• 제목/요약/키워드: Maleic Anhydride

검색결과 257건 처리시간 0.025초

Sodium Bis(alkyl decaoxyethylene) Sulfonated Succinate류의 합성 (The Synthesis of Sodium Bis(alkyl decaoxyethylene) Sulfonated Succinates)

  • 이학봉;정노희;남기대
    • 한국응용과학기술학회지
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    • 제11권1호
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    • pp.61-70
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    • 1994
  • New anionic oligomeric surfactants, sodium bis(alkyl decaoxyethylene) sulfonated succinates, had been synthesized through the addition reaction of sodium hydrogen sulfite to bis(alkyl decaoxyethylene) maleates. Bis(alkyl decaoxyethylene) maleates were obtained by esterification with maleic anhydride and long chain alkyl decaoxyethylene ethers which were also obtained by addition ethylene oxide 10 mole to straight long chain alcohol with alkyl group having from 10 to 18 carbon atoms, their structure of the synthetic compounds have been characterized with IR. $^{1}H$ NMR and elemental analysis respectively.

Effects of High-Intensity Ultrasound & Supercritical Nitrogen on PP-MA Reactive Extrusion

  • Sohn, Chang-Hee;Shim, Dong-Chul;Lee, Jae-Wook
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.369-369
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    • 2006
  • Compatibilizers contribute to many processes in polymer industry, such as manufacturing polymer blends and composites. They are usually designed to be block or graft form which is combined in polar and non-polar parts in the first synthesis process level, for example, the general form of maleic anhydride (MA) as a compatiblizer is a grafted counterpart. However, the process of making the compatibilizer is related to the first synthesis level and it has some problems, such as high cost, poor processability, limitation on use and properties, and so on. So, in order to improve its poor processability and overcome the limitation on use, we developed compatibilizers which have various chemical forms by high intensity ultrasound and super critical fluid nitrogen in polymer melt reactive extrusion.

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Effects of a Compatibilizer on the Tensile Properties of Low-Density Polyethylene/Modified Starch Blends

  • Park, Jin-Woo;Kim, Gue-Hyun;Moon, Jin-Bok
    • 한국환경과학회지
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    • 제22권10호
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    • pp.1287-1294
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    • 2013
  • In this study, thermoplastic starch (TPS), cross-linked starch (CS), and cross-linked starch modified with glycerol (CTPS) were prepared, and the mechanical properties of the compatibilized low-density polyethylene (LDPE) blends (LDPE/TPS, LDPE/CS, and LDPE/CTPS) were investigated and compared with those of uncompatibilized LDPE/TPS, LDPE/CS, and LDPE/CTPS blends. Maleic-anhydride-grafted polyethylene was used as the compatibilizer. The enhanced tensile strength and elongation at break for the compatibilized LDPE/modified starch blends are a result of the improved compatibility between LDPE and the modified starch, which was confirmed by torque measurements and scanning electron microscopy.

적분형 구성방정식을 이용한 폴리프로필렌/층상 실리케이트 나노복합재료의 유변학적 특성 분석 (Rheological Characterization of Polypropylene/Layered Silicate Nanocomposites Using Integral Constitutive Equations)

  • 이승환;윤재륜
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2005년도 추계학술발표대회 논문집
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    • pp.137-140
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    • 2005
  • Exfoliated nanocomposites of polypropylene/layered silicate were prepared by a melt compounding process using maleic anhydride modified polypropylene (PP-g-MAH) and organoclay. It was found that polypropylene/layered silicate nanocomposites exhibited remarkable reinforcement compared with the pure polypropylene or conventional composite filled with agglomerated organoclay. The polypropylene /layered silicate nanocomposites showed stronger and earlier shear thinning behaviors and outstanding strain hardening behavior than pure polypropylene or other conventional composites in shear and uniaxial elongational flows, respectively. We simulated rheological modeling for the pure polymer matrix and polypropylene/layered silicate nanocomposite in shear and elongational flows using K-BKZ integral constitutive equation. The two types of K-BKZequations have been examined to describe experimental results of shear and uniaxial elongational viscosities of pure polypropylene and polypropylene/layered silicate nanocomposite.

