• 제목/요약/키워드: Maillard

검색결과 234건 처리시간 0.032초

인삼의 구증구포에 의한 산성다당체, 페놀성화합물의 변환 및 항산화능 (Conversion of Acidic Polysaccharide and Phenolic Compound of Changed Ginseng by 9 Repetitive Steaming and Drying Process, and Its Effects of Antioxidation)

  • 김도완;이연진;민진우;김유진;노영덕;양덕춘
    • 동의생리병리학회지
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    • 제23권1호
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    • pp.121-126
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    • 2009
  • Korean ginseng (Panax ginseng C. A. Meyer) has been used as an important medicinal plant in the Orient for a long time. It has been claimed that ginseng has many beneficial bioactive effects on human health, such as antitumor, antistress, antiaging and enhancing immune functions. Red ginseng possibly have new ingredients converted during steaming and dry process from fresh ginseng. In this study, pharmacological efficacy and ingredient conversion of ginseng by 9 repetitive steaming and drying process were investigated measuring conversion efficiency of acidic-polysaccharide, phenolic compounds and inhibition of peroxide lipides. It was found that acidic-polysaccarides were increased by heat treatment. In addition, maltol of phenolic compounds, strong antioxidant, produced during the process of red ginseng by Maillard reaction. Acidic-polysaccarides and maltol were increased after the 1st and 3rd steaming and drying treatments, but they were decreased gradually after 5th, 7th, and 9th treatments. Antioxidant activity was increased as increasing treatment times of steaming and drying without significance. Effect of red ginseng extract on inhibition of peroxide was increased gradually until after the 7th treatment, but remarkably decreased after the 9th treatment.

Determination of the Nutritive Value of Tropical Biomass Products for Monogastrics Using Rats: 2. Effects of Drying Temperature, Ensiling and Level of Inclusion of Cassava Leaves and Sweet Potato Vines

  • Phuc, Bui Huy Nhu;Lindberg, Jan Erik;Ogle, Brian;Thomke, Sigvard
    • Asian-Australasian Journal of Animal Sciences
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    • 제14권7호
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    • pp.994-1002
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    • 2001
  • In a balance experiment with rats either 0, 25 or 50% of the crude protein (CP) provided as casein in the control diet was replaced with cassava leaves (CL) (Manihot esculenta Crantz) or sweet potato vines (SPV) (Ipomoea balala). CL were either sun-dried or oven-dried at $60^{\circ}C$ or $105^{\circ}C$ or ensiled, while the SPY were either sun-dried or ensiled. The experiment included 3 blocks with 30 rats in each and six individuals per treatment group. Drying at $105^{\circ}C$ resulted in a reduction of the lysine (Lys) content, suggestive of the occurrence of Maillard reactions. Ensiling CL and SPV slightly decreased the CP. content as well as the sum of essential amino acids. The apparent fecal CP digestibility (dCP) and nitrogen retention were negatively affected by increasing the level of replacement (p<0.01 and p<0.001, respectively). The impaired amino acid profile observed when drying CL at $105^{\circ}C$ was found to be related to a slight decrease in dCP (p<0.001) as well as N retention (p<0.005). The effects of sun-drying and oven-drying in reducing the HCN content in CL were more potent than when ensiling. By increasing the total dietary HCN supply serum thiocyanide level, as well as urinary thiocyanate and linamarin output, were increased, with a weak relationship between them. Sun-drying and ensiling with cane molasses as additive successfully preserved the nitrogenous constituents and could be a means of preserving fresh green feed under tropical conditions.

Maltol, Kojic Acid, Levulinic Acid, Furfural, 5-Hydroxymethyl Furfural과 Pyrazine의 항산화작용 (Antioxidant Activity of Maltol, Kojic Acid, Levulinic Acid, Furfural, 5- Hydroxymethyl Furfural, and Pyrazine)

