multiple indoor and outdoor measurements. Subsequently, the ventilation rate and NO2 source strength were estimated. Geometric means of ventilation rate were 1.44 ACH in Brisbane, assuming a residential NO2 deposition constant of 1.05 hr-1, and 1.36 ACH in Seoul, with the measured residential NO2 deposition constant of 0.94 hr-1. Source strengths of N02 were 15.8 ${\pm}$ 18.2 ${\mu}$g/m3${\cdot}$hr and 44.7 ${\pm}$ 38.1 ${\mu}$g/m3${\cdot}$hr in Brisbane and Seoul, respectively. In conclusion, indoor environmental factors were effectively characterized by this method using multiple indoor and outdoor measurements.

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Metabolic Analysis of Poly(3-Hydroxybutyrate) Production by Recombinant Escherichia coli

  • WONG, HENG HO;RICHARD J. VAN WEGEN;JONG-IL CHOI;SANG YUP LEE
    • Journal of Microbiology and Biotechnology
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    • v.9 no.5
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    • pp.593-603
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    • 1999
  • Poly(3-hydroxybutyrate) (PHB) production by fermentation was examined under both restricted- and ample-oxygen supply conditions in a single fed-batch fermentation. Recombinant Escherichia coli transformed with the PHB production plasmid pSYLl07 was grown to reach high cell density (227 g/l dry cell weight) with a high PHB content (78% of dry cell weight), using a glucose-based minimal medium. A simple flux model containing 12 fluxes was developed and applied to the fermentation data. A superior closure (95%) of the carbon mass balance was achieved. When the data were put into use, the results demonstrated a surprisingly large excretion of formate and lactate. Even though periods of severe oxygen limitation coincided with rapid acetate and lactate excretion, PHB productivity and carbon utilization efficiency were not significantly impaired. These results are very positive in reducing oxygen demand in an industrial PHA fermentation without sacrificing its PHA productivity, thereby reducing overall production costs.

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Development of the vac Source Profile using Collinearity Test in the Yeosu Petrochemical Complex (여수석유화학산단의 공선성 시험을 이용한 VOC 오염원 분류표 개발)

  • Jeon Jun-Min;Hur Dang;Hwang In Jo;Kim Dong-Sul
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.3
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    • pp.315-327
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    • 2005
  • The total of 35 target VOCs (volatile organic compounds), which were included in the TO-14, was selected to develop a VOCs' source profile matrix of the Yeosu Petrochemical Complex and to test its collinearity by singular value decomposition(SVD) technique. The VOCs collected in canisters were sampled from 12 different sources such as 8 direct emission sources (refinery, painting, wastewater treatment plant, incinerator, petrochemical processing, oil storage, fertilizer plant, and iron mill) and 4 general area sources (gasoline vapor emission, graphic art activity, vehicle emission, and asphalt paving activity) in this study area, and then those samples were analyzed by GC/MS. Initially the resulting raw data for each profile were scaled and normalized through several data treatment steps, and then specific VOCs showing major weight fractions were intensively reviewed and compared by introducing many other related studies. Next, all of the source profiles were tested in terms of degree of collinearity by SVD technique. The study finally could provide a proper VOCs' source profile in the study area, which can give opportunities to apply various receptor models properly including chemical mass balance (CMB).

THERMAL ANALYSES AND VERIFICATION FOR HAUSAT-2 SMALL SATELLITE (HAUSAT-2 소형위성 열해석 검증 및 보드-레벨 열해석)

  • Lee Mi-Hyeon;Kim Dong-Woon;Chang Young-Keun
    • Journal of Astronomy and Space Sciences
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    • v.23 no.1
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    • pp.39-54
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    • 2006
  • HAUSAT-2 is nano satellite with 25kg mass being developed by Space System Research Lab. in Hnakuk Aviation University. This paper addresses HAUSAT-2 small satellite thermal analyses and its verification at satellite system, electronic box, and PCB levels. Thermal model which is used for system-level and box-level thermal analyses was verified and corrected through thermal vacuum/balance test. The new board-level thermal analysis methodology, modelling high-power dissipating EEE parts directly, was proposed. The proposed methodology has been verified with test results.

