• 제목/요약/키워드: Malachite Green

검색결과 99건 처리시간 0.019초

밀양 국전광산의 녹-청색 구리-아연 수화황산염 광물 (Green-blue Coloured Cu-Zn Hydrated Sulfate Minerals from Gukjeon Mine in Miryang)

  • 구효진;장정규;도진영;정기영;조현구
    • 자원환경지질
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    • 제51권6호
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    • pp.473-483
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    • 2018
  • 경남 밀양시에 소재한 납-아연 스카른 광상인 국전광산의 갱내 벽면을 따라 지하수로부터 침전된 청-녹색의 광물들이 암반을 피복하고 있는데, 이 광물들은 과거 문헌에서 남동석과 공작석으로 기재되어 왔으나, 최근 연구를 통해 녹색의 광물은 데빌린(devilline), 청색의 광물은 수화구리아연황산염 광물들로 보고되었다. 그러나 자세한 연구가 이루어지지 않아 정확한 동정이나 광물학적 특성은 알려지지 않았다. 본 연구에서는 청-녹색 이차 광물들을 외형적 특징에 따라 5개 그룹으로 구분하고, X-선회절분석와 주사전자현미분석을 실시하여 정확한 광물 동정과 광물학적 특성을 규명하였다. GJG-1은 밝은 청록색을 띠는 그룹으로 브로칸타이트(brochantite)와 석영, GJG-2는 연두색을 띠며 쉽게 부스러지는 특징을 가지는 그룹으로 슐럼버가이트(schulenbergite)와 소량의 석고(gypsum)로 확인되었다. 연한 청색의 GJG-3와 유리광택을 가지는 청록색의 GJG-4는 외형적 특징은 달랐지만 구성 광물은 서피어라이트(serpierite)와 석고로 동일하고, 석고의 함량이 달라 특징이 다르게 나타난다. GJG-5는 연한 청색과 진한 청색의 광물들이 혼합된 겔(gel)상으로 하이드로우드워다이트(hydrowoodwardite), 글로코세리나이트(glaucocerinite), 베체러라이트(bechererite), 서피어라이트와 석고로 구성된다. 국전광산에서 산출되는 6가지의 녹-청색 광물들은 Cu:Zn 비, (Si+Al) 함량 및 Si:Al 비, Ca 함량 등에 의해 구분될 수 있으며, 각 광물들의 형성 환경은 주변 유체 내에서 이와 같은 지화학적 요인들에 의하여 조절된 것으로 사료되고, 추가적인 연구를 통해 정확한 형성 환경을 밝혀낼 수 있을 것으로 기대된다. 본 연구에서 확인된 서피어라이트, 글로코세리나이트, 베체러라이트 등의 수화황산염 광물들은 국내에서 최초로 보고되며, 해외에서도 보고된 사례가 매우 적어 광물학적으로 큰 의의가 있다.

우리나라 내수면 양식업의 현황 및 발전방향에 관한 소고 (The current status and future directions of Korean inland freshwater aquaculture)

  • 이정삼;김대영
    • 수산경영론집
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    • 제37권3호
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    • pp.1-24
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    • 2006
  • In terms of the size of aquaculture farms and production volume, inland freshwater aquaculture is much smaller than marine aquaculture in Korea. However, freshwater aquaculture provides fish which is not produced in the sea. Freshwater aquaculture plays an important role in the efficient use of resources, development of local areas and economy vitalization in under - developed areas. freshwater aquaculture also helps ecosystem recovery by stocking farmed fry. As addressed above, inland freshwater aquaculture plays various roles and can not be ignored. However, freshwater aquaculture has been off the interest of fisheries authority. Considering a series of changes in the circumstances such as the government's disapproval of pen - raised aquaculture, higher standard for discharged water from aquaculture farms and a rapid increase in import of low price fish from other countries, it is difficult to expect the quantitative expansion of the freshwater aquaculture any more. Furthermore, freshwater aquaculture lost the trust of people because of the use of Malachite green, and the consumption of farmed product plummeted last year. Even though it would be difficult to expect the quantitative expansion, we could expect qualitative growth and let the inland freshwater aquaculture keep playing the own roles. In order to achieve competitive advantage and regain the trust by providing safer farmed product, the government's support and freshwater aquaculture industry's active and voluntary efforts are very important. This paper suggests several points for the future oriented inland freshwater aquaculture in Korea such as strategic intensive development of selected species, the technical improvement and its diffusion, increased cooperation among the government authority, industry and scientists.