  • 이범홍;김동훈
    • 한국식품과학회지
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    • 제14권3호
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    • pp.265-270
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    • 1982
  • 마이얄 갈색화반응의 중요한 중간생성체로 알려진 maltol, kojic acid, levulinic acid, furfural, 5-hydroxymethyl furfural(5-HMF)와 pryazine의 항산화작용을 조사하였다. 각 화합물의 작용은 이들 화합물의 0.01M의 농도로 들어있는 콩기름 기질들과 실험대조기질의 유도기간의 길이를 비교함으로써 추정하였다. 기질들은 $45.0{\pm}1.0^{\circ}C$에서 30일간 저장되었으며, 이들 기질의 과산화물값이 60 meq/kg oil가 되는데 소요된 시간으로써 그 기질의 유도기간으로 삼았다. 실험대조기질, kojic acid, 5-HMF, furfural, maltol, levulinic acid와 pyrazine의 유도기간은 각각 468, 592, 510, 498, 486, 450와 402시간 였었다. Kojic acid는 뚜렷한 산화방지작용을 갖고 있는 반면에 furfural와 5-HMF는 약한 작용을, maltol은 아주 약한 작용을 갖고 있었다. 한편, pryazine과 levulinic acid는 산화촉진작용을 보였었다. Pryazine은 뚜렷한 촉진작용을 보였으나, levulinic acid의 산화촉진작용은 매우 미약했었다.

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당(糖) 분해생성물의 돌연변이원성 억제작용 (Desmutagenic Action of Sugar Degradation Products)

  • 김선봉;김인수;염동민;박영호
    • 한국식품과학회지
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    • 제20권1호
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    • pp.119-124
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    • 1988
  • 식품의 안전성 평가를 위한 기초자료를 얻기 위하여, 식품의 가공, 저장 및 조리중에 식품성분간의 상호반응인 Maillard 반응을 이용하여 당의 분해로 생성되는 각종 카르보닐화합물을 강력한 돌연변이원성물질로 알려진 Trp-P-1, Trp-P-2, Glu-P-1, Glu-P-2 및 IQ에 각각 작용시켜서 이들 물질의 돌연변이성 억제효과를 연구 검토하였다. 그 결과, 카르보닐화합물에 의하여 돌연변이원성물질의 돌연변이원 활성이 크게 억제되었다. 사용한 카르보닐화합물중 ${\alpha}$-hydroxycarbonyl 화합물의 경우, glyceraldehyde, glycolaldehyde 및 dihydroxyacetone에서 돌연변이원성 억제효과가 크게 나타났다. ${\alpha}$-dicarbonyl 화합물의 경우, diacetyl에서 그 억제효과가 우수한 것으로 나타서, 전반적으로 ${\alpha}$-dicarbonyl 화합물이 ${\alpha}$-hydroxycarbonyl 화합물보다 돌연변이성 억제효과가 높게 나타났다. 한편, 공시한 카르보닐화합물 단독으로는 돌연변이 성을 나타내었으나, Trp-P-1등의 돌연변이원성물질과의 상호반응로 이들 두 물질의 돌연변이성이 동시에 소실되는 것이 입증되었다.

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고추의 건조방법(乾燥方法)에 따른 성분(成分) 변화(變化)에 관(關)한 연구(硏究) - 제 2 보 Free amino acid 및 Free sugar의 변화(變化) - (A Study on the Influence of Drying Methods upon the Chemical Changes in Red Pepper - 2. Changes of Free amino acid, Free sugar -)

  • 박춘란;이강자
    • Journal of Nutrition and Health
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    • 제8권4호
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    • pp.33-37
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    • 1975
  • This investigation was designed to determine the influence of drying methods on the free amino acids and free sugars in red pepper and to study the browning mechanism of brown-colored red pepper. Three different drying methods were employed: 1) Sun-drying at $25{\sim}28^{\circ}C$ for 15 days, 2) Drying in oven at $60^{\circ}C$ for 49 hours, and 3) Drying in oven at $90^{\circ}C$ for 8 hours. Dried and ground peels were used for the analysis of free amino acids and free sugars. The results were as follows; 1. Sixteen kinds of amino acids i.e. asparagine, methionine, and cystine etc. were identified. Total amino acid content of the sun-dried sample was not different from that of the fresh sample, but the samples dried at $60^{\circ}C$ and $90^{\circ}C$ in the oven were decreased to 24.9% and 67.4% respectively. Of amino acids identified, methionine, lysine and aspartic acid were decreased in all treatments. Especially, methionine ana aspartic acid were decreased rapidly to 71.8% and 73.3% , respectively. 2. Three kinds of free sugars i.e. glucose, fructose and sucrose were identified. The total content of free sugars was significantly decreased in each treatment. Among the reducing sugars, glucose was rapidly decreased; 65.9% for the glucose of sample dried at $90^{\circ}C$ in the oven. 3. At the higher drying temperature, the darker red color was found. Brown-color appeared at $90^{\circ}C-drying$ showed appreciable losses in carotenoid content, but the major color seems to be due to the large increase in browning compounds. 4. It was assumed that increased browning compounds of red pepper were due to the Maillard reaction which is a nonenzymatic browning process.

