• Title/Summary/Keyword: Mambrane

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Thallium(Ⅰ)-Selective Membrane Potentiometric Sensor Based on Dibenzyldiaza-18-Crown-6

  • Khayatian, Gholamreza;Shariati, Satar;Salimi, Abdollah
    • Bulletin of the Korean Chemical Society
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    • v.24 no.4
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    • pp.421-425
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    • 2003
  • A new thallium(Ⅰ) selective electrode based on dibenzylidaza-18-crown-6 as mambrane carrier was successfully prpared. The electrode exhibitis a near-Nernstian response for $ T1^+$ ions over a wide concentration range from $1.0×10^{15}-1.0×10^{-1}$M at 25℃, and was found to be selective, precise and useable within the pH range 4.0-11.0. The electrode was successfully used as an indicator electrode in potentiometric titration of thallium ions.

Hydrogen Impurities Analysis From Proton Exchange Membrane Hydrogen Production (양자교환막을 이용하여 생산된 수소의 불순물 분석)

  • Lee, Taeckhong;Kim, Taewan;Park, Taesung;Choi, Woonsun;Kim, Hongyoul;Lee, Hongki
    • Journal of Hydrogen and New Energy
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    • v.24 no.4
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    • pp.288-294
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    • 2013
  • This gas analysis data come from the hydrogen which is produced by proton exchange membrane. Main impurities of hydrogen are methane, oxygen, nitrogen, carbon monoxide, and carbon dioxide. The concentration of impurities is ranged between 0.0191 to $315{\mu}mol/mol$ for each impurity. Methane contamination is believed from the electrode reaction between carbon doped electrode and produced hydrogen. Nitrogen contamination should take place the sampling process error, not from PEM hydrogen Production system.

RESEARCH PAPERS : THE KINETICS ON THE BIOLOGICAL REACTION IN MEMBRANE BIOREACTOR (MBR) WITH GRAVITATIONAL AND TRANSVERSAL FILTRATION

  • Jang, Nam-J.;Hwang, Moon-H.;Yeo, Young-H.;Shim, Wang-G.;S. Vigneswaran;Kim, In-S.
    • Environmental Engineering Research
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    • v.9 no.5
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    • pp.238-247
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    • 2004
  • The objective of this study was to develop kinetic model for the MBR and investigate kinetic characteristics of the gravitational flow transverse direction MBR system. Kinetic model was derived by mass balance of substratc and biomass combined with empirical membranc filtration rerm for the MBR. To find kinctic values, permeale flux and COD removal were analyzed through the laboratory, MBR operation as different solids retention times. Permeate flux was ranged 2.5-5.0 LMH (L/m$^2$/hr) as sludge characteristics in each run. Although the soluble COD in the bioreactor was changed, the effluent COD was stable as average 99% removal rate during the experimental periods. Y$_g$ of this MBR system was higher than those of cross-flow MBR processes. The kinetics of this MBR showed that smaller k, larger b, and larger K$_s$ values than the conventional activated sludge process. These results indicated that substrate was used for cell maintenance rather than growth in this MBR system.

EVALUATION OF BIODEGRADABILITY, BIOCOMPATIBILITY AND TISSUE REGENERATIVE CAPACITY OF SYNTHETIC BIODEGRADABLE MEMBRANES IN BEAGLE DOGS (수종의 생분해성 차폐막의 생채분해도, 생채친화도 및 조직재생유도 능력에 관한 실험적 연구)

  • Seol, Y.J.;Kim, T.I.;Lee, J.I.;Bae, C.M.;Lee, S.J.;Chug, C.P.
    • Journal of Periodontal and Implant Science
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    • v.25 no.3
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    • pp.603-613
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    • 1995
  • The purpose of this investigation was to evaluate on the biodegradability, biocompatibility and tissue regenerative capacity of synthetic bioabsorbable membranes in beagle dogs. For animal study, 9 adult beagle dogs were used to examination, on the surgical implantation of membranes and histological analysis. In each animal, the 3rd and 4th premolars of the both sides of the mandible were selected as test teeth. Two types of bioresorbable membranes including "Guidor membrane", "S-membranes" were used to examining for biological activity, and also Gore-tex membranes was used for positive control. Surgically created defects were made in 2 premolars of both sides of the mandible at $3{\times}4mm^2$ in size and tested membranes were implanted in the defected area. A plaque control regimen was instituted with daily tooth brushing with a 0.1% chlorhexidine digluconate during experimental periods. All the experimental animals were sacrificed after 2, 4, and 8 weeks from surgery and undecalcified slides were prepared using the "sawing and grinding" technique described by Donath and Breuner". In biodegradability, all the membranes were started their biodegradation from two weeks after implantation and gradually demolished of their frame morphology from eight weeks. However, demolition of membranes in 8 weeks after implantation was highest in Guidor membranes and followed by S-membranes. Biocompatibilityof two kinds of biodegradable membranes including Guidor and S-mambrane were shown to be well tolerated to the surrounding tissue, and were minimal accumulation of inflammatory cell infiltration around the implanted membranes to compare with Gore-tex membrane. Regeneration of defected alveolar bone was initiated from two weeks of membrane implantation and new bone formation was gradually increased from that time. However, pattern of new bone formation on the defected areas of two kinds of biodegrable membranes was almost similar and quite competitive comparing with Gore-tex membrane. These results implicate that bioresorbable membranes should be highly useful tool for guided tissue regeneration of periodontal defects.

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