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삼칠근(三七根)의 형태(形態)에 관한 연구(硏究) (A Study on a Morphological Identification of Notoginseng Radix)

  • 문성호;이영종
    • 대한본초학회지
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    • 제23권2호
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    • pp.25-31
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    • 2008
  • Objectives : In order to distinguish morphological characteristics of trunk bark and root bark of Ulmus davidiana var. japonica (Rehder) Nakai and the trunk bark and root bark of Hemiptelea davidii Planchon were sampled and compared in terms of their external and internal features with flour states according to their medical use, through microscopic examination. Methods : The slice of the tested material made by paraffin section technique was colored with Safranine Malachite Green contrast methods, and the flour of it was mounted by the liquid made by the same ratio of each of glycerin, acetic acid, and water, and then observed and photographed by olymphus-BHT. Results : 1. Internal Features 1) A large parenchymatous cell was observed in the phloem of the slice of both trunk bark and root bark of Ulmi Cortex, However, both of the trunk bark and root bark of Hemipteleae Cortex did not have parenchymatous cell in the phloem; instead, stone cells including much square crystal of calcium oxalate were distributed around fiber bundle, and the parenchymatous cell included much druse crystal of calcium oxalate. 2) In both the Ulmi Cortex and Hemipteleae Cortex, rhytidome was observed in trunk bark, but not in root bark, but in the parenchymatous cell of the root bark of the Ulmi Cortex contained starch grain. 2. Flour States 1) In the flour of root bark of the Ulmi Cortex, a large parenchymatous cell was observed. However, in the flour of trunk bark and root bark of Hemipteleae Cortex, no parenchymatous eel was found; instead, stone cell including square crystal of calcium oxalate and druse crystal of calcium oxalate were observed. 2) There was no remarkable difference between the trunk bark and root bark of Hemipteleae Cortex. However, starch grain was contained in the parenchymatous cell of the root bark of Ulmi Cortex but not in the trunk bark of it. Conclusions : There were some morphological differences in external, internal, and flour parts of Ulmi Cortex and Hemipteleae Cortex. In particular, there was a morphological difference in flour states between the trunk bark and root bark of Ulmi Cortex, it is possible to use microscope to distinguish their flour states.

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황금(黃芩)의 형태(形態)에 관한 연구(硏究) (A Study on a Morphological Identification of Scutellariae Radix)

  • 김호선;한효상;이영종
    • 대한본초학회지
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    • 제23권2호
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    • pp.33-40
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    • 2008
  • Objectives : In order to distinguish morphological characteristics, because the inside portion of the root bark of Scutellariae Radix decomposes as time goes by, 2nd, 3rd, and 5th year Scutellariae Radix were sampled and compared according to their external, internal, and flour states through optical microscope. Methods : The slice of the tested material made by paraffin section technique was colored with Safranine Malachite Green contrast methods, and the flour of it was mounted by the liquid made by the same ratio of each of glycerin, acetic acid, and water, and then observed and photographed by olymphus-BHT. Results : 1. The inside of 2nd year Scutellariae Radix was rich and golden, the transverse section of Scutellariae Radix that was 3rd years of age was golden, but there were many Scutellariae Radix whose center portion turned redish brown, and the center portion of 5th year Scutellariae Radix had been decomposed or empty. 2. 2nd year Scutellariae Radix had the most starch grain, 5th year Scutellariae Radix had the least, and the middle portion of xylem that was 5 years of age had a cell ring that was corkish, but 2nd and 3rd year Scutellariae Radix did not have it. 3. In the flour state, 2nd, 3rd, and 5th year Scutellariae Radix did not have any difference, but the amount of starch grain was the most in 2nd year Scutellariae Radix and the least in 5th year Scutellariae Radix.

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Biochemical and Molecular Characterization of Laccases from Wild Mushrooms