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마이크로웨이브 Roasting 중 Cocoa Bean의 이화학적 성분 변화 (Changes in Chemical Components of Cocoa Beans during Microwave Roasting)

  • 김석신;이주희;장규섭
    • 한국식품과학회지
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    • 제32권4호
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    • pp.814-821
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    • 2000
  • 마이크로웨이브를 이용한 cocoa bean의 roasting을 수행하여 pH, 적정산도, 색의 변화, 갈변도, 유기산의 변화, 당조성의 변화를 조사하였다. pH는 roasting 온도와 시간에 따른 변화가 거의 없었고 적정산도 역시 roasting 여부에 따른 차이는 있었으나 roasting 온도와 시간에 따른 차이는 거의 없었다. 색의 변화, 갈변도, 당조성은 roasting 온도와 시간에 따라 변화하였으나 대조군과 비교하였을 때 변화의 폭이 작았고 이로부터 Maillard reaction이 대조군에 비해 덜 일어난 것으로 판단되었다. 유기산은 raw bean에 비해 roasting을 한 모든 시료에서 증가하였으며 그 정도는 유기산의 종류에 따라 차이가 있었다.

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효소 처리에 의한 고온가압 연어 frame 추출물의 수율 및 건강 기능성 개선 (Improvement on Yield and Functional Properties of Autoclave-Treated Salmon Frame Extracts using Commercial Enzymes)

  • 허민수;지승길;구재근;권재석;한병욱;김정균;김형준;김진수
    • 한국수산과학회지
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    • 제42권6호
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    • pp.537-544
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    • 2009
  • This study was conducted to improve yield and functional properties of autoclave-treated salmon frame extracts (SFETA) using commercial enzymes (Alcalase 2.4 L FG, Flavourzyme 500 MG, Neutrase 0.8 L and Protamex 1.5 MG). Yield and angiotensin I converting enzyme (ACE) inhibitory activity of all enzymatic hydrolysates improved compared to those of control (undigested extracts), which were the highest in hydrolysates incubated with Protamex 1.5 MG for 4 hrs (P4-treated hydrolysates) and 2 hrs (P2-treated hydrolysates), respectively. However, antioxidant activities of all enzymatic hydrolysates showed less than 29%. According to the trichloroacetic acid soluble-N, volatile component intensity and sensory evaluation, when compared to control, taste of P4-treated hydrolysates improved, while its fish odor strongly smelt. Therefore, for efficient use of P4-hydrolysates, the fish odor should be improved by Maillard reaction of extracts or pre-treatment of salmon frame.

홍삼으로부터 분리한 수용성 갈변물질의 기능성 연구 2. Linoleic acid, Ox-brain autoxidant및 Fe$^{2+}$ ADP/NADP system에서 항산화 활성 중심으로 (Function of the Water Soluble Browning Reaction Products Isolated from Korean Red Ginseng 2. Linoleic acid, Ox-brain autoxidant and Fe$^{2+}$ ADP/NAD system)

