• 암석학회지
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• 제10권3호
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• pp.133-147
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• 2001

최근 기존 연대측정법의 한계를 극복하여 절대연령 측정 대상을 획기적으로 넓힐 수 있는 방법으로 개발되고 있는 단계적 용해에 의한 연대측정법을 국내 시료에 적용하여 이 방법에 의한 연대측정의 성공가능성에 대해 평가하여 보았다. 대상 시료는 옥천변성대 대전 남부지역 창리층의 함우라늄 흑색 점판암, 영남육괴 북동부의 선캠브리아 내덕리 화강암에서 분리한 전기석 및 옥방광산의 회중석 등을 선정하였다. 이들에 대한 단계적 용해를 위해 산의 종류와 시간을 달리하여 점차 그 세기를 늘려가며 납을 용출시켰으며, 각 단계에서 얻은 용액들에 대해 납 등위원소 비율과 함께 납과 우라늄 함량을 열이온화 질량분석기로 측정하였 다. 그 결과 창리층 혹색 점판암과 내덕리 화강암으로부터는 상당한 Pb 동위원소 값의 분산을 얻을 수 있었으며 단계적 용해에 의한 Pb-Pb 연대측정이 성공적일 수 있음을 보여준다. 단계적 용해 과정에서 시료의 종류마다 우라늄과 납의 거동이 다르며 이는 구성 광물의 종류에 따라 우라늄과 납이 차지하는 결정 내에서의 위치에 지배되는 것으로 판단된다.

• 암석학회지
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• 제25권4호
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• pp.335-348
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• 2016

제주도의 전 지역에 걸쳐 넓게 분포하고 있는 하성 퇴적층인 탐라층은 역암, 사암, 이암 등으로 구성되어 있다. 대부분의 탐라층 이암 내에 다양한 크기의 석영이 다량 함유하는 것이 확인되었다. XRD 분석의 결과, 탐라층에는 석영, 사장석, 칼륨장석, 운모, 자철석, 적철석, 감람석, 휘석, 깁사이트, 방해석, 아날심, 그리고 점토광물로서 일라이트, 카올린나이트, 버미큘라이트, 스멕타이트, 녹니석, $10{\AA}$-할로이사이트 등의 다양한 광물들이 산출되었다. 석영이 많은 곳일수록 카올린나이트, 버미큘라이트, 녹니석의 함량이 많아지는 경향이 나타났다. 이상의 결과들로 보아 탐라층의 근원암은 제주도의 화산암에서 기원된 것만이 아니며, 석영을 다량 함유한 기반암이 포함된 것으로 사료된다. 따라서 탐라층은 이전에 존재했던 기반암과 함께 제주도 화산암류의 물질들이 첨가되어 퇴적된 후, 속성작용, 열수작용, 풍화작용 등의 변질작용을 받아 형성된 것으로 생각된다.

• 자원환경지질
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• 제40권1호
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• pp.1-14
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• 2007

금성광상은 캠브리아기-오르도비스기 조선누층군 중 영월층군의 탄산염암과 쥐라기 제천화강암체와의 남측 경계부를 따라 백운석질 석회암과 석회암의 조성차이를 반영하여 서로 다른 유형의 스카른대가 배태되고 있다. 금성광상에서 스카른화작용은 전반적으로 규산염광물-산화광물-황화광물이 순차적으로 교대-정출되는 특징을 보이고 있으며, 공간적으로 상부 스카른에 배태된 점이성 스카른형 Mo광상과 하부 스카른에 배태된 근지성 스카른과 함께 수반되는 단방향 결정성장조직의 큐폴라형 Mo광상으로 양분된다. 금성광상의 상부 스카른대는 휘수연석${\pm}$자철석${\pm}$적철석과 함께 석회암이 교대된 Ca계열 스카른광물인 석류석+단사휘석+녹렴석+양기석+녹니석${\pm}$규회석${\pm}$사장석${\pm}$베스비아나이트의 광물조합을 보이고 있는 반면, 하부 스카른대는 자철석과 함께 백운석질 석회암이 교대된 Mg계열 스카른광물인 감람석+투휘석+투각섬석+금운모+사문석${\pm}$고니석${\pm}$활석으로 구성되어 있다. Ca계열 및 Mg계열 스카른광물의 공생관계 및 열역학적 자료를 종합적으로 검토한 결과, 전진 스카른 단계 스카른화 작용은 약 0.5kbar, $XCO_2<0.1$의 조건의 약 $500^{\circ}{\sim}400^{\circ}C$ 온도범위에서 진행되었으며, 후퇴 스카른 단계 함수규산염광물의 안정영역은 약 $500^{\circ}{\sim}400^{\circ}C$ 온도범위로 추정된다.

• Advances in environmental research
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• 제2권3호
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• pp.167-177
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• 2013

We investigated that removal of aqueous U(VI) by nano-sized Zero Valent Iron (nZVI) and Fe(II) bearing minerals (controls) in this study. Iron particles showed different U(VI) removal efficiencies (Mackinawite: 99%, green rust: 95%, nZVI: 91%, magnetite: 87%, pyrite: 59%) due to their different PZC (Point of Zero Charge) values and surface areas. In addition, noticeable amount of surface Fe(II) (181 ${\mu}M$) was released from nZVI suspension in 6 h and it increased to 384 ${\mu}M$ in the presence of U(VI) due to ion-exchange of U(VI) with Fe(II) on nZVI surface. Analysis of Laser-Induced Breakdown Detection (LIBD) showed that breakdown probabilities in both filtrates by 20 and 200 nm sizes was almost 24% in nZVI suspension with U(VI), while 1% of the probabilities were observed in nZVI suspension without U(VI). It indicated that Fe(II) colloids in the range under 20 nm were generated during the interaction of U(VI) and nZVI. Our results suggest that Fe(II) colloids generated via ion-exchange process should be carefully concerned during long-term remediation site contaminated by U(VI) because U could be transported to remote area through the adsorption on Fe(II) colloids.

• 자원환경지질
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• 제26권3호
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• pp.267-278
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• 1993

Serpentinite rocks which are composed mainly of olivine, serpentine and clinopyroxene, cropped out in the anorogenic Kyongsang sedimentary basin of South Korea. The serpentinites contain high content of MgO (36.87~41.99%) and 47~67 ppm Co, 1185~2042 ppm Ni and 979~3582 ppm Cr, which are quite similar to those of ultrabasic rocks such as peridotite and dunite. Isotopic compositions of serpentinites range from -95.5 to -105.7‰ in ${\delta}D$ and +1.7 to 7.1‰ in ${\delta}^{18}O$ corresponding to the continental antigorite type. A wide variation of oxygen isotopic values and $H_2O^+$ content of serpentinites reflect the different water/rock ratios during serpentinization processes. Formation temperature of serpentine minerals are estimated to be unusually high temperature of $488{\sim}646^{\circ}C$ by serpentine-magnetite isotopic fractionation, which belong to continental antigorite type. Calculated ${\delta}^{18}O$ value of serpentinized fluid during serpentinization is suggested that the hydrothermal fluid responsible for serpentinization be originated from the magmatic fluid with a minor influx of paleo-meteoric water in this area.

• 보존과학회지
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• 제3권1호
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• pp.13-18
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• 1994

Chemical analysis and metallographic observations of the iron slag were carried out in an attempt to estimate the old iron-making process. The slag containing $9.3\%\;TiO_2$ without Cu indicates that the ore used for smelting was sand iron, not rock ore. The phases identified in the slag were $ulv\ddot{o}spinel$, magnetite, $w\ddot{u}stite$, fayalite etc. This also supports the fact that the smelted ore was iron sand. The total amount of Fe and slag-making components$(=SiO_2+Al_2O_3+MgO+CaO)$ were $40.7\%\;and\;36.1\%$, respectively. These values were average ones found in the old slags formed in the ancient iron-making process. Assuming that $TiO_2$ in the ore combines with FeO, resulting in the formation of $ulv\ddot{o}spinel$, the estimated temperature of smelting was found to be about $1200^{\circ}C$.

