• Title/Summary/Keyword: Major ion analysis

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An Effective Defensive Response in Thai Aromatic Rice Varieties(Oryza sativa L. spp. indica) to Salinity

  • Cha-um, Suriyan;Vejchasarn, Phanchita;Kirdmanee, Chalermpol
    • Journal of Crop Science and Biotechnology
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    • v.10 no.4
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    • pp.257-264
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    • 2007
  • Rice is one of the world's staple crops and is a major source of carbohydrate. Rice is exported from several countries, providing a major source of income. There are many documents reporting that rice is a salt-sensitive crop in its developmental stages. The objective of this investigation is to evaluate the effective salt-tolerance defense mechanisms in aromatic rice varieties. Pathumthani 1(PT1), Jasmine(KDML105), and Homjan(HJ) aromatic rice varieties were chosen as plant materials. Rice seedlings photoautotrophically grown in-vitro were treated with 0, 85, 171, 256, 342, and 427 mM NaCl in the media. Data, including sodium ion$(Na^+)$ and potassium ion$(K^+)$ accumulation, osmolarity, chlorophyll pigment concentration, and the fresh and dry weights of seedlings were collected after salt-treatment for 5 days. $Na^+$ in salt-stressed seedlings gradually accumulated, while $K^+$ decreased, especially in the 342-427 mM NaCl salt treatments. The $Na^+$ accumulation in both salt-stressed root and leaf tissues was positively related to osmolarity, leading to chlorophyll degradation. In the case of the different rice varieties, the results showed that the HJ variety was identified as being salt-tolerant, maintaining root and shoot osmolarities as well as pigment stabilization when exposed to salt stress or $Na^+$ enrichment in the cells. On the other hand, PT1 and KDML105 varieties were classified as salt-sensitive, determined by chlorophyll degradation using Hierarchical cluster analysis. In conclusion, the HJ-salt tolerant variety should be further utilized as a parental line or genetic resource in breeding programs because of the osmoregulation defensive response to salt-stress.

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Characteristics of Nitrate Concentration Measured at Gosan: Measurement Data of PM2.5 and TSP between 1998 and 2002 (고산에서 측정한 입자상 질산염 농도 특성: 1998∼2002년 PM2.5와 TSP 측정자료)

  • 김나경;김용표;강창희;문길주
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.1
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    • pp.119-128
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    • 2004
  • The nitrate concentrations in PM$_{2.5}$ and TSP measured at Gosan, Jeju Island, Korea, between March 1998 and February 2002, are discussed. Especially, the characteristics of high nitrate concentration days were analyzed. High nitrate concentration cases in PM$_{2.5}$ were highly correlated with anthropogenic species such as NH$_4$$^{[-10]}$ , and high nitrate concentration cases in TSP were highly correlated with crustal species such as nss-Ca$^{2+}$ and nss -Mg$^{2+}$ Backward trajectory analysis results show the cases of high correlation between nitrate and anthropogenic species occurred when the air parcels moved from China, and the cases of high correlation between nitrate and crustal species occurred when the air parcels moved from Mongolia. Also, high nitrate concentration cases occurred most often in spring (65%) when the air parcels moved from Mongolia and China.ina.

Characteristics study II of biological materials using pyrolysis-mass spectrometry (열분해 질량분석법을 이용한 생물학 물질의 특성 연구(II))

  • Choi, Sun-Kyung;Park, Young-Kyu;Park, Byeng-Hwang
    • Journal of the Korea Institute of Military Science and Technology
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    • v.8 no.3 s.22
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    • pp.83-91
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    • 2005
  • Pyrolysis-mass spectrometry has been used to characterize the 17 biological materials including bacteria and proteins. In this study, an in situ thermal-hydrolysis methylation(THM) procedure using tetramethylammonium hydroxide(TMAH) was employed. The biological materials are ionized using chemical ionization(CI) method with ethanol by ion trap mass spectrometer(ITMS), which attached with our own made pyrolyzer module, and then their pyrolysis mass spectra were obtained. The major distinct characteristic peaks were selected from all the range of mass spectra, and analyzed using principal component analysis(PCA) method to assess the classification/identification possibility of biological materials.