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Synthesis and Anti-inflammatory Activity of [2-(Benzothiazol-2-ylimino)-4-oxo-3-phenylthiazolidin-5-yl]-acetic Acid Derivatives

  • Sushilkumar S. Bahekar;Devanand B. Shinde
    • 대한화학회지
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    • 제47권3호
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    • pp.237-240
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    • 2003
  • 소염작용을 가진 일련의 싸이아졸리딘아세트산 유도체들을 싸이오유레아와 말레산무수물로부터 합성하고 분광학적인 방법으로 구조를 확립하였다. 또한 이 화합물들의 소염작용을 표준시약인 디클로펜악 소듐과 비교한 결과 어느정도의 효과를 가지고 있음을 검정하였다.

Changes in Functional Properties of Casein by Different Chemical Modifications

  • Kim, Il-Sung;Choi, Jin-Ho;Hong, Jeong-Hwa
    • Preventive Nutrition and Food Science
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    • 제2권1호
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    • pp.17-22
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    • 1997
  • Casein was chemically modified with acetic, succinic, and maleic anhydride and changes in functional pro-perties were evaluated as affected by the degree of modification. Chemical modification resulted in casein with unique functional properties depending upon the type of anhydrid used and the degree of modification. It was possible to control heat coagulation, calcium precipitability, forming and emulsion capacity and stability. At pH 4.5 heat coagulation was 0% in the case 74.1% acetylated casein; on the contrary, succinylation and maleyation resulted in highly heat sensitive protein. Foaming properties were improved markedly by suc-cinylation and maleylation at pH 4.5. However, emulsifying properties were enhanced only by maleylation.

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가소화 처리 목편으로부터 재조된 복합재료의 물성 (Properties of WPC with Chemical Modified Wood Particles)

  • 김철현;김강재;엄태진
    • 펄프종이기술
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    • 제40권3호
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    • pp.53-58
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    • 2008
  • Wood composite, could generally be made from very fine wood powder(<150 mesh) because more large size of wood particle had much less plasticity compared of polymer. To make more high plasticity of relatively large size of wood particle, wood particles were chemically modified with some reagent for acetylation and esterification, etc. WPC(wood plastic composite) was prepared with chemically modified wood particles and the mechanical properties of WPC were evaluated. WPC of esterified wood with maleic anhydride shows the highest level in tensile strength and breaking elongation.

XLPE 절연케이블내 금속성 불순물이 절연파괴에 미치는 영향 (Effects of Dielectric Breakdown in XLPE Insulation Cables by Metal Impurities)

  • 이우선;최창주;정용호;김남오;김정구;김상준
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1997년도 하계학술대회 논문집 C
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    • pp.1196-1198
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    • 1997
  • In this work, simultaneous measurement such as change distribution and electrical conduction of maleic anhydride grafted XLPE was investigated. Heterocharge was found in XLPE and it decreased with increasing MAR graft ratio in XLPE-g-MAH. Conduction currents also decreased with increasing MAR graft ratio. The relationship between the space change behavior and the electrical conduction characteristics in XLPE-g-MAH is discussed.

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Thermal and Dynamic-Mechanical Characterization of Rice-Husk Filled Polypropylene Composites

  • Rosa, Simone M.L.;Nachtigall, Sonia M.B.;Ferreira, Carlos A.
    • Macromolecular Research
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    • 제17권1호
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    • pp.8-13
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    • 2009
  • Natural fiber-filled polymer composites have attracted great interest due to increasing environmental concerns and their low costs. In this study, the properties of rice husk flour-filled polypropylene (PP) were analysed in view of the large quantities of this agricultural product available as residue in Brazil. The rice husk flour (RHF) was characterized by SEM and particle size distribution. The properties of the composites were studied by MFI, DMA, DSC and TGA analyses. A commercial PP modified with maleic anhydride (MAPP) was used as coupling agent. It was verified that RHF decreased the MFI of the composites and that the coupling agent decreased it even more. The efficiency of MAPP was confirmed by the high storage modulus and high loss factor of the coupled composites.