• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.339-344
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• 2005

A PEMFC system model for FCEV was constructed and simulated numerically to examine the heat/water flow of the system and air/fuel humidification process for various operation conditions (ambient pressure /temperature/humidity, operating temperature, power load). We modeled PEMFC stack which can generate maximum electricity of about 80 kW. This stack consists of 400 unit cells and each unit cell has $250cm^2$ reacting area. Uniform current density and uniform operating voltage per each cell was assumed. The results show the flow characteristics of heat and water at each component of PEMFC system in macro-scale. The capacity shortage of the radiator occurred when the ambient was hot $(over\;40^{\circ}C)$ and power level was high (over 50 kW). In spite of some heat release by evaporation of water in stack, heat unbalance reached to 20kW approximately in such a severe operating condition. This heat unbalance could be recovered by auxiliary radiators or high speed cooling fan with additional cost. In cold environment, the capacity of radiator exceeded the net heat generation to be released, which may cause a problem to drop the operating temperature of stack. We dealt with this problem by regulating mass flow rate of coolant and radiator fan speed. Finally, water balance was not easily broken when we retrieved condensed and/or unused water.

• Journal of the Korean Society of Propulsion Engineers
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• v.21 no.5
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• pp.10-18
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• 2017

The problem of non-ideal detonation propagation velocities in heterogeneous hybrid mixtures is studied in the case of a high explosive with suspended fine aluminum (Al) particles. Since there exist difference in the time scales of the characteristic induction and combustion of High Explosives and solid particles, the process of energy release behind the leading shock front occurs over an extended period of time. The problem is analyzed by the theory of the mechanics of multiphase media with mass, momentum and heat exchanges between particles and gases. The numerical results match the available experimental results of heavily aluminized (5~25% Al weight) HMX explosive obtained previously.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.8
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• pp.767-773
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• 2010

In recent years, there has been considerable concern over the release of methyl tert-butyl ether (MTBE), a gasoline additive, into the aquifers used as potable water sources. MTBE readily dissolves in water and has entered the environment via gasoline spills and leaking storage tanks. In this study air stripping and ozonation of MTBE in aqueous solution were performed in a laboratory scale batch reacter. The mass transfer rate (N) was evaluated and a values about $1.24{\times}10^{-6}\;mol{\cdot}sec^{-1}$ was found. In the ozonation of MTBE a 8.3% decrease of the COD and a 6.5% decrease of the TOC lead to BOD/COD = 0.03. The peudo first-order rate constants of the ozonation of MTBE was $3.75{\times}10^{-5}\;sec^{-1}$. The resulting Ea of 4.80 kcal；mol-1 was observed for molecular ozone reactions.

• Journal of Soil and Groundwater Environment
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• v.26 no.1
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• pp.1-7
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• 2021

Air-water interfacial area is of great importance for the analysis of contaminant mass transfer processes occurring in the soil systems. Capillary bundle model has been proposed to estimate the specific air-water interfacial areas in unsaturated soils. In this study, the measured air-water interfacial areas of a soil (loam) using the gaseous interfacial tracer technique were compared to those from capillary bundle model. The measured values converged to the specific solid surface area (7.6×104 ㎠/㎤) of the soil. However, the simulated air-water interfacial areas based on the capillary bundle model deviated significantly from those measured. The simulated values were substantially over-estimated at low end of the water content range, whereas the model under-estimated the air-water interfacial area for the most of the water content range. This under-estimation is considered to be caused by the nature of the capillary bundle model that replaces the soil pores with a bundle of glass capillaries and thus no surface roughness at the inner surface of the capillaries is taken into account for the estimation of the air-water interfacial area with the capillary bundle model. Subsequently, appropriate correction is necessary for the capillary bundle model to estimate the air-water interfacial area in soils. Since the soil-moisture release curve data is the basis of the capillary bundle model, the model can be of use due to its simplicity, while the gaseous tracer technique requires complicated experimental equipment followed by moment analysis of the breakthrough curves. The size distribution profile of the pores filled with gas estimated by the water retention curve was found to be similar to that of particle size at different size range. The shifted distribution of gas-filled pores toward smaller size side compared to the particle size distribution was also found.

