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A Review on the Deposition/Dissolution of Lithium Metal Anodes through Analyzing Overpotential Behaviors (과전압 거동 분석을 통한 리튬 금속 음극의 전착/탈리 현상 이해)

  • Han, Jiwon;Jin, Dahee;Kim, Suhwan;Lee, Yong Min
    • Journal of the Korean Electrochemical Society
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    • v.25 no.1
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    • pp.1-12
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    • 2022
  • Lithium metal is the most promising anode for next-generation lithium-ion batteries due to its lowest reduction potential (-3.04 V vs. SHE) and high specific capacity (3860 mAh/g). However, the dendritic formation under high charging current density remains one of main technical barriers to be used for commercial rechargeable batteries. To address these issues, tremendous research to suppress lithium dendrite formation have been conducted through new electrolyte formulation, robust protection layer, shape-controlled lithium metal, separator modification, etc. However, Li/Li symmetric cell test is always a starting or essential step to demonstrate better lithium dendrite formation behavior with lower overpotential and longer cycle life without careful analysis. Thus, this review summarizes overpotential behaviors of Li/Li symmetric cells along with theoretical explanations like initial peaking or later arcing. Also, we categorize various overpotential data depending on research approaches and discuss them based on peaking and arcing behaviors. Thus, this review will be very helpful for researchers in lithium metal to analyze their overpotential behaviors.

Methodology for Classifying Hierarchical Data Using Autoencoder-based Deeply Supervised Network (오토인코더 기반 심층 지도 네트워크를 활용한 계층형 데이터 분류 방법론)

  • Kim, Younha;Kim, Namgyu
    • Journal of Intelligence and Information Systems
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    • v.28 no.3
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    • pp.185-207
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    • 2022
  • Recently, with the development of deep learning technology, researches to apply a deep learning algorithm to analyze unstructured data such as text and images are being actively conducted. Text classification has been studied for a long time in academia and industry, and various attempts are being performed to utilize data characteristics to improve classification performance. In particular, a hierarchical relationship of labels has been utilized for hierarchical classification. However, the top-down approach mainly used for hierarchical classification has a limitation that misclassification at a higher level blocks the opportunity for correct classification at a lower level. Therefore, in this study, we propose a methodology for classifying hierarchical data using the autoencoder-based deeply supervised network that high-level classification does not block the low-level classification while considering the hierarchical relationship of labels. The proposed methodology adds a main classifier that predicts a low-level label to the autoencoder's latent variable and an auxiliary classifier that predicts a high-level label to the hidden layer of the autoencoder. As a result of experiments on 22,512 academic papers to evaluate the performance of the proposed methodology, it was confirmed that the proposed model showed superior classification accuracy and F1-score compared to the traditional supervised autoencoder and DNN model.

A Study on the Ecological Characteristics and Changes of the Shigeru Ban Exhibition Space (시게루 반 전시공간의 생태적 특성과 변화 연구)

  • Tian, Hui;Yoon, Ji-Young
    • The Journal of the Korea Contents Association
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    • v.22 no.2
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    • pp.147-161
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    • 2022
  • This study examined changes in the ecological characteristics and design characteristics of Ban's exhibition space in three representative temporary exhibition halls and three permanent exhibition halls designed by Ban Shigeru since 2000. Through the investigation of the concepts and characteristics of ecological architecture, the design characteristics of exhibition space, the analysis framework of the design characteristics of exhibition space and the design elements of ecological architecture is obtained. The analysis results show that there are big changes between the temporary exhibition space and the permanent exhibition space in terms of building scale, space composition, function, materials and technology. On the one hand, the temporary exhibition space used recyclable materials, such as paper tubes, containers to be assembled on site into a single-layer space focused on display. The assembly method was simple and the construction period was short. After the exhibition, the exhibition space were dismantled. The materials were either transported to the next display site or recycled and reused. On the other hand, the permanent exhibition space used reinforced concrete as the main structure, and used a large amount of wood and glass materials to construct a multi-layered composite cultural space that separated the exhibition space and the leisure space. In terms of ecological characteristics, the building materials of the temporary exhibition space were recycled and no industrial wastes were generated after the demolition. The permanent exhibition hall uses eco-friendly wood for the roof and walls, so it is easy to replace and repair. Both types of exhibition halls are changing ecological architecture in a more sustainable direction by saving resources and energy through natural light and ventilation.