Modelling of Grain Boundary in Polysilicon Film for Photodetector Through Current-Voltage Analysis (광검출기용 다결정 실리콘 박막의 전도특성 분석을 통한 결정립계의 모형화)

  • Lee, Jae-Sung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.4
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    • pp.255-262
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    • 2020
  • Grain boundaries play a major role in determining device performance, particularly of polysilicon-based photodetectors. Through the post-annealing of as-deposited polysilicon and then, the analysis of electric behavior for a metal-polysilicon-metal (MSM) photodetector, we were able to identify the influence of grain boundaries. A modified model of polysilicon grain boundaries in the MSM structure is presented, which uses a crystalline-interfacial layer-SiOx layer- interfacial layer-crystalline system that is similar to the Si-SiO2 system in MOS device. Hydrogen passivation was achieved through a hydrogen ion implantation process and was used to passivate the defects at both interfacial layers. The thin SiOx layer at the grain boundary can enhance the photosensitivity of an MSM photodetector by decreasing the dark current and increasing the light absorption.

pH Variance Model Depending on Phosphate Ion Form (인산염 이온 형태에 의한 pH 변량 모형)

  • Soh, Jae-Woo;Soh, Soon-Yil;Nam, Sang-Yong
    • Horticultural Science & Technology
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    • v.33 no.6
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    • pp.854-859
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    • 2015
  • This experiment was performed to develop a model for nutrition ion concentration and EC in regard to change in pH from 4.0 to 8.0 in nutrient solution. The pH changes according to the variation of $HPO_4{^{-2}}$ and $H_2PO_4{^-}$ in the nutrient solution while variation of EC increased from pH 4.0 to 5.0, stabilized from pH 5.0 to 7.0 and increased again from pH 7.0 to 8.0. For the variance of major elements in the nutrient solution, K, Ca, N and P increased while pH was higher, especially the variables for K and P were increased largely. On the other hand, variables of Mg and S were stable. Based on analysis of the ion balance model of nutrient solution, the cation increased than anion over rising the variation of pH while balance point of ion moved from a-side to d-side. In addition, the imbalance increased while it moved away from the EC centerline as variance of pH increased. It was larger than effect of EC variance to correction values of equivalence ratios of K and Ca about variation of $HPO_4{^{-2}}$ and $H_2PO_4{^-}$ while as variance of pH increased, K decreased but Ca increased. These showed the result that variance of pH about correction values of equivalence ratios of K and Ca gave a second-degree polynomial model rating of 0.97. Through this research, it was identified the pH variable model about variance among pH, ion and EC according to gradient of phosphate.

Investigation of the observed solar coronal plasma in EUV and X-rays in non-equilibrium ionization state

  • Lee, Jin-Yi;Raymond, John C.;Reeves, Katharine K.;Shen, Chengcai;Moon, Yong-Jae
    • The Bulletin of The Korean Astronomical Society
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    • v.43 no.1
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    • pp.53.1-53.1
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    • 2018
  • During a major solar eruption, the erupting plasma is possibly out of the equilibrium ionization state because of its rapid heating or cooling. The non-equilibrium ionization process is important in a rapidly evolving system where the thermodynamical time scale is shorter than the ionization or recombination time scales. We investigate the effects of non-equilibrium ionization on EUV and X-ray observations by the Atmospheric Imaging Assembly (AIA) on board Solar Dynamic Observatory and X-ray Telescope (XRT) on board Hinode. For the investigation, first, we find the emissivities for all the lines of ions of elements using CHIANTI 8.07, and then we find the temperature responses multiplying the emissivities by the effective area for each AIA and XRT passband. Second, we obtain the ion fractions using a time-dependent ionization model (Shen et al. 2015), which uses an eigenvalue method, for all the lines of ion, as a function of temperature, and a characteristic time scale, $n_et$, where $n_e$ and t are density and time, respectively. Lastly, the ion fractions are multiplied to the temperature response for each passband, which results in a 2D grid for each combination of temperature and the characteristic time scale. This is the set of passband responses for plasma that is rapidly ionized in a current sheet or a shock. We investigate an observed event which has a relatively large uncertainty in an analysis using a differential emission measure method assuming equilibrium ionization state. We verify whether the observed coronal plasmas are in non-equilibrium or equilibrium ionization state using the passband responses.