Estimation of Source Emission Rate on Volatile Organic Compounds and Formaldehyde Using Indoor Air Quality Modeling in New Apartment (실내공기질 모델을 이용한 신축공동주택의 VOCs 및 HCHO 배출량 추정)

  • Sim, Sang-Hyo;Kim, Yoon-Shin;Yang, Won-Ho
    • Journal of Environmental Science International
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    • v.15 no.10
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    • pp.929-933
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    • 2006
  • Indoor air quality is the dominant contributor to total personal exposure because most people spend a majority of their time Indoors. Especially when indoor environments have sources of contaminants, exposure to in-door air can potentially pose a greater threat than exposure to ambient air. In this study, estimations of volatile organic compounds and formaldehyde omission rate in indoor environments of new apartments were carried out using mass balance model in indoor environment, because indoor air quality can be affected by source generation, outdoor air level, ventilation, decay by reaction, temperature, humidity, mixing condition and so on. Considering the estimated emission rate of volatile organic compounds and formaldehyde, it Is suggested that new apartment should be designed and constructed in the aspect of using construction materials to emit low hazardous air pollutants.

An Experiment on Verification of Multi-Gas Tracer Technique for Air Exchange Rate Between Rooms (실간환기량 측정을 위한 멀티추적가스법의 검증실험)

  • Han, Hwa-Taik;Cho, Seok-Hyo
    • Proceedings of the SAREK Conference
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    • 2007.11a
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    • pp.99-104
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    • 2007
  • Tracer gas technique is widely used to measure the ventilation rates and/or ventilation effectiveness of building spaces. However, the conventional method using a single tracer gas can measure only outdoor air change rates in a single zone. This paper deals with the multi-gas tracer technique to measure air exchange rates between rooms. Interzonal air movements are important to characterize overall ventilation performance of complicated multi-zone buildings. Experiments are conducted in a simple two-room model with known airflow rates using tracer gases of SF6 and R134a. The concentration decays of two tracer gases are measured after simultaneous injections in each room. The governing equations are derived from the continuity and the mass balance of each room. The data reduction procedure are developed to obtain the inter-room airflow rates using the governing matrix inversion, and various data manipulation methods are tested, such as data shift, interpolation, smoothing, and etc, to improve the estimate and interpretation of the results.

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Investigation of blasting impact on limestone of varying quality using FEA

  • Dimitraki, Lamprini S.;Christaras, Basile G.;Arampelos, Nikolas D.
    • Geomechanics and Engineering
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    • v.25 no.2
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    • pp.111-121
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    • 2021
  • Large deformation and rapid pressure propagation take place inside the rock mass under the dynamic loads caused by the explosives, on quarry faces in order to extract aggregate material. The complexity of the science of rock blasting is due to a number of factors that affect the phenomenon. However, blasting engineering computations could be facilitated by innovative software algorithms in order to determine the results of the violent explosion, since field experiments are particularly difficult to be conducted. The present research focuses on the design of a Finite Element Analysis (FEA) code, for investigating in detail the behavior of limestone under the blasting effect of Ammonium Nitrate & Fuel Oil (ANFO). Specifically, the manuscript presents the FEA models and the relevant transient analysis results, simulating the blasting process for three types of limestone, ranging from poor to very good quality. The Finite Element code was developed by applying the Jones-Wilkins-Lee (JWL) equation of state to describe the thermodynamic state of ANFO and the pressure dependent Drucker-Prager failure criterion to define the limestone plasticity behavior, under blasting induced, high rate stress. A progressive damage model was also used in order to define the stiffness degradation and destruction of the material. This paper performs a comparative analysis and quantifies the phenomena regarding pressure, stress distribution and energy balance, for three types of limestone. The ultimate goal of this research is to provide an answer for a number of scientific questions, considering various phenomena taking place during the explosion event, using advanced computational tools.