Card Transaction Data-based Deep Tourism Recommendation Study (카드 데이터 기반 심층 관광 추천 연구)

  • Hong, Minsung;Kim, Taekyung;Chung, Namho
    • Knowledge Management Research
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    • v.23 no.2
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    • pp.277-299
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    • 2022
  • The massive card transaction data generated in the tourism industry has become an important resource that implies tourist consumption behaviors and patterns. Based on the transaction data, developing a smart service system becomes one of major goals in both tourism businesses and knowledge management system developer communities. However, the lack of rating scores, which is the basis of traditional recommendation techniques, makes it hard for system designers to evaluate a learning process. In addition, other auxiliary factors such as temporal, spatial, and demographic information are needed to increase the performance of a recommendation system; but, gathering those are not easy in the card transaction context. In this paper, we introduce CTDDTR, a novel approach using card transaction data to recommend tourism services. It consists of two main components: i) Temporal preference Embedding (TE) represents tourist groups and services into vectors through Doc2Vec. And ii) Deep tourism Recommendation (DR) integrates the vectors and the auxiliary factors from a tourism RDF (resource description framework) through MLP (multi-layer perceptron) to provide services to tourist groups. In addition, we adopt RFM analysis from the field of knowledge management to generate explicit feedback (i.e., rating scores) used in the DR part. To evaluate CTDDTR, the card transactions data that happened over eight years on Jeju island is used. Experimental results demonstrate that the proposed method is more positive in effectiveness and efficacies.

Detecting Backward Erosion Piping Using a Tracer (추적자를 이용한 후퇴 침식 파이핑 현상 탐지법 개발 연구)

  • Jeong, Won;Kim, Byunguk;Seo, Il Won;Park, Yong Sung
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.43 no.1
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    • pp.55-62
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    • 2023
  • Internal erosion is one of the main causes of levee damage and collapse, and representative of this is backward erosion piping. This type of internal erosion accounts for one-third of the damage to levees, meaning it is important to predict and prevent it. In this work, experiments were conducted with the aim of detecting piping in advance by using a tracer. Experiments were undertaken by changing the head difference, soil diameter, and the installation of the cutoff wall. A tracer was injected twice, once at the beginning of the experiment and once after the piping occurred. A key finding was that the piping process significantly affectedthe concentration variation of the tracer in a soil layer. Hence, a tracer concentration curve monitored at downstream could provide information about piping occurrence. It is expected that the results of this study can be used to prevent levee damage and collapse caused by piping.

γ'-Precipitation Free Zone and γ' Rafting Related to Surface Oxidation in Creep Condition of Directionally Solidified CM247LC Superalloy (일방향 응고 CM247LC 초내열합금의 크리프 조건에서 표면 산화와 연계된 γ'-석출 고갈 지역 및 γ' 조대화)

  • Byung Hak Choe;Kwang Soo Choi;Sung Hee Han;Dae Hyun Kim;Jong Kee Ahn;Dong Su Kang;Seong-Moon Seo
    • Korean Journal of Materials Research
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    • v.33 no.10
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    • pp.406-413
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    • 2023
  • This study used optical and scanning electron microscopy to analyze the surface oxidation phenomenon that accompanies a γ'-precipitate free zone in a directional solidified CM247LC high temperature creep specimen. Surface oxidation occurs on nickel-based superalloy gas turbine blades due to high temperature during use. Among the superalloy components, Al and Cr are greatly affected by diffusion and movement, and Al is a major component of the surface oxidation products. This out-diffusion of Al was accompanied by γ' (Ni3Al) deficiency in the matrix, and formed a γ'-precipitate free zone at the boundary of the surface oxide layer. Among the components of CM247LC, Cr and Al related to surface oxidation consist of 8 % and 5.6 %, respectively. When Al, the main component of the γ' precipitation phase, diffused out to the surface, a high content of Cr was observed in these PFZs. This is because the PFZ is made of a high Cr γ phase. Surface oxidation of DS CM247LC was observed in high temperature creep specimens, and γ'-rafting occurred due to stress applied to the creep specimens. However, the stress states applied to the grip and gauge length of the creep specimen were different, and accordingly, different γ'-rafting patterns were observed. Such surface oxidation and PFZ and γ'-rafting are shown to affect CM247LC creep lifetime. Mapping the microstructure and composition of major components such as Al and Cr and their role in surface oxidation, revealed in this study, will be utilized in the development of alloys to improve creep life.