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Effects of Extraction Method on the Histidine Containing Low Molecular Weight Peptide and Pro-oxidants Contents of Tuna Boiled Extracts (참치자숙액 추출물 중의 히스티딘계 저분자 펩타이드 및 산화촉진물질 함량에 미치는 추출방법의 영향)

  • Kang, Ok-Ju
    • Korean journal of food and cookery science
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    • v.24 no.3
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    • pp.349-357
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    • 2008
  • In an effort to augment extractability of carnosine and anserine at the levels of pro-oxidants such as iron and protein in Tuna boiled extracts(Skipjack, Yellowfin and Bigeye), we assessed the effects of heated and ion exchange chromatography(IEC) and ultrafiltration(UF) using a MW 500 cut-off(500 MWCO). We also evaluated the antioxidant activity of these extracts processed as free radical scavengers and reducing agents. Tuna boiled extracts of dark and ordinary muscle protein and total iron were reduced, whereas carnosine and anserine concentrations and antioxidant activity were increased. The carnosine and anserine concentrations of the ion exchange and permeate UF(IEC-UF) extracts were higher than those observed in the heated and permeate UF(heat-UF), whereas the protein and total iron contents were lower than that observed in the heat-UF. The quantity of carnosine and anserine in ordinary muscle was higher than that detected in dark muscle. HPLC analysis and SDS-PAGE were shown to removes the effect of UF on high molecular weight impurities in the tuna boiled extracts. The major free amino acids(FFAs) from Skipjack, Yellowfin and Bigeye tuna IEC-UF extracts were anserine, histidine and carnosine. These three peptides constituted more than 80~85%. of the detected amino acid. The IEC-UF treated ordinary muscle extracts evidenced the highest levels of DPPH radical scavenging activity and the highest levels of reducing power among the various extracts. The IEC-UF extracts evidenced a DPPH radical scavenging effect equal to that of 1mM ascorbic acid.

Bioequivalence and Pharmacokinetics of Carvedilol (25mg) Tablets in Volunteers (카베딜롤(25mg)정제의 생물학적 동등성 및 약물동태연구)

  • 우수경;김호순;강종성;권광일
    • YAKHAK HOEJI
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    • v.45 no.6
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    • pp.650-655
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    • 2001
  • Carvedilol is a nonselective $\beta$-blocking agent with vasodilating properties that are attributed mainly to its blocking activity at $\alpha$$^{1}$-receptors. Carvedilol is used in the treatment of mild to moderate hypertention and angina pectoris and is often used in combination with other drugs. This study was carried out to evaluate the bioequivalence and pharmacokinetics of two carvedilol 25mg tablet formulations according to the guidelines of Korea Food and Drug Administration (KFDA). Twenty healthy volunteers are enrolled and received a single dose (25mg as carvedilol) of each drug in the fasting state, in a randomized 2-way crossover design. After oral administration, blond samples were collected for a period of 30 hours. Plasma concentrations of carvedilol were determined by a rapid and sensitive HPLC method with spectrofluorometric detection. The major pharmacokinetic parameters such as AU $C_{0-}$30hr/, AU $C_{inf}$ , $C_{max}$, $T_{max}$, $t_{1}$2 / Cl/F and V $_{\beta}$//F were calculated. ANOVA test and t-test were utilized for the statistical analysis of each parameter. The results showed that the differences in AU $C_{0-}$30hr/, $C_{max}$ and $T_{max}$ between two were ~5.66, 1.74 and 0.00%, respectively. Minimum detectable differences ($\Delta$) at $\alpha$=0.05 were less than$\pm$ 20% except $T_{max}$ (8.44, 18.36, and 33.86%, respectively). The 90% confidence intervals of all parameters were within $\pm$20% (-10.60~ -0.72, -9.00~12.49 and -19.81~19.81%, respectively). Therefore, it is concluded that the two formulations are bioequivalent for both the extent and the rate of absorption after single dose administration.ation.ion.ion.ation.ion.n.

