• Title/Summary/Keyword: Makoto

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Synthesis, End-Functionalization and Characterization of Hyperbranched Polysiloxysilanes from $AB_3$ Type Monomer

  • Ishida, Yoshihito;Yokomachi, Kazutoshi;Seino, Makoto;Hayakawa, Teruaki;Kakimoto, Masa-aki
    • Macromolecular Research
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    • v.15 no.2
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    • pp.147-153
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    • 2007
  • Hyperbranched polysiloxysilanes (HBPSs), with a variety of terminal functional groups (vinyl, epoxy, carboxyl and hydroxyl), were synthesized by the self-polymerization of an $AB_3$ type monomer of tris(dimethylvinylsiloxy) silane, with subsequent end-functionalizations, such as epoxidation and radical addition reaction, respectively. The ratio of the $\alpha-and$ $\beta-addition$ linkages in the HBPS polymerized by hydrosilylation of the $AB_3$ monomer was found to be approximately 1 to 3. The thermal stability and solubility were affected by the terminal functional groups.

Basic Study on Quality Assurance of Concrete Structure by using Odor Sensor (후각센서 사용에 의한 콘크리트 구조물의 품질평가에 관한 기초적 연구)

  • Shirokado, Yoshitsugu;Kagaya, Makoto;Lee, Sang-Hun
    • 한국방재학회:학술대회논문집
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    • 2010.02a
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    • pp.42-42
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    • 2010
  • In order to assure the quality of concrete structure in construction process, the odor strength measured by using odor sensor was used to evaluate curing effect. Then, the compressive strength and odor strength in ordinary concrete N were shown in water curing(=standard curing), indoor and outdoor atmospheric curing condition. The difference between odor strength in the standard curing and that in each curing condition was defined as the difference in the odor strength. And the difference in odor strength in slag powder concrete BP cured in water curing(=standard curing) for different period before exposing in outdoor atmosphere in winter season were evaluated at the age of 14 days. A necessity to prolong the moisture curing for the slag powder concrete BP compared with the ordinary concrete N to obtain a required curing effect was shown by measuring the odor strength and long term compressive strength.

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Synthesis, Characterization and Enhanced Selectivity in RP-HPLC of Polar Carbonyl Group Embedded Poly (Vinyl Octadecanoate) Grafted Stationary Phase by Simple Heterogeneous "Graft from" Technique

  • Rana, Ashequl A.;Karim, Mohammad Mainul;Takafuji, Makoto
    • Bulletin of the Korean Chemical Society
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    • v.32 no.1
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    • pp.77-82
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    • 2011
  • A new high performance liquid chromatograpgy (HPLC) stationary phase that possesses an internal carbonyl functional group is synthesized by heterogeneous "graft from" method. This new stationary phase, poly (vinyl octadecanoate) grafted silica (Sil-2) is then characterized by different physico-chemical methods such as diffuse reflectance infrared fourier transform, suspension state $^1H$ NMR, solid state $^{13}C$ CP/MAS NMR, $^{29}Si$ CP/MAS NMR, elemental analysis and thermogravimetric analysis. Chromatographic properties of Sil-2 were evaluated under reversed phase condition by separating polycyclic aromatic hydrocarbons (PAHs) and comparing the chromatographic results with those on polymeric as well as monomeric octadecylated silica stationary phases.

Application of Ionic Liquids Based on 1-Ethyl-3-Methylimidazolium Cation and Fluoroanions to Double-Layer Capacitors

  • Ue, Makoto;Takeda, Masayuki
    • Journal of the Korean Electrochemical Society
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    • v.5 no.4
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    • pp.192-196
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    • 2002
  • Ionic liquids based on l-ethyl-3-methylimidazolium cation $(EMI^+)$ and inorganic or organic anions containing fluorine atoms were applied to electrolyte materials for double-layer capacitors. The double-layer capacitors composed of a pair of activated carbon electrodes and an ionic liquid selected from $EMIBF_4,\; EMINbF_6,\;EMITaF_6,\;EMICF_3SO_3,\;EMI(CF_3SO_2)_2N,\;and\;EMI(C_2F_5SO_2)_2N$ showed inferior low-temperature characteristics to those of a conventional nonaqueous electrolyte based on propylene carbonate (PC) solvent. On the other hand, the capacitor using $EMIF{\cdot}2.3HF$ showed excellent low-temperature characteristics due to its high conductivity at low temperatures, however, it had a lower working voltage $(\~2V)$ than the conventional nonaqueous counterpart $(\~3V)$.