Analysis of Petrological Characteristics and Lacquer Gilding Materials of the Stone Buddha Head Excavated from the Temple Site No.4 of Yaksugok-Valley in Namsan Mountain, Gyeongju (경주 남산 약수곡 제4사지 출토 석재 불두의 암석학적 특징과 옻칠 도금 재료 분석)

  • Yu Jia;Lee Myeongseong;Lee Eunwoo
    • Conservation Science in Museum
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    • v.30
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    • pp.47-70
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    • 2023
  • In 2019, the first excavation survey was conducted at the Temple Site No. 4 of Yaksugok Vally in Namsan Mountain, Gyeongju to determine the original location of the headless stone Buddha statue and the structure of the temple site. The survey excavated a stone Buddha head that was confirmed in a comparative analysis to be petrologically and mineralogically identical to a headless stone seated Buddha statue found derelict nearby. Traces of gold leaf and black adhesive were found on a portion of the right side of the face of the Buddha head buried in the ground. Since it is exceedingly rare for lacquer and gilding techniques to have been applied to a large stone Buddha statue without a base layer, this study examines the gilding techniques of the time by analyzing the characteristics of the materials used. In this process, the structure of the gold foil was observed through analytical microscopy and scanning electron microscopy with energy dispersive X-ray spectrometry, and the gold (Au) component was identified. As a result of analyzing the black adhesive using pyrolysis-gas chromatograph/mass spectrometry (pyrolysis-GC/MS), pyrolysis compounds such as hydrocarbons, fatty acids, catechol, and catechol oxidation products were detected. This was identical to the characteristics identified upon analyzing lacquer collected from species of lacquer tree whose main component is urushiol. Therefore, it was confirmed that the stone Buddha head excavated from the Temple Site No. 4 of Yaksugok Valley was separated from a nearby stone seated Buddha statue, and that the gold foil was attached using lacquer sap collected from lacquer trees, which grow in Korea, China, and Japan.

The Water Quality in the Soho Coastal Seawaters of Gamak Bay Before and After a Typhoon (가막만 소호해역에서 태풍 전후 수질 변동특성)

  • Lee Young-Sik;Moon Seong-Yong
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.11 no.3
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    • pp.117-123
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    • 2006
  • The water quality before and after a typhoon was investigated as a part of a study on the increase of organic matter and on the fundamental measures to counter chemical oxygen demand (COD) in the eutrophic Soho coastal seawaters of Gamak Bay. The dissolved oxygen (DO) saturations were <54% when water column was stratified. The DO saturation was similar at surface and in the bottom layer after a typhoon $(78\sim88%)$, and a very high DO saturation (234%) was observed in the surface water after mass phytoplankton growth. The highest values of $NH_4-N,\;NO_3-N,\;PO_4-P$, and $SiO_2-Si$ were 18.22, 38.90, 1.58, and $52.10{\mu}M$, respectively, when freshwater entered after heavy rainfall events. In addition, high concentrations of $NH_4-N,\;PO_4-P$, and $SiO_2-Si$ were detected with low DO saturations in bottom water (>5m). A maximum chlorophyll (Chl.) concentration of $311.0{\mu}gl^{-1}$ was observed after typhoon, when a high-density Scrippsiella trochoidea red tide occurred with cell density of 42,000 cells $ml^{-1}$. The algal growth potential (AGP) was high after the typhoon. Nitrogen was always a limiting nutrient for phytoplankton growth. The highest COD level was $10.55mgl^{-1}$, and the main reason of the variation in COD was likely to be phytoplankton growth $(r^2=0.612,\;p=0.000)$. Organic matter, which entered the water column when the typhoon stirred the sediments, seems to have little effects on COD increase.