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Chemical Composition of Respirable PM2.5 and Inhalable PM10 in Iksan City during Fall, 2004 (익산지역 가을철 대기 중 호흡성 및 흡입성 먼지입자의 화학조성)

  • Kang, Gong-Unn
    • Journal of Environmental Health Sciences
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    • v.36 no.1
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    • pp.61-71
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    • 2010
  • Intensive measurements of airborne respirable $PM_{2.5}$ and inhalable $PM_{2.5}$ were conducted in the downtown area of Iksan city. The $PM_{2.5}$ and $PM_{2.5}$ samples were collected twice a day in the Iksan city of Korea from October 17 to November 1, 2004. The purpose of the study was to determine the inorganic water-soluble components and trace elements of $PM_{2.5}$ and $PM_{2.5}$ in the atmospheric environment and estimate the contribution rate of major chemical components from a mass balance of all measured particulate species. The chemical analysis for PM samples was conducted for water-soluble inorganic ions using ion chromatography and trace elements using PIXE analysis. The mean concentrations of respirable $PM_{2.5}$ and inhalable $PM_{2.5}$ were $51.4{\pm}29.7$ and $79.5{\pm}39.6\;{\mu}g/m^3$, respectively, and the ratio was 0.62. The ion species of $NO_3$, $SO_4^2$, and $NH_4^+$ were abundant in both $PM_{2.5}$ and $PM_{2.5}$. These components predominated in respirable $PM_{2.5}$ fraction, while $Na^+$, $Mg^{2+}$, $Ca^{2+}$ mostly existed in coarse particle mode. Elemental components of S, Cl, K, and Si were abundant in both $PM_{2.5}$ and $PM_{2.5}$. These elements, except for Si, were considered to be emitted from anthropogenic sources, while Si, Al, Fe, Ca existed mainly in coarse particle mode and were considered to be emitted from crustal materials. The averaged mass balance analysis showed that ammonium nitrate, ammonium sulfate, crustal component, and other trace elements were composed of 18.4%, 13.2%, 4.8%, 3.5% for PM2.5 and 17.0%, 11.6%, 13.7%, 4.4% for $PM_{2.5}$, respectively.

Urban Nonpoint Source Pollution Assessment Using A Geographical Information System (GIS를 이용한 도심지 Nonpoint Source 오염 물질의 평가연구)

  • ;Stephen J. Ventura;Paul M. Harris;Peter G. Thum;Jeffrey Prey
    • Spatial Information Research
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    • v.1 no.1
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    • pp.39-53
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    • 1993
  • A geographical information systems(GIS) was a useful aid in the assessment of urban nonpoint source pollution and the development of a pollution control strategy. The GIS was used for data integration and display, and to provide data for a nonpoint source model. An empirical nonpoint source loading model driven by land use was used to estimate pollutant loadings of priority pollutant. Pollutant loadings were estimated at fine spatial resolution and aggregated to storm sewer drainage basins(sewershedsl. Eleven sewersheds were generated from digital versions of sewer maps. The pollutant loadings of individual land use polygons, derived as the unit of analysis from street blocks, were aggregated to get total pollutant loading within each sewershed. Based on the model output, a critical sewershed was located. Pollutant loadings at major sewer junctions within the critical sewershed were estimated to develop a mi t igat ion strategy. Two approaches based on the installat ion of wet ponds were investigated -- a regional approach using one large wet pond at the major sewer outfall and a multi-site approach using a number of smaller sites for each major sewer junction. Cost analysis showed that the regional approach would be more cost effective, though it would provide less pollution control.

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