  • Ro, Hyeon-Su
    • 한국균학회소식:학술대회논문집
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    • 한국균학회 2014년도 춘계학술대회 및 임시총회
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    • pp.43-43
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    • 2014
  • White rot fungi have been useful source of enzymes for the degradation of environmental pollutants including polycyclic aromatic hydrocarbons (PAHs) and synthetic dyes. PAHs are widespread organic compounds present in fossil fuels and are routinely generated by incomplete fuel combustion. PAHs are some of the major toxic pollutants of water and soil environments. Synthetic dyes are major water-pollutants, which are toxic to organisms in water environments and interfere photosynthesis of water plants. Removal of PAHs and synthetic dyes has been of interests in the environmental science especially in the environmental microbiology. Mushrooms are fungal groups that function as primary degraders of wood polyphenolic lignin. The ligninolytic enzymes produced by mushroom, including manganese peroxidase, lignin peroxidase, and laccase, mediate the oxidative degradation of lignin. The catalytic power of these enzymes in the degradation of aromatic ring compounds has been sought for the degradation of various organic compounds. In this project, we have screened 60 wild mushroom strains for their degradation activity against two representative PAHs, naphthalene and anthracene, and five aromatic dyes, including alizarin red S, crystal violet, malachite green, methylene blue, rose bengal. The degradation of PAHs was measured by GC while the decolorization of dyes was measured by both UV spectrophotometer and HPLC. As results, 9 wild mushroom strains showed high activity in degradation of PAHs and textile dyes. We also describe the secretive enzyme activities, the transcription levels, and cloning of target genes. In conjunction with this, activities of degradative enzymes, including laccase, lignin peroxidase, and Mn peroxidase, were measured in the liquid medium in the presence of PAHs and dyes. Our results showed that the laccase activity was directed correlated with the degradation, indicating that the main enzyme acts on PAHs and dyes is the laccase. The laccase activity was further simulated by the addition of $Cu^{2+}$ ion. Detailed studies of the enzyme system should be sought for future applications.

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반하(半夏), 수반하(水半夏) 및 천남성(天南星)의 형태(形態) 감별에 관한 연구 (A Study on a Morphological Identification of Pinelliae Tuber, Typhonii Flagelliformis Rhizoma and Arisaematis Rhizoma)

  • 최영성;길기정;이영종
    • 대한본초학회지
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    • 제22권2호
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    • pp.103-108
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    • 2007
  • Objectives : A morphological classification among Pinelliae Tuber, Typhonii Flagelliformis Rhizoma and Arisaematis Rhizoma was made through microscopic observation. Method : The slice of the tested material made by paraffin section technique was colored with Safranine Malachite Green contrast methods, and then observed and photographed by olymphus-BHT. Result : 1. Pinelliae Tuber is like a ball with a $1{\sim}1.5cm$ diameter, with a concave apex and pockmarked root trace around. 2. Typhonii Flagelliformis Rhizoma is somewhat oval or like a cone, with a $4{\sim}8mm$ diameter, a $7{\sim}15mm$ height, a projected round apex, and a pin-pointed back. 3. Arisaematis Rhizoma is somewhat flat round with a $2{\sim}2.5cm$ diameter, a little than Pinelliae Tuber, and its apex has incomplete lobopodium and root trace. 4. Fundamental tissues of Pinelliae Tuber, Typhonii Flagelliformis Rhizoma, and Arisaematis Rhizoma have starch grains and mucilage cells, and their mucilage cells include the raphides of calcium oxalate. Conclusion : Internal forms of Pinelliae Tuber, Typhonii Flagelliformis Rhizoma, and Arisaematis Rhizoma are difficult to distinguish from one another, but Pinelliae Tuber and Arisaematis Rhizoma can be distinguished by their external forms and sizes, and Pinelliae Tuber and Typhonii Flagelliformis Rhizoma were distinguished by the forms of apex.

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천궁(川芎)의 형태(形態)에 관한 연구(硏究) (A Study on a Morphological Identification of Cnidium Rhizome and Ligusticum Rhizome)

  • 최정국;임덕빈;이영종
    • 대한본초학회지
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    • 제20권4호
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    • pp.95-101
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    • 2005
  • Objectives : In order to distinguish Cnidii Rhizoma and Ligustici Chuanxiong Rhizoma (cultivated in Korea and China), their external and internal states were observed via microscopic examination. Methods : The slice of the tested material made by paraffin section technique was colored with Safranine Malachite Green contrast methods, and then observed and photographed by olymphus-BHT. Results : Cnidii Rhizoma, Ligustici Chuanxiong Rhizoma (from Korea), and Ligustici Chuanxiong Rhizoma (from China) all demonstrated similar patterns as following : 1. external form 1) showing irregular nodular form with $2{\sim}7cm$ diameter. 2) having several trochites in parallel, and nodulose root trace on surface. 3) in addition to yellow-white or yellow-gray intersections, yellow-brown oil sacs were distributed, with cambium resembling a form of annulus. 2. internal form 1) its root and rhizome is composed of 10 layers of cork, with narrow cortical layers. 2) its phloem is wide, and oval light yellow-brown oil sacs are distributed around. The closer to the cambium, the smaller it is. 3) cambium is a form of a wave-like ring or an irregular polygon. 4) xylem and vessel are rare, most of which are arranged in a 'V' format, and sometimes xylem fiber is found. 5) pith is composed of parenchymatous cell, and parenchyma is full of starch grains. Conclusions : In conclusion, C officinale, L. chuanxiong (from Korea), and L. chuanxiong (from China) have rhizomes in a similar form with no special difference. Therefore, it is concluded that C. officinale, L. chuanxiong (from Korea), and L. chuanxiong (from China) are categorized into the same species.