An Analysis of Korean Middle School Student Achievement in Environmental Science in TIMSS 2003 (우리나라 중학생들의 환경 영역 성취도 국제 비교 분석)

  • Jeong, Eun-Young
    • Journal of The Korean Association For Science Education
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    • v.26 no.2
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    • pp.200-211
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    • 2006
  • The purpose of this study was to analyze Korean middle school student achievement in environmental science based on the TIMSS 2003 (Trends in International Mathematics and Science Study), a student comparison of 46 participating nations. Korea ranked the fourth with a mean score of 554 in environmental science. However, all 3 environment science topics assessed in TIMSS are not included in the Korean science curriculum through 8th grade, even though they are included in most other participating nations' curricula. The average percent correct of items was analyzed according to the main topic, the item type and the cognitive domain. Items that showed differences between the average percent correct of Korea and the international average as well as differences between the average percent correct of boys and girls were further analyzed. Results revealed that Korean students performed better than the international average, especially in 'use and conservation of natural resources', multiple-choice items, and items requiring 'factual knowledge'. Also, male students demonstrated significantly higher achievement than female students. On the other hand, Korean students showed relatively lower achievement in constructed-response items, items that contained content they had not learned in science lessons and items requiring descriptions of the uses and effect of science and technology. Moreover, Korean student lacked understanding about acid rain, global warming, and ozone layer destruction. Korean female students showed relatively lower environmental conceptions and lower performance on items requiring data analysis than Korean male students. On the basis of these results, this study suggested that topics of environmental science be included in the science curriculum and taught in the science classroom to help middle school students more fully comprehend environmental issues.

Change of Green Space Arrangement and Planting Structure of Apartment Complexes in Seoul (서울시 아파트단지의 녹지배치 및 식재구조 변화 연구)

  • Lee, Dong-Wook;Lee, Kyong-Jae;Han, Bong-Ho;Jang, Jae-Hoon;Kim, Jong-Yup
    • Journal of the Korean Institute of Landscape Architecture
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    • v.40 no.4
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    • pp.1-17
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    • 2012
  • This study was carried out to propose the improved method by analyzing the change of green space arrangement and planting structure of apartment complexes in Seoul. 12 survey sites, which have obvious differences, were selected by reflecting the change of floor area ratio, underground parking place, and green space ratio. We divided the survey sites into four types that high green ratio(over 40%) apartment on natural ground, low green ratio(under 40%) apartment on natural ground, low green ratio(under 40%) apartment on artificial ground, and high green ratio(over 40%) apartment on artificial ground each period based on green space ratio and ground structure, plant crown volume, planting density, and planting pattern. The main factors of change of green space arrangement were green space ratio and ground structure. The Green space ratio was changed by the floor area ratio with constructing underground parking place and floor area ratio was adjusted by government policy and economic status. Average width of front green area has been changed from 10.0m in high green ratio apartment on natural ground for 3.5m, 2.7m, and 4.5m each period. The average width of the buffer green area has been changed from 15.0m in high green ratio apartment on natural ground of 7.7m, and 2.7m by extending parking place in the low green ratio apartment of artificial ground, so buffer green areas have been reduced and disconnected. So buffer green area in apartment complexes has been extended that the average width of the buffer green area was 3.8m caused by growing recognition of green since 2001. The ratio of native plant in canopy layer was increased from 45.1 % in the case of the high green ratio apartment of natural ground in 1980~1983 to 55.6%. Average plant crown volume increased from $1.27m^3/m^2$ in high green ratio apartment on natural ground for $3.47m^3/m^2$ in a low green ratio apartment on natural ground. But average plant crown volume is $0.27m^3/m^2$ in the high green ratio apartment of the artificial ground plant density of canopy layer was changed from 5 individuals per $100m^2$ to 14.5 individuals per $100m^2$. We should construct the buffer green area with natural ground and get the function of ecological and beautiful environment regarding to garden concept in case of front green area, width 4.5m. We should get the function of increasing green volume by multi-layer planting with shade woody species and flower woody species in case of back-side green area, width over 5.0m. We should get the function of covering the wall and increasing green landscape by planting with high woody species in case of side green area. We should apply the ecological planting technique to buffer green area and connect buffer green area to inner green area in apartment complexes.