• 한국세라믹학회지
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• 제31권11호
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• pp.1346-1354
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• 1994

In this study, the formation of magnetite using Fe(II) and Fe(III) hydroxides was investigated; The effects of hydroxide synthesizing pH and temperature, reaction temperature, and total water volume of hydroxide suspensions on the magnetite formation were studied. And the basic reaction behaviors of magnetite formation was discussed in the view of hydroxide formation reaction of Fe(II) and Fe(III) by titration. The characteristics of products were examined by TEM, VSM, XRD. From these experimental data, solid-solid reaction between Fe(II) and Fe(III) hydroxides is proposed as a new ferrite formation mechanism.

• 한국대기환경학회지
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• 제15권2호
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• pp.183-190
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• 1999

Magnetite was synthesized with $FeSO_4$, and NaOH for the decomposition of carbon dioxide and for the study of the methane formation. The chemical equivalent ratio was changed from 0.5 to 1.50 for the magnetite synthesis. The chemical equivalent ratio was fixed in 1.00, and Nickel chloride and Rhodium chloride equally added and synthesized with the ratio was of 0.10~10.00 mole%. The crystal strucure of the synthesized magnetite was measured XRD. Putting synthesized magnetite in the reactor and using hydrogen gas oxygen-deficient magnetite was made. Injecting carbon dioxide in the reactor, the decomposition reaction was experimented. The formation of methane was confirmed injecting hydrogen gas in the reactor after carbon dioxide was decomposed.

• Bulletin of the Korean Chemical Society
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• 제24권7호
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• pp.957-960
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• 2003

A method of preparation of magnetite nanoparticles in ordered systems, as in vesicle and microemulsion, consisting of soybean lecithin and water has been introduced. The size of magnetite grain was controlled by the content of soybean lecithin and size of liposomes in the systems. It was found by experiment that magnetite nanoparticles were formed inside the double layer vesicles. The magnetite nanoparticles were separated by magnetic separation and centrifugation and the dispersion of the magnetite nanoparticles prepared at 10% (w/w) soybean lecithin was particularly stable. The formation of pure magnetite nanoparticles was confirmed by analyses of XRD and electron diffraction pattern.

• 한국환경보건학회지
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• 제21권2호
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• pp.68-74
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• 1995

The optimum conditions was synthesized for the formation of Magnetite ($Fe_3O_4$) by air bubbling with the suspensions obtained by mixing Ferrous sulfate ($FeSO_4\cdot 7H_2O$) and Sodium Hydroxide (NaOH) solution in various values equivalent ratio($R=2NaOH/FeSO_4$) were studied. The changes of the structure were measured with XRD, $EM and BET. Equivalent ratio R: 0.65 was synthesized Goethite ($\alpha$-FeOOH), which becomes Maghemite ($\gamma=Fe_2O_3$) by dehydration, reduction and oxidation process. At the equivalent ratio over 1 (R>1), Magnetite ($Fe_3O_4$) was synthesized directly. The oxygen-deficient Magnetite ($Fe_3O_{4-\delta}$), which is obtained by flowing $H_2$ gas(100 ml/min) through the synthesis Magnetite at 350$\circ$C for 4 hr. By using it, was researched the decomposition reaction of $CO_2$. $CO_2$ was decomposed nearly 100% in 45 minutes by the oxygen-deficient Magnetite.

• 한국재료학회지
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• 제20권6호
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• pp.301-306
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• 2010

The chemical formula of magnetite ($Fe_3O_4$) is $FeO{\cdot}Fe_2O_3$, t magnetite being composed of divalent ferrous ion and trivalent ferric ion. In this study, the influence of the coexistence of ferrous and ferric ion on the formation of iron oxide was investigated. The effect of the co-precipitation parameters (equivalent ratio and reaction temperature) on the formation of iron oxide was investigated using ferric sulfate, ferrous sulfate and ammonia. The equivalent ratio was varied from 0.1 to 3.0 and the reaction temperature was varied from 25 to 75. The concentration of the three starting solutions was 0.01mole. Jarosite was formed when equivalent ratios were 0.1-0.25 and jarosite, goethite, magnetite were formed when equivalent ratios were 0.25-0.6. Single-phase magnetite was formed when the equivalent ratio was above 0.65. The crystallite size and median particle size of the magnetite decreased when the equivalent ratio was increased from 0.65 to 3.0. However, the crystallite size and median particle size of the magnetite increased when the reaction temperature was increased from $25^{\circ}C$ to $75^{\circ}C$. When ferric and ferrous sulfates were used together, the synthetic conditions to get single phase magnetite became simpler than when ferrous sulfate was used alone because of the co-existence of $Fe^{2+}$ and $Fe^{3+}$ in the solution.

• 한국세라믹학회지
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• 제27권1호
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• pp.109-117
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• 1990

Magnetite for Water-based ferrofluid was synthesized by air oxidation of aqueous suspension in the pH range 7-12 at $65^{\circ}C$. The optimum condition of magneite formation was delineated by examining various physicochemcial properties such as Fe2+ content, phase characteristics, MHC and $\sigma$max. The point of zero charge of iron oxide powders obtained at various pH conditions were correlated with the oxidation state of Fe in the iron oxide. The magnetite powder prepared at pH 9 ws dispersed using sodium oleate and sodium dodecylbenzenesulfonate (SDBS) as dispersants, and the dispersion characteristics of the magnetite ferrofluid were examined by means of the fraction of solid dispersed, zeta potential data and FT-IR spectrum. A simple calculation on the potential energy of two interacting magnetite particles showed that the dispersion stability was directly correlated with height of the potential energy barrier or the shape of zeta potential.