  • 이종원;손형옥;도재호
    • Journal of Ginseng Research
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    • 제24권1호
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    • pp.35-40
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    • 2000
  • 홍삼에서 분리한 수용성 갈변물질의 항산화 활성을 linoleic acid, Ox-brain autoxidant, Fe$^{2+}$ ADP/NAD 및 cumene hydoperoxide 시스템에서 조사한 결과를 다음과 같다. 1. Linoleic acid :투석내액의 갈변물질보다 투석외액의 갈변물질 쪽에서 hydroperoxy radical 저해율이 높은 것으로 나타났으며, 이때 S-2의 산화저해율은 S-1, L시험구보다 적은 농도에서 저해율이 높았다. S-2의 산화저해율은 49,52, 62.44 및 97.5%로 나타나 첨가농도가 증가함에 따라 linoleic acid 산화저해율은 높았다. 2. Ox-brain autoxidant : 자동산화에의한 항산화활성을 조사한 결과, 투석내액의 갈변물질보다 투석외액의 갈변물질 쪽에서 자동산화에 의한 항산화활성이 높은 것으로 나타났다. 특히S-2의 항산화 활성은 22.5, 31.7, 31.9 및 33.5%로 나타났다. 3. Fe$^{2+}$ ADP/NAD 및 cumene hydroperoxide : 횐쥐 간의 microsome 분획을 분리하여 수용성 갈변물질의 ADP/NABP 및 cumene hydroperoxide 항산화 활성을 조사한 결과, 모든 시험구에서 반응 초기에 항산화 활성이 있으나, 반응 시간이 길수록 항산화 활성은 감소하였다. 그 활성의 순서는 S-2>S-1>L순으로 나타났으나 항산화 활성의 강도는 전체적으로 약하게 나타났다.

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볶음과정에서의 참깨의 물리화학적 특성변화 (Studies on the Physicochemical Characteristics of Sesame with Roasting Temperature)

  • 김현위;정소영;우순자
    • 한국식품과학회지
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    • 제31권5호
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    • pp.1137-1143
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    • 1999
  • 볶음참깨 및 참기름 제조시 필요한 기초자료를 마련하기 위하여 볶음온도$(110^{\circ}C{\sim}230^{\circ}C)$변화에 따른 참깨의 물리적 변화 및 화학적 변화를 알아보았다. 볶음참깨의 물리적 특성에 있어서 수분함량, 부피변화, 착유수율, 참깨박함량 및 색도는 $170^{\circ}C$이상에서 유의적으로 변하였고, 참깨박 중의 지방함량 및 단백질함량은 약간 변화하였다. 착유수율과 관능적 특성을 고려할 때 볶음최적온도는 $220^{\circ}C$로 판단된다. Arginine, serine, threonine, lysine, cystine, tyrosine 등의 총아미노산과 대부분의 유리아미노산, 그리고 유리당 중의 sucrose는 $170^{\circ}C$$190^{\circ}C$ 이상에서 유의적으로 감소하였다. 이러한 당과 아미노산 함량의 감소는 볶음참깨의 갈색색소 및 고소한 맛과 풍미 형성에 중요한 역할을 한 것으로 추측한다. 이러한 반응은 비교적 높은 온도에서 수분이 적고, 기름함량이 많은 식품계에서 당과 아미노화합물의 상호작용에 의한 열분해반응임을 알 수 있었다.

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마른명태 저장중(貯藏中)의 수분활성(水分活性)과 갈변반응(褐變反應) (Non-Enzymatic Browning Reactions in Dried Alaska Pollak Stored at Different Water Activities)

  • 김무남;최호연;이강호
    • 한국식품영양과학회지
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    • 제2권1호
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    • pp.41-47
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    • 1973
  • In the present work, the quality stability of sun-dried Alaska pollack, Theragra chalcogramma, was discussed in the aspects of non-enzymatic discoloration as a function of relative humidity during storage at room temperature$(20^{\circ}C)$. Frozen Alaska pollack was dressed, filleted, dried for 48 hours in the open air, and finally stored in cylindrical acrylic chambers which contained saturated specific salt solutions proposed by Rockland(1960) for humidity control. The color development of the product was analyzed by spectrophotometry at 10 day-intervals during the storage. Lipid oxidation was measured as TBA value at wavelength of 538nm. And browning pigments were extracted, divided into two fractions and measured at 460nm: one was chloroform-methanol (2:1 v/v)soluble fraction attributed to lipid oxidation, and the other was water dialyzed fraction caused by so called Maillard reaction. The TBA value showed a maximum on 30 day storage, hereafter, intended to decrease gradually. On the other hand, the rate of brown pigment development in water dialyzed fractions as well as in chloroform-methanol soluble fractions was lower at 34 to 45%RH than at any other case, and propagation of lipid oxidation was also diminished at the same levels of humidity. From the facts described previously, it is recognized that storage at 34 to 45%RH provides higher quality stability for sun-dried Alaska pollack.

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