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인천 유통 수산물 중 잔류동물용의약품 조사 (Monitoring of Residual Veterinary Drugs in Incheon Fishery Products Distribution)

  • 장진섭;허명제;김명희;한영선;권성희;여은영;홍성희;김지선;이승리
    • 한국환경보건학회지
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    • 제44권5호
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    • pp.444-451
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    • 2018
  • Objectives: This study was carried out to provide safe seafood to the public through simultaneous analysis rapid inspections for residual veterinary drugs in 150 fishery products in 2016. Methods: Quinolones (9), Sulfonamides (14), Penicillins (2), Cephalosporins (3), Tetracyclines (4), Macrolides (4), Lincosamides (2), Pleuromutilin (1), Phenicols (4), benzylpyrimidines (2), Others (1) Malachite green (2), and Melamine (1) were analyzed for 49 species using by HPLC and HPLC-MSMS. Results: There were six unsuitable samples, five among fish and one for crustaceans. Within the standard detection were five fish. The antibiotics found were Quinolones (50%), Tetracyclines (33%) and Penicillins (17%). Conclusions: As a result of the experiment, there were six unsuitable samples, five for fish and one for crustaceans. The most prevalent antibiotics were Quinolones. The quinolone antibiotics are highly persistent in fish tissues, so they require more time than the withdrawal period for other common veterinary drugs. Careful attention is required when they are used in fish farms.

강활(羌活)의 형태(形態) 감별에 관한 연구 (A Study on a Morphological Identification of Ostericum Root)

  • 김성흠;길기정;이영종
    • 대한본초학회지
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    • 제21권2호
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    • pp.181-188
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    • 2006
  • Objectives : Southern, northern, and wild types of Osterici Radix, and Notopterigii Rhizoma et Radix imported from China are circulated in Korea. Morphological identification was attempted by comparing external and internal forms of these materials. Methods : The slice of the tested material made by paraffin section technique was colored with Safranine Malachite Green contrast methods, and then observed and photographed by olymphus-BHT. Results : 1. Southern type of Osterici Radix has short rhizome and many small and long roots, while northern type of it is mostly composed of rhizomes with little small reds and sometimes looks like bamboo because of the extention of the parts between joints. 2. Parenchymal cell of southern type of Osterici Radix is filled with starch grain, while that of nothern type includes less starch grain with lamination crossed on its cell wall. 3. Surface of root and rhizome of wild Osterici Radix has some marks of fibrous root raised in the form of nodule, but cultivated Osterici Radix does not have this kind of marks. 4. Notopterigii Rhizoma et Radix is mostly composed of rhizomes, and its form is similar to that of a silkworm or joints of bamboo. Parenchymal cell is filled with starch grains, and lamination is crossed on its cell wall but not salient. Conclusion : Southern, northern, and wild types of Osterici Radix, and Notopterigii Rhizoma et Radix circulated in Korea can be easily identified because of their differences in their external and internal forms.

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Maghnia 산 Montmorillonite 수용액으로부터 양이온 염료의 제거 비교연구 (Comparison Study on the Removal of Cationic Dyes from Aqueous Suspension of Maghnia Montmorillonite)

  • Elaziouti, A.;Laouedj, N.
    • 대한화학회지
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    • 제54권3호
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    • pp.300-309
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    • 2010
  • 대상 수용액으로부터 상업용 염료인 메틸렌 블루(MB)와 말라카이트 그린 옥살레이트(MG)의 제거를 위한 소듐-교환된 점토 입자의 흡착능을 다양한 실험조건에서 조사하였다. 용액의 pH, 교반 시간, 흡착물 농도, 흡착제 투여량 등의 효과를 조사하였다. pH 7, 298 K 조건에서 0.03 그람 점토를 사용한 경우 수용액으로부터 최대 > 90%의 염료가 제거되었다. 흡착과정은 빨랐으며 5분 내에 평형에 도달하였다. 사용된 염료들의 흡착반응에 대해 반응속도론 실험에서 유사 2차반응이 관찰되었고 실험 데이터와 잘 일치하였다. 흡착평형은 높은 회귀계수 $R^2$ > 0.98로 Langmuir 와 Dubini-Radushkevich (D-R) 등온에 따랐다. 이 D-R 모델로부터 평균자유에너지 $E_a$ 는 MB와 MG 염료에 대해 각기 3.779와 2.564가 이었으며, 이것은 물리적 흡착과 정에 해당된다.