• Corrosion Science and Technology
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• v.21 no.6
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• pp.434-444
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• 2022

Corrosion inhibitors based on Zn-Al hydrotalcites containing benzoate (ZnAlHB) with different molar ratios of Zn/Al were prepared with a co-precipitation process. Compositions and structures of the resulting hydrotalcites were studied with suitable spectroscopic methods such as inductively coupled plasma mass spectrometry (ICP-MS), ultraviolet-visible spectrophotometry (UV-Vis), scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and surface zeta potential measurements, respectively. Results of physico-chemical studies showed that crystallite sizes, compositions of products, and surface electrical properties were significantly changed when the molar ratio of Zn/Al was increased. The release of benzoate from hydrotalcites also differed slightly among samples. Anticorrosion abilities of hydrotalcites intercalated with benzoate at a concentration of 3 g/L on carbon steel were analyzed using electrochemical impedance spectroscopy (EIS), polarization curve, energy-dispersive X-ray spectroscopy (EDX), and SEM. Corrosion inhibition abilities of benzoate modified hydrotalcites in 0.1 M NaCl showed an upward trend with increasing Zn/Al ratio. The reason for the dependence of corrosion resistance on the Zn/Al ratio was discussed, including changes in the microstructure of hydrotalcites such as crystal size, density, uniformity, and formation of ZnO.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2011.06a
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• pp.27-28
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• 2011

A solar flares have the 11-year cycle and release a large energy which may produce coronal mass ejections (CME). The NOAA (National Oceanic and Atmospheric Administration) predicted that the sun spot activity will be maximized in 2013-2014. A strong solar flare can cause the disturbance of global positioning system including various communication of TV, radio broadcasting. The actual solar storm in 1989 caused power outages in Canada during 9 hours and about 600 million people had experienced a blackout. Such a solar storm can shorten the GPS satellite's life span about 5 to 10 years which can be resulted in economic loss considering the amount of multi-billion won. This paper analyzed the recent solar storm of X-class occurred on 15th of February about 10:45 this year that was reached Korea (Bohyun observatory) on 18th of February about 10:30 (local time), and compared with the data of before and after a week. The proton data of 18th of February considered that the solar strom reached on earth showed a fluctuation compared to the data of before and after a week. The positioning results at Daejeon also showed higher positioning error compared to the data of before and after a week results.

• Journal of Navigation and Port Research
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• v.35 no.6
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• pp.477-482
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• 2011

Solar flares have the 11-year cycle and release a large energy which may produce coronal mass ejections (CME). The NOAA (National Oceanic and Atmospheric Administration) predicted that the sun spot activity will be maximized in 2013-2014. A strong solar flare can cause the disturbance of global positioning system including various communication of TV, radio broadcasting. The actual solar storm in 1989 caused power outages in Canada during 9 hours and about 600 million people had experienced a blackout. Such a solar storm can shorten the GPS satellite's life span about 5 to 10 years which can resulted in economic loss considering the amount of multi-billion won. This paper analyzed the influence of recent X-class solar storm occurred on 15th of February about 10:45 this year that was reached Korea (Bohyun observatory) on 18th of February about 10:30 (01:30 - UTC), and compared with the data before and after a week. The proton data of 18th of February considered that the solar storm reached on earth showed a fluctuation compared to the data before and after a week. The positioning results at Daejeon and Seoul of Korea also showed higher positioning error compared to the data before and after a week results.

• Journal of the Korea Organic Resources Recycling Association
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• v.23 no.2
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• pp.36-46
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• 2015

Integration of crop-livestock farming has been a problem-solving mode for abatement of environmental pollution and recovery of resources in recent years. The objectives of this study were 1) to suggest the customized integration of crop-livestock farming model reflecting the regional characteristics through in-depth analysis of case study and 2) to analyze the livestock nutrients flow in terms of three primary elements as nitrogen(N), phosphorous(P), and potassium(K). The personal interview and survey were carried out in 2012 for a total of 161 farms from four different regions(NS, NW, JJ, YC) in South Korea. The mass balance analysis was used to suggest and evaluate the models for two sites(JJ and YC). The results showed that NS and NW sites produced relatively more livestock manure than the sites of YC and JJ because of the regional differences in livestock numbers and urbanization. The models were suggested for the site JJ and site YC, and 'two track model(energy and resource recovery)' and 'dispersal type model' were assigned respectively. For the nutrient flows, the releasing P and K with new models had increased up to 7%, while N release had decreased down to 15% in both YC and JJ sites compared to the present treatment system. Estimated value showed that there was oversupply of N (719 ton/yr) and $P_2O_5$ (1,269 ton/yr) in YC and deficiency of N (671 ton/yr) and excessive $P_2O_5$ (32 ton/yr) in JJ respectively. Therefore, P runoff has to be considered an eutrophication occurs in rural small stream when an integration of crop-livestock farm system is applied into both sites.