Estimation of Alkali Overdosing in a Lime Neutralization Process for Acid Mine Drainage

  • Cheong, Young-Wook;Cho, Dong-Wan;Lee, Jin-Soo;Hur, Won
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.109-112
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    • 2022
  • Lime has been used for the neutralization of acidic waste because it is cheap and available in large quantities. The resulting sludge often contains a considerable amount of unreacted lime due to alkali overdosing, even during automatic neutralization processes, which mainly arises from the poor solubility of lime. The sludge cake from lime neutralization of Ilkwang Mine also contained high percentages of calcium and magnesium. The elemental content of the sludge cake was compared with those obtained from a simulation of the lime neutralization facility installed at Ilkwang Mine. A Goldsim® model estimated the degree of lime overdosing to be 19.1% based on the fractions of ferrous oxide. The analysis suggests that resolubilization of aluminum hydroxide could occur in the settling basin, in which pH exceeded 10 due to the continued dissolution of the overdosed lime. The present study demonstrated that chemical analysis of sludge combined with process simulation could provide a reasonable estimate of mass balance and chemistry in a neutralization facility for acid mine drainage.

Simulated Nitrogen Removal for Double-Layered PVA/Alginate Structure for Autotrophic Single-Stage Nitrogen Removal (2중 구조의 PVA/alginate 겔 비드에서의 독립영양 단일공정 질소제거효율 시뮬레이션)

  • Bae, Hyokwon
    • Journal of Korean Society on Water Environment
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    • v.38 no.4
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    • pp.171-176
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    • 2022
  • Recently, an autotrophic single-stage nitrogen removal (ASSNR) process based on the anaerobic ammonium oxidation (ANAMMOX) reaction has been proven as an economical ammonia treatment. It is highly evident that double-layered gel beads are a promising alternative to the natural biofilm for ASSNR because of the high mechanical strength of poly(vinyl alcohol) (PVA)/alginate structure and efficient protection of ANAMMOX bacteria from dissolved oxygen (DO) due to the thick outer layer. However, the thick outer layer results in severe mass transport limitation and consequent lowered bacterial activity. Therefore, the effects of the thickness of the outer layer on the overall reaction rate were tested in the biofilm model using AQUASIM for ammonia-oxidizing bacteria (AOB), nitrite-oxidizing bacteria (NOB) and ANAMMOX bacteria. A thickness of 0.5~1.0 mm is preferred for the maximum total nitrogen (TN) removal. In addition, a DO of 0.5 mg/L resulted in the best total nitrogen removal. A higher DO induces NOB activity and consequent lower TN removal efficiency. The optimal density of AO B and NO B density was 1~10% for a 10% ANAMMOX bacterial in the double-layered PVA/alginate gel beads. The real effects of operating parameters of the thickness of the outer layer, DO and concentrations of biomass balance should be intensively investigated in the controlled experiments in batch and continuous modes.

The Impact of Monsoon on Seasonal Variability of Basin Morphology and Hydrology (호수 지형 및 수리수문학적 변화에 대한 몬순 영향)

  • An, Kwang-Guk
    • Korean Journal of Ecology and Environment
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    • v.33 no.4 s.92
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    • pp.342-349
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    • 2000
  • This paper demonstrates the influence of intensity of the monsoon on morpho-hydrological fluctuations in Taechung Reservoir during 1993${\sim}$1994. During the study, hydrological variables including rainfall, inflow, and discharge volume showed distinct contrast between 1993 and 1994. Interannaul differences in rainfall occurred during the monsoon in July${\sim}$August monsoon and influenced inflow, discharge, and water residence time (WRT). Total inflow in 1993 was four times greater than that of 1994, and summer inflow in 1993 was 8 times greater than summer 1994. Annual Mean WRT was 93.2 d in 1993 vs. 158.6 d in 1994 and the largest differences occurred between monsoons of 1993 and 1994. Morphometric variables reflected the interannual contrasts of hydrology, so that in 1993 surface area, total volume, shoreline development, and mean depth increased consistently from premonsoon to postmonsoon and over this same period in 1994 they decreased. This outcome indicates that the area of shallow littoral zones in 1993 was greater than in 1994. Also, the drainage area to surface area (D/L) at 80 m MSL was 60.7 which was much greater than values in Soyang and Andong reservoirs and natural lakes world-wide. The morpho-hydrodynamic conditions seemed to influence in-reservoir nutrient concentration which is one of the most important factors regulating the eutrophication processes. I believe, under the maximum hydrodynamic fluctuations in Korean waterbodies during the monsoon, applications of mass balance models to man-made lakes for assessments of external loading should be considered because the models can be used under the seasonally stable inflow and water residence time.

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