Self-Alignment Ink-Jet Printed Light Emitting Devices and Light Emitting Seals

  • Okada, Hiroyuki;Matsui, Kenta;Naka, Shigeki;Shibata, Miki;Ohmori, Masahiko;Kurachi, Naomi;Sawamura, Momoe;Suzuki, Shin-Ichi;Inoue, Toyokazu;Miyabayashi, Takeshi;Murase, Makoto;Takao, Yuuzou;Hibino, Shingo;Bessho, Hisami
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.449-452
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    • 2009
  • Ink-jet printed (IJP) self-aligned (SA) organic light emitting diodes (OLEDs) and its application to light emitting seal have investigated. Ink-jet printing of light emitting material is carried out onto transparent anode covered with insulating material. Laminated light emitting seal with SA IJP OLED without photo - lithographic process and any vacuum process, noncontact type electromagnetic power supply without electric power supply line, and light emitting tag with network type RF communication terminal by controlling display information were demonstrated.

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Advanced Nanoimprinting Material for Liquid Crystal Alignment

  • Gwag, Jin-Seog;Oh-e, Masahito;Yoneya, Makoto;Yokoyama, Hiroshi;Satou, H.;Itami, S.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.534-537
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    • 2007
  • To promote liquid crystal application of nanoimprint lithography, a polymer with new concept is proposed. The material consists of a polyamic acid for good LC alignment and an epoxy resin for good imprinting. The result of sum-frequency generation (SFG) vibrational spectroscopy proves that this material is a functionally gradient material. This material shows excellent capability as a nanoimprinting material as well as an LC alignment layer.

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3D/BIM Applications to Large-scale Complex Building Projects in Japan

  • Yamazaki, Yusuke;Tabuchi, Tou;Kataoka, Makoto;Shimazaki, Dai
    • International Journal of High-Rise Buildings
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    • v.3 no.4
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    • pp.311-323
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    • 2014
  • This paper introduces recent applications of three-dimensional building/construction data modeling (3D) and building information modeling (BIM) to large-scale complex building construction projects in Japan. Recently, BIM has been utilized as a tool in construction process innovation through planning, design, engineering, procurement and construction to establish a front-loading-type design building system. Firstly, the background and introduction processes of 3D and BIM are described to clarify their purposes and scopes of applications. Secondly, 3D and BIM applications for typical large-scale complex building construction projects to improve planning and management efficiency in building construction are presented. Finally, future directions and further research issues with 3D and BIM applications are proposed.

A Study on the Automatic Counting Method of Number of Chlorella

  • Ota, Makoto;Sumi, Yasuaki;Yabuki, Noboru;Obote, Shigeki;Matsuda, Yoshitaka;Fukui, Yutaka
    • Proceedings of the IEEK Conference
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    • 2000.07b
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    • pp.789-792
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    • 2000
  • Marine chlorella (Nannochloropsis oculata) is cultivated at the fish farming association of experimental fishery laboratory. In the culture of the chlorella, it is necessary to count the number of chlorella in order to understand the condition of increase. For that purpose, we develop automatic chlorella counter using the image processing and the neural network. Its effectiveness is confirmed through the experiment.

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Microwave Dielectric Absorption Spectroscopy Aiming at Novel Dosimetry Using DNAs

  • Izumi, Yoshinobu;Hirayama, Makoto;Matuo, Youichirou;Sunagawa, Takeyoshi
    • Journal of Radiation Protection and Research
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    • v.42 no.1
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    • pp.21-25
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    • 2017
  • Background: We are developing L-band and S-band microwave dielectric absorption systems aiming novel dosimetry using DNAs, such as plasmid DNA and genomic DNA, and microwave technology. Materials and Methods: Each system is composed of a cavity resonator, analog signal generator, circulator, power meter, and oscilloscope. Since the cavity resonator is sensitive to temperature change, we have made great efforts to prevent the fluctuation of temperature. We have developed software for controlling and measurement. Results and Discussion: By using this system, we can measure the resonance frequency, f, and ${\Delta}Q$ (Q is a dimensionless parameter that describes how under-damped an oscillator or resonator is, and characterizes a resonator's bandwidth relative to its center frequency) within about 3 minutes with high accuracy. Conclusion: This system will be expected to be applicable to DNAs evaluations and to novel dosimetric system.