• Nuclear Engineering and Technology
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• 제44권7호
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• pp.773-780
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• 2012

The article presented is concerned with an evaluation of the corrosion behavior of SA-508 low alloy steel (LAS) and Type 309L stainless steel (SS) cladding of a reactor pressure vessel under the simulated primary water chemistry of a pressurized water reactor (PWR). The uniform corrosion and galvanic corrosion rates of SA-508 LAS and Type 309L SS were measured in three different control conditions: power operation, shutdown, and power operation followed by shutdown. In all conditions, the dissimilar metal coupling of SA-508 LAS and Type 309L SS exhibited higher corrosion rates than the SA-508 base metal itself due to severe galvanic corrosion near the cladding interface, while the corrosion of Type 309L in the primary water environment was minimal. The galvanic corrosion rate of the SA-508 LAS and Type 309L SS couple measured under the simulated power operation condition was much lower than that measured in the simulated shutdown condition due to the formation of magnetite on the metal surface in a reducing environment. Based on the experimental results, the corrosion rate of SA-508 LAS clad with Type 309L SS was estimated as a function of operating cycle simulated for a typical PWR.

• Corrosion Science and Technology
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• 제7권3호
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• pp.182-186
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• 2008

The microstructures of the oxide scale developed at high temperature on steels are very complex and their development depends on many factors including time, temperature, oxidation conditions and alloying elements. The classical model of an oxide scale on steel consisting of wüstite, magnetite and haematite layers, is more complicated in reality and its properties change with the factors that affect their development. An understanding of the oxide scale formation and its properties can only be achieved by careful examination of the scale microstructure. The oxide scale microstructure may be difficult to characterise by conventional techniques such as optical or standard scanning electron microscopy. An unambiguous characterisation of the scale and the correct identification of the phases within the scale are difficult unless the crystallographic structure for each phase in the scale is considered and a simultaneous microstructure-microtexture analysis is carried out. In the current study Electron Backscatter Diffraction (EBSD) has been used to investigate the microstructure of iron oxide layers grown on low carbon steels at different times and temperatures. EBSD has proved to be a powerful technique for identifying the individual phases in the oxide scale accurately. The results show that different grain shapes and sizes develop for each phase in the scale depending on time and temperature.

• 한국재료학회지
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• 제18권4호
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• pp.218-221
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• 2008

A $Fe(OH)_2$ suspension was prepared by mixing iron sulfate and a weak alkali ammonia solution. Following this, iron oxides were synthesized by passing pure oxygen through the suspension (oxidation). The effects of different reaction temperatures ($30^{\circ}C$, $50^{\circ}C$, $70^{\circ}C$) and equivalent ratios ($0.1{\sim}10.0$) on the formation of iron oxides were investigated. An equilibrium phase diagram was established by quantitative phase analysis of the iron oxides using the Rietveld method. The equilibrium phase diagram showed a large difference from the equilibrium phase diagram of Kiyama when the equivalent ratio was above 1, and single $Fe_3O_4$ phase only formed above an equivalent ratio 2 at all reaction temperatures. Kiyama synthesized iron oxide using iron sulfate and a strong alkali NaOH solution.

• Applied Microscopy
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• 제45권3호
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• pp.177-182
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• 2015

The boiler tubes of X20CrMoV12.1 used in fossil-fired power plants were obtained and analyzed for the effect of water treatment on the steam corrosion-induced oxide scale in an effort to better understand the oxide formation mechanism, as well as pertinent method of maintenance and lifetime extension. The specimens were analyzed using various microscopy and microanalysis techniques, with focuses on the effect of water treatment on the characters of scale. X-ray diffraction analysis showed that the scales of specimens were composed of hematite ($Fe_2O_3$), magnetite ($Fe_3O_4$), and chromite ($FeCr_2O_4$). Electron backscatter diffraction analysis showed that the oxides were present in the following order on the matrix: outer $Fe_2O_3$, intermediate $Fe_3O_4$, and inner $FeCr_2O_4$. After all volatile treatment or oxygenated treatment, a dense protective $Fe_2O_3$ layer was formed on the $Fe_3O_4$ layer of the specimen, retarding further progression of corrosion.