• 한국세라믹학회지
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• 제47권1호
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• pp.8-18
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• 2010

When metal oxides are exposed to chemical potential gradients, ions are driven to diffusive mass transport. During this transport process, the divergence of ionic fluxes offers the formation/annihilation of oxides. Therefore, the divergence of ionic flux may play an important role in the void formation in oxides. Kinetic equations were derived for describing chemical potential distribution, ionic fluxes and their divergence in oxides. The divergence was found to be the measure of void formation. Defect chemistry in scales is directly related to the sign of divergence and gives an indication of the void formation behavior. The quantitative estimation on the void formation was successfully applied to a growing magnetite scale in high temperature oxidation of iron at 823 K.

• 자원환경지질
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• 제29권1호
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• pp.1-11
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• 1996

Magnetite ores of the Janggun mine are embedded in dolomitic limestone of the Janggun Limestone Formation contacting with Chunyang granite, and are closely associated with skarn minerals. Mineralization of magnetite deposits can be divided into two stages as deep-seated skarn stage and shallow hydrothermal replacement stage. Mineralogies of skarn stage consist of magnetite, pyrrhotite and base-metal sulfides, and those of hydrothermal stage is base-metal sulfides, native bismuth, bismuthinite, tetrahedrite, boulangerite, bournonite and stannite. The FeS mole % in sphalerite and As atom % in arsenopyrite range from 22.47 to 26.30 and from 31.39 to 31.66 in skarn stage, and are from 17.54 to 32.54 and 28.87 to 30.70 in hydrothermal stage, respectively. Based on mineralization characteristics, mineral assemblages, chemical compositions and thermodynamic considerations, formation temperatures, sulfur fugacities ($-logf_2$), pH and oxygen fugacity ($-logfo_2$) estimated to be from 345 to $382^{\circ}C$, from 8.1 to 9.7atm, from 6.5 to 7.2 and from 30.5 to 31.2atm in the skarn stage, respectively, and temperature and $-logfs_2$ are from 245 to $315^{\circ}C$ and from 10.4 to 13.2atm in the hydrothermal stage.

• 한국재료학회지
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• 제21권4호
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• pp.225-231
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• 2011

The effect of ferrous/ferric molar ratio on the formation of nano-sized magnetite particles was investigated by a co-precipitation method. Ferrous sulfate and ferric sulfate were used as iron sources and sodium hydroxide was used as a precipitant. In this experiment, the variables were the ferrous/ferric molar ratio (1.0, 1.25, 2.5 and 5.0) and the equivalent ratio (0.10, 0.25, 0.50, 0.75, 1.0, 2.0 and 3.0), while the reaction temperature ($25^{\circ}C$) and reaction time (30 min.) were fixed. Argon gas was flowed during the reactions to prevent the $Fe^{2+}$ from oxidizing in the air. Single-phase magnetite was synthesized when the equivalent ratio was above 2.0 with the ferrous/ferric molar ratios. However, goethite and magnetite were synthesized when the equivalent ratio was 1.0. The crystallinity of magnetite increased as the equivalent ratio increased up to 3.0. The crystallite size (5.6 to 11.6 nm), median particle size (15.4 to 19.5 nm), and saturation magnetization (43 to 71 $emu.g^{-1}$) changed depending on the ferrous/ferric molar ratio. The highest saturation magnetization (71 $emu.g^{-1}$) was obtained when the equivalent ratio was 3.0 and the ferrous/ferric molar ratio was 2.5.

• 폴리머
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• 제27권1호
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• pp.40-45
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• 2003

본 연구에서는 $Fe_3O_4$ (magnetite)의 함량 변화와 온도 변화가 NBR/$Fe_3O_4$ 혼합물의 전기걱도도 ($\sigma$)에 미치는 영향을 조사하였다. 최소 최적 혼합비 (percolation threshold, $P_c$) 개념이 본 연구에서 제조한 전도성 입자가 충전된 복합체에 적용되며, 혼합물내 $Fe_3O_4$의 농도가 22%를 초과할 때 $\sigma$가 급격히 증가함을 확인하였다. $\sigma$의 온도 의존성은 $P_c$ 또는 그 이하에서 열적으로 활성화되며, 마그네이트가 NBR 고무의 강화 및 전도성 충전제로서의 역할을 할 수 있음을 조사하였으며, 충전제 함량이 30 phr인 복합체는 실온에서 고전압을 걸어줄 경우 전류는 전압제곱에 비례한 것으로 나타났다. 또한, 50 pk의 마그네이트가 충전된 복합체가 최적의 물리적 가교점으로 인하여 가장 우수한 인장강도와 파단시 신장율을 보였으며 모듈러스가 마그네이트의 강화효과 및 혼합물의 토오크 곡선으로부터 얻은 점도와 관련이 있음